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(a)
Spin (1)
(b)
(c)
2p
2s
E n e rg y
1s
2
(d)
(e)
(f)
1
[10]
2.
(a)
Relative mass
Relative charge
+1
(1)
1
)
1840
(1)
(1)
Proton
Electron
0 (or
Neutron
3
(b)
(c)
(d)
acceleration (1)
Reason 2
deflection (1)
20
80
10 +
11 (1)
100
100
= 10.8 (1)
(e)
(i)
%H = 18.8 (1)
81.2 18.8
B:H=
:
(1)
10.8 1
= 2 : 5 : B2H5 (1)
(ii)
B4H10 (1)
4
[13]
3.
(a)
12
12 (1)
(b)
(c)
(i)
Moles NaH =
(ii)
pV = nRT (1)
0.0417 8.31 293
=
(1) allow consequential
100000
3
= 0.00102 m (1)
3
3
(allow 0.00101 0.00103) (allow in dm or cm )
(iii)
vol HCl =
2
1
1
(1)
24
moles NaOH = Moles NaH = 0.0417 (1)
2
3
= 0.167 mol dm (1)
(allow 0.166 0.168)
moles
0.00417
1000 =
1000 (1)
0.112
0.112
3
= 37.3 cm (1)
(allow 37.1 to 38.0 and conseq.)
8
[11]
4.
(a)
34
S (1)
16 (1)
2
2
6
(b)
1s 2s 2p (1)
(c)
(d)
1.65 10
24
(1)
2 158 10 23
12 (1) = 1299 (1)
1 993 10 23
23
or 6.023 10 2.158 10
= 12.998 (1)
12
23
13
12 98 9 13 1 1
(1)
100
100
= 1201 (1)
6
[10]
5.
(a)
0240 (1)
Mr (TiC14) = 190 (1)
moles TiC14 =
0 24
= 006 (1)
4
(c)
moles NaOH
vol NaOH
moles
(1)
conc
0 12
3
= 109cm (1)
1 1
moles HC1
= 006 (1)
2
moles H2
(allow conseq)
V
nRT
(1) or PV = nRT
p
0 06 8 31 293
(1)
98 000
3
= 149 10 m (1)etc
(if chemical error on moles H2, max2) (2)
4
[11]
6.
(a)
pV = nRT or n = pV/RT or pV =
m
RT or seen in substituted form (1)
M
(1)
(1)
(1)
3
n = PV/RT = 1.50 10 70 10 / 8.314 313 = 4.03 (mol)
5
(b)
(1)
(1)
3
(1) (1)
2.69 65 = 172 g (unit required)
[8]
7.
(a)
(i)
(ii)
(b)
(i)
(ii)
(iii)
(c)
79
79
79
81
81
81
81
79
79
81
81
(d)
appropriate diagram, with one lone pair and three bonding pairs
for ammonia (1)
appropriate diagram with two bonding pairs joining C to each
O in CO2 and
two lone pairs on each oxygen (1)
if inner electrons are shown they must be correct
2
[15]
8.
(a)
(b)
max 4
(c)
(i)
(ii)
(d)
aqueous solution (not water alone, unless solvent penalised in (i)) (1)
structure to suit CH3CH(OH)CH3 (1)
(i)
cyanide ion / CN / NC
(ii)
(iii)
(iv)
9.
(a)
(b)
= 6.02 10
23 (1)
(d)
(i)
charge (1)
(ii)
MgI2 + 2FE
(i)
nRT
(or pV = nRT) (1)
V
9000 (1)
Mr
17
3+
Mg
2+
= 1.99 10 Pa (1)
+ I2 + 2Fe
2+
(1)
(ii)
1.99 10
1000
7
= 2.49 10 Pa (1)
800
(allow conseq)
(iii)
9000
3
= 9.0 mol dm (or M)
1000
(1)
(1)
7
[12]
10.
(a)
(b)
(c)
protons
mass +1
charge + (1)
neutrons
mass +1
charge zero (1)
electrons
mass ~ zero (or<1/1800),
charge (1)
nitrogen 14 has a nucleus with 7 protons and 7 neutrons (1)
surrounded by electrons in shells (or orbitals) (or 2,5) (1)
2
2 3
with configuration 1s 2s 2p (scores last 2 marks) (1)
isotopes have the same atomic number (or same number of protons
or same element) (1)
but different number of neutrons (or mass number) (1)
(d)
max 14
(e)
4
[30]
11.
(a)
(b)
= 1:2:6
CaN2O6 (1)
(c)
Mr (1)
(d)
(i)
n=
3
1
PV
(1) (allow PV = nRT)
RT
95 10 3 1.53 10 3
8.31 293
=
(1)
(iii)
25
= 0.00597 (1)
1000
volume
0.00597
3
= 39.8 (cm ) (1)
0.15
= 1000
(allow conseq
3
allow 0.0398 dm )
6
[11]
12.
(a)
(b)
(i)
Ionisation (1)
with an electron gun (1) (or stream of electrons or high energy electrons)
which knocks out an electron from an atom or molecule (1)
producing a positive ion (1) (note this also scores ionisation mark)
(ii)
(c)
Detection (1)
Ion falls on collector producing a current (1) (or electrically
detected or falls on a ve plate)
fed into computer for analysis (1) (or displayed on a graph)
Max 12
11
(If use Li to Ne, use same mark scheme with 2s, 2p but max 7 out of 9)
[30]
13.
(a)
conversion of volume units (to 4.60 10 m ) (or dm with pressure in kPa) (1)
conversion of temperature units (to 1473 K) (1)
correct answer (0.036g to 0.037 g) (1)
3
[7]
14.
(a)
(i)
(ii)
mass p > mass e so deflected less / mass C > mass A so deflected less (1)
allow this mark for valid difference in property and explanation of shape
allow reference to other particles here
10
(b)
(i)
(ii)
(c)
(d)
(i)
81.7g 24 dm O2 (1)
81.7
24
g = 3.4lg 1 dm O2 (1)
11
15.
(a)
(b)
accelerated (1)
(c)
speed (1)
(d)
82 1 83 1 84 5 86 2
[1]
9 [1]
= 84.1 (1)
3
[6]
(d)
12
12 (1)
= 1.19 10 m (1)
(ii)
7
[11]
17.
(a)
(b)
(1)
Li(g) Li (g) + e
(i)
(ii)
(iii)
2+
12
nd
6
[9]
18.
(a)
(b)
Relative mass
1 (1)
Relative charge
0 (1)
In common
Difference
(c)
41
19
(d)
(i)
(1) K (1)
(ii)
Measurement 1
M/Z (1)
Measurement 2
(iii)
(e)
2s
2s
6 e le c tro n s (1 )
c o rre c t a rra n g e m e n t (1 )
1s
6 electrons (1)
correct arrangement (1)
(f)
1s 2s (1)
1
[14]
19.
(a)
12
= 6.031023 (1)
1.99 10 23 [[1]
13
(b)
(c)
12
(1) 12 (1)
(d)
CHO = 29
174
= 6 (1)
29
C6 H6 O6 (1)
(e)
CH4O+
3
O2
2
CO2+2H2O (1)
1
[8]
20.
(a)
20.0
(1)
17.0
moles of NH3
moles of HND3
volume
1.18
(1)
2
3
(i)
PV
= nRT (1)
PV
95000 0.0500
=
(1)
RT
8.31 298
1.92
(1) 1.28 mol
1.5
6
[10]
21.
(a)
17
(b)
O (1 )
(1 )
14
(c)
(i)
Particle
proton
Mass /g
1.6725 10
Relative charge
(d)
neutron
24
+1
24
1.6748 10
0
(ii)
1.6734 10
(iii)
1.0078 g (1)
(iv)
(i)
(ii)
magnet (1)
(iii)
electron
24
0.0009 10
24
g (1)
4
(v)
Measurement 1
Measurement 2
abundance (1)
z (1)
6
[13]
22.
(a)
12
12 (1)
(b)
(c)
(i)
2
1
%O = 65.7 (1)
C:H:O =
= 1.96: 1 : 2.93
= C2 HO3 (1)
(ii)
C4 H2 O6 (1)
15
(d)
mass 1000
Mr
16 = 62.5 (1)
(1)
(i)
P
100000
= 3.1 0 m
(1)
6
[13]
23.
(a)
(b)
9
5
B (1)
(1)
(allow Boron in words) penalise 9.0
2
(c)
1s 2s 2p (1)
1s 2s 2p (1)
3
2p 2p
16
(d)
12
12 (1)
or
12
C atoms
st
mark
12 (1)
(i)
(ii)
= 841 (1)
(ignore units)
(iv)
Kr (1)
(allow conseq)
7
[15]
24.
(a)
Avogadros
(b)
(i)
pV=nRT (1)
allow {V=
nRT
m
etc., pV=
RT
P
Mr
17
(ii)
V=
=
nRT
P
1 8 31 298
(1)
100 000
= 0.0248
m (1)
(iii)
n=
pV
RT
500000 0.005
(1)
8.31 273
s
st
two marks
= 1.10mol (1)
(allow 1.1 to 1.11)
Mr (CO2)
= 44 (1)
mass
(allow 4849)
(note can use calculation involving
P1V1
3
st
and 22.4 dm instead of 1 mark T
(c)
moles HC1
100
5.0 = 0.5(0)(mol) (1)
1000
moles H2
moles HC1
(1) = 0.25 (mol)
2
mass H2
18
(d)
(i)
O = 44.4 (1)
38.9
16.7 44.4
:
:
(if use At, CE)
55.8 (or 50) 12.0 16.0
=1:2:4
Fe C2 O4 (1)
(ii)
CO (1)
(mark independent of d (ii))
4
[15]
25.
pV = nRT (1)
6
mol) (1)
9
V = 2.03 10 m
26.
(a)
(b)
1
1
19
(c)
(i)
(ii)
(or average)
m e a n m a s s o f a n a to m (1 )
12
( m a s s ) 1 a to m o f 12C
or
12
C atoms
(1 )
12 (1)
(iii)
(1)
= 84.16
(d)
1s22s22p 63s23p64s23d
10
4p
(1)
5
(1 )
(f)
2
th
2
[12]
20
27.
(a)
12
(i)
mass 100
(1) = 1.64(1)
Mr
61
allow 1.63 to 1.64
PV = nRT (1)
V=
P
100 000
(1)
= 0 .1 6 4 m
if no 3 CE
(1)
(ii)
V = V1
T2
1000
0.164
T1
400
(1)
= 0.410 (m )
(1)
(1)
P
100 000
st
or (for 1 mark)
10
allow 2 marks ignore units
4
(c)
2
0.0454 (1)
44
21
(d)
25.9 74.1
:
(1)
14 16
= 1 : 2.5
N2O5 (1)
NO3 gains first two marks probably
(e)
N2O5 2NO2 +
1
O2 (1)
2
allow 2
if (d) is NO3
1
O2
2
[14]
28.
(a)
1
(b)
23
11
(1) Na (1)
23
OR Na 11
or Na (1) + unambiguous statement of mass no. and
atomic no.
(c)
1s 2s 2p 3s 3p (1)
2
Allow Ne 3s 3p
1
(d)
14 (1)
22
(e)
12
12
C atom or relative
C when taken as 12
2
(f)
(i)
(ii)
(particles must be charged) (ions) before attraction to a charged plate (or electric
field) (1)
(or only ions can be attracted or accelerated by an electric field)
or converse; if not charge not attracted to electric field
(iii)
(iv)
(g)
(i)
= 24.5 (1)
Allow 24.5 to 24.52
ignore units
(ii)
(iii)
5
[16]
23
29.
moles HCl in 25 cm
3
moles of HCl in 250 cm
moles ZCl4
Mr
Ar
Therefore element is
If not / 4 C.E. from there on but can score 2 independent marks for (mass /
moles / method and identity of element)
(for candidates who use m1v1 = m2v2 and calculate [HCl] = 0.0972 allow 1
marks
if 25 and 21.7 wrong way round only award 1/3)
st
[9]
30.
(a)
L=
1.0078
mass of 1 mol
(1) or
24
mass of 1 atom
1.6734 10
must show working
23
= 6.0225 10 (1)
Ignore wrong units
NB answer only scores 1
2
(b)
equal (1)
Or same or 1:1
24
(c)
PV = nRT (or n =
=
PV
) (1)
RT
98000 0.0352
(1)
8.31 298
= 1.39 (1)
Allow 1.390 to 1.395
ignore units even if incorrect
answer = 1.4 loses last mark
(d)
0.732
1000
3
= 2.93 (1) mol.dm (1)
250
3
OR M, mol/dm , mol.l
(e)
(i)
moles H2SO4 =
25
1.24 = 0.0310
1000
1000
3
= 2.01 (1) (mol dm )
30.8
25
(ii)
6
(f)
2
[16]
31.
(a)
(b)
12
12 or in words
26
7
[14]
32.
(a)
mass
19.6
=
(1) (= 0.537)
Mr
36.5
0.537
Concentration =
(1)
0.25
3
= 2.15 (mol dm ) (1)
mass
Conseq on
correct
Mr
Moles HCl =
(b)
(i)
21.7
0.263 = 5.7(1) 103 (mol) (1)
1000
5.7 to 5.71 10
(ii)
5.71 10 3
3
= 2.85 10 (mol) (1)
2
Conseq
(iii)
0.394
= 138 (1)
2.85 10 3
Conseq
27
(iv)
6
[9]
33.
(a)
(b)
Moles of X: n
PV
110000 2.34 10 4
(1) =
RT
8.31 473
3
= 6.55 10 (1)
6.5 to 6.6 10
RT
If write n
zero here, but can score Mr
PV
m
(1)
n
= 62 (1)
4
(c)
H = 9.68 / 1
O = 57.6(2) / 16
= 9.68
= 3.23
(1)
CH3O (1)
(d)
62
CH3O) = C2H6O2 (1)
31
1
[9]
28
34.
(a)
Ionisation (1)
High speed or high energy electrons or electron gun (1)
NOT bombard
NOT beam or stream of electrons
Ti + e Ti + 2 e worth 2 marks
Ignore state symbols
Acceleration (1)
By electric field or attraction to negative plate or electrostatic attraction (1)
NOT repelled by + plate
Allow passed through positive & negative plates / oppositely
charged plates
Not just charged plates
Deflection (1)
By magnetic field or magnet or electromagnet (1)
Detection (1)
Idea that ions collected at detector and generate current (1)
Both ions have the same m / z value (of 24) or valid arguments
48 2+
in terms of the doubled charge on Ti exactly counteracting its
doubled mass (1)
Deflected equally (so detected together) or deflection dependent
on m / z value (1)
Cant get this from previous section
10
(b)
29
(c)
12
(1) 12 (1)
mass of an atom of 12 C
mass of 1 mol of atoms
OR
(1) 12 (1)
mass of 1 mol of 12 C
Ar = (46 .0802) + (47 .0731) + (48 .7381) + (49 .0554) + (50 .0532) (1)
= 47.93 answer to 2 d.p (1)
47.92 is acceptable
Must be 5 sets of values
Ignore transcription errors BUT DONT ignore missing 100 C.E.
If missing isotope C.E.
4
[18]
35.
(a)
(b)
(c)
(i)
Protons = 24 (1)
(ii)
Neutrons = 28 (1)
(iii)
(i)
(ii)
(iii)
30
(d)
(i)
(ii)
[13]
36.
(a)
(i)
(ii)
(iii)
23/6.023 10 (1)
CE = 0 if inverted or multiplied
23
tied to M1 3.8(2) 10
2
23
(b)
1s 2s 2p 3s (1)
accept subscripted figures
(c)
(d)
15
7
2
[9]
31
37.
(a)
(b)
(c)
(d)
2
[6]
38.
(a)
(i)
(ii)
(iii)
32
(iv)
mark conseq
range = 89.5 - 90.5%
If % expression inverted, lose M4 and M5
(b)
(i)
S = 25.5/32(.1)
O = 38.0/16 (1)
= 0.794
= 2.375
= 2:1:3 (1)
If no % of oxygen Max 1 (allow M2 only)
If % for Na and S transposed, or atomic numbers used, M1 only
available
(ii)
33
39.
Calculation: n = pV/RT =
[5]
40.
(a)
(b)
(c)
Proton
Electron
mass = 1
charge = +1
4
mass 1/1800 Or 5.6 10
charge = 1
(Do not accept +1 for proton mass or g units)
1
1
(i)
13
(ii)
Si
1
1
34
(d)
1
1
(e)
1
[10]
41.
(a)
2.43 10
(mark conseq on (a)(ii))
3.01/2.43 10
(mark conseq on (a)(iii))
124
(i)
4.86 10
(ii)
2.43 10
(mark conseq on (a)(i))
(iii)
(iv)
(b)
Mr(Na2CO3) = 106
Mr (xH2O) = 250 106 = 144
(mark conseq on M1)
x=8
(mark conseq on M2)
(Penalise sf errors once only)
1
1
1
(c)
(i)
PV = nRT
(ii)
1
3
1
1
[12]
35
42.
(a)
2+
(b)
Mg (g) Mg (g) + e
+
2+
Or Mg (g) + e Mg (g) + 2e
(c)
(d)
Equation
State symbols (Tied to M1)
1
1
1
1
1
1
[8]
43.
(a)
(i)
(ii)
1
1
OR
(1)
(1)
OR
(1)
(1)
12
(b)
10
(i)
2s 2p 3s 3p 4s 3d
(accept 3d 4s )
(accept subscripts or caps)
[Penalise missing shell numbers]
(ii)
d/D
(iii)
36
[NOT 36.0]
36
(c)
63
65
(i)
(ii)
Electron from electron gun / high speed electron / high energy electron
(accept electron gun fired at)
[NOT bombarded with electrons]
(iii)
63
1
1
2+
Cu or equivalent
Notes on
(c)
(iii)
[12]
44.
(a)
100 l0 0.500 =
(ii)
27.3 10 0.600 =
(iii)
1.64 10 (mol)
Mark conseq on (ii)
(iv)
(v)
5.00 10 (mol)
(i)
accept 5 10 / 0.05
1.68 10 l32(.l)
or 1.39 10 132(.l)
Mark for Mr
= 2.22 g
or 1.83 g
37
(b)
pV = nRT
n 0.143
17
T
pV
nR
8.4(1) 10 (mol)
100000 2.86 10 4
(1)
8.31 8.4 10 3
[11]
45.
(a)
(i)
(ii)
(b)
(i)
1
1
1
1
1
(ii)
(c)
(i)
1s 2s 2p 3s 3p ;
1
1
1
38
(ii)
OR
(iii)
no difference;
OR
same chemical properties;
OR
chemical properties determined by electrons;
(M2 tied to correct answer for M1)
1
[13]
46.
(a)
moles HN03
=
175 X 10 1.5 = (0.2625 mol);
moles Pb(NO3 )2 =
0.2625 = (0.131 mol);
Mr Pb(NO3 )2
=
331(.2);
mass Pb(NO3 )2 =
331.2 x 0.131=43.5 g;
(accept 43.2 - 43.8)
(M1 & M2 are process marks. If error in M1, or in M2, do not
mark M4
consequentially, i.e. do not award M4)
(if atomic numbers used in M3, do not award M4)
1
1
1
1
(b)
(i)
pV = nRT;
pV 100000 1.5 10 4
n
;
RT
8.31 500
=
3.61 X 10 ;
(If pressure not converted to Pa, max 2)
RT
(If n =
used = CE; M2 = M3 = 0)
pV
1
1
39
(ii)
molesN02 =
4/5 3.61 10 ;
[mark is for use of 4/5]
3
Mr NO2
1
3
= 2.89 10 OR 1.7810 ;
46;
3
massNO2 =
46 2.89l0
= 0.1.33(g) OR 0.0821 (g);
( if atomic numbers used, M3 = M4 = 0)
1
[11]
47.
neutron:
relative mass = 1
(not neutral)
relative charge = 0
electron:
relative mass = 1/1800 0/negligible or
4
5.56 10 0 relative charge = 1
(b)
17
O/O
17
mass number
oxygen symbol O
(if oxygen + mass number = 17(1))
(if oxygen+ mass number = 17(0))
0
(if at N given but 8, treat as con for M2)
(if lp on Be, diagram = 0)
(ignore bond angles)
(not dot and cross diagrams)
1
1
(c)
C l
B e
Cl
C l
Cl
40
(d)
0.0343 1000
= 34.3 34.5 (cm3) (unless wrong unit)
1
(if candidate used 0.017 or 0.0171 lose M2)
(just answer with no working, if in range = (4). if, say, 34 then =(2))
(if not 2:1 ratio, lose M3 and M4)
(if work on HCl, CE = 0/4)
vol HCl =
[12]
48.
-3
(i)
(ii)
pV = nRT or n = pV/RT
moles O2 = n =
pV
100000 1.22 10 4
= (1)
(1)
RT
8.31 298
(i)
(ii)
45.9
39.1
16.5
14
37.6
(1)
16
1.17
1.18
2.35
KNO
(1)
(M3 tied to M2), (M3 can be transferred from equation if ratio correct
but EF not given) (if calc inverted, lose M2 and M3), (if used At N 1 /
wrong No for Ar then CE, lose M2 and M3) (if % of O missing,
award M2 only)
41
(c)
2 2
(accept 2KNO K N O + O )
(do NOT accept Y in equation)
[10]
49.
(a)
1
1
12
C)
identity: zinc / Zn
42
50.
(a)
(b)
37
17 Cl
1
1
(c)
(i)
2s 2p 3s 3p 3d 4s 4p
2
10
[allow reversed 4s 3d ]
[allow capitals/subscripts]
(ii)
Ar =
17 & Cl
Mass number
[Not 37.0] [Mark independently] [ignore charges]
10
= 72.4
1
[Answer to 1 d.p.] [Mark conseq on transcription error]
(iii)
(iv)
72
Ge 2 only
1
36 +
Same m/z as S
[Mark independently]
1
[11]
51.
(a)
(i)
23
in 12.(00)g of C
43
(ii)
2
Moles O2 = 0.350 (= 1.09 10 mol)
32
(iii)
= 29 ( 1.09 10 )
[Accept answers via 4 separate mole calculations]
(1)
(= 0.0438 mol)
1
1
(b)
mRT
nRT
or p =
V
V
0.873 8.31 1100
nRT
p=
=
V
1.00 10 3
pV = nRT or pV =
1
1
[11]
44