Feed Stream

Component
Crystalline salicylic acid

Flow rate kg /hr

Temperature

2000 kg/hr

70

5000 L/hr

70

Liquid acetic anhydride (pure)

2

Liquid concentrated (95%)

phosphoric acid

22000 L/hr

70

???
4

acetylsalicylic acid
Water

????
22000

25

Outlet stream from the reactor

???

25

???

Mixer outlet Stream

Molar Mass (M.W) Melting Point

Boiling Point

Density

138.10

159

211

1.44

102.10

-73

139

1.08

98.00

21

158

1.68

180.20
18.00

135
0

140
100

1.35
1.00

Streaming heat Capacity

4.184 J/g C
1.67 J/g C
3.41 J/g C

Heat Balace

Flows: (kg/hr)
Crystalline salicylic acid

Processor Feed
2000

acetic anhydride (pure)

phosphoric acid
acetylsalicylic acid
Acetic Acid
Water
Total
Temp
Pressure (kPa)

5000
2100
0
0

70

Reactor Outlet

Mixer Outlet

70

Pump Outlet

Cooler Outlet

Seperator Outlet

Seperator Outlet

1251
5000
2705
8956

For hot fluid

side of a heat
exchanger let,
mH: mass
flow rate of
the hot fluid
in kg/hr
CpH: mass
heat capacity
of the hot
fluid in
Joules/kg0C
TiHand ToH:
Respectively
inlet and
outlet
temperatures
on exchanger
hot side in0C
mC: mass
flow rate of
the cold fluid
in kg/hr

CpC: mass
heat capacity
of the cold
fluid in
Joules/kg0C
TiCand ToC:
Respectively
inlet and
outlet
temperatures
on exchanger
cold side
in0C
Heat lost by
the hot fluid =
-Q = mH
CpH (ToHTiH) (1)
Heat gained
by the cold
side = Q =
mC CpC
(ToC- TiC)
(2)
Comparing
equations (1)
and (2),
mH CpH (TiH - ToH) = mC CpC (ToC - TiC) (3)

Gas Condensate PVT Analysis Workbook

Written by Robert Mott, August 2003
This worksheet analyses results from CVD and CCE tests on a gas condensate fluid
Data should only be entered on yellow cells
First enter CVD data (below the dew point) on the sheet 'CVD Data'
Then enter CCE relative volumes (above the dew point) on the sheet 'CCE Data'
Recovery factors for individual components and for stock tank oil and gas are shown on the sheet 'Recovery factors'
The sheet 'CVD analysis' contains material balance calculations which can be used as a consistency check of CVD data
These checks are described in 'Phase Behavior', SPE Monograph 20, by Whitson and Brule
The material balance checks calculate liquid phase densities and compositions.
Densities and K-values from the material balance calculation are displayed as charts.

Non-monotonic behaviour for the K-value or liquid density curves will cast some doubt on the validity of the CVD measuremen
If the liquid composition is measured at the end of the CVD, two other material balance checks can be used.
A 'Forward Material Balance' calculates the final liquid composition from the original composition, liquid saturations, Z-factors,
amounts of gas removed, and the gas compositions at each step.
A 'Backward Material Balance' calculates the original composition from the final liquid composition, final liquid saturation, final
Z-factor, the amounts of gas removed, and the gas compositions at each step. This is a better check for lean condensates.
The Material Balance checks are shown on the sheet 'Material Balance'.

JACK KNIFE 1
Nitrogen
Carbon
Methane
Ethane
Propane
Isobutane
n-Butane
2,2
Isopentane
n-Pentane
2,2
Cyclopentane
2,3

n-Hexane
Heptanes

Dioxide

Dimethylpropane

Dimethylbutane
Dimethylbutane
2 Methylpentane
3 Methylpentane
Plus

0
0
0.002
0.008
0.154
0.188
0.608
0.004
0.835
1.099
0.055
0
0.356
0.84
0.56
1.423
93.867

N2
CO2
H2S
C1
C2
C3
iC4
nC4
iC5
nC5
C6
C7+

0.000
0.000
0.000
0.002
0.008
0.154
0.188
0.608
0.839
1.099
3.234
93.867

CVD Data
The first pressure must be the dew point pressure
The number of pressure entries must be set to display the charts correctly
Number of pressure entries

Plus fraction

C7+

Pressure (psig)

5535

4500

3500

Wellstream produced (cum %)

Liquid volume (%)
Equilibrium gas Z-factor

0
0
1.0823

7.976
17
0.9202

21.98
22.842
0.8515

Equilibrium gas composition

N2
CO2
H2S
C1
C2
C3
iC4
nC4
iC5
nC5
C6
C7+

0.393
1.776
0.000
68.250
7.024
6.625
1.418
2.319
0.857
0.842
0.968
9.529

0.405
1.829
0.000
71.913
7.178
6.501
1.352
2.178
0.800
0.787
0.857
6.200

0.433
1.863
0.000
74.339
7.244
6.501
1.312
2.113
0.766
0.757
0.771
3.900

C7+ molecular weight

C7+ specific gravity

169.53
0.8163

149.703
0.8013

136.501
0.7897

Total composition

100.00

100.00

100.00

mol vol
Plus fraction prod
Cum moles

207.7

186.8
172.9
0.494512 0.546156
0 0.494512 1.040668
5.2%
10.9%

Vol prod
Cum vol

Initial moles
Vol

92.38728
94.404
92.38728 186.7913
4.7%
9.4%
9.529
1978.992

Equilibrium
Liquid
(last stage)

0.000
0.000
0.000
0.002
0.008
0.154
0.188
0.608
0.839
1.099
3.234
93.867

N2
CO2
H2S
C1
C2
C3
iC4
nC4
iC5
nC5
C6
C7+

189.3 C7+ molecular weight

0.8276 C7+ specific gravity
100.00

182.4085 Residual liq MW

No of pressures in CVD
N_pres

MW
Mwref
28.013
44.01
34.076
16.04
30.07
44.09
58.12
58.12
72.15
72.15
86.17

C7+ molecular weight

C7+ specific gravity

Residual liq MW

Density
(lb/ft3)

35.01
36.45
39.13
39.3
41.19

Plus fraction
3

1
2
3
4
5
6
7
8
9
10

N_plus
PlusFrac

Plus fraction
2
7
C7+

C6+
C7+
C8+
C9+
C10+
C11+
C12+

General Information
NS-1 fluid
Reservoir temperature (deg F)
Initial pressure (psig)

263
10440

Definition of oil for surface oil and

gas recoveries

C5+

CCE Data
only enter data at or above dew point pressure
enter pressures in descending order
Pressure
Relative
psig
volume
10440
0.83715
5535
1

C4+
C5+
C6+
C7+
Oil frac

Calculated oil gas ratio - assumes surface oil = C5+

Tstd
Pstd

520 deg R
14.7 psia

Forward material balance

Calculates residual liquid composition

Backward material balance

Calculates initial gas composition
Calculated density of residual liquid
Density to use in calculation

N2
CO2
H2S
C1
C2
C3
iC4
nC4
iC5
nC5
C6
C7+

Measured Calculated
0.00
0.20
0.00
1.33
0.00
0.00
0.00
37.28
0.01
5.89
0.15
7.28
0.19
1.96
0.61
3.37
0.84
1.32
1.10
1.28
3.23
1.97
93.87
38.12
100.00

100.00

N2
CO2
H2S
C1
C2
C3
iC4
nC4
iC5
nC5
C6
C7+

41.3
51.28

Measured Calculated
0.39
0.68
1.78
2.99
0.00
0.00
68.25
117.46
7.02
11.85
6.63
10.93
1.42
2.30
2.32
3.75
0.86
1.40
0.84
1.40
0.97
1.65
9.53
17.47
100.00

171.86

lb/ft3
lb/ft3
Calculated

0.8214

Recovery factors

Recovery factors from depletion, no water influx

100.0%
90.0%
80.0%
70.0%
60.0%
50.0%
40.0%

C1

C2

C3

C4's

C5's

C6

C7+

Gas

Oil

30.0%
20.0%
10.0%
0.0%
12000

10000

8000

6000

4000

abandonment pressure (psig)

2000

OGR (bbl/MMscf)

Calculated oil gas ratio - assumes surface oil = C5+

250.00

200.00

150.00

100.00

50.00

0.00
3000

3500

4000

4500

pressure (psia)

5000

5500

6000

K-values calculated from material balance analysis of CVD data

10.0000
CO2
C1
C2
C3
iC4
nC4
iC5
nC5
C6
Row
126
Row
127
Row
128
Row
129

1.0000

0.1000

0.0100
3000

3500

4000

4500

pressure (psia)

5000

5500

6000

Oil and Gas Densities calculated from material balance analysis of CVD data

density (Kg/m3)

700.00

600.00

500.00

400.00

300.00

liquid density
(kg/m3)
gas density (kg/m3)

200.00

100.00

0.00
3000

3500

4000

4500

pressure (psia)

5000

5500

6000

Calculated modified black oil properties

Pressure (psia)
Pressure (psia)
Moles of Gas
up to C3
C4
C5
C6
Gas volume at surface
(ft3/mol of equil gas)

Moles of oil
iC4
nC4
iC5
nC5
C6
C7
C8
C9
C10
C11
C7+
Volume of Oil
iC4
nC4
iC5
nC5
C6
C7
C8
C9
C10
C11
C7+
Oil volume at surface (ft3/mol
of equil gas)
Oil-gas ratio (bbl/MMscf)
GOR (scf/STB)
Gas FVF (res bbl/Mscf)

5535
5549.7

4500
4514.7

3500
3514.7

84.068
3.737
0
0

87.826
3.53
0
0

90.38
3.425
0
0

333.339

346.820

356.117

0
0
0.857
0.842
0.968
0
0
0
0
0
9.529

0
0
0.8
0.787
0.857
0
0
0
0
0
6.2

0
0
0.766
0.757
0.771
0
0
0
0
0
3.9

0.0000
0.0000
0.0158
0.0155
0.0203
0.0000
0.0000
0.0000
0.0000
0.0000
0.3171

0.0000
0.0000
0.0148
0.0144
0.0179
0.0000
0.0000
0.0000
0.0000
0.0000
0.1856

0.0000
0.0000
0.0141
0.0139
0.0161
0.0000
0.0000
0.0000
0.0000
0.0000
0.1080

0.3687

0.2328

0.1522

196.98
5077
0.8082

119.53
8366
0.8118

76.11
13138
0.9397

Carbon_no
4
5
6

4
4
5
5
6
7
8
9
10
11
7
MW
58.12
58.12
72.15
72.15
86.17
100.2
114.2
128.3
142.3
156.3

Carbon_no

Density
(lb/ft3)
35.01
36.45
39.13
39.30
41.19
42.58
44.19
45.35
45.68
46.00

Calculated recovery factors

Calculated recovery factors for each component
Abandonment pressure (psia)

10440

5535

4500

3500

2500

1700

Component
C1
C2
C3
C4's
C5's
C6
C7+

0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%

#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!

#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!

#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!

#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!

#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!

Gas
Oil

0.0% #VALUE! #VALUE! #VALUE! #VALUE! #VALUE!

0.0% #VALUE! #VALUE! #VALUE! #VALUE! #VALUE!

Moles produced at each step

N2
CO2
H2S
C1
C2
C3
iC4
nC4
iC5
nC5
C6
C7+

0
0
0
0
0
0
0
0
0
0
0
0

0.032
0.146
0.000
5.736
0.573
0.519
0.108
0.174
0.064
0.063
0.068
0.495

0.061
0.261
0.000
10.410
1.014
0.910
0.184
0.296
0.107
0.106
0.108
0.546

0.079
0.342
0.000
13.586
1.342
1.169
0.234
0.380
0.130
0.129
0.126
0.468

0.071
0.315
0.000
12.391
1.242
1.059
0.216
0.344
0.112
0.111
0.105
0.326

Moles of gas produced

up to C3
C4
C5
C6
Total
Cumulative total

0.000
0.000
0.000
0.000
0.000
0.000

7.005
0.282
0.000
0.000
7.287
7.287

12.657
0.480
0.000
0.000
13.136
20.423

16.518
0.614
0.000
0.000
17.132
37.555

15.079
0.560
0.000
0.000
15.639
53.194

Moles of oil produced

iC4
nC4
iC5
nC5

0.000
0.000
0.000
0.000

0.000
0.000
0.064
0.063

0.000
0.000
0.107
0.106

0.000
0.000
0.130
0.129

0.000
0.000
0.112
0.111

C6
C7+

0.000
0.000

0.068
0.495

0.108
0.546

0.126
0.468

0.105
0.326

Volume of oil produced (ft3/mol of equil gas)

iC4
nC4
iC5
nC5
C6
C7+
Total
Cumulative total

0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

0.000
0.000
0.001
0.001
0.001
0.015
0.019
0.019

0.000
0.000
0.002
0.002
0.002
0.015
0.021
0.040

0.000
0.000
0.002
0.002
0.003
0.012
0.020
0.059

0.000
0.000
0.002
0.002
0.002
0.008
0.014
0.074

900

#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!

#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!

#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!

#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!

#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!

V_Pinit
V_Pdew
N_init

#VALUE! #VALUE! #VALUE! #VALUE! #VALUE!

#VALUE! #VALUE! #VALUE! #VALUE! #VALUE!

0.076
0.344
0.000
13.220
1.361
1.258
0.259
0.418
0.144
0.135
0.124
0.354

0.067
0.321
0.000
11.960
1.428
1.610
0.396
0.645
0.241
0.229
0.252
2.745

0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

16.259
0.676
0.000
0.000
16.935
70.129

15.385
1.041
0.000
0.000
16.426
86.555

0.000
0.000
0.000
0.000
0.000
86.555

0.000
0.000
0.000
0.000
0.000
86.555

0.000
0.000
0.000
0.000
0.000
86.555

0.000
0.000
0.144
0.135

0.000
0.000
0.241
0.229

0.000
0.000
0.000
0.000

0.000
0.000
0.000
0.000

0.000
0.000
0.000
0.000

Carbon_no
4
5
6

4
4
5
5

Initial gas
84.068
3.737
0.000
0.000
87.805

Initial oil
0.000
0.000
0.857
0.842

0.124
0.354

0.252
2.745

0.000
0.000

0.000
0.000

0.000
0.000

0.000
0.000
0.003
0.002
0.003
0.009
0.016
0.090

0.000
0.000
0.004
0.004
0.005
0.074
0.088
0.178

0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.178

0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.178

0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.178

6
7

0.968
9.529

0.000
0.000
0.016
0.015
0.020
0.317
0.369

#VALUE!
#VALUE!
#VALUE!

Initial gas

MW
58.12
58.12
72.15
72.15
86.17
Initial oil

Density
(lb/ft3)
35.01
36.45
39.13
39.3
41.19

temperature (deg R)

Tres

722.67 deg R

pressure (psia)

5549.7

4514.7

3514.7

wellstream produced (cum fraction)

liquid volume (fraction)
eq gas Z-factor

Np
SL
Z

0
0
1.0823

0.07976
0.17
0.9202

0.2198
0.22842
0.8515

Produced gas phase composition

N2
0.393
CO2
1.776
H2S
0
C1
68.25
C2
7.024
C3
6.625
iC4
1.418
nC4
2.319
iC5
0.857
nC5
0.842
C6
0.968
C7
0
C8
0
C9
0
C10
0
C11
0
C7+
9.529

0.405
1.829
0
71.913
7.178
6.501
1.352
2.178
0.8
0.787
0.857
0
0
0
0
0
6.2

0.433
1.863
0
74.339
7.244
6.501
1.312
2.113
0.766
0.757
0.771
0
0
0
0
0
3.9

gas phase composition

MW_plus

169.53

149.703

136.501

MW_gas

37.259

30.695

26.987

vol of 1 lb mole (ft3)

Gas density (lb/ft3)
Gas density (Kg/m3)

V
gas density (lb/ft3)
gas density (kg/m3)

1.5125
24.634
394.58

1.5808
19.417
311.03

1.8790
14.363
230.06

Lb Moles gas produced

Vol of gas in cell
Lb moles of gas in cell
Lb moles of liquid

Ngas_p
Vgas
Ngas
Nliq

0
1.5125
1.0000
0.0000

0.07976
1.2554
0.7942
0.1261

0.14004
1.1670
0.6211
0.1591

Mass removed
Mass of gas in cell
Mass of liquid
MW of liquid

Mgas_p
Mgas
Mliq

0.000
37.26
0.00

2.448
24.38
10.43
82.75

3.779
16.76
14.27
89.69

Liquid density (lb/ft3)

Liquid density (Kg/m3)

liquid density (lb/ft3)

liquid density (kg/m3)

40.58
650.00

41.30
661.57

moles of each component

remaining in cell

N2
CO2

0.361
1.630

0.300
1.369

0.393
1.776

(after extra gas has been removed)

moles of liquid in cell

MW of C7+ fraction in liquid

H2S
C1
C2
C3
iC4
nC4
iC5
nC5
C6
C7
C8
C9
C10
C11
C7+

0
68.25
7.024
6.625
1.418
2.319
0.857
0.842
0.968
0
0
0
0
0
9.529

0.000
62.514
6.451
6.106
1.310
2.145
0.793
0.779
0.900
0.000
0.000
0.000
0.000
0.000
9.034

0.000
52.104
5.437
5.196
1.126
1.849
0.686
0.673
0.792
0.000
0.000
0.000
0.000
0.000
8.488

Total

100.001

92.025

78.021

N2
CO2
H2S
C1
C2
C3
iC4
nC4
iC5
nC5
C6
C7
C8
C9
C10
C11
C7+

0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

0.039
0.178
0.000
5.404
0.751
0.944
0.236
0.416
0.158
0.154
0.219
0.000
0.000
0.000
0.000
0.000
4.111

0.031
0.212
0.000
5.932
0.938
1.158
0.312
0.537
0.210
0.203
0.313
0.000
0.000
0.000
0.000
0.000
6.066

Total

0.000

12.610

15.912

#VALUE!

#VALUE!

Calculated liquid phase composition (mol %)

N2
0.31
CO2
1.41
H2S
0.00
C1
42.86
C2
5.96
C3
7.48
iC4
1.88
nC4
3.30
iC5
1.25
nC5
1.22
C6
1.74
C7
0.00
C8
0.00

0.20
1.33
0.00
37.28
5.89
7.28
1.96
3.37
1.32
1.28
1.97
0.00
0.00

C9
C10
C11
C7+

0.00
0.00
0.00
32.60

0.00
0.00
0.00
38.12

1.3073
1.2985
#DIV/0!
1.6779
1.2051
0.8687
0.7210
0.6608
0.6390
0.6434
0.4933
0.1902

2.2137
1.3975
#DIV/0!
1.9941
1.2291
0.8930
0.6701
0.6261
0.5800
0.5932
0.3922
0.1023

Backward material balance calculation

Calculate original gas composition from residual liquid and produced gas compositions
4514.7

3514.7

K-values
N2
CO2
H2S
C1
C2
C3
iC4
nC4
iC5
nC5
C6
C7+

N2
CO2
H2S
C1
C2
C3
iC4
nC4
iC5
nC5
C6

C7+

0.6781
2.9855
0.0000
117.4593
11.8481
10.9277
2.3009
3.7464
1.4046
1.3990
1.6455
0.0000
0.0000
0.0000
0.0000
0.0000
17.4683

0.0323
0.1459
0.0000
5.7358
0.5725
0.5185
0.1078
0.1737
0.0638
0.0628
0.0684
0.0000
0.0000
0.0000
0.0000
0.0000
0.4945

0.0606
0.2609
0.0000
10.4104
1.0144
0.9104
0.1837
0.2959
0.1073
0.1060
0.1080
0.0000
0.0000
0.0000
0.0000
0.0000
0.5462

171.8634

7.9760

14.0039

UGC

Vcell
Init mass

10.732

1.513
37.26

Measured
liquid
composition
189.3

0.00
0.00
0.00
0.00
0.01
0.15
0.19
0.61
0.84
1.10
3.23
0.00
0.00

0.00
0.00
0.00
93.87

Residual gas Residual liquid

0.2921
1.2570
0.0000
50.1560
4.8875
4.3862
0.8852
1.4256
0.5168
0.5107
0.5202
0.0000
0.0000
0.0000
0.0000
0.0000
2.6313

0.0000
0.0000
0.0000
0.0002
0.0008
0.0162
0.0198
0.0641
0.0885
0.1160
0.3412
0.0000
0.0000
0.0000
0.0000
0.0000
9.9036

67.4687

10.5506

Moles of residual liquid

Gas molar vol
Liq molar vol
Total moles
Liq sat
Liq mole frac

1.8790
3.5571
0.7802
0.2284
0.1352

Moles resid liq

Moles_resid_gas

0.1055
0.6747