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Question1.
Phenolassociatesinbenzenesolventtoformdoublemolecules.Bythefreezingpointdepressionmethod,thevant'sHoff'sfactorhas
beenfoundtobe0.54.Towhatdegree,phenolisassociated?
[A]
[B]
[C]
[D]
0.46
0.54
0.98
0.92
Question2.
Whichofthefollowingwillhavethehighestfreezingpointatoneatmosphere?
[A]
[B]
[C]
[D]
0.10MNaCl
0.1MSugarsolution
0.1MBaCl2
0.1MFeCl3
Question3.
Theequilibriumvapourpressureofaliquidincreaseswithincreasingtemperaturemainlybecause
[A]
[B]
[C]
[D]
asthetemperatureisincreased,agreaterfractionofthemoleculescanescapetheliquid'ssurfaceandenterthevapourphase
allgasesexpandwhenheated
athighertemperature,therateofcondensationofmoleculestoliquidphaseisless
astemperaturerises,moleculeshitthewallofcontainerwithlessforce
Question4.
WhichofthefollowingliquidpairsshowsapositivedeviationfromRaoult'slaw?
[A]
[B]
[C]
[D]
Waterhydrochloricacid
benzenemethanol
waternitricacid
acetonechloroform
Question5.
InamixtureAandB,componentsshowsnegativedeviationas
[A]
[B]
[C]
[D]
interactionisweakerthan
interaction
Noneoftheabovereasoniscorrect
Question6.
Whichofthefollowingisthecorrectrepresentationofrelativeloweringofvapourpressure?
[A]
[B]
[C]
[D]
Question7.
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0.1MNaCland0.1Mglucosewouldexert
[A]
[B]
[C]
[D]
sameosmoticpressure
osmoticpressureintheratioof1:3
Question8.
Thevapourpressureoftwoliquids(A)and(B)are100and80torrrespectively.Thetotalpressureofthesolutionobtainedbymixing2.0
molesofAand3molofBwouldbe.
[A]
[B]
[C]
[D]
20torr
36torr
88torr
180torr
Question9.
WhenaconcentratedsolutionisseparatedfromadilutesolutionbySemipermeableMembranewhichisthebestdescriptionofwhatis
occurring?
[A]
[B]
[C]
[D]
Solutemoleculesflowfromthesolutionofhigherconcentration
Solutemoleculesflowfromthesolutionoflowerconcentration
Solventmoleculesmoveineachdirectionwithanoverallmovementfromconcentratedtothedilutesolution
Solventmoleculesmoveineachdirectionwithanoverallmovementfromdilutetoconcentratedsideofthesolution
Question10.
Whichofthefollowingaqueoussolutionwillboilatthehighesttemperature?(Note:allofthesaltslistedbelowarecompletelysolublein
water)
[A]
[B]
[C]
[D]
A0.10msolutionofNaCl
A0.10msolutionofNa2SO 4
A0.10msolutionofNa3PO 4
A0.10msolutionofC6H12O 6
Question11.
Thepartialpressureofethaneoverasaturatedsolutioncontaining
ofethaneis1bar.Ifthesolutioncontains
ofethane,thenwhatshallbethepartialpressureofgas?
[A]
[B]
[C]
[D]
0.762bar
0.0762bar
7.62bar
1.4bar
Question12.
Themolecularmassofanonelectrolytic,nonvolatilesolutewastobedeterminedbyperformingfreezingpointdepressionexperiment.
Theminimumdatarequiredforthedeterminationofthemolecularweightare:
[A]
[B]
andmassofbothsoluteandsolvents
[C]
andmassofsolute
[D]
,massofbothsoluteandsolventandidentityofsolvent
Question13.
ThesolubilityofCaCl2inliquidwaterat
solution?(
is5.4molal.Assumingidealbehaviour,whatisthefreezingpointofasaturatedCaCl2(aq)
)
[A]
[B]
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[C]
[D]
Question14.
Anopenbeakercontainingapuresolventandasecondbeakercontainingasolutioninthesamesolventwithanonvolatilesolute,are
sealedinacontainer.Overtheperiodoftime
[A]
[B]
[C]
[D]
thevolumeofsolutionincreasesandthevolumeofsolventdecreases
thevolumeofbothsolutionandsolventincreases
thevolumeofsolutiondecreaseswhilevolumeofsolventincreases
thevolumeofbothsolutionandsolventdecreases
Question15.
Whichofthefollowingisnotcorrectforanidealsolution?
[A]
[B]
Raoult'slawisobeyedforentireconcentrationrangeandtemperatures
[C]
[D]
Question16.
Inthemolecule:
[A]
[B]
[C]
[D]
bothCNBondsareformedbysp2sp2overlaps
oneCNbondisformedbysp2sp2overlapswhiletheotherbysp2sp3overlaps
bothCNbondsareformedbysp2sp3overlaps
bothCNbondsareformedbysp3sp3overlaps
Question17.
Amongthesewhicharecanonicalstructures?
[A]
[B]
[C]
[D]
IandII
IandIII
IIandIII
allofthese
Question18.
Amongthese,functionalisomersare
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[A]
[B]
[C]
[D]
QuestionRevision
IandII
IandIII
IIandIII
I,II,III
Question19.
[A]
[B]
[C]
[D]
IIonly
IIIonly
bothIIandIII
Noneofthese
Question20.
WhichamongtheabovecanshowTautomerism?
[A]
[B]
[C]
[D]
IandII
IandIII
IIandIII
Noneofthese
Question21.
Whichofthefollowingcompoundswillexhibitgeometricalisomerism?
[A]
[B]
[C]
[D]
Question22.
Whichofthefollowingcompoundshasasymmetriccentre?
[A]
[B]
[C]
[D]
II
III
II,III
I,II,III
Question23.
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Whichoftheabovemoleculesis/areopticallyactive?
[A]
[B]
[C]
[D]
IandII
IIandIII
IIIonly
Allofthese
Question24.
Thecorrectorderofstabilityofgivencarbocationsis:
[A]
[B]
[C]
[D]
I>II>III
III>II>I
II>I>III
II>III>I
Question25.
Whichofthefollowingordersiscorrectforstabilityofthesecarbocations?
[A]
[B]
[C]
[D]
I>II>III
III>II>I
II>I>III
II>III>I
Question26.
Whichofthefollowingordersiscorrectforthestabilityoftheabovecarbocations?
[A]
[B]
[C]
[D]
I>II>III
III>II>I
II>I>III
Question27.
Whichofthefollowingordersiscorrectforthestabilityofthesecarbocations?
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[A]
[B]
[C]
[D]
QuestionRevision
I>II>III
III>II>I
I>III>II
II>III>I
Question28.
SelectthecorrectquestionsIUPACofthefollowingcompound:
[A]
[B]
[C]
[D]
2,3Dimethylcylohex1ene
1,2Dimethylcyclohex1ene
Question29.
SelectthecorrectIUPACnameofthefollowingcompound:
[A]
[B]
[C]
2Propyl3methoxybutanoate
3Methoxy2propylbutanoate
Methylethyl3methoxybutanoate
[D]
3Methoxy
Methylethylbutanoate
Question30.
Selectthecorrectorderofstabilityoffollowingcompounds:
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[A]
[B]
[C]
[D]
QuestionRevision
I>II>III
III>I>II
I>III>II
III>II>I
Question31.
Thedimensionof
is:
[A]
[B]
[C]
[D]
Question32.
AparticleofmassmandchargeqisplacedatrestinauniformelectricfieldEandthenreleased.Thekineticenergyattainedbythe
particleaftermovingadistanceyis:
[A]
[B]
[C]
[D]
qEy 2
qE2y
qEy
q2Ey
Question33.
Forthesituationshowninthefigure,selectthecorrectstatement(s):
[A]
Potentialoftheconductoris
[B]
Potentialoftheconductoris
[C]
Potentialoftheconductorcantbedeterminedasnatureofdistributionofinducedchargesisnotknown
[D]
PotentialatpointBduetoinducedchargedis
Question34.
Intheelectricfieldduetoapointchargeq,atestchargeiscarriedfromAtothepointsB,C,DandElyingonthesamecirclearoundq.
Theworkdoneis:
[A]
[B]
[C]
[D]
theleastalongAB
theleastalongAD
zeroalonganyoneofthepathsAB,AD,ACandAE
theleastalongAE
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Question35.
Asphericalcavityismadeinsideanegativelychargesphereofvolumechargedensity
inthecavity?
.Whichofthefollowingfieldpatterniscorrect
[A]
[B]
[C]
[D]
Question36.
Apointchargeisplacedatadistance2afromthecenterofathinconductingunchargedsphericalshellofAofradius'a'asshowninthe
figure.Thenthechargeontheshellwillbe:
[A]
[B]
[C]
[D]
Q
zero
Question37.
AconductingobjecthavingachargeQisplacedinaconductingshellofcharges+2Q.Ifweconnectthetwoconductorsbyaconducting
wire,thechargeflownis:
[A]
[B]
+Qfrom1to2
dependentontheshapeoftheconductors1and2
[C]
[D]
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Question38.
Therearethreeconductingsphericalshells.Theshells1and3areearthed.Thepotential(involt)ofthemiddleconductingshellcarrying
acharge
[A]
[B]
[C]
[D]
is:
1
2
3
Noneofthese
Question39.
Theunitofpermittivityoffreespace,
[A]
[B]
[C]
[D]
,is:
Coulomb/Newtonmeter
Coulomb2/Newtonmeter 2
Newtonmeter 2/coulomb2
Coulomb2/(Newtonmetre) 2
Question40.
Theratioofthetotalpotentialsat1and2
[A]
[B]
[C]
[D]
is:
1:2
2:1
Question41.
Achargeqisplacedinthecavityinaconductor.Theforceactingonit:
[A]
[B]
[C]
iszero
cannotbezero
maybezero
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[D]
QuestionRevision
mayormaynotbezero
Question42.
TwoconcentricspheresofradiiRand2RhavechargesQand2Q.ThepotentialatapointPsituatedatapoint3R/2distancefrom
commoncentreisV,nowoutersphereisearthed,thepotentialatpointPnowis:
[A]
[B]
[C]
[D]
V/5
V/10
V/3
V
Question43.
ThepotentialdifferenceoftheconcentricconductingspheresisV.WhentheoutersphereBisearthed,thepotentialdifferencebetween
themwillbe:
[A]
[B]
[C]
[D]
V
zero
Question44.
AmetalsphereAofradiusaischargedtoapotentialV.WhatwillbeitspotentialifitisenclosedbyasphericalconductingshellBof
radiusbandthetwoareconnectedbyawire:
[A]
[B]
[C]
[D]
zero
Question45.
Thefieldpatternisshownduetotwopointcharges1and2.Then
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[A]
[B]
[C]
[D]
Noneofthese
Question46.
Thepotentialdifferencebetween1to2if
[A]
[B]
[C]
[D]
intheelectricfield
is:
+2
Noneofthese
Question47.
FigureshowsthreepointsA,BandCinaregionofuniformelectricfield
.ThelineABisperpendicularandBCisparalleltothefield
lines.Thenwhichofthefollowingholdsgood.WhereVA,VBandVC representstheelectricpotentialatpointA,BandCrespectively:
[A]
[B]
[C]
[D]
VA=VB=VC
VA=VB>VC
VA=VB<VC
VA>VB=VC
Question48.
Theanglesofinclinationofthesuspendedchargedidenticalpendulumare
surfacechargedensity
respectively.Then
duetoelectricfieldoftheinfinitesheetsof
[A]
[B]
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[C]
[D]
Question49.
Anelectronistakenfrom
.Theworkdonebytheelectricfieldis:
[A]
[B]
[C]
[D]
Noneofthese
Question50.
AandBaretwoconcentricconductingshells.IfAisgivenachargeQwhileBisearthedasshowninfigure.
[A]
[B]
[C]
[D]
ThechargedensityofAandBaresame
ThefieldinsideandoutsideAiszero
ThefieldbetweenAandBisnotzero
ThefieldinsideandoutsideBiszero
Question51.
AsolidsphereofradiusRischargeduniformly.TheelectrostaticpotentialVisplottedasafunctionofdistancerfromthecentreofthe
sphere.Whichofthefollowingbestrepresentstheresultingcurve?
[A]
[B]
[C]
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[D]
Question52.
Thenetelectricfieldinathinchargedconductingshelliszero.Thentheshell:
[A]
[B]
[C]
[D]
mustbespherical
isuniformlycharged
mayhaveanyshape
Noneofthese
Question53.
TheVxgraphisgiven.WhichofthegraphsisforE=f(x)?
[A]
[B]
[C]
[D]
Question54.
Markcorrectstatement:
[A]
[B]
[C]
[D]
Ifaconductingsphericalshellisplacedinauniformelectricfieldthenelectricfieldinsidetheshellisnonzero
Electricfieldinachargedconductingsphericalshellcanbeequaltozeroonlywhenthechargeisuniformlydistributed
Ifpotentialinsideasphericalshelliszerothenitisnecessarilyelectricallyneutral
Electricalpotentialisavectorquantity.
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Question55.
AchargeQisdistributedwiththeratiox:ybetweentwopointobjectssothattheyexperiencemaximumelectrostaticforceatadistance
Rofseparation.Thenx:yis:
[A]
[B]
[C]
1:2
1:1
2:1
[D]
Question56.
TheExpatternofthegivenVxpatternis:
[A]
[B]
[C]
[D]
Question57.
If
,thefieldintensityduetotheringatOis:
[A]
[B]
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QuestionRevision
[C]
[D]
Question58.
Twothinconcentricconductingsphericalshellshaveradiirand3rrespectively.TheouteronecarriesachargeQ.Iftheinnerconductor
isearthed,thechargeflownfromconductorstoearthis:
[A]
[B]
[C]
[D]
Noneofthese
Question59.
ApositivechargeQisplacedatthecentreofasquareofsidel.ThenthenetforceonthecentralchargeQduetotheotherfourcharges
Q,2Q,3Qand4Qplacedattheverticesofthesquareis:
[A]
[B]
[C]
[D]
Question60.
Twoidenticalmetalballswithcharges+2QandQareseparatedbylargedistance,andexertaforceFoneachother.Theyarejoined
byaconductingwire.Whichisthenremoved.Theforcebetweenthemwillnowbe:
[A]
[B]
[C]
[D]
F
F/2
F/4
F/8
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QuestionRevision
Question61.
Let
[A]
[B]
[C]
[D]
.If
hasexactlyonerealsolution,thenthevalueofkis:
3
0
1
2
Question62.
Thedomainof
,where
,is:(where[.]representsgreatest
integerfunction)
[A]
[B]
[C]
[D]
Noneofthese
Question63.
Ifthegraphoffunction
[A]
issymmetricalabouttheyaxis,thennequals:
[B]
[C]
[D]
Question64.
Thedomainof
,(where{.}denotesthefractionalpart)in
,is:
[A]
[B]
[C]
[D]
Question65.
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QuestionRevision
If
,then:
[A]
[B]
[C]
[D]
Noneofthese
Question66.
,isequalto:
[A]
[B]
[C]
[D]
Noneofthese
Question67.
(where[.]denotesthegreatestintegerfunction)is:
[A]
[B]
[C]
[D]
5
6
7
Doesnotexist
Question68.
(where{x}denotesthefractionalpartofx)isequalto:
[A]
[B]
[C]
doesnotexist
1
[D]
Question69.
If
[A]
[B]
[C]
[D]
thenthenumberofpointsofdiscontinuityof
is:
1
2
3
Noneofthese
Question70.
If
[A]
[B]
for
iscontinuousat
,thenthevalueoff(5)is:
0
5
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[C]
[D]
QuestionRevision
10
25
Question71.
Letf:
beafunctiondefinedby
.Thesetofallpointswheref(x)isnotdifferentiableis:
[A]
[B]
[C]
[D]
Question72.
Whichofthefollowingfunctionsisdifferentiableatx=0?
[A]
[B]
[C]
[D]
Question73.
Thefunctiongivenby
isdifferentiableforallrealnumbersexceptthepoints:
[A]
[B]
[C]
[D]
Question74.
Thedifferentialcoefficientof
withrespecttox,where
,is:
[A]
[B]
[C]
[D]
Noneofthese
Question75.
If
[A]
[B]
[C]
[D]
then
isa:
functionofxonly
functionofyonly
functionofxandy
Constant
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QuestionRevision
Question76.
If
,then
[A]
[B]
[C]
[D]
Question77.
Letf:
[A]
besuchthat
and
.Then
[B]
[C]
[D]
Question78.
giventhat
[A]
doesnotexist
[B]
isequalto
[C]
isequalto
[D]
isequalto3
and
Question79.
Iff(x)isdifferentiableandstrictlyincreasingfunction,thenthevalueof
[A]
[B]
[C]
[D]
is:
1
0
2
Question80.
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QuestionRevision
Thefunction
is:
[A]
[B]
Differentiableatallpoints
Differentiableatallpointsexceptat
[C]
[D]
Continuousatallpointsexceptat
and
and
whereitisdiscontinuous.
Noneofthese
Question81.
Iftheline
isthedirectrixoftheparabola
,thenoneofthevaluekis?
[A]
[B]
[C]
8
4
[D]
Question82.
Tangenttothecurve
atapoint
touchesthecircle
atapointQ.Thenthe
coordinateofQare:
[A]
[B]
[C]
[D]
Question83.
If
[A]
[B]
[C]
[D]
,then
equals:
8
6
10
Infinite
Question84.
Iftangentsaredrawntotheellipse
,thenlocusofthemidpointoftheinterceptmadebythetangentsbetweenthe
coordinateaxesis:
[A]
[B]
[C]
[D]
Question85.
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QuestionRevision
Theequation
[A]
Nolocusif
[B]
Anellipseif
[C]
Apointif
[D]
Ahyperbolaif
represents:
Question86.
Whichofthefollowingisindependentof
[A]
[B]
[C]
[D]
inthehyperbola
Eccentricity
Abscissaoffoci
Directrix
Vertex
Question87.
Iftheline
touchesthehyperbola
,thenthepointofcontactis:
[A]
[B]
[C]
[D]
Question88.
Thelocusofthefootoftheperpendicularformthecentreofthehyperbola
onavariabletangentis:
[A]
[B]
[C]
[D]
Question89.
Locusofthepointwhichdividesdoubleordinatesoftheellipse
intheratio1:2internallyis:
[A]
[B]
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[C]
[D]
Noneofthese
Question90.
Thepointofintersectionofthetangentsoftheparabola
,drawnatendpointsofthechord
lieson:
[A]
[B]
[C]
[D]
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