CAREER POINT

MAJOR # 1
HINTS & SOLUTIONS

CHEMISTRY
Qus.
Ans.
Qus.
Ans.

1
3
16
2

2
3
17
3

3
4
18
2

4
1
19
1

5
3
20
4

6
1
21
2

7
1
22
2

8
4
23
2

9
3
24
3

10
2
25
1

11
1
26
3

12
3
27
2

13
1
28
2

14
2
29
2

15
1
30
1

MATHEMATICS
Qus. 31
Ans 2
Qus. 46
Ans 3

32
2
47
3

33
4
48
4

34
2
49
3

35
3
50
2

36
2
51
2

37
2
52
2

38
2
53
2

39
3
54
1

40
4
55
3

41
3
56
3

42
3
57
4

43
4
58
1

44
3
59
3

45
4
60
4

68
1
83
1

69
2
84
3

70
1
85
1

71
3
86
3

72
3
87
2

73
3
88
1

74
1
89
1

75
1
90
3

6.

Ans. first order

Hint : Fact

7.

Ans. Boyle's law

Hint : At sealevel atmospheric pressure is high.
Hence air has high density
PM = dRT
dp
Ans. Cs+ > Rb+ > K+ > Na+
Hint : larger is the size of ion greater will be
ionic mobility in aqueous solution.

PHYSICS
Ques. 61
Ans. 1
Ques. 76
Ans. 4

62
1
77
2

63
2
78
2

64
3
79
2

65
1
80
1

66
4
81
1

67
4
82
4

CHEMISTRY
1.
2.

Ans. Excited state of Mg

Hint : 12 Mg is 1s2 2s2 2p6 3s2
Ans.

of the presence of vacant d-orbitals on

chlorine which are absent in case of NF3
Hint : NF3 is not hydrolysed due to lack of dorbitals in N and F. NCl3 is hydrolysed
since d-orbitals are present in chlorine
which can now accept lone pair of electron
from water.

3.

Ans. RCH2CH2OH
Hint : Hydroboration

4.

Ans. enantiomers
Hint : Compounds having (R) & (S) configurations
are enantiomers.

5.

8.

9.

Ans. 2.5 M
Hint :
Fe0.8O Fe2O3

Ans. 13
Hint : 12 Octahedral voids are present at the 12
edge centres and one at the body centre.

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+ 2.5

E Fe 0.8O

+3

0.5 0.8
= 0.4
M
= 2.5 M
=
0.4

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CH3

10. Ans.
Cl
+ H CH3

COOH
KMnO4

Hint :
+ M Cl

Cl

Sodalime

NO2
d2sp3 all e paired

Cl
(only isomer)

11. Ans.

[Cr(H2O)6]3+

12. Ans.

charge transfer from O to Cr

22. Ans.

Na < Al < Mg < Si < S < P < Cl

CH3

Hint :
18. Ans.

23. Ans.

hydrometallurgy

A R; B P ; C S; D Q
+
Hint :
Mg-Br + DOD

If both Statement- I and Statement- II are

true, and Statement - II is the correct
explanation of Statement I.
3 and 8
CH3
*
*

0.059
(100)1/ 2
log
1
1
= 0.059 V

=0

25. Ans.

OH
Hint : Phenol

17. Ans.

PH1 /22
0.0591
log
n
[H + ]

24. Ans. Cannizzaro reaction

Hint : It is a cannizaro reaction

15. Ans.

16. Ans.

0.059 V

Hint : E = E

13. Ans. tetrahedral

Hint : PBr4+ has tetrahedral geometry
(sp3 hybridisation)
14. Ans.

clay mineral
43
(92 a)

21. Ans. [Fe(CN)6]4 is strongly paramagnetic

Hint : [Fe(CN)6]4 =
4p
3d
4s

Cl
CH3
Conc. HNO3

20. Ans. 47%

Hint : silica
water
45
12
a
8
45
a
=
43 92 a
a = 47 %

26. Ans.

A S; B P; C Q; D R

27. Ans.
*

OH

4.76
1
M,
3
2
1
[CH3COONa] = 0.5
= M.
3
3
As both are equal, pH = pKa = 4.76

Hint : After mixing, [CH3COOH] =

19. Ans. (125 x) mL where x is small

Hint : The volume can be little more (or less)
than 125 mL depending on positive (or
negative) deviations from Raoult's law.

can be negative but numerically smaller

than x/298
Hint : It is because of the fact that for spontaneity
the value of G = (H TS) should < 0.
If S is ve the value of TS has to be
less that H
or value of S has to be less than H/T
i.e., x/298

28. Ans.

CCl3CHCH2OH
Cl

+
H2O + Cl2
Hint : CH2 = CH CCl3
CH2CHCCl3
+
I
(HOCl)

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EAR

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OH Cl

29. Ans. III > I > II

Hint : (I) complete octet and + ve charge on more
EN element
(II) Incomplete octet
(III) Complete octet and + ve charge on
less EN element
so order of stability III > I > II
Me

34. Ans. 24
Hint: First can be coloured for 3 ways and
remaining every can be coloured by 2 ways
Total ways 3 2 2 2 = 24
35. Ans. 1/2
Hint: (TH) (TTH) (TTT)
Required prob. =
1 1 1 1 1 1
1
+
2
2 2 2 2 2 2
= 4 =
1 1 1 1 1 1 1 1 1 4
+ +
2 2 2 2 2 2 2 2 2

Me
Me

30. Ans.
Hint :

OH

Me

OH

HNO2

Me

NH2

Me
..
Me
Me
Me

OH

H2O

Me

36. Ans. Assumend mean

Me

Hint: x is called assumed mean

37. Ans. ~q ~p

H shift

OH
OH

Me

Hint ~ q ~p (contrapositive statement)

OH

Me
Me
Me
Stable by resonance

38. Ans. e (

, 1)

Hint: Radius of the circle having

SS' as diameter is
y

Me
Me
Me

MATHEMATICS
s

31. Ans. AB =

s'

Hint: AB = (AB) (A B)
A

r = ae,
If it cuts an ellipse,
then r > b
ae > b ,
a2e2 > b2

A B =
32. Ans. 2

Hint: C1(1,1) r1 = 2
C2 (1,1) r2 = 2
C1C2 = 2 2 2.8

b2

e2 >

a2

e2 > 1e2

r2r1 = 2 2 0.6

e2 >

r2 + r1 = 2 + 2 3.4
r2 r1 < C1C2 < r1 + r2

e>

1
2
1

e(

, 1)

39. Ans. n + 2
33. Ans. (0, )

Hint: a x = t

Hint: D 0
cos2p 4sinp (cos p1) 0
cos2p + 4sinp (1cosp) 0
p (0, ) satifyies
(cos2 p 0 , sin p > 0, 1cos p > 0)

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(a t ) t

dt

a n +2
(n + 1)(n + 2)

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40. Ans. ( , 0) (0, 1] [2, )

(u + v)
i.e. x is given by x =
=
| AD | 2 cos
2

x 1
0, we have two cases
x 2{x}

Hint:

(i) x 1 x > 2{x} x 2

x [2, )
(ii) x 1 x < 2{x} x < 1, x 0
common part is x ( , 0) (0, 1)
finally x = 1 is also a part of domain.

AD

Statement (1) is false & statement (2) is true

44. Ans. statement-I is true but statement-II is false.

Hint:

x 1 y z + 2
=
=
= () ..(1)
1
1
2

P(1, 2, 4)

41. Ans. 12

Hint:
(1) Q

Any point on the line (1) is

( + 1, , 2 2)Q ( R)
Also PQ is perpendicular to the line (1)
1() + (1)(2)+ 2 (22) = 0
6 + (2) = 0
1
=
3

Externally
c1c2 = r1 + r2
length of direct common tangent
L.D.T =
=

(c1c 2 ) 2 (r1 r2 ) 2

( r1 + r2 ) 2 ( r1 r2 ) 2

= (4 + 9) 2 (4 9) 2 = 169 25 =12
42. Ans. coplanar and form triangle

a = i + 2 j + 3k

Hint: b = 2i j + k

c = 3i + j + 4k

PQ =

c = a+ b

Hint: In an isosceles triangle ABC in which

AB = AC, the median & the bisector from A must
be the same line
A

4
3

1
3

4
3

4 1
4

1 + 2 + + 4
3
3
3

1 49 64
114
+
+
=
9 9
9
9

Statement (1) is true but statement (2) is false

45. Ans. statement-I is false but statement-II is true

Hint: If
1
[a + (a + d) + (a + 2d) + .(a + 2nd)]
2n + 1
X = (a + nd)
M.D. from mean
M.D =

2n

1
| (a + rd) (a + nd) |
(2n + 1) r =0

M.D. =

1
(2n + 1)

u+ v
Now, AD =
2

1
2
2cos

2
2

So, | AD | = cos
2
Therefore, unit vector along AD

And | AD | 2 =

X =

1 2
3 3
2

43. Ans. statement-I is false but statement-II is true

1
3

Q + 1, , 2 = , ,

2n

| (r n) |d
r =0

n (n + 1)
M.D =
d
(2n + 1)
i. e, statement I is wrong
but statement II is correct

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46. Ans. statement-I is true but statement-II is false.

Hint: In =

tan

n 2

x (sec 2 x 1)dx

In =

tan

In =

(tan x )n 1 I

n 2

x sec x dx I n 2
2

n 1
Put n = 6

n 2

dy
dy
sin x 1 +
= cos x 1
dx
dx

dy
cos x sin x
=
order = 1
dx
sin x + cos x
degree = 1

48. Ans.

1
5

Hint: 3sin + 4cos = 5

sin cos = k (Let)
5 + 4k
then
= sin
7
5 3k
= cos
7
2

tan 5 x
I4 + I4 =
5
47. Ans. (1,1)

Hint:

51. Ans.

1
sq. unit
3

Hint:
y = x23x+2
1

O
y = x23x+2
2

= 2 ( x 2 3x + 2)dx

5 + 4k 5 3k

+
=1
7 7
25k2 + 10k +1 = 0
(5k+1)2 = 0 k = 1/5
52. Ans. (0, )

Hint: Let f(x) = sin x + x. cos xdx = x. sin x

& f(0) = f() = 0
0 & are 2 roots of f(x) = 0
So between (0, ) f '(x) = 0
sin x +x cos x = 0 has atleast one root
53. Ans. /4 < x < 3/8
Hint: f(x) = sin4x + cos4x
f '(x) = 4sin3x cosx 4cos3x sinx
f '(x) > 0
4sinx cosx (sin2x cos2x) > 0
sin4x < 0

< 4x < 2
<x<
4
2
54. Ans. x = 0
Hint: by graph

1
2

x 3 3x 2

=2
+
2x
2
1
3
=

1
sq. unit
3

49. Ans. 1
Hint: f(x) = f(x)
f '(x) = f '(x)
f "(x) = f "(x)
50. Ans. ln10(tanx + x. sec2x)

Hint: 10xtanx 10 x tan x

dx

=10xtanx[10xtanx log10(tanx + x sec2x)]

= log 10(tanx + x sec2x)

at x = 0 f(x) has vertical tangent where slope =

55. Ans. 1320

Hint: (x1)(x2) .(x 10)

= x10(1+2+3+.+10)x9 +
(1.2 + 1.3 + .... + 1(10)

+ 2.3 + .... + 2(10)

+ ...... x8

+ .....

+ 9(10)

8
Coeff of x = S
(1 + 2 + 3 + .... + 10) 2 (12 + 2 2 + .... + 10 2 )
=
2

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10 11 10 11 21
2

=
2
1
= 55 2 55 7 = 1320
2

60. Ans.6
Hint: for y2 = x
Latus rectum =
(3x 4 y 2) 2
9 + 16
Focus (3, 2), directrix 3x 4y 2 = 0
Now distance between focus and directrix
| 3(3) 4(2) 2 |
=
9 + 16

For (x3)2 + (y + 2)2 =

56. Ans. 5151

Hint: No of terms 100+31C31 = 102C2
102 101
=
=5151
2
57. Ans.11
Hint: 5A + 4B + 3C + 2D + E = (1)+'(1)
= 0 + (11)
= 11
58. Ans. y 3x + 9 = 0, 3y + x 3 = 0
Hint:
A(3, 0)

45

45
m=1/2

15
=3
5

L.R = 2(3) = 6
So = 6

PHYSICS
61. Ans. 0.506
Hint : At P, E1 = E2
kq1R
kq 2 (2R )
=
2
2 3/ 2
2
(R + R )
[R + ( 2R ) 2 ]3 / 2
q1
2 23 / 2
25 / 2
=
=
= 0.506
q2
53 / 2
53 / 2

Slope of required lines will be

1
1
tan 45
+ tan 45
2
and 2
1
1
1 + tan 45
1 tan 45
2
2
1

and 3
3
59. Ans. 32
2ab
Hint:
=8
a+b
2ab = 8 (a + b)
ab = 4(a + b)
A.M G.M
a + b 2 ab
ab

2 ab ab 8
4
ab 64
1
= ab
2
1
min = (64)
2
= 32

Q(q2 q1 )
4 0 R

1
1

10

Hint : W1 2 = Q (V2 V1)

kq
kq
kq1
kq 2
1 +
= Q 2 +
2
2 R
2
R
R + (3R )
R + (3R ) 2

62. Ans.

kQ(q 2 q1 )
1
1

R
10

63. Ans. 0.01 mm

Hint : LC count should be as least as possible
64. Ans. Spherometer
65. Ans. increase
Hint : If length increase, potential gradient
decrease so balance length increases.
66. Ans.

9R
0.65

1
1

R1 R 2
0.6 1
1 10
= (1.65 1)
=
9R
R 9R
9R
f=
0.65

Hint :

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1
= ( 1)
f

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67. Ans. 0.8 mm

(2n 1) ( 2 1 )
D
Hint : x =
2d
(2 1) (560 400) 10 9
=
1 = 0.8 mm
2 10 4

68. Ans. 3 : 4
0 I1
I
= 0 2
2r
2r 2
I
3
3
Where =
2 , hence 1 =
I2
4
4

Hint : B =

69. Ans. If both statement-I and statement-II are

true, and statement-II is the correct explanation
of statement-I.
Hint : A freely body is in state of weightlessness.
70. Ans. A Q, B P, C S, D S
F
Hint : F = const so a =
= constant so A Q
m
kx
{x decreases} so B P
For spring F = kx a =
m
Because there can not be friction for force equal to
zero.
CS;DS
71. Ans. a line perpendicular to the plane of rotation
Hint : Angular momentum is an axial vector
72. Ans. 2.5 m/s
Hint : Momentum of A =

M
3
4

M
Momentum of B =
4=M
4
A m = M/4 kg
v = 3 m/s

B
m = M/4 kg
v = 4 m/s

m = M/2 kg
v = v'

Resultant momentum

3M 2

5
2
=
M
+M =
4
4

Now C must have a momentum 5/4. M along OC

M
5

v' =
M or v' = 2.5 m/s
2
4

M m
73. Ans.
v
M +m
Hint : The total momentum before = (Mm)v
collision momentum after collision
= (M + m) V,
where V is the speed of composite body. Applying
the law of conservation of momentum, we have
(M + m) V = (M m) v
Mm
V=
v
M+m

74. Ans. 6/5

Hint : Given, y = kt2,

dy
= 2kt
dt

d2 y
= 2k = 2 1 = 2ms2
dt 2
So point of suspension of pendulum is moving
upwards with acceleration a = 2ms2
The effective acceleration due to gravity on
pendulum
g' = (g + a) = 10 + 2 = 12 ms2

and

T1 = 2

l
l
and T2 = 2
g
g'

g' 12
T12
6
=
=
=
2
g
10
5
T2

75. Ans. 84 cm, 28 cm, 21 cm

133 cm

Hint :
f1

l1

f2

l2

f3
l3

f1 : f 2 : f3 = 1 : 3 : 4
1 1
= 12 : 4 : 3
l1 : l2 : l3 = 1 : :
3 4
1
as f
l
On solving,
we get
l1 = 84 cm, l2 = 28 cm , l3 = 21 cm

76. Ans. If statement-I is false but statement-II is true.

77. Ans. 4 times
Hint : Vrms =
Vrms =

3RT
Mw

8 RT
V

Vrms Vav

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78. Ans.

NRT
4

Hint : initial energy = N

f
5NRT
RT =
2
2

N
particle dissociate so N particle becomes of
2
3
monatomic total of energy =
RTN
2
N
N 5
remains
diatomic =
RT
2
2 2
3
NRT
total final energy = N
RT + 5
2
4
11
=
NRT
4
11
5
1
heat required =
NRT
NRT =
NRT
4
9
4

79. Ans. V = 331 sin (100 t)

Hint : E = E0 sin t
voltage read in rms value

85. Ans. RC
Hint : The resistance in the middle plays no part in
the charging process of C, as it does not alter either
the potential difference across the RC combination
or the current through it.
86. Ans. their dimensions are very different
Hint : As the bulb and the heater have the same
power rating, they must radiate the same power.
The power radiated depends on the surface area
and the temperature of the filament. The filament
of the heater is much longer and thicker than that
of the bulb, and hence greater surface area. It can
therefore radiate the same power as the bulb, at a
temperature lower than that of the bulb.
87. Ans.

2
m
3

Hint : m

1
T

88. Ans. A Q; B S; C P; D R
Hint : [G] =

E0 = 2 234 volt
= 331 volt

[F][ L]2
and [] = [F] [L]
[ M ]2

and [P] = [M] [V] and [P] = [F] [L]2

and t = 2nt = 2 50 t
= 100 t
Thus, the equation of the line voltage is given by
E = 331 sin (100 t)

80. Ans. the stopping potential will be still 2.0 V

Hint : The no. of ejected photoelectrons is directly
proportional to the intensity of incident light.
Hence an increasing the intensity, the K.E of
photoelectrons will not change therefore stopping
potential will remain 2.0V

89. Ans. 10m, 6m, 1.2 m/s

Hint : (i) Distance traveled = |upper area under the
curve| + |Lower area under the curve|
(ii) Displacement = |upper area under the curve|
|lower area under the curve|
| displacment |
(iii) V avg. =
time inetrval

90. Ans. and J may or may not be in same

direction

81. Ans. A R, B Q, C Q, D P
Hint : Basic knowledge
82. Ans. 18, 8
18

Hint : 7X15 + 24 1P1 + 8 Y

83. Ans. Tellurium, germanium, silicon

Hint : As size of atom increases, energy gap
decreases
84. Ans. ln (10/9)
Hint : Q = Q0 (1 et/) = 0.1 Q0
or et/ = 0.9
or et/ = 10/9

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