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12. GROUP 17 ELEMENTS (VII A GROUP ELEMENTS)
PREVIOUS EAMCET BITS
1. The correct order of reactivity of hydrogen halides with ethyl alcohol is [EAMCET 2008 M]
1) HF > HCl > HBr > HI 2) HCl > HBr > HF > HI
3) HBr > HCl > HI > HF 4) HI > HBr > HCl > HF
Ans: 4
Sol: Order of reactivity of hydrogen halide is HI > HBr > HCl > HF
2. The correct order of vander walls radius of F, Cl and Br is [EAMCET 2006 M]
1) Cl > F > Br 2) Br > Cl > F 3) F > Cl > Br 4) Br > F > Cl
Ans: 2
Sol: Vander walls radius order Br (1.95A) > Cl (1.80 A) > (1.35A°)
3. Which one of the following pairs of reactants does not form oxygen when they react with each other
[EAMCET 2005 E]
1. F2, NaOH solution (hot, conc) 2. F2, H2O
3. Cl2, NaOH solution (cold, dilute) 4. CaOCl2, H2SO4 (dilute, small amount)
Ans: 3
Sol: 2NaOH + Cl 2 ⎯⎯ → NaCl + NaOCl + H 2 O
4. Which of the following is used during the preparation of fluorine by Whytlaw Gray method
[EAMCET 200 5M]
1. aqueous KF 2. aqueous HF 3. molten KHF2 4. NH4F
Ans: 3
Sol: In Whytlaw Gray method molten KHF2 is used as electrolyte
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10. One mole of fluorince is reacted with two moles of hot and concentrated KOH. The products formed
are KF, H2O and O2. The molar ratio of KF, H2O and O2 respectively is
[EAMCET 2002 E]
1) 1 : 1 : 2 2) 2 : 1 : 0.5 3) 1 : 2 : 1 4) 2 : 1 : 2
Ans: 2
Sol: 2F2 + 4KOH ⎯⎯⎯→ 4HF + O 2 + 2H 2 O
hot con
−
11. Fluorine oxidises HSO4 to ..... [EAMCET 2002 E]
1) S2O32- 2) S2O82- 3) S4062- 4) SO2
Ans: 2
−
Sol: 2HSO 4 + F2 ⎯⎯ → S2 O82− + 2HF
12. The number of unpaired electrons present in the first excited state of chlorine atom is [EAMCET
2002 E]
1) 1 2) 3 3) 5 4) 2
Ans: 2
Sol: Cl = 1s 2s 2p 3s 3p 3d
2 2 6 2 5 0
Cl = 1s 2 2s 2 2p 6 3s 2 3p 4 3d1
Ans: 4
NH 3 + 3Cl2 ⎯⎯
→ NCl3 + 3HCl
Sol: excess
14 Which one of the following order is correct for the bond energies? [EAMCET 2001 E]
1) I2 >Cl2 > Br2 2) Br2 > Cl2 > I2 3) I2 > Br2 > Cl2 4) Cl2 > Br2 > I2
Ans: 4
Sol: order of bond energy is Cl2 > Br2> I2
15 Bond dissociation energies of HF, HCI, HBr follow the order [EAMCET 2001 E]
1) HCl>HBr>HF 2) HF>HBr>HCl 3) HF>HCl>HBr 4) HBr>HCl>HF
Ans: 3
Sol: Stability order HF > HCl > HBr
Bond energy order HF > HCl > HBr
7777
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