Pace Analyl/cal Services, Inc.

1700 Elm Street

Minneapolis, MN 55414
ace Analyical" Phone: 612.607.1700
www.pacelabs.com Fax: 612.607.6444

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This report contains 13 pages.

The results reported herein conform to the most current NELAC standards, where applicable, unless otherwise
narrated in the body ofthe report.

Project Name: Tittabawassee River - Reach 0

Project Number: 805-012-0709-012

Purchase Order Number: 20405.016.012.0293.00

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
ill. ACCOIi

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 Pace Analyl/cal ServIces, Inc.
1700 Elm Street

ace Analyical" Minneapolis, MN 55414

Phone: 612.607.1700
www.pacelabs.com REPORT OF: CHEMICAL ANALYSES Fax: 612.607.6444

PROJECT: Pcnn/PcnF ANAl YSFS DATE: October 4, 2007

ISSUED TO: Weston Solutions of Michigan REPORT NO: 07-1059729

Attn: Katie Mooney
2501 Jolly Road, Suite 100
Okemos, MI 48864-3515

INTRoni lCTION

This report presents the results from the analyses performed on three samples submitted by a
representative of Weston Solutions of Michigan. The samples were analyzed for the presence or
absence of polychlorodibenzo-p-dioxins (PCDDs) and polychlorodibenzofurans (PCDFs) using USEPA
Method 1613B.

SAMPLE IDENTIFICATION

Client ID Sample Type Date Received PACF in

START-RMU-4-3 Solid 09/26/07 1059729001

START-RMU-4-2 Solid 09/26/07 1059729002
START-RMU-4-1 Solid 09/26/07 1059729003

RESULTS

The results from the analyses are presented in the following:

Appendix A - Chain of Custody Documentation

Appendix B - PCDD/PCDF Analysis Results

DISCUSSION

The recoveries of the isotopically labeled PCDD/PCDF internal standards in the sample extracts ranged
from 48-88%. All of the labeled standard recoveries obtained for this project were within the target
ranges specified in Method 1613B. Since the quantification of the native 2,3,7,8-substituted isomers
was based on isotope dilution, the data were automatically corrected for variation in recovery and
accurate values were obtained.

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, inc.
,II ACCOI¡

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 Pace Analyl/cal ServIces, Inc.
1700 Elm Street

ace Analytical" Minneapolis, MN 55414

Phone: 612.607.1700
www.pacelabs.com REPORT OF: CHEMICAL ANALYSES Fax: 612.607.6444

PROJECT: PCDD/PCDF ANAl YSFS DATE: October 4, 2007

PAGE: 2 REPORT NO: 07-1059729

nlSCUSSION (Cont )

A laboratory method blank was prepared and analyzed with the sample batch as part of our
routine quality control procedures. The results, found at the beginning of Appendix B, show the
blank to be free of PCDDs and PCDFs at the reporting limits. These results indicate that the
laboratory processing procedures did not significantly impact the sample results.

Laboratory spike samples were also prepared with the sample batch using clean sand that had
been fortified with native standards. Recoveries of the spiked native compounds ranged from 90-
118%, with relative percent differences of 0.0-9.2%. This indicates high degrees of accuracy and
precision for these determinations.

RFMARKS

The sample extracts wil be retained for a period of 15 days from the date of this report and then
discarded unless other arrangements are made. The raw mass spectral data will be archived for a
period of not less than one year. Questions regarding the data contained in this report may be
directed to the author at the number provided below.

Pace Analytical Services, Inc.

-( ~ ,
S tt . U nze
roj t Manager, MS
) 607-6383

REPORT OF LABORATORY ANALYSIS

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without the written consent of Pace Analytical Services, Inc.
,II ~CCQI¡
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 Pace Analyl/cal ServIces, Inc.
1700 Elm Street

ace Analyical" Minneapolis, MN 55414

Phone: 612.607.1700
www.pacelabs.com Fax: 612.607.6444

APPENDIX A

REPORT OF LABORATORY ANALYSIS

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without the written consent of Pace Analytical Services, Inc.
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 CHAIN-OF-CUSTODY I Analytical Request Document
The Chain-af-Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
~e~n~!l!!q~.
Section A Section B Section C Page: of
Required Client Information; Required Project Information: Invoice Information: toçqj'2Ci
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SAMPLER NAME AND SIGNATURE o

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 Pace Analytical Services, Inc.
1700 Elm Street
ace Analyical" Minneapolis, MN 55414
Phone: 612.607.1700
www.pacelabs.com Fax: 612.607.6444

APPENDIX B

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Anaiytical Services, Inc.
1\,_ACCQ.l
",'/_1 1-' '''",
"",~¿- ~l;\'.!!4+

.ihoi'zfr"
 Pace Analytical ServIces, Inc.
1700 Elm Slreet - Sulle 200
Minneapolis, MN 55414

'ace Analvtical'" Tel: 612-607-1700

Fax' 612- 607-6444
Method 16138 Blank Analysis Results
Client - Weston Solutions, Inc.

lab Sample ID BlANK-14344 Matrix Solid

Filename U71002A_05 Dilution NA
Total Amount Extracted 20.1 9 Extracted 09/28i2007
ICAl Date 09/27/2007 Analyzed 10/02i2007 13:56
CCal Filename(s) U71002A_01 Injected By SMT

Native Cone EMPC PRl Internal ng's Percent

Isomers ngiKg ng/Kg ng/Kg Standards Added Recovery
2,3,7,8-TCDF ND 0.50 2,3,7,8-TCDF-13C 2.00 59
Total TCDF ND 2,3,7,8- TCDD-13C 2.00 50
1,2,3,7,8-PeCDF-13C 2.00 54
2,3,7,8-TCDD ND 0.50 2,3,4,7,8-PeCDF-13C 2.00 58
Total TCDD ND 1,2,3,7,8-PeCDD-13C 2.00 58
1,2,3,4,7,8-HxCDF-13C 2.00 71
1,2,3,7,8-PeCDF ND 2.50 1,2,3,6,7,8-HxCDF-13C 2.00 72
2,3,4,7,8-PeCDF ND 2.50 2,3,4,6,7,8-HxCDF-13C 2.00 67
Total PeCDF ND 1 ,2,3,7 ,8,9-HxCDF-13C 2.00 63
1,2,3,4,7,8-HxCDD-13C 2.00 74
1,2,3,7,8-PeCDD ND 2.50 1,2,3,6,7,8-HxCDD-13C 2.00 58
Total PeCDD ND 1,2,3,4,6,7,8-HpCDF-13C 2.00 70
1,2,3,4,7,8,9-HpCDF-13C 2.00 57
1,2,3,4,7,8-HxCDF ND 2.50 1,2,3,4,6,7,8-HpCDD-13C 2.00 63
1,2,3,6,7,8-HxCDF ND 2.50 OCDD-13C 4.00 47
2,3,4,6,7,8-HxCDF ND 2.50
1,2,3,7,8,9-HxCDF ND 2.50 1,2,3,4- TCDD-13C 2.00 NA
Total HxCDF ND 1,2,3,7,8,9-HxCDD-13C 2.00 NA

1,2,3,4,7,8-HxCDD ND 2.50 2,3,7,8-TCDD-37CI4 0.20 48

1,2,3,6,7,8-HxCDD ND 2.50
1,2,3,7,8,9-HxCDD ND 2.50
Total HxCDD ND

1,2,3,4,6,7,8-HpCDF ND 2.50 TotaI2,3,7,8-TCDD

1,2,3,4,7,8,9-HpCDF ND 2.50 Equivalence: 0.00 ng/Kg
Total HpCDF ND (Using 2005 WHO Factors)
1,2,3,4,6,7,8-HpCDD ND 2.50
Total HpCDD ND

OCDF ND 5.00
OCDD ND 5.00

Cone = Concentration (Totals include 2,3,7,8-substituted isomers). I = Interference

EMPC = Estimated Maximum Possible Concentration E = PCDE Interference
PRl = Pace Analytical Reporting Limit ND = Not Detected
A = Limit of Detection based on signal to noise NA = Not Applicable
P ~ Recovery outside of method 1613 control limits NC = Not Caiculated
Nn = Value obtained from additional analysis J = Value below calibration range
'" = See Discussion

Report No.....1059729

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services. Inc.
 Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414

'ace Analvtica( Tel: 612-607-1700

F::x' 612- 607-6444
Method 16138 Analysis Results
Client - Weston Solutions, Inc.
Client's Sample ID START-RMU-4-3
lab Sample ID 1059729001
Filename F71003C_13
Injected By BAl
Total Amount Extracted 14.6 9 Matrix Solid
% Moisture 15.7 Dilution NA
Dry Weight Extracted 12.3 9 Collected 09i25/2007
ICAl Date 08/30/2007 Received 09i26/2007
CCal Filename(s) F71003C_01 Extracted 09/28/2007
Method Blank ID BlANK-14344 Analyzed 10104i2007 00:44
Native Cone EMPC PRl Internal ng's Percent
Isomers ng/Kg ngiKg ng/Kg Standards Added Recovery
2,3,7,8-TCDF 1.2 0.81 2,3,7,8-TCDF-13C 2.00 71
Total TCDF 2.2 2,3,7,8-TCDD-13C 2.00 68
1,2,3,7,8-PeCDF-13C 2.00 68
2,3,7,8-TCDD ND 0.81 2,3,4,7,8-PeCDF-13C 2.00 74
Total TCDD ND 1,2,3,7,8-PeCDD-13C 2.00 84
1,2,3,4,7,8-HxCDF-13C 2.00 66
1,2,3,7,8-PeCDF ND 4.10 1,2,3,6,7,8-HxCDF-13C 2.00 73
2,3,4,7,8-PeCDF ND 4.10 2,3,4,6,7,8-HxCDF-13C 2.00 70
Total PeCDF ND 1,2,3,7,8,9-HxCDF-13C 2.00 70
1,2,3,4,7,8-HxCDD-13C 2.00 70
1,2,3,7,8-PeCDD ND 4.10 1,2,3,6,7,8-HxCDD-13C 2.00 79
Total PeCDD ND 1,2,3,4,6,7,8-HpCDF-13C 2.00 69
1,2,3,4,7,8,9-HpCDF-13C 2.00 58
1,2,3,4,7,8-HxCDF ND 4.10 1,2,3,4,6,7,8-HpCDD-13C 2.00 72
1,2,3,6,7,8-HxCDF ND 4.10 OCDD-13C 4.00 62
2,3,4,6,7,8-HxCDF ND 4.10
1,2,3,7,8,9-HxCDF ND 4.10 1,2,3,4-TCDD-13C 2.00 NA
Total HxCDF ND 1,2,3,7,8,9-HxCDD-13C 2.00 NA

1,2,3,4,7,8-HxCDD ND 4.10 2,3,7,8- TCDD-37CI4 0.20 65

1,2,3,6,7,8-HxCDD ND 4.10
1,2,3,7,8,9-HxCDD ND 4.10
Total HxCDD ND

1,2,3,4,6,7,8-HpCDF ND 4.10 TotaI2,3,7,8-TCDD

1,2,3,4,7,8,9-HpCDF ND 4.10 Equivalence: 0.12 ng/Kg
Total HpCDF ND (Using 2005 WHO Factors)
1,2,3,4,6,7,8-HpCDD ND 4.10
Total HpCDD ND

OCDF ND 8.10
OCDD ND 8.10
Results reported on a dry weight basis
I = Interference
Conc = Concentration (Totals include 2,3,7,8-substituted isomers). E = PCDE Interference
EMPC = Estimated Maximum Possible Concentration
ND = Not Detected
PRL = Pace Analytical Reporting Limit.
A = Limit of Detection based on signal to noise NA = Not Applicable
B = Less than 10 times higher than method blank level NC = Not Calculated
P = Recovery outside of method 1613 control limits J = Value below calibration range
Nn = Value obtained from additional analysis * = See Discussion
Report No.....1059729

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full.
without the written consent of Pace Analytical Services, Inc.
 Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414

Tel: 612-607-1700
âce Analvtica( F::x' 612- 607-6444
Method 16138 Analysis Results
Client - Weston Solutions, Inc.
Client's Sample ID START-RMU-4-2
lab Sample ID 1059729002
Filename F71003C_14
Injected By BAl
Total Amount Extracted 16.0 9 Matrix Solid
% Moisture 18.3 Dilution NA
Dry Weight Extracted 13.1 9 Collected 09/25/2007
ICAl Date 08/30i2007 Received 09/26/2007
CCal Fllename(s) F71003C 01 Extracted 09/28/2007
Method Blank ID BlANK-14344 Analyzed 10/04/2007 01 :31
Native Conc EMPC PRl Internal ng's Percent
Isomers ng/Kg ng/Kg ng/Kg Standards Added Recovery
2,3,7,8-TCDF 0.99 0.76 2,3,7,8-TCDF-13C 2.00 77
Total TCDF 0.99 2,3,7,8-TCDD-13C 2.00 75
1,2,3,7,8-PeCDF-13C 2.00 77
2,3,7,8- TCDD ND 0.76 2,3,4,7,8-PeCDF-13C 2.00 80
Total TCDD ND 1,2,3,7,8-PeCDD-13C 2.00 88
1,2,3,4,7,8-HxCDF-13C 2.00 77
1,2,3,7,8-PeCDF ND 3,80 1,2,3,6,7,8-HxCDF-13C 2.00 82
2,3,4,7,8-PeCDF ND 3.80 2,3,4,6,7,8-HxCDF-13C 2.00 79
Total PeCDF ND 1,2,3,7,8,9-HxCDF-13C 2.00 83
1,2,3,4,7,8-HxCDD-13C 2.00 78
1,2,3,7,8-PeCDD ND 3.80 1,2,3,6,7,8-HxCDD-13C 2.00 88
Total PeCDD ND 1,2,3,4,6,7,8-HpCDF-13C 2.00 82
1,2,3,4,7,8,9-HpCDF-13C 2.00 68
1,2,3,4,7,8-HxCDF ND 3.80 1,2,3,4,6,7,8-HpCDD-13C 2.00 86
1,2,3,6,7,8-HxCDF ND 3.80 OCDD-13C 4.00 70
2,3,4,6,7,8-HxCDF ND 3.80
1,2,3,7,8,9-HxCDF ND 3.80 1,2,3,4- TCDD-13C 2.00 NA
Total HxCDF ND 1,2,3,7,8,9-HxCDD-13C 2.00 NA

1,2,3,4,7,8-HxCDD ND 3.80 2,3,7,8- TCDD-37CI4 0.20 70

1,2,3,6,7,8-HxCDD ND 3.80
1,2,3,7,8,9-HxCDD ND 3.80
Total HxCDD ND

1,2,3,4,6,7,8-HpCDF ND 3.80 TotaI2,3,7,8-TCDD

1,2,3,4,7,8,9-HpCDF ND 3.80 Equivaience: 0.10 ngiKg
Total HpCDF ND (Using 2005 WHO Factors)
1,2,3,4,6,7,8-HpCDD ND 3.80
Total HpCDD ND

OCDF ND 7.60
OCDD 8.10 7.60
Results reported on a dry weight basis
I = Interference
Cone = Concentration (Totals include 2,3,7,B-subsliuted Isomers). E = PCDE Interference
EMPC = Estimated Maximum Possible Concentration
ND = Not Detected
PRl = Pace Analytical Reporting Limit.
A = Limit of Detection based on signal to noise NA = Not Applicable
B = Less than 10 times higher than method blank level NC = Not Calculated
P = Recovery outside of method 1613 control limits J = Value below calibration range
Nn = Value obtained from additional analysis * = See Discussion
Report No.....1 059729

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
 Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414

Tel: 612-607-1700
âce Ana/vtiGal" Fax' 612- 607.6444
Method 16138 Analysis Results
Client - Weston Solutions, Inc.
Client's Sample ID START-RMU-4-1
lab Sample ID 1059729003
Filename F71003C_15
Injected By BAl
Total Amount Extracted 15.9 9 Matrix Solid
% Moisture 11.1 Dilution NA
Dry Weight Extracted 14.2 9 Collected 09/25i2007
ICAl Date 08/30/2007 Received 09/26i2007
CCal Filename(s) F71003C 01 Extracted 09/28/2007
Method Blank ID BlANK-14344 Analyzed 10/0412007 02:18
Native Cone EMPC PRL Internal ng's Percent
Isomers ngiKg ng/Kg ng/Kg Standards Added Recovery
2,3,7,8-TCDF ND 0.71 2,3,7,8- TCDF-13C 2.00 52
Total TCDF ND 2,3,7,8- TCDD-13C 2.00 52
1,2,3,7,8-PeCDF-13C 2.00 53
2,3,7,8-TCDD ND 0.71 2,3,4,7,8-PeCDF-13C 2.00 56
Total TCDD ND 1,2,3,7,8-PeCDD-13C 2.00 64
1,2,3,4,7,8-HxCDF-13C 2.00 54
1,2,3,7,8-PeCDF ND 3.50 1,2,3,6,7,8-HxCDF-13C 2.00 59
2,3,4,7,8-PeCDF ND 3.50 2,3,4,6,7,8-HxCDF-13C 2.00 58
Total PeCDF ND 1,2,3,7,8,9-HxCDF-13C 2.00 56
1,2,3,4,7,8-HxCDD-13C 2.00 55
1,2,3,7,8-PeCDD ND 3.50 1,2,3,6,7,8-HxCDD-13C 2.00 66
Total PeCDD ND 1,2,3,4,6,7,8-HpCDF-13C 2.00 58
1,2,3,4,7,8,9-HpCDF-13C 2.00 48
1,2,3,4,7,8-HxCDF ND 3.50 1,2,3,4,6,7,8-HpCDD-13C 2.00 62
1,2,3,6,7,8-HxCDF ND 3.50 OCDD-13C 4.00 51
2,3,4,6,7,8-HxCDF ND 3.50
1,2,3,7,8,9-HxCDF ND 3.50 1,2,3,4-TCDD-13C 2.00 NA
Total HxCDF ND 1,2,3,7,8,9-HxCDD-13C 2.00 NA

1,2,3,4,7,8-HxCDD ND 3.50 2,3,7,8- TCDD-37CI4 0.20 49

1,2,3,6,7,8-HxCDD ND 3.50
1,2,3,7,8,9-HxCDD ND 3.50
Total HxCDD ND

1,2,3,4,6,7,8-HpCDF ND 3.50 TotaI2,3,7,8-TCDD

1,2,3,4,7,8,9-HpCDF ND 3.50 Equivalence: 0.00 ng/Kg
Total HpCDF ND (Using 2005 WHO Factors)
1,2,3,4,6,7,8-HpCDD ND 3.50
Total HpCDD ND

OCDF ND 7.10
OCDD ND 7.10
Results reported on a dry weight basis
I = Interference
Cone = Concentration (Totals include 2,3,7,B-substituted isomers).
E = PCDE Interference
EMPC = Estimated Maximum Possible Concentration
ND = Not Detected
PRL = Pace Analytical Reporting Limit.
A = Limit of Detection based on signal to noise NA = Not Applicable
B = Less than 10 times higher than method blank level NC = Not Calculated
P = Recovery outside of method 1613 control limits J = Value below calibration range
Nn = Value obtained from additional anaiysis . = See Discussion
Report No.....1059729

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
 Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
T"

'ace AnalvtiGal Tel: 612-607-1700

Fax' 612- 607-6444

Method 16138 Laboratory Control Spike Results

Client - Weston Solutions, Inc.

Lab Sample ID LCS-14345

Filename U71002A_02 Matrix Solid
Total Amount Extracted 20.0 9 Dilution NA
ICAL Date 09/27/2007 Extracted 09/28i2007
CCal Filename U71002A 01 Analyzed 10102/2007 11:35
Method Blank ID BLANK-14344 Injected By SMT

Lower Upper %
Compound Cs Cr Limit Limit Rec.
2,3,7,8-TCDF 10 9.3 7.5 15.8 93
2,3,7,8-TCDD 10 9.3 6.7 15.8 93
1,2,3,7,8-PeCDF 50 51.5 40.0 67.0 103
2,3,4,7,8-PeCDF 50 49.3 34.0 80.0 99
1,2,3,7,8-PeCDD 50 45.5 35.0 710 91
1,2,3,4,7,8-HxCDF 50 49.1 36.0 67.0 98
1,2,3,6,7,8-HxCDF 50 47.6 42.0 65.0 95
2,3,4,6,7,8-HxCDF 50 51.3 35.0 78.0 103
1,2,3,7,8,9-HxCDF 50 49.9 39.0 65.0 100
1,2,3,4,7,8-HxCDD 50 47.3 35.0 82.0 95
1,2,3,6,7,8-HxCDD 50 51.3 38.0 67.0 103
1,2,3,7,8,9-HxCDD 50 47.4 32.0 81.0 95
1,2,3,4,6,7,8-HpCDF 50 46.7 41.0 61.0 93
1,2,3,4,7,8,9-HpCDF 50 52.0 39.0 69.0 104
1,2,3,4,6,7,8-HpCDD 50 49.9 35.0 70.0 100
OCDF 100 113.7 63.0 170.0 114
OCDD 100 101.9 78.0 144.0 102
2,3,7,8- TCDD-37CI4 10 6.3 3.1 19.1 63
2,3,7,8-TCDF-13C 100 77.1 22.0 152.0 77
2,3,7,8-TCDD-13C 100 69.3 20.0 175.0 69
1,2,3,7,8-PeCDF-13C 100 69.2 21.0 192.0 69
2,3,4,7,8-PeCDF-13C 100 72.9 13.0 328.0 73
1 ,2,3,7 ,8-PeCDD-13C 100 72.9 21.0 227.0 73
1,2,3,4,7,8-HxCDF-13C 100 84.7 19.0 202.0 85
1,2,3,6,7,8-HxCDF-13C 100 94.0 21.0 159.0 94
2,3,4,6,7,8-HxCDF-13C 100 83.8 22.0 176.0 84
1 ,2,3,7 ,8,9-HxCDF-13C 100 79.2 17.0 205.0 79
1,2,3,4,7,8-HxCDD-13C 100 79.6 21.0 193.0 80
1,2,3,6,7,8-HxCDD-13C 100 90.2 25.0 163.0 90
1,2,3,4,6,7,8-HpCDF-13C 100 86.5 21.0 158.0 87
1,2,3,4,7,8,9-HpCDF-13C 100 68.5 20.0 186.0 69
1,2,3,4,6,7,8-HpCDD-13C 100 78.0 26.0 166.0 78
OCDD-13C 200 129.5 26.0 397.0 65

Cs ~ Concentration Spiked (ng/mL)

Cr = Concentration Recovered (ng/mL)
Rec. = Recovery (Expressed as Percent)
Control Limit Reference: Method 1613, Table 6, 10/94 Revision
X = Background subtracted value
P = Recovery outside of control limits
Nn = Value obtained from additional analysis Report No.....1 059729
* = See Discussion

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc.
 Pace Analytical Services, Inc.
1700 Elm Street - Suite 200
Minneapolis, MN 55414
TM

Tel: 612-607-1700
âce Analvtical Fax' 612- 607w6444

Method 16138 Laboratory Control Spike Results

Client - Weston Solutions, Inc.

Lab Sample ID LCSD-14350

Filename U71002A_03 Matrix Soiid
Total Amount Extracted 20.2 9 Dilution NA
iCAL Date 09/27/2007 Extracted 09/28/2007
CCai Filename U71002A_01 Analyzed 10/02/2007 12:20
Method Biank ID BLANK-14344 Injected By SMT

Lower Upper %
Compound Cs Cr Limit Limit Rec.
2,3,7,8-TCDF 10 9.6 7.5 15.8 96
2,3,7.8-TCDD 10 9.5 6.7 15.8 95
1,2,3,7,8-PeCDF 50 51.9 40.0 67.0 104
2,3,4,7,8-PeCDF 50 50.4 34.0 80.0 101
1,2,3,7,8-PeCDD 50 44.8 35.0 71.0 90
1,2,3,4,7,8-HxCDF 50 48.9 36.0 67.0 98
1,2,3,6,7,8-HxCDF 50 49.0 42.0 65.0 98
2,3,4,6.7,8-HxCDF 50 51.8 35.0 78.0 104
1,2.3,7,8,9-HxCDF 50 49.6 39.0 65.0 99
1,2,3,4,7,8-HxCDD 50 51.4 35.0 82.0 103
1,2,3.6,7,8-HxCDD 50 47.1 38.0 67.0 94
1,2,3,7,8,9-HxCDD 50 48.3 32.0 81.0 97
1,2,3,4,6,7,8-HpCDF 50 48.6 41.0 61.0 97
1,2,3,4,7,8,9-HpCDF 50 52.5 39.0 69.0 105
1,2,3,4,6,7,8-HpCDD 50 48.8 35.0 70.0 98
OCDF 100 117.6 63.0 170.0 118
OCDD 100 105.8 78.0 144.0 106

2,3,7,8- TCDD-37CI4 10 6.4 3.1 19.1 64

2,3,7.8-TCDF-13C 100 71.6 22.0 152.0 72
2.3,7,8-TCDD-13C 100 67.6 20.0 175.0 68
1,2,3,7.8-PeCDF-13C 100 63.1 21.0 192.0 63
2,3,4,7,8-PeCDF-13C 100 66.4 13.0 328.0 66
1,2,3,7,8-PeCDD-13C 100 68.8 21.0 227.0 69
1,2,3,4,7,8-HxCDF-13C 100 74.8 19.0 202.0 75
1,2,3,6,7.8-HxCDF-13C 100 82.8 21.0 159.0 83
2.3,4,6.7.8-HxCDF-13C 100 75.6 22.0 176.0 76
1,2.3,7,8,9-HxCDF-13C 100 77.8 17.0 205.0 78
1,2,3,4,7,8-HxCDD-13C 100 71.4 21.0 193.0 71
1,2,3,6,7,8-HxCDD-13C 100 83.1 25.0 163.0 83
1,2,3,4.6,7,8-HpCDF-13C 100 76.7 21.0 158.0 77
1,2,3,4,7,8,9-HpCDF-13C 100 65.6 20.0 186.0 66
1,2,3,4,6,7,8-HpCDD-13C 100 75.8 26.0 166.0 76
OCDD-13C 200 126.1 26.0 397.0 63

Cs = Concentration Spiked (ng/mL)

Cr = Concentration Recovered (ng/mL)
Rec. = Recovery (Expressed as Percent)
Control Limit Reference: Method 1613, Table 6,10/94 Revision
X = Background subtracted value
P = Recovery outside of control limits
Nn = Value obtained from additional analysis Report No.....1 059729
* = See Discussion

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
 Pace Analyllcal ServIces, Inc.
1700 Elm Street
ace Analyical" Minneapolis, MN 55414
Phone: 612.607.1700
www.pacelabs.com Fax: 612.607.6444
SPIKE RECOVERY RELATIVE PERCENT DIFFERENCE (RPD) RESULTS

Client.............. Weston Solutions, Inc.

SPIKE 1ID................................LCS-14345
SPIKE 1 Filename...................... U71002A_02
SPIKE 2 ID................................ LCS-14350
SPIKE 2 Filename...................... U71002A_03

SPIKE 1 SPIKE 2
COMPOUND REC,% REC,% RPD,%

2378-TCDF 93 96 3.2

2378-TCDD 93 95 2.1

12378-PeCDF 103 104 1.0

23478-PeCDF 99 101 2.0

12378-PeCDD 91 90 1.1

123478-HxCDF 98 98 0.0
123678-HxCDF 95 98 3.1
234678-HxCDF 103 104 1.0
123789-HxCDF 100 99 1.0

123478-HxCDD 95 103 8.1

123678-HxCDD 103 94 9.1
123789-HxCDD 95 97 2.1

1234678-HpCDF 93 97 4.2
1234789-HpCDF 104 105 1.0

1234678-HpCDD 100 98 2.0

OCDF 114 118 3.4

OCDD 102 106 3.8

REC = Percent Recovered

RPD = The difference between the two values divided by the average.
NA = Not Applicable
Report No..... 1059729

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
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