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ii
1 D
CO2
2 C
ideal gas
PV
3 A
4 D
5 C
7 A
9 A
10 C
11 a An oxidising agent gains electrons and the oxidation
number of its element decreases.
[2]
b i
c i
c i
8 B
P (atm)
6 D
I
iii Br2
Gains electrons more readily than X
Br2 + 2e 2Br
[1]
[1]
[1]
[1]
[1]
[1]
= 71
[1]
b i
2C
[2]
[1]
[1]
[2]
[2]
n =
8.31 225
= 0.0132 mol
mass
ii Relative molecular mass = _____
mole
0.94
= _______
0.0132
5
3H2
Hf(C2H6)
2Hf(CO2) 3Hf(H2O)
C2H6
HC(C2H6)
+1560 kJ mol1
2CO2
3H2O
arrow reversed
so sign changes
[2]
ii H (C2H6) = 2
H (CO2) + 3H (H2O)
H (C H6)
= (2 393) + (3 286) (1560)
= 84kJmol1
[2]
c i
c
2
[1]
energy kJ
Hr
1000
25
= 0.044moldm3
Hsolnve
endothermic
iv
NH4NO3(S)+aq
iv
NH4NO3(aq)
Hp
reaction pathway
[4]
E = mcT
= 100 4.2 12.2
= +5124J
= +5.12kJ
16
Number of moles of ammonium nitrate = ___
80
= 0.2 mole
0.2 mole produces 5.12kJ
Therefore 1 mole produces
5.12
____
= +25.60kJmol1
0.2
b i
[1]
[1]
C
H
O
26.67
2.22
71.11
26.67
2.22
71.11
No. of moles ______
_____
_____
12
1
16
= 2.22
= 2.22 = 4.44
2.22
2.22
4.44
Mole ratio _____
_____
_____
2.22
2.22
2.22
1
:
1
:
2
Empirical formula is CHO2
To calculate molecular formula
n(CHO2) = 90
n(45) = 90
n=2
Molecular formula is therefore C2H2O4.
[2]
Colourless to pink
[1]
c i
[ ]
b i
[2]
[1]
ii
] [ ] [ ]
[1]
[ ] [ ]
[1]
[1]
[1]
21.5
1000
= 0.00043 mole [1]
From the mole ratio:
2 moles potassium manganate(vii)
reacts with 5 moles oxalic acid
Therefore 0.00043 moles potassium
manganate(vii) reacts with
5 0.00043
____________
[1]
2
= 0.0011 mole
[1]
molar
molar
mass
=
concentration concentration mass
= 0.044 90
= 3.96gdm3
[1]
ii Mg(g) Mg+(g) + e
ii
Mass in 100g
15 a i
[1]
[1]
c i
ionisation energy
1 2 3 4 5 6
number of electrons
removed
c E
cell = +0.72V
5Ag(s) + MnO4(aq) + 8H+(aq)
5Ag+(aq) + Mn2+(aq) + 4H2O(l)
1 D
2 A
4 D
5 D
6 B
7 B
Cl ions from the salt bridge would react with Ag+ ions
in the anode compartment to produce a precipitate of
AgCl, which would affect ionic mobilities and therefore
the cell function.
[2]
13 a i
8 C
9 D
10 B
b i
Initial pH = 3.0
at equilibrium [H+] = 1 103, [acid]
= 0.112 1 103 = 0.111
3 2
(1 10 )
Ka = __________
= 9.0 106moldm3
0.111
[1]
b i
[3]
[1]
e i
[3]
pH = 3.5
[1]
[reactant]
[2]
3 B
[2]
time
Draw a tangent to the curve at t = 0, then find the
gradient of the tangent.
[2]
[1]
(0.125moldm3 ) (0.125moldm3 )2
[2]
= 7.42dm6mol2s1
Ag(aq)
(1 mol dm3)
Pt(s)
[cathode]
[2]
Mn2(aq)
(1 mol dm3)
Ag(s)
[anode]
v Rate = ( 7.42dm6mol2s1)(0.30moldm3)
(0.14moldm3)2
= 0.044moldm3s1
b i and ii
V
H(aq)
MnO4(aq)
(1 mol dm3)
[5]
7 a i
1 D
2 C
3 B
4 D
[2]
ii
[4]
[2]
2
A metal which forms at least one ion with a
partially filled d sub-shell.
[2]
3+
c i
b i
b i
[2]
2+
6 a i
2+
5 A
c i
[3]
[1]
2+
2+
b i
10 a
state
gas
Element/
symbol
F
solid
Cl
Br
I
b.pt.
density
Increasing
[2]
b i
[2]
[2]
Cl2 + 2e 2Cl
E = +1.36V
Br2 + 2e 2Br
E = +1.07V
I2 + 2e 2I
E = +0.54V
From the above electrode potentials, the ease with
which the halogen accepts electrons (oxidising agent)
decreases as the group is descended; the +ve character
of E decreases.
[3]
[1]
[2]
[1]
iv Ba(OH)2(aq) + 2HNO3(aq)
Ba(NO3)2(aq) + 2H2O(l)
[2]