Time

Volume of titrating NaOH (ml)

1
6.3

5
21.3

10
24.1

Volume of quenching HCl Unreacted with

NaOH in Sample (ml) [C]

2.52

8.52

9.64

Volume of HCl reacted with NaOH in

Sample (ml)

7.48

1.48

0.36

Mole of HCl reacted with NaOH in Sample

Mole of NaOH Unreacted in Sample

0.00187
0.00187

0.00037
0.00037

0.00009
0.00009

Concentration of NaOH Unreacted with

Ethyl Acetate (mol/L)
Steady state fraction of NaOH, XA

0.00374
0.9626

0.00074
0.9926

0.00018
0.9982

0.04626

0.09926

0.09982

Mole of NaOH reacted with Ethyl Acetate

10000
in Sample

0.02313

0.04963

5000
Concentration
of Ethyl Acetate Reacted
with NaOH (moles/L)
0

0.04991 -2

0.04626

0.09926

0.09982 -4

1/CA
Concentration of NaOH reacted with
Ethyl
Acetate (mol/L)
15000

10

15

20

25

30

Concentration
of Ethyl Acetate Unreacted
-5000
(moles/L)
0.05374 0.00074 0.00018 -6
-10000
Time
1
5
10
-15000
ln
-2.923598 -7.20886 -8.622554-8
-20000
1/CA
18.60811 1351.351 5555.556
-25000
-30000

-10
-12

f(x) = - 0.339
R = 0.812400

15
24.6

20
25.2

25
25.0

9.84

10.08

10

0.16

-0.08

0.00004
0.00004

-0.00002
-0.00002

0
0

0.00008
0.9992

-0.00004
1.0004

0
1

0.09992

0.04996
-2

0.10004
5

0.05002

0.1
10

ln
15

0.05

0.06
20

25

30

0.05

f
R

0.04

0.10004
0.1
-40.09992
30
f(x) = - 0.3397488057x - 4.1975875381
-60.00008
R = 0.8124008581
-0.00004
0
15
20
-8
-9.433484 -10.12663
12500
-25000

-10
-12

25
Err:502
#DIV/0!

0.03

Axis Title
0.02
0.01
0
0
-0.01

0.06
Concentration of Ethyl
Acetate Unreacted
(moles/L)

0.05
f(x) = -0.0162257008 ln(x) + 0.0438252831
R = 0.7828551998

0.04
0.03

Axis Title
0.02
0.01
0
0
-0.01

10

15

Axis Title

20

25

30

hyl

30

Time

10

Volume of titrating NaOH (ml)

26.8

24.5

24.0

Volume of quenching HCl Unreacted

with NaOH in Sample (ml) [C]

10.72

9.8

9.6

Volume of HCl reacted with NaOH in

Sample (ml)

-0.72

0.2

0.4

Mole of HCl reacted with NaOH in

Sample
Mole of NaOH Unreacted in Sample

-0.00018
-0.00018

0.00005
0.00005

0.0001
0.0001

Concentration of NaOH Unreacted

with Ethyl Acetate (mol/L)
Steady state fraction of NaOH, XA

-0.00036
1.0072

0.0001
0.999

0.0002
0.998

Concentration of NaOH reacted with

Ethyl Acetate (mol/L)

0.05036

0.0499

0.0498

Mole of NaOH reacted with Ethyl

Acetate in Sample

0.02518

0.02495

0.0249

Concentration of Ethyl Acetate

Reacted with NaOH (moles/L)

0.05036

0.0499

0.0498

Concentration of Ethyl Acetate

Unreacted (moles/L)

0.04964

0.0501

0.0502

Time
ln (CA)
1/CA

1
5
10
-3.002958 -2.9937342709 -2.99174
20.14504 19.9600798403 19.92032

1/CA
20.2
20.15
20.1
20.05
f(x) = - 0.0038383803x + 20.046200224
R = 0.2045195593

20
19.95
19.9
19.85
19.8

10

15

20

25

30

R = 0.2045195593
19.95
19.9
19.85
19.8

10

15

20

25

30

15

20

25

25.0

24.8

24.7

10

9.92

9.88

0.08

0.12

0
0

0.00002
0.00002

0.00003
0.00003

0
1

0.00004
0.9996

0.00006
0.9994

0.05

0.04996

0.04994

0.025

0.02498

0.02497

0.05

0.04996

0.04994

0.05

0.05004

0.05006

15
20
25
-2.995732 -2.994933 -2.994533
20 19.98401 19.97603

ln (CA)
-2.986
-2.988

10

15

-2.99
-2.992
-2.994
-2.996
-2.998
-3
-3.002
-3.004
30

f(x) = 0.0001911191x - 2.998025959

R = 0.2036786669

20

25

30

-2.998
-3
-3.002
-3.004
30

ln (CA)
30

-2.986
-2.988

10

15

-2.99
-2.992
-2.994
-2.996
-2.998
-3
-3.002
-3.004

f(x) = 0.0001911191x - 2.998025959

R = 0.2036786669

20

25

30

-2.998
-3
-3.002
-3.004

30

Time
Volume of titrating NaOH (ml)

1
26.7

5
25.2

10
25.6

15
25.6

Volume of quenching HCl

Unreacted with NaOH in Sample
(ml) [C]

10.68

10.08

10.24

10.24

Volume of HCl reacted with NaOH

in Sample (ml)

-0.68

-0.08

-0.24

-0.24

Mole of HCl reacted with NaOH in

Sample
-0.00017 -0.00002 -0.00006 -0.00006
Mole of NaOH Unreacted in Sample -0.00017 -0.00002 -0.00006 -0.00006
Concentration of NaOH Unreacted
with Ethyl Acetate (mol/L)
-0.00034 -0.00004 -0.00012 -0.00012
Steady state fraction of NaOH, XA 1.0034
1.0004
1.0012
1.0012
Concentration of NaOH reacted
with Ethyl Acetate (mol/L)

0.05034

0.05004

0.05012

0.05012

Mole of NaOH reacted with Ethyl

Acetate in Sample

0.02517

0.02502

0.02506

0.02506

Concentration of Ethyl Acetate

Reacted with NaOH (moles/L)

0.05034

0.05004

0.05012

0.05012

Concentration of Ethyl Acetate

Unreacted (moles/L)
Time
lnCa
1/ca

0.04966 0.04996 0.04988 0.04988

1
5
10
15
-3.002555 -2.996533 -2.998135 -2.998135
20.13693 20.01601 20.04812 20.04812

20
25.8

25
25.0

10.32

10

-0.32

lnCa
-2.992

10

15

20

25

-2.994

-0.00008
-0.00008

0
0

-2.996
-2.998

-0.00016
1.0016

0
1

0.05016

0.05

f(x) = 0.0001525083x - 3.0002697859

R = 0.3399662853

-3
-3.002
-3.004

0.02508

0.025

0.05016

0.05

1/ca
20.15

0.04984
0.05
20
25
-2.998937 -2.995732
20.06421
20

20.1
f(x) = - 0.0030616771x + 20.0910113028
R = 0.3401334708

20.05
20
19.95
19.9

10

15

20

Concentration of Ethyl Acetate Unreacted (moles/L)

0.0501
0.05 25

20

30
f(x) = 7.59677419354853E-006x + 0.0497737742
R = 0.3397987317

0.0499
0.0498
0.0497
0.0496
0.0495
0.0494

10

3028

15

20

25

30

15

20

25

30