Escolar Documentos
Profissional Documentos
Cultura Documentos
SOHAIMI KLING
MAY 2007
ii
Signature
Name
Date
iii
iv
ACKNOWLEDGEMENT
ABSTRACT
bagi
Treatment Vol. 4
jenis
pembangunan
(kediaman,
perdagangan,
perindustrian
dan
vi
pembangunan bercampur). Selain itu, kajian ini, akan seterusnya menentukan
perbezaan ciri-ciri air-sisa bedasarkan pembangunan dengan saiz yang berbeza. Ini
akan menjadi asas kepada penetapan garispanduan akan datang, yang boleh
mendorong kepada penambahbaikan serta menghasilkan rekabentuk optima bagi
proses rawatan air sisa domentik.
vii
ABSTRACT
viii
TABLE OF CONTENTS
CHAPTER
II
TITLE
PAGE
DECLARATION
ii
DEDICATION
iii
ACKNOWLEDGEMENT
iv
ABSTRACT
TABLE OF CONTENTS
viii
LIST OF TABLES
LIST OF FIGURES
xi
LIST OF ABBREVIATIONS
xii
LIST OF SYMBOLS
xiii
INTRODUCTION
1.1
Background
1.2
1.3
Scope of Study
LITERATURE REVIEW
2.1
2.2
In-pipe treatment
11
2.3
2.4
practices
13
15
ix
III
2.5
16
2.6
19
METHODOLOGY
3.1
3.2
3.3
IV
21
22
3.4
Sampling
22
3.5
Elimination of outliers
23
4.1
24
4.1.1
24
4.1.2
26
4.1.3
27
4.1.4
29
4.1.5
30
4.2
4.3
32
21
36
CONCLUSIONS
5.1
5.2
44
Recommendations
46
REFERENCES
47
Appendices
51
LIST OF TABLES
TABLE NO
Table .1.1
TITLE
Table 2.1
34
Table 5.1
32
Table 4.3
10
Table 4.2
Table 4.1
Table 2.2
PAGE
37
45
xi
LIST OF FIGURES
TABLE NO
TITLE
PAGE
Figure 4.1
25
Figure 4.2
BOD Percentile
25
Figure 4.3
26
Figure 4.4
COD Percentile
27
Figure 4.5
28
Figure 4.6
AMN Percentile
28
Figure 4.7
SS Concentration range
29
Figure 4.8
SS Percentile
30
Figure 4.9
pH Concentration range
31
Figure 4.10
pH Percentile
31
Figure 4.11
Figure 4.12
35
38
Figure 4.13
39
Figure 4.14
40
Figure 4.15
41
Figure 4.16
42
Figure 4.17
42
xii
LIST OF ABBREVIATIONS
A/ITI
Alkalinity
AMN
Ammonical Nitrogen
BOD
COD
DOE
Department of Environment
GDV
IWK
MS
Malaysian Standard
PE
Population Equivalent
pH
Hydrogen-ion concentration
SS
Suspended Solid
SSD
STP
UTM
xiii
LIST OF SYMBOLS
mg/l
l/p/d
CHAPTER I
INTRODUCTION
1.1 Background
2
Therefore, new plants under Category 1 shall be designed to meet either Standard A
or B based on compliance to the proposed revised effluent standard in Table 1.1
shown below.
Table 1.1: Proposed revised effluent discharge standard for Category 1 STP.
Parameter
(mg/l )
Effluent Discharge to
River/Stream
Effluent Discharge to
Stagnant Water Bodies**
Standard A
Standard B
Standard A
Standard B
BOD5
20
50
20
50
SS
50
100
50
100
COD
120
200
120
200
AMN
10
20
Nitrate
Nitrogen
Phosphorus
20
50
10
10
na
na
10
O&G
10
10
Currently, data with regards to the characteristics of raw sewage in the country is
based on MS 1228, which emphasizes on 2 main parameters i.e. 250 mg/l BOD, and
300 mg/l SS as design parameters. However, no local in-depth studies have been
carried out to verify the characteristics of raw sewage in the country.
Differences in the constituents that are generated from various types of development
have not been determined to observe its significance. Similarly, no record has ever
been initiated to determine the variables that influence the domestic wastewater
generated from difference sizes of developments. Estimation of wastewater
characteristics is necessary to determine the design capacity of the treatment plant.In
case of new development projects where the actual wastewater data is not available,
the wastewater loading and flowrates are derived from population estimates and the
3
wastewater load and composition are solely based on the locally accepted typical
values.
1.2
Objectives
The objectives of this study are as follows: To determine the ranges of typical composition of raw sewage in terms of BOD,
SS, COD, AMN, and pH values.
To study the typical characteristics of raw sewage generated from various types
of developments in the country i.e. from residential, commercial and from mixed
developments.
To identify the typical raw sewage measured in relation to the size of the
developments.
1.3
Scope of study
4
Although the data are gathered based on grab sampling carried out during halfperiods of the weekday, yet it involved an extensive representation in samplings
with a total number of approximately 30,000 samples, and cover a broad span in
terms of locations, numbers, type and size of developments.
This study however, does not include Phosphorous and Oil &Grease constituents in
the domestic wastewater.
Likewise, this study does not include treatment processes applied to meet the
prescribed effluent standards.
CHAPTER II
LITERATURE REVIEW
2.1.
6
The most accurate way to determine the character and quantity of domestic
wastewater is to measure the existing wastewater flow over a sufficient length of
time to determine its variability in terms of composition, concentration and load.
However, in the case of new development, a prescribed wastewater flow and typical
characteristics of the domestic wastewater need to be adopted for the design stage of
a new treatment system in meeting with the stipulated discharge standard.
There were literature that outlined the typical influent characteristics of domestic
wastewater studied elsewhere and one which is widely refered to is tabulated in
Table 2.1.
The treatment of sewage will require the processing of both organic and inorganic
solid matter as explained by Rendell (1999). This matter will be in the form of
dissolved solids and suspended solids. The inorganic load is comprised of grits and
salt. Sewage with high industrial waste element will consist of compounds and
possibly include highly toxic chemicals. To enable the nature of the liquid to be
described there is a need to define two things: firstly a characteristic that reflects the
nature of the compound and secondly, its concentration in the solution. The
concentration will be expressed in terms of mass per unit volume The more usual
units is mg/l. Another form in which the quantity of a compound will be expressed is
a load. This type of unit is used to define loadings on the system and is calculated
from concentration and the flowrate e.g gm per day.
7
Table 2.1: Typical Characteristic of Untreated Domestic Wastewater
Contaminants
Unit
Concentration
Weak
Medium
Strong
mg/L
390
720
1230
mg/L
270
500
860
Fixed
mg/L
160
300
520
Volatile
mg/L
110
200
340
mg/L
120
210
400
Fixed
mg/L
25
50
85
Volatile
mg/L
95
160
315
Settable solids
mg/L
10
20
BOD5, 20C
mg/L
110
190
350
mg/L
80
140
260
COD
mg/L
250
430
800
Nitrogen (total as N)
mg/L
20
40
70
Organic
mg/L
15
25
Free ammonia
mg/L
12
25
45
Nitrites
mg/L
Nitrates
mg/L
mg/L
12
Organic
mg/L
Inorganic
mg/L
10
Chlorides
mg/L
30
50
90
Sulfate
mg/L
20
30
50
mg/L
50
90
100
<100
100-400
>400
Phosphorus (total as P)
Volatile
organic mg/L
compound
Total Coliform
#/100mL
106~108
107~10 9
107~10 10
Fecal Coliform
#/100mL
103~105
104~10 6
105~10 8
8
In the standard measurement of BOD5, the oxygen demand measured is influenced
by three conditions: (a) Oxygen demand by the breakdown of soluble carbonaceous
matter (b) Oxygen demand by the breakdown of suspended particulate carbonaceous
matter (c) Oxygen demand by the oxidation of ammonia to nitrate by nitrifying
bacteria present in the effluent sample. As the amount of residual soluble
carbonaceous BOD5 matter in the effluent, after undergoing treatment in the
secondary reactor, reduces in concentration to below 15 mg/l, nitrifying bacteria
populations tend to grow rapidly feeding on ammonia present in the partially treated
sewage. Nitrification may not be complete at levels of 5 mg/l of residual soluble
carbonaceous biodegradable matter; it depends on whether sufficient oxygen is
available for oxidation of ammonia to nitrate.
BOD is used not only to indicate the strength of a wastewater but also that of a
treated effluent and the efficieny of the various stages of treatment. The BOD of
domestic sewage may be expected to lie in the range of 150 to 600 mg/l whereas for
industrial wastes values from 0 to 100,000 mg/l may be found, depending upon the
nature of the industry. (Pescod, 1999)
Sewage also contains solid material that can settle on the bottom or in suspension
solids form that can increases turbidity and impact the light availability for aquatic
life. The desired solids removal in sewage treatment should reflect the absolute SS
discharge limit of 50mg/l and 100mg/l for Standard A and Standard B catchment.
COD content reflects the chemically oxidized organic matter; hence it includes
refractory fractions of organic matter as well as reduced inorganic constituents
present in the wastewater. The measure of COD offers a quick estimate of
carbonaceous material compared to conventional BOD measurements. Additionally,
high COD reflects the potential industrial contamination in the form of inert reduced
inorganic elements and unbiodegradable organics. Based on the bisubstrate
hypothesis, COD fractions of readily biodegradable, slowly biodegradable and
unbiodegradable estimates are also adopted in advanced modeling for STP design
whereby the different fractions vary in susceptibility to microbial respiration and
degradation.
9
Wastewater may contain high levels of nutrients. Excessive release to the
environment can lead to a build-up of nutrients, i.e. eutrophication, which can in turn
encourage the overgrowth of algae. Not just an aesthetic issue, some algal species
produce toxins which contaminate drinking water supplies, while in serious cases, so
much algal/plant matter can be present that the consumption of dead plant matter by
bacteria decay depletes the oxygen in the water and suffocates fish and other aquatic
life. Removal of nitrogenous compounds needs to be considered in STP design. It is
found in varying forms that are detrimental to natural water bodies and potable
consumption. To ensure compliance with the prescribed effluent discharge standard,
the characteristic of the nitrogenous constituent shall be determined in order that
adequate nitrifications and denitrification in the secondary biological reactors design
is provided. (Sewerage Services Department, 1998).
10
Table 2.2: Mean Results of Wastewater Characteristics.
PLANT
BOD
COD
SS
TKN
O&G
A/ITI
AMN
204
422
101
40
26
186
22
164
262
132
78
24
222
33
Taman Timor
253
429
104
79
33
222
22
372
678
81
40
19
189
28
137
259
108
42
29
189
32
233
417
101
74
52
136
36
Sub-Catchment 6, TSP
292
443
96
34
26
163
23
Sub-Catchment 6, TSP
255
448
98
34
32
167
30
MEAN
239
420
103
53
30
184
28
STDEV
74
130
14
20
10
29
From the study, the mean results of wastewater characteristics identified for BOD,
COD, SS and AMN are 239mg/l, 420 mg/l, 103 mg/l and 28 mg/l respectively.
Sewage flows conveyed in sewer lines are not constant but vary considerably over
the day and they exhibit a diurnal pattern. The extent of variation will be dependent
on the P.E count served, and on the extent of sewerage discharges from commercial,
industrial and institutional premises located within a specific area, or over an entire
catchment. It is normally expected that higher rates of sewage flow occurs during
the early morning when mans body cleansing, food preparation and utensil
cleansing activities peak.(Sewerage Services Department, 1998). Particularly low
rates of flow occurs usually in the very early morning (4 am) when man is usually at
rest. As can be expected, the average daily rates of flow generation is also dependent
significantly on the socio-economic status of the community, particularly with
respect to its affluence and standard of living, representing the number of toilets and
bathrooms in a house and size of the family. In case of new development projects
where the hydraulic data is not available, the wastewater flows and characteristics
are developed from population estimates. The Malaysian Sewerage Code of Practice
11
recommended that for sewerage system design purposes it can be assumed that a
single person resident generates an average daily sewage flow of 225 litres per day.
The inherent wastewater load will also change due to changed diet habits e.g.
consumption of more processed food and use of kitchen grinder/macerator for
disposal of scrap food into sewerage system. Also, a tendency for using household
chemicals which include detergent and cleaning agents increased the amount of less
degradable materials into the sewer. Determination of wastewater characteristic and
concentration is necessary to ensure that the design capacity as well as the process
requirements of the treatment plant is fulfilled. The availability of the actual flow
and loading pattern will lead to a better design and ways of operating the STP
facility.
2.2.
In-pipe treatment
12
considerably reduced and fermentation of organic matter will result in a more easily
biodegradable wastewater.
Boon (1995) further testified that septicity in sewerage systems results from the
activity of bacteria, growing in sewage and on submerged surfaces which, under
anaerobic conditions, reduce sulphur-containing organic compounds and sulphates
to form sulphides and
ventilation, low velocity of sewage in large diameter sewers or small diameter rising
mains and high temperature, BOD or COD of sewage, will inevitably result in
septicity.
Balmer and Tagizadeh-Nasser (1995) in their paper states that wastewater engineers
often are heard to blame their failures on the fact that wastewaters are so different.
As long as wastewaters are predominantly of domestic origin it is however suprising
that they are different. The only rational explanation is that wastewaters are
transformed during transport from households to the wastewater treatment plant. The
per capita lengh of sanitary sewers is 3m to 10m and if the biofilm of the wetted
sewer perimeter is assumed to have the same activity as a biofilm in a trickling filter
or in a rotating biological contactor, it is obvious that a substantial part of the
organic matter in the wastewater can be metabolised before the wastewater enters
the wastewater treatment plant.The study also confirmed that energy dissipation is a
key factor for oxygen transfer in sewers.
Abdul-Talib et al (2003) hence advocated that sewer networks can and should be
designed not only for conveyance of water and pollutants, but also for obtaining a
wastewater quality that is suitable for the treatment processes at the receiving
wastewater treatment plant. It is well known that more than half of the cost to
provide a sewerage system is taken up by the sewer network. Therefore, it will be a
waste if the lengths and volumes of the sewers, which have potential treatment
capability are not fully utilised.
Conventional sewer systems in urban areas are designed and constructed in order to
transport wastewater from its source to treatment plants. During the transport of
wastewater
in
sewer
systems,
many
physical,
chemical
and
biological
13
transformations may result in significant changes in the wastewater composition.The
microbial transformation can be determined based on three types of conditions:
aerobic,anaerobic or anoxic, depending on the type of electron acceptors that are
present in the wastewater. Each of them produces different processes that will
change the quality of the wastewater transported upon arrival to the wastewater
treatment plants. Therefore, it is possible to design sewer systems to achieve dual
purposes: transport and biotransformation of wastewater as presented by Ujang et al
(2004). Results from a laboratory-scale sewer system as a bioreactor under tropical
anoxic condition revealed that the overall removal efficiency between 0 to 3 km
samples in the sewer system are as follows:suspended solids 58%,turbidity 24%,
COD 30% and BOD 25%.
Today, the importance of the sewerage system as a biological reactor ,in which
aerobic or anaerobic biochemical processes will occur, has been recognised. The
benefits of wastewater pretreatment under aerobic conditions can be maximised by
ensuring that sewerage systems are designed to achieve reaeration of wastewater at a
rate greater than the rate at which microorganisms (present in the wastewater and
attached to submerged surfaces in the pipework) consume dissolved oxygen.
Sewerage systems should include long gravity sewers which operate at selfcleansing velocities, ensure adequate reaeration and include vertical-lift pumping to
avoid excessive periods of wastewater storage in the absence of adequate reaeration
(Pescod, 1999).
There is growing realisation among water suppliers and academics that water
demand stems from routine behavior and norms which develop within a particular
social background and this has been studied by Smith and Ali (2006).This is is in
contrast to other types of consumer demand in which customers exercise conscious
choice. Despite such acnowledgement, the idea that ethnic background and religion
14
may both form a fundamental basis for water consumption norms and practices is
largely overlooked.The study conducted in UK revealed that water use patterns are
highly characterised by ethnicity and religious practice.
Design Guidelines for Water Supply Systems published by the Malaysian Water
Association (1994) specified that, per capita water demand should be classified
under three categories. The guideline below gives a range of per capita consumption
for each of the three categories:
The design guidelines also reported that the daily demand varies slightly due to the
weather and festive seasons. In most states, daily water demand increases slightly in
the month of January and February. During festive seasons, experience has shown
that in some urban centres, there is a change in demand due to shutting down of
factories while there is an increase in demand in rural areas and smaller urban
centers due to people leaving big urban centres for their hometowns and villages.
The MS 1228 specify that sewerage systems be designed based on an average daily
per capita flow of 225 litres and the process design of a domestic waste treatment
shall be on the basis of 55 grams of BOD per capita per day and 68 grams of
suspended solids per capita per day, which equate to concentration of 245 mg/l and
302 mg/l for BOD and SS respectively
Galil and Shpiner (2001) explained the effect of kitchen sink macerator; that the
domestic garbage disposer is an electro-mechanical device which is installed
underneath the kitchen sink and is used to grind solid wastes resulting from food
preparation. The mixture of grinded solids and water is flushed to the sewerage
system and to the sewage treatment works. As a result of grinded garbage
discharged to the collection system, a change in the quality and quantity of crude
sewage is usually reported due to the addition of suspended solids, as well as the
increased water consumption for the flushing action. The disadvantages associated
15
with garbage grinders are based on the fact that the solid waste is grinded and mixed
with fresh water, transforming it into wastewater, and adding to the load on the
sewerage system. This may cause deposition and clogging problems in sewers, and
can result in an additional organic loading and an increased amount of sludge.
The separation at source could be an option for public health protection: blackwater
from toilets is treated in individual septic tanks or small sewage plants, and the
greywater or sometimes called sullage, is discharged to the hydraulically well
designed stormwater drain, or into a sullage soakaway (Abdul-Hamid and Ujang,
2006). However, separation at source can also contribute to water pollution. In this
situation, stormwater drains contain high concentrations of washing chemicals, oil
and grease and residuals of food. Most of the stormwater drains in urban areas in
tropical countries are connected to tributaries of major rivers. As a result it is a
phenomenon that tropical rivers are mainly polluted due to untreated greywater.
2.4.
16
establishments. Comparison of the above-mentioned studies shows that higher
wastewater strengths can induce a faster decline of treatment-system performance.
by which
17
these effects can help operators optimize facilities and minimize the negative effect
on capital and operations and maintenance cost, as well as permit compliance.
Infiltration into sewer systems are contributed by factors such as (i) age of sewer, (ii)
condition of connection either direct to pipe or to manhole, (iii) illegal connection of
roof gutter and drain to sewer system, (iv) permeability of soil around sewer, (v)
groundwater elevation and (vi) quality of construction. Besides infilling during
raining season due to high water table, on the contrary will cause leakages and
diffusion of wastewater to the ground adjoining the pipeline during dry weather.
18
for a treatment plant in a developing region, the aspects relevant to its sustainability
must be judiciously incorporated (Von Sperling and Chernicharo, 2006).
In the design of treatment process or a transfer system, the ideal condition for the
design is that the loadings should be constant. Because the limited buffering of flows
within the sewerage system (unlike buffering effect of a water service reservoir), the
design and operation of a sewerage system become more difficult due to the high
flow variation. (Rendell, 1999) The term population and water consumption are
closely linked to social changes and the way in which a community uses water. The
industrial loads have to be estimated with knowledge of the type of industry that
exists in the catchment. The daily and seasonal variation in industrial flows will be
dictated by the type of the industry and the mode of operation.
The causes of flow variation within a system are: (a) a long term variation due to
change in water use (b) the annual flow variations due to such factors as holiday
populations and seasonal industrial processes (c) weekly variation will be
predominantly caused by commercial and industrial work patterns and (d) diurnal
variation due to the normal life patterns of the domestic consumer. For a large or
widely spread sewerage system with flow within the system that have average
velocities of 0.8 m/s, thus the time between flows entering the system and arriving at
a collection point will vary greatly. The effect of this is that the system, due to its
volume, will act as a buffer and attenuate the peak flow. The contribution of
industrial wastes can be biological in nature dictated by the industrial process such
as poultry packing and dairies although the concentration is much higher.
Both turbulence in the water phase and the pH were found to play a crucial role in
the transfer of hydrogen sulfide. The air-water transfer process of hydrogen sulfide,
which also incorporates the association process, can be related to the reaeration
process in terms of their transfer rates. A relationship between the two processes is
primarily established for the pH range typical for domestic wastewater (Yongsiri et
al, 2004).
Depending on the length of sewer networks, the flow generated from source may
require several hours to flow through the sewer network system because of flow
19
dampening effect and prolonged by the available storage capacity in the sewer
system. Intermittent inflow can also occur due to the collection and delayed
discharged via network pumping stations that is being controlled and triggered the
flow by water levels or timer which is then transferred to the downstream trunk line.
Delay inflow hence is due to the collection and discharged via network pumping
stations that transferred flow to the downstream trunk line toward the headworks of
the treatment plant.
2.6.
Rushforth et al (2003) states that the presence of sediments in sewers can cause a
number of problems for operators. Deposits of sediments in pipes can reduce
hydraulic capacity, either by reducing the flow area or increasing the hydraulic
resistence.In-sewer deposits are also believed to store pollutants which are released
when deposits are mobilized during intense storm events. Accordingly, erosion of
such deposits is thought to be responsible for sudden large increases in suspended
solids which are observed at the leading edge of storms in a number of catchments.
Sewage treatment plants are designed to flow as much as possible under gravity, in
order to minimise the number of pumps in the catchment area depending on
topography. The hydraulic processes in the pumping stations may include pumping
system hydraulics, closed conduit hydraulics and in some cases transient hydraulics.
In the event of pump failures, which may be due to electrical failures, mechanical
20
failures or breakdown of the pumping systems, the hydraulic processes in the
approaching sewers will change drastically. In the sewage pumping stations, the
operations are intermittent as the incoming flow varies over time according to
diurnal distribution. The intermittent operations of pumps may lead to occurrences
of transient flow and no flow conditions. This in a way will have effect to the
mobilization and deposition of sediments in the sewer pipes.
21
CHAPTER III
METHODOLOGY
3.1
3.2
Another set of data was made available defining the type of customer
(residential, commercial and industrial premises) that are connected to a particular
22
STP asset reference. Influent data were collected from approximately 1,400 sewage
treatment systems where the types of development have been verified .Analysing of
data that linked the influent sampling result with the different type of properties will
ascertain the characteristics of domestic wastewater in relation to the type of
developments.
3.3
3.4
Sampling.
Samplings of influent for the study were taken at the headwork of STP, that
include mechanical and non-mechanized plants; suspended and fixed growth process
systems and with a wide range of STP sizes, from less than 500 PE to more than
100,000 PE. The laboratory samplings undertaken are based on operational
instruction as set by the Company. Samples taken are properly labeled with the STP
reference number, date, sampling point, samplers initial and preserved as per
requirement outlined in the Standard Methods for the Examination of Water and
Wastewater document (APHA, 1995).
23
3.5
Elimination of outliers.
Outliers were removed by eliminating data that fall within one percent of the
lowest band and also those data that fall within one percent of the uppermost bands
These data are considered extreme values that may be influenced by sudden surges
of loading due to the possibility of illegal pollution discharge from unidentified
sources or may be due to the effect of high rate infiltration that severely diluted the
raw sewage influent into the sewerage system.
24
CHAPTER IV
4.1
The mean and at 90 th and 95th percentile value of typical composition are
being analysed in this study based on 3 years influent sampling data of raw sewage
taken at headworks of all the Sewage Treatment Plants. The parameters that are
being studied covers the five main sewage characteristics i.e. BOD, SS, COD, AMN
and pH. Other parameters including phosphorous and oil & grease are not included
in this study.
25
BOD
9000
8000
No of Samples
7000
6000
5000
4000
3000
2000
1000
51
-1
00
15
120
0
25
130
0
35
140
0
45
150
0
55
160
0
65
170
0
75
180
0
BOD
% C ummulative Frequency
1.2
1
0.8
0.6
0.4
0.2
0
05
51 0
-1
10 00
11
15 50
12
20 00
12
25 50
13
30 00
13
35 50
14
40 00
14
45 50
15
50 00
15
55 50
16
60 00
16
65 50
17
70 00
17
75 50
180
0
80
1-
26
220 mg/l and 280 mg/l of BOD at 90% and 95% percentile respectively, which is
within the typical value of 250 mg/l adopted in the local guideline.
COD
4500
Nu mb er o f Samp les
4000
3500
3000
2500
2000
1500
1000
500
0
19
10
0
01 0
-1
11 05
51 0
-1
13 20
01 0
-1
16 40
01 0
19 170
01 0
-2
22 00
01 0
-2
30
0
85
70
175
0
55
160
0
40
145
130
25
10
115
27
COD
1.2
% Cummulative Frequency
1
0.8
0.6
0.4
0.2
0
10
115
0
25
130
0
40
145
0
55
160
0
70
175
0
85
190
10
0
01
-1
05
11
0
51
-1
20
13
0
01
-1
40
16
0
01
-1
70
19
0
01
-2
00
22
0
01
-2
30
0
Based on the graph in Figure 4.4 above, the number of samples analysed depicted
that the value of COD at 90% and 95% percentile are approximately 470 mg/l and
625 mg/l respectively. The 90% percentile value of COD above falls within the
medium strength value of 430 mg/l as shown in Table.2.1.
4.1.3
The AMN chart in Figure 4.5 below, shows that the highest number of
samples for AMN concentration falls under the 16 to 25 mg/l. range. The mean
value of AMN averaging from a total number of 29,674 samples is 23 mg/l.
28
AMN
6000
Number of Samples
5000
4000
3000
2000
1000
0
0 1-5 6- 11- 16- 21- 26- 31- 36- 41- 45- 51- 56- 60- 6510 15 20 25 30 35 40 45 50 55 60 65 70
AMN Concentration mg/l
AMN
% Cummulative Percentile
1.2
1
0.8
0.6
0.4
0.2
0
0
1-5
29
mg/l and 45 mg/l respectively, which fall within the medium and the high strength
category presented in Table 2.1.
4.1.4
From the SS chart in Figure 4.6 below, it is found that the highest number of
samples for SS concentration fall under the range of 100 to 200 mg/l. The mean
value of SS from a total number of 29,655 samples is 124 mg/l.
SS
14000
Number of Samples
12000
10000
8000
6000
4000
2000
50
0
>1
0
51
-1
00
15
120
0
25
130
0
35
140
0
50
160
0
70
180
0
90
110
00
11
01
-1
20
13
0
01
-1
40
0
SS concentration mg/l
Results from the percentile distribution shown in Figure 4.8 below demonstrate that
the value of SS at 90% and 95% percentile are approximately 200 mg/l and 330 mg/l
respectively. The 95% percentile is within the typical value of 300 mg/l SS adopted
in the local guideline.
30
SS
%Cummula tive Frequency
1.2
1
0.8
0.6
0.4
0.2
SS concentration mg/l
50
0
>1
40
0
20
0
01
-1
13
00
11
01
-1
110
90
180
70
160
0
50
0
140
0
35
130
0
25
120
15
10
0
51
-
4.1.5
From the pH graph as shown in Figure 4.9 below, the highest number of
samples for pH value falls under the range of 6.7 to 7.4. The mean value of pH from
a total number of 29,374 samples is 6.96.
31
pH
12000
% cummulative percentile
10000
8000
6000
4000
2000
0
0
5.9 -6.2
6.3-6.6
6.7-7.0
7.1-7.4
7.5-7.8
7.9 -8.2
8.3
7.5-7.8
7.9-8.2
8.3
pH value
pH
% cummulative percentile
1.2
1
0.8
0.6
0.4
0.2
0
0
5.9-6.2
6.3-6.6
6.7-7.0
7.1-7.4
pH value
Likewise, from Figure 4.10 above, the number of samples analysed also shows that
the value of pH at 90% and 95% percentile are approximately 7.2 and 7.4
respectively. All the values for pH either the mean or the 90% and 95% percentile,
32
are considered within the optimum value that is conducive for bacterial growth
which lies between 6.5 and 7.5 levels as suggested in Metcalf and Eddy (2004).
Contamin
Unit
ants
Number
Concentration
of
90th
Sample
Mean
UTM-
Metcalf
95th
IWK
& Eddy
Percen
Percen
Study
(medium
tile
tile
(mean)
strength)
BOD
mg/L
29,660
135
220
280
239
190
COD
mg/L
29,676
294
470
625
420
430
AMN
mg/L
29,674
23
36
45
28
25
SS
mg/L
29,655
124
200
330
103
210
pH
29,374
6.96
7.2
7.7
6.5-7.5
Table 4.1 shown above summarised the value of all the five parameter analysed
from the entire data made available in the study. The result illustrates that the 90 th
percentile values in the analysis are the values comparable with the results from both
the UTM-IWK collaborative study (2003) and the value outlined in Metcalf & Eddy
(2004).
4.2
33
the residential units are fully discharging domestic wastewater loads to the sewer
system. There are many instances in which the outflow from kitchen sinks and
washing machines are directly discharged to the perimeter drainage system mostly
located at the back of residential units.
In addition, the domestic wastewater load is also affected by the type of the
development it originated. Townships are today encouraging industrial parks and
commercial complexes to spur economic growth for the area. Commercial premises
include assembly halls, camps, clubs, hotels, institutions, offices, restaurants,
schools, stores, laundry, swimming pool, theater, rest and service areas, bus station,
wholesale, retail, finance, auto repair, amusement centres, clinic, museum and
airport etc. Whilst, industrial establishment include factories that manufacture food,
textile, paper, printing, chemical, plastic and electronic product etc. Although the
sewer system provided for these areas are designed to cater for domestic wastewater
(the trade wastewater are to be treated separately), it is an almost impossible task to
control the wastewater from entering the sewage especially via spillage, inflow from
washing activities or illegally discharged into the sewer connection. All these has
bearing to the sewage characteristics transported into the treatment system.
A typical example is wastewater generated from verhicle services centre that include
spills in the form of lubrication oil, engine coolant, traces of petrol and diesel,
solvent from paintworks, cleaning agent and eletrolyte from batteries. Since source
control at service centres are not enforced, the result is considered ineffective due to
lack of enviromental awareness amongst the workshop operators. Hence, what is
needed is effective enforcement efforts that help to contain illegal trade waste
discharge.
This scope of the study is an attempt to identify the typical difference in the
characteristics of raw sewage generated from various types of developments in the
country i.e. from residential, commercial, industrial and also mixed developments.
The raw sewage data are divided into seven different types of development
categories that have been identified as: (i) residential only (ii) commercial only (iii)
industrial and commercial institutions (iv) developments with industrial plots (v)
developments with commercial plot (vi) Industrial and industrial plus commercial
34
and (vii) residential and commercial developments. Samples were sorted and
analysed based on the above category of developments. A summary of the mean
value of sewage characteristics is as in Table.4.2 below.
BOD
COD
AMN
pH
SS
No of
Samples
Commercial only
227
482
210
435
174
365
21
6.8
147
134
134
295
20
6.9
144
5866
130
290
20
7.0
140
9575
127
281
20
6.9
139
5453
121
262
17
6.7
130
352
Commercial and
Industrial
19
6.9
212
23
6.8
170
401
106
Industrial and
Commercial plus
Industrial
Mixed development with
commercial plots*
Residential only
Residential and
Commercial
Mixed development with
Industrial plots**
Note: The influent from fully Industrial plots are not being analysed as
the sampling data are very minimal from only 3 areas with full
industrial premises.
* Development with commercial only and commercial plus residential.
**Development with industrial only, industrial plus commercial, industrial
plus residential and industrial plus commercial plus residential.
35
Based on the results as show in Table 4.2 above and Figure 4.11 below, all the three
BOD, COD and SS parameters were found higher from source that originated from
development with commercial plots, medium from residential premises and the
lowest from mixed development with industrial plots.
All the three parameters i.e. for BOD are descending from 227 mg/l to 121 mg/l ,
COD from 482 mg/l to 262 mg/l and SS from 212 mg/l to 130 mg/l.
As for parameter for AMN, the level was found lower from mixed development with
industrial plot areas and higher from commercial plus industrial premises. The AMN
values ranged from 17mg/l to 23 mg/l.
Dev.type
600
BOD
COD
AMN
PH
SS
500
400
300
200
100
0
Type of Developments.
36
Mean levels of pH concentrations are within the range of 6.7 to 7.0 indicating that
the results are within the tolerable value.
All the values identified in Section 4.2 differ slightly from the results gathered and
anlysed in Section 4.1. The finding in Section 4.1 dealt with influent data collected
from more than 4,200 STP for overall analysis. In comparison, the analysis in
Section 4.2 are based on a lower number of samplings linked to customers database,
from roughly 1,400 sewage treatment systems of which the types of connected
premises of the development have been duly verified.
4.3
The study in this section will identify the typical raw sewage characteristics
measured in relation to the size of developments which are normally linked to the
length of sewer reticulation, area of coverage, in-pipe storage, duration of flow and
infiltration. The determination in the size of development in this analysis is based on
the connected PE to the Sewage Treatment Plant.
37
BOD
COD
AMN
pH
SS
Samples
< 1000
164
393
25
7.1
202
11,266
1,001 - 2,000
152
342
23
7.1
165
4,645
2,001 - 3,000
153
338
23
7.1
156
4,052
3,001 - 5,000
147
316
22
7.1
141
3,624
5,001 - 10,000
141
313
22
7.0
137
3,267
10,001 -20,000
140
308
22
7.0
140
2,057
20,001 - 50,000
122
279
20
6.9
139
898
50,001 - 100,000
126
285
22
7.1
138
233
>100,001
119
261
18
6.9
147
268
Table 4.3 above and Figure 4.12 below illustrated the relationship between sizes of
development and human populations with concentration of the wastewater
constituents. Based on the analysis as tabulated above, the sewage characteristics
from the various development shows a peculiar and distinctive pattern that
correspond to the changes in size of the development. Seemingly, the sewage
concentration is indicating a significantly lower value from the large developments
and the parameters incrementally higher from those that originated from smaller
development.
38
Dev. size
BOD
COD
450
AM N
PH
400
Characteristic mg /l (exc.pH)
SS
350
300
250
200
150
100
50
0
< 1000
1,001 2,000
2,001 3,000
3,001 5,000
5,001 10,000
Size of Development
Figure 4.12: Mean wastewater characteristic by size of Developments.
A development with higher population normally have more sewer networks and
reticulation system covering the catchments area, hence any substantial part of
cracks, damage and infill of flow due to infiltration will result in weak sewage
concentrations. During wet weather, the system is affected by flow variation due to
inflow and infiltration that significantly changed the hydraulic quantity into the
system. Factors that can contribute to extraneous inflow and infiltration are: (i) area
of network,(ii) length of sewer,(iii) age of sewer lines,(iv) location of sewer near
river and high groundwater level,(v) quality of sewer construction and (vi) possible
sewerline subsidence due to soil failure.
39
Depending on the length of sewer networks, the flow generated from the source may
require several hours to flow through the sewer network system because of flow
dampening effect and prolonged by the available storage capacity in the sewer
system.
The findings generated from the above scenario prompted this study to further look
at the impact of the decreasing pattern associated with the changes in size of the
development. Pursuant to this, all the parameters analysed earlier are now plotted
individually to observe its significance. It is necessary to be aware that the current
sewerage guideline which stipulates that development with more than 30 units
(150PE) shall be served by a connected sewerage system and a treatment plant.
Likewise, a sewerage asset record shows that only two percent of the developments
in the country are served by STPs with more than 100,000 PE. In the following
analysis, all development less than 150PE and 150,000PE and above are omitted and
consideration is made to observe only developments between the 150PE to 150,000
PE range.
BOD
800
700
600
500
400
300
y = -0.0003x + 135.93
200
100
0
0
20000
40000
60000
Size of Development
40
The BOD analysis involved a total number of 29,070 sampling data. Comparison
done to BOD concentration levels in the graph in Figure 4.13 shows that for
development with 150 PE indicates BOD mean value of 135 mg/l and the value
decreases to 106mg/l. for development with more than100,000 PE. This is
equivalent to a reduction of approximately 20% in the value of BOD concentration
between this two development ranges.
COD
2500
2000
1500
1000
y = -0.0007x + 300.45
500
0
0
The COD analysis involved a total number of 29,173 sampling data. Again
comparison is made to the COD concentration levels as shown in Figure 4.14 which
illustrated that for development with 150 PE indicates the a COD value of 300 mg/l
and the value decreases to 230mg/l for development with more than 100,000 PE.
This is equivalent to a reduction of approximately 23% in the value of COD
concentration between this two development ranges.
41
AMN
A M N concentration mg/l
80
70
60
50
y = -6E-05x + 23.35
40
30
20
10
0
0
20000 40000
Size of Development
Figure 4.15: AMN variation with increase in development size.
42
SS
SS concentration mg/l
1800
1600
1400
1200
1000
800
600
y = -0.0002x + 125.65
400
200
0
0
20000 40000
Size of Developments
pH
9
8
ph value
7
6
y = -1E-06x + 7.0525
5
4
3
2
1
0
0
20000
40000
60000
Size of Development
43
Meanwhile, analysis of pH in relation to different development size involved a total
number of 29,165 sampling data. Figure 4.17 shows the pH level for development
with 150 PE indicates the mean value of 7.0 and the value decreases to 6.9 for
development with more than 100,000 PE. This is equivalent to a reduction of
approximately 1.4% in the value of pH concentration between this two development
ranges.
Results from analyses for all the 5 parameters as depicted in the above
charts, revealed that the domestic wastewater characteristics generated from
100,000PE developments are lower in strength (by 20% for BOD, 23% for COD,
25% for AMN, 16% for suspended solids
44
CHAPTER V
CONCLUSIONS
5.1
i)
The mean and at 90th and 95th percentile values for all samples of raw
domestic wastewater based on five main sewage characteristics i.e. BOD, SS,
COD, AMN and pH are as shown in Table 5.1.
45
Table 5.1: Characteristics of domestic wastewater from all samples.
Concentration
Contaminants
Unit
Mean
ii)
90th
95th
Percentile
Percentile
BOD
mg/L
135
220
280
COD
mg/L
294
470
625
AMN
mg/L
23
36
45
SS
mg/L
124
200
330
pH
6.96
7.2
7.7
iii)
46
5.2 Recommendations
47
REFERENCES
Abdul-Talib, S., Thorkild, J.V. and Jacobsen, T.H. (2003). Benefiting From
Microbial Processes in Sewer Networks during Transport of Municipal Wastewater.
Board of Engineers Malaysia, Buletin Ingeniur. p16-31.
APHA. (1995). Standard Methods for the Examination of Water and Wastewater.
19th Edition. American Public Health Association /American Water Works
Association / Water Environment Federation, Washington DC, USA.
Balmer, P. and Nasser, M.T. (1995). Oxygen Transfer in Gravity Flow Sewer. Water
Science Tech. Vol. 31, No 7, p127-135.
48
Galil, N. and Shpiner, R. (2001). Additional Pollutants and Deposition Potential
from Garbage Disposers. Journal Chartered Institute of Water Engineering &
Management. p 34-39
Howarth, D. (2002). Greywater - Its Time Will Come. Water & Environmental
Manager. The Chartered Institution of Water and Environmental Management. p14.
Lesikar, J., Garza, O.A., Persyn, R.A., Kenimer, A.L. and Anderson, M.T. (2006).
Food-Service Establishment-Wastewater Characterization. Water Environment
Research, Vol. 78, No8. p 805-809.
Malaysian Water Association. (1994). MWA Design Guidelines for Water supply
system.
Metcalf and Eddy. (2004). Wastewater Engineering, Treatment and Reuse, 4th
Edition. McGraw Hill publication.
Muirhead, W.M. (2005). Biological effect on alkalinity and pH. Water Environment
and Technology. p 96-100.
Othman, M.N. (2003). Determination of per capita load and water consumption in
sewage treatment design. UTM-IWK Research collaboration, Final Report.
49
Pescod, M.B. (1999). Developments in Wastewater Treatment. Public Lecture Series
on Environmental Control and Management. Institute of Environmental & Water
Resource Management UTM.
Rushforth, P.J., Tait, S.J. and Saul, A.J. (2003).Use of a full scale test facility to
examine sewer-sediment mobility. The Journal. V17 N1. p 40-44.
Smith, A. and Ali, M. (2006). Understanding the impact of cultural and religious
water use. Water and Environment Journal 20. p 203-209.
Tanaka, N., Jacobsen, T.H. and Horie, T. (2000). Transformation of Carbon and
Sulphur Wastewater Components under Aerobic-Anaerobic Transient Conditions in
Sewer System. Water Environment Research, Vol. 72, No 6. p 651-674.
Ujang, Z., Yong, E.L., Ong, P.T., Osuna, R.R. and Anderson, G.K. (2004). The
degradation of organic matter by microbial activity under anoxic conditions during
transport in tropical sewer systems. Ujang, Z. and Henze, H. Environmental
Biotechnology: Advancement in Water and Wastewater Applications in the Tropics.
Water and Environmental Management Series. IWA publishing. p 51-59.
Vollertsen, J., Jacobsen, T.H. and Nielsen, A.H. (2005). Stochastic Modeling of
Chemical Oxygen Demand Transformations in Gravity Sewers. Water Environment
Research, Vol. 77, No 4. p 331-339.
50
Water Environment Federation. (1998). Design of Municipal Wastewater Treatment
Plant. WEF Manual of Practice No.8. 4th Edition.
Yongsiri, C., Vollertsen, J., Rasmussen, M. and Jacobsen, T.H. (2004). Air-Water
Transfer of Hydrogen Sulfide: An Approach for Application in Sewer Network.
Water Environment Research. p 81-88.
51
APPENDIX A
Cumulative
BOD range
samples
Percentage
percentage.
0-50
4489
15.13%
15.13%
51-100
6765
22.81%
37.94%
101-150
7842
26.44%
64.38%
151-200
5809
19.59%
83.96%
201-250
2369
7.99%
91.95%
251-300
986
3.32%
95.27%
301-350
551
1.86%
97.13%
351-400
236
0.80%
97.93%
401-450
155
0.52%
98.45%
451-500
115
0.39%
98.84%
501-550
85
0.29%
99.13%
551-600
66
0.22%
99.35%
601-650
65
0.22%
99.57%
651-700
49
0.17%
99.73%
701-750
32
0.11%
99.84%
751-800
31
0.10%
99.94%
>801
15
0.05%
100.00%
29660
100.00%
52
APPENDIX B
Cumulative
COD range
samples
Percentage
percentage.
0-50
1357
4.57%
4.57%
51-100
2316
7.80%
12.37%
101-150
2763
9.31%
21.68%
151-200
3619
12.20%
33.88%
201-250
3936
13.26%
47.14%
251-300
4237
14.28%
61.42%
301-350
3583
12.07%
73.49%
351-400
2671
9.00%
82.49%
401-450
1586
5.34%
87.84%
451-500
852
2.87%
90.71%
501-550
484
1.63%
92.34%
551-600
414
1.40%
93.74%
601-650
281
0.95%
94.68%
651-700
265
0.89%
95.58%
701-750
196
0.66%
96.24%
751-800
176
0.59%
96.83%
801-850
123
0.41%
97.24%
851-900
93
0.31%
97.56%
901-950
72
0.24%
97.80%
951-1000
53
0.18%
97.98%
1001-1050
62
0.21%
98.19%
1051-1100
39
0.13%
98.32%
1101-1150
46
0.16%
98.47%
1151-1200
42
0.14%
98.62%
1201-1250
31
0.10%
98.72%
1251-1300
26
0.09%
98.81%
1301-1400
54
0.18%
98.99%
1401-1500
40
0.13%
99.12%
53
1501-1600
57
0.19%
99.32%
1601-1700
42
0.14%
99.46%
1701-1800
29
0.10%
99.56%
1801-1900
34
0.11%
99.67%
1901-2000
37
0.12%
99.80%
2001-2100
22
0.07%
99.87%
2101-2200
20
0.07%
99.94%
>2201
18
0.06%
100.00%
29676
100.00%
54
APPENDIX C
Cumulative
AMN range
samples
Percentage
percentage.
1-5
1419
4.78%
4.78%
6-10
2393
8.06%
12.85%
11-15
4108
13.84%
26.69%
16-20
5517
18.59%
45.28%
21-25
5184
17.47%
62.75%
26-30
4229
14.25%
77.00%
31-35
2737
9.22%
86.23%
36-40
1716
5.78%
92.01%
41-45
1050
3.54%
95.55%
45-50
645
2.17%
97.72%
51-55
275
0.93%
98.65%
56-60
220
0.74%
99.39%
60-65
123
0.41%
99.80%
>65
58
0.20%
100.00%
29674
100.00%
55
APPENDIX D
Cumulative
pH range
samples
Percentage
percentage.
0.00%
5.9-6.2
732
2.49%
2.49%
6.3-6.6
4293
14.61%
17.11%
6.7-7.0
10657
36.28%
53.39%
7.1-7.4
9677
32.94%
86.33%
7.5-7.8
3063
10.43%
96.76%
7.9-8.2
883
3.01%
99.77%
>8.3
69
0.23%
100.00%
29374
100.00%
56
APPENDIX E
samples
0-50
Cumulative
Percentage
percentage.
5805
19.58%
19.58%
51-100
11770
39.69%
59.26%
101-150
6371
21.48%
80.75%
151-200
2355
7.94%
88.69%
201-250
998
3.37%
92.06%
251-300
554
1.87%
93.92%
301-350
387
1.31%
95.23%
351-400
220
0.74%
95.97%
401-500
343
1.16%
97.13%
501-600
193
0.65%
97.78%
601-700
145
0.49%
98.27%
701-800
109
0.37%
98.63%
801-900
79
0.27%
98.90%
901-1000
77
0.26%
99.16%
1001-1100
79
0.27%
99.43%
1101-1200
41
0.14%
99.56%
1201-1300
50
0.17%
99.73%
1301-1400
31
0.10%
99.84%
1401-1500
29
0.10%
99.94%
>1500
19
0.06%
100.00%
29655
100.00%
57
APPENDIX F