CHEMISTRY

4541/2
SULIT

Name:

Class:

SMK CHUNG HUA MIRI

PEPERIKSAAN PERCUBAAN 1 SPM 2014
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CHEMISTRY
PAPER 2
2 HOURS 30 MINUTES
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SECTION A [60 marks]
Answer all questions in this section.
1. Table 1 shows the melting point and boiling point of three substances.
Substance Melting point, C
Boiling point, C
P
- 42
-10
Q
65
110
R
200
450
Table 1

(a) Based on table 1, answer the following questions.

(i) What is the physical state of Q at 80C?
____________________________________________________________________________________________
[1 mark]
(ii) Draw the arrangement of particles of R at room temperature.

Substance R
[1 mark]
(iii) The particles of which substance have the highest kinetic energy at 10C?
____________________________________________________________________________________________
[1 mark]
(b) Table 2 shows a list of elements represented by letters U, V, W, X, Y and Z with their nucleon numbers and proton
numbers.
Symbol
U
V
W
X
Y
Z
Nucleon number
12
4
19
23 40 39
Proton number
6
2
9
11 18 19
Table 2

Based on Table 2, answer the following questions.

(i) List the elements that are members of the same period in the Periodic Table.
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[1 mark]
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(ii) Name the element that exists as diatomic molecule.

_______________________________________________________________________________________________
[1 mark]
(iii) Arrange the elements U, V, W, X, Y and Z in order of increasing atomic size.
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[1 mark]
(iv) Explain the position of Y in the Periodic Table of Elements.
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[2 marks]
(v) The reaction between element X and water is less reactive than the reaction between element Z and water. Explain
the situation.
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[3 marks]

2.

(a) Table 3 shows the electrical conductivity and melting point of substance D,E and F
Substance
Electrical conductivity in the state of
Melting point/ C
Solid
Molten
Aqeous
D
No
No
No
< -120
E
No
No
No
80 - 90
F
No
Yes
Yes
> 900
Table 3

(i) Explain why substance D has a low melting point.

_______________________________________________________________________________________________
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[2 marks]
(ii) State how the bonds are formed in substance E.
_______________________________________________________________________________________________
[1 mark]
(iii) State the types of particle and bonding of substance E.
Particle: ____________________
Bonding: ___________________
[2 marks]

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(b) Diagram 1 shows the electrolysis of molten substance F.

The results of the experiment above are shown in Table 4.
Electrode
Anode
Cathode

Observation
A pungent brown gas that changes damp blue litmus paper to red before
bleaching it is released.
Brown solid is deposited
Table 4

(i) Suggest the name of substance F.

_______________________________________________________________________________________________
[1 mark]
(ii) Substance F is an electrolyte. State the meaning of electrolytes.
_______________________________________________________________________________________________
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[1 mark]
(iii) Write the half-equation at cathode.
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[1 mark]
(iv) State the name of the products formed at anode and cathode.
Anode: _______________________________

Cathode: ____________________________
[2 marks]

3.

(a) Diagram 2 shows the set-up of apparatus to prepare salt X.

Diagram 1

(i) Name the salt X.

_______________________________________________________________________________________________
[1 mark]
(ii) Write a balanced equation for the reaction.
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[1 mark]

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(iii) State the colour change of the phenolphthalein during the titration process.
_______________________________________________________________________________________________
[1 mark]
(iv) 25 cm3 of 1.0 mol dm-3 sodium hydroxide solution was titrated with 1.0 mol dm-3. Calculate the volume of
sulphuric acid required to react completely with the sodium hydroxide solution.

[2 marks]
(c) The sting of a jelly-fish is alkaline and causes pain.
Suggest one substance that can be applied to the skin to relieve the pain without causing further injury. Give reason for
your suggestion.
_______________________________________________________________________________________________
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[2 marks]
(b) Sulphuric acid is a strong acid. Table 5 shows two solution of sulphuric acid Y and Z, of different concentrations.
Sulphuric acid solution Concentration(mol dm-3)
Y
0.100
Z
0.001
Table 5

Solutions Y and Z have different pH values.

(i) State the meaning of an acid.
_______________________________________________________________________________________________
[1 mark]
(ii) Which solution gives a lower pH value?
_______________________________________________________________________________________________
[1 mark]
(iii) Give one reason for the answer in (b)(ii)
_______________________________________________________________________________________________
[1 mark]
4.

Diagram 3 shows a series of reactions of lead(II) carbonate.

Lead(II) carbonate

heat
I

Residue A

Dilute nitric acid

Colourless gas B

II
Potassium iodide solution

Solution C

III

Diagram 3

Precipitate X

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(a) Give two chemical substances that can be used to prepare lead(II) carbonate in the laboratory.
_______________________________________________________________________________________________
[2 marks]
(b)(i) Draw a labelled diagram of the set-up apparatus can be used to identify the gas B in step I.

[2 marks]
(b)(ii) Write the chemical equation for the decomposition of lead(II) carbonate when heated.
_______________________________________________________________________________________________
[1 mark]
(b)(iii) 13.35 g of lead(II) carbonate is heated to decompose completely, calculate the mass of residue A produced.
[Relative atomic mass: Pb=207, C=12, O=16]

[2 marks]
(c) (i) State the colour of precipitate X.
_______________________________________________________________________________________________
[1 mark]
(ii) What is the ion that give the colour stated in e(i)?
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[1 mark]

5. The following information is about a compound which has a molecular formula of CH 3CH2COOCH3.

Two layers of colourless liquid are formed

Has a pleasant smell

(a) What is the name of this compound?

_______________________________________________________________________________________________
[1 mark]
(b) State the name of reaction that involved in producing this compound.
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[1 mark]

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(c) Compound CH3CH2COOCH3 can be prepared from a reaction between compound K and compound L.
(i) Draw the structural formulae of compound K and compound L.

[2 marks]
(ii) Reaction of compound L with zinc metal will produce colourless gas, describe a chemical test to determine the
colourless gas produced.
_______________________________________________________________________________________________
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[2 marks].
(d) The following information is about an organic compound J.
Empirical formula is CH2O
Relative molecular mass is 60
Reacts with calcium carbonate to produce a type of gas that turns lime water chalky
Based on the information given:
(i) Determine the molecular formula of compound J.
[Relative atomic mass: C=12, H=1, O=16]

[2 marks]
(ii) State the name of homologous series for compound J and explain your answer.
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[2 mark]
6. Diagram 4 shows the set-up of apparatus to investigate a redox reaction. After a few minutes, the iron(II) sulphate
solution changes from light green to brown.

Diagram 4

(a) Iron(II) sulphate solution changes from light green to brown due to the formation of a certain metal ion.
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(i) Name the metal ion formed.

_______________________________________________________________________________________________
[1 mark]
(ii) Write the half-equation for the formation of the metal ion.
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[1 mark]
(iii) State the type of reaction involved in the formation of the metal ion. Explain your answer in terms of the electron
transfer.
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[2 marks]
(b) Acidified potassium manganate(VII) solution undergoes a certain reaction too.
(i) State the colour change of acidified potassium manganate(VII) solution.
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[1 mark]
(ii) What is the role of acidified potassium manganate(VII) solution in this reaction?
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[1 mark]
(iii) By referring to the reaction that takes place in acidified potassium manganate(VII) solution, calculate the
oxidation number of manganese in manganate(VII) ion, MnO4.

[1 mark]
(c) Draw the arrows to show the direction of electron flow across the galvanometer in Diagram 4.
[1 mark]
(d) Name one chemical that can replace acidified potassium manganate(VII) solution for a similar reaction to occur.
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[1 mark]
(e) State the function of the dilute sulphuric acid in Diagram 4.
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[1 mark]

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SECTION B
[20 MARKS]
Answer any one question in this section.

7.
(a) State two factors affecting the rate of reaction.
[2 marks]
(b) A group of students carried out an experiment to determine the rate of reaction between 50 cm 3 of 0.1 mol dm-3
nitric acid and excess calcium carbonate powder at room temperature. The reaction was completed within 300 seconds.
(i) Calculate the maximum volume of carbon dioxide expected to be released at room conditions.
[Relative atomic mass: H=1, C=12, O=16, Ca=40, N=14, molar volume of gas at room conditions is 24 dm 3]
[3 marks]
(ii) Calculate the overall rate of reaction.
[1 mark]
(iii) Diagram 5 shows the graph of volume of carbon dioxide evolved from the reaction.

Diagram 5

By referring to the graph, explain the rate of reaction at the point X, Y and Z.
[3 marks]
(c) Three experiments were conducted to investigate the reaction between hydrochloric acid and zinc metal. Table 6
shows the quantities of the substances used, temperature and time taken to collect 30 cm 3 of the gas released.
Experiment
I
II
III
Quantities of
25.0 cm3 of 0.5 mol dm-3
25.0 cm3 of 0.5 mol dm-3
25.0 cm3 of 0.5 mol dm-3
substances
hydrochloric acid and 2.0 g hydrochloric acid and 2.0 g hydrochloric acid and 2.0 g
of zinc powder
of granular zinc
of granular zinc
Temperature of the
30
30
50
mixture, C
Time,s
10.0
16.0
11.0
Table 6

Based on the information in Table 5, compare the rate of reaction between

(i) Experiment I and Experiment II
(ii) Experiment II and Experiment III
Explain your answer by using the collision theory
[8 marks]
(iii) Sketch the graph of the total volume of gas collected against time for Experiment II and Experiment III on the
same axes.
[3 marks]

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8. (a) The flowchart in Diagram 6 shows the industrial process for the manufacture of sulphuric acid by the Contact
process.
Stage I
S

Stage II
SO2

Stage III
SO3

Stage IV
H2S2O7

H2SO4

Diagram 6
(i) Based on the information in Diagram 6, explain all the four stages of the process of manufacturing sulphuric acid in
industry.
[7 marks]
(ii) State two uses of sulphuric acid.
[2 marks]
(b) Table 7 shows three different composite materials, V, W and X and their uses.
Composite materials
V
W
X

Uses
Used in bridges and highway
Used in computer chips and
transformers
Used in water storage tanks and
small boats
Table 7

Based on Table 6, state the names of V, W and X.

Give one of the properties of each substance to support your answers.
[6 marks]
(c) Glass and ceramics are two industrial products that have some common similarities as well as the differences.
(i) Give two similarities between glass and ceramics.
[2 marks]
(ii) State any type of glass, one of its property and one of its uses.
[3 marks]

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SECTION C
[20 MARKS]
Answer any one question in this section.
9. (a) Diagram 7 shows some of the apparatus and chemicals given to a student to set-up a simple chemical cell in the
school laboratory.

solution

Diagram 7
(i) State the energy change in the chemical cell.
[1 mark]
(ii) Draw a labeled diagram to show the simple chemical cell that can be constructed by using the apparatus and
chemicals in Diagram 7.
[2 marks]
(iii) Describe the reactions that occur at the negative terminal and positive terminal of the chemical cell. Include the
following aspects in your explanation: The terminal of the electrode
Half equation for the reaction
Explanation about the intensity of the solution
[6 marks]
(b) You have a ring that is made of aluminium. To improve its appearance, you want to electroplate it with silver.
Describe how you would do this in the laboratory. Your description should include the following aspects:
i.
List of materials and apparatus
ii.
Procedure of the experiment
iii.
Half equation involved in the reaction
iv.
Observations at both electrodes
[11 marks]

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10.
(a) Diagram 8 shows a water droplet on a piece of iron.

Diagram 8

Based on Diagram 8, describe the reactions that take place at the edge of water droplet (cathode) and centre of water
(anode) during the rusting of iron. Include the half equations in your description.
[4 marks]
(b) Diagram 9 shows the reaction between potassium iodide solution and liquid bromine.

Diagram 9

Explain the reaction that occurs in both potassium iodide solution and liquid bromine. Explain your answer based on
the following aspects:
The change in oxidation number for both reactants
The type of reaction that has occurred to each reactant.
The role of each reactant in the redox reaction
[6 marks]
(c) You are asked to determine the position of metal in the reactivity series based on their reaction with oxygen gas.
You are provided with the chemicals such as magnesium powder, zinc powder, copper powder and solid potassium
manganate(VII). Briefly describe the experiment and your description should include the following:
i.
The diagram of the set-up apparatus
ii.
The procedure of the experiment
iii.
Chemical equations for the reactions
[10 marks]

END OF QUESTION PAPER

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