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1.
Introduction
There are several semiconductor devices that can be used to detect the presence of
photons. These devices, known as photodetectors, are used to convert optical signals to electrical
signals. When excess electrons and holes are generated in a semiconductor due to illumination
by photons, the conductivity of the semiconductor material is increased. This principle is the
basis of operation of photodetectors[1].
The main types of photodetectors are thermal and photonic detectors. The thermal effects
of the incident radiation can be followed through many temperature dependent phenomena.
Bolometers and micro bolometers are based on changes in resistance. Thermocouples and
thermopiles use the thermoelectric effect. Golay cells follow thermal expansion. In IR,
spectrometers the pyroelectric detectors are the most widespread.
The response time and sensitivity of photonic detectors can be much higher, but usually
these have to be cooled to cut thermal noise. The materials in these are semiconductors with
narrow band gaps. Incident IR photons can cause electronic excitations. In photoconductive
detectors, the resistivity of the detector element is monitored. Photovoltaic detectors contain a
p-n junction on which photoelectric current appears upon illumination.
HgCdTe[2] is a pseudo-binary alloy semiconductor that crystallizes in a zinc-blende
structure. Because of its band gap tunalbility with Hg1xCdxTe has evolved to become the most
important/versatile material for detector applications over the entire IR range. As the Cd
composition increases, the energy gap for Hg1xCdxTe gradually increases from a negative value
for HgTe to a positive value for CdTe. The band gap energy tunability results in IR detector
applications that span the short wavelength IR (SWIR: 13 m), middle wavelength (MWIR: 3
5 m), long wavelength (LWIR: 814 m) and very long wavelength (VLWIR:1430 m)
ranges. At present HgCdTe is the most widely used variable gap semiconductor for IR
photodetectors. This paper will focus on photonic detectors based on Mercury Cadmium
Telluride (HgCdTe, also known as MERCATEL in various texts)[3].
This paper summarizes the fundamental properties of HgCdTe semiconductor, and relates
these material properties, which have successful applications as an IR detector material. The
intent is to concentrate on mainly on photovoltaic detectors.
2.
Historical Perspective[6]
The 1959 publication by Lawson and coworkers triggered the development of variable
3.
structure in the vicinity of the -point of the Brillouin zone. The energy gap of this compound at
4.2 K ranges from 0.300 eV for semi-metallic HgTe, goes through zero at about x = 0.15 and
opens up to 1.648 eV for CdTe. The band structure of Hg1xCdxTe is shown in Figure 2.
Figure 2. The bandgap structure of Hg1xCdxTe near the -point for three different values of
the Eg.
3.2
(Eq. 1)
The effective mass of heavy hole mhh is high; the measured values range between
0.3 and .7mo. The value of mhh= 0.55 mo is frequently used in modeling of IR detectors. The
electron me and light hole mlh effective masses in the narrow gap mercury compounds are close
and they can be approximated by me/m 0.071 Eg, where Eg is in electronvolts.
3.3
Electron Affinity
The expression for HgCdTe electron affinity (eV) is can be approximated by the
following expression
(x,T) = 4.32 0.813 [Eg(x,T) 0.083]
3.4
(Eq. 2)
Mobilities
Due to small effective masses the electron mobilities in HgCdTe are remarkably high,
while heavy-hole mobilities are two orders of magnitude lower. The transport properties of holes
are less studied than those of electrons mainly because the contribution of holes to the electrical
conduction is relatively small due to their low mobility. Very often in transport measurements,
the electron contribution predominates even in p-type materials unless the electron density is
sufficiently low. The electron mobility in Hg1xCdxTe (expressed in cm2 V1 s1), in composition
range 0.2 x 0.6 and temperature range T >50 K, can be approximated as:
The empirical formula (valid for 0.18 x 0.25) for the variation of e with x at 300 K is:
e = 104(8.754x 1.044)1 in cm2(V-s)1
(Eq. 3)
The hole mobilities at room temperature range from 40 to 80 cm2(V-s)1, and the
temperature dependence is relatively weak. At 77 K, hole mobility is by one order of magnitude
higher. For modeling IR photodetectors, the hole mobility is usually calculated assuming that the
electron-to-hole mobility ratio b = e/h is constant and equal to 100.
3.5
Optical Properties
Optical absorption coefficient data for several alloy compositions of Hg1xCdxTe versus
wavelength are plotted in Figure 3. We can see that the absorption strength generally decreases
as the gap becomes smaller.
3.6
Lattice Constants
The use of CdTe for passivation is very promising since it has high resistivity, is lattice
matched, and is chemically compatible to Hg1xCdxTe. Barriers can be found in both the
conduction and valence band. The comparison of lattice constants of various materials is shown
in Figure 4.
3.7
GenerationRecombination Processes
The generation processes which compete against the recombination processes directly affect
4.
IR detector technology. Figure 5 illustrates the basic operation of a simple p-n homojunction
detector under illuminated zero-bias and reverse bias conditions. Incident photons with energy
greater than the material bandgap (Eph>Eg) generate electron-hole pairs in the material on either
side of the p-n junction.
Carriers generated within a diffusion length of the space-charge region diffuse to the
electrical junction and are separated by the strong electric field. The electron and hole minority
carrier diffusion lengths Ln and Lp (cm) are given by
(Eq. 5)
where n and p are the electron and hole minority carrier recombination lifetimes(s), and Dn and
Dp are the electron and hole minority carrier diffusion coefficients (cm2s-1).
Figure 5. Schematic of structure and energy band diagram of a HgCdTe p-n homo-junction
photodetector device at zero-bias (inset) and under reverse bias and illumination.
The optically excited minority carriers that are injected into the opposite side of the
junction by the Efield become majority carriers. By this process, a photocurrent density Jph is
generated by the incident radiation, increasing the dark saturation current value as illustrated in
Figure 6.
The total current density Jtotal (A/cm2) in the p-n junction photodiode is given by[3]
(Eq.6)
where Jdark depends on Vbias, and Jph depends on the incident photon flux density (ph/cm2s). In a
simple photovoltaic detector with no gain, the photocurrent is equivalent to[3]
Iph = JphA = nqA
4.1
(Eq. 7)
Detector Structure
Most commonly used photovoltaic HgCdTe photodiodes are fabricated in a homojunction
configuration with a highly doped n+ cap layer in contact with a lightly doped, narrow bandgap
p-type absorber (base) layer, or in a heterojunction configuration with wide bandgap (denoted by
capitalized letter) P+ cap layer in contact with a lightly doped, narrow bandgap n-type absorber
layer, as shown in Figure 7.
In these structures, the absorber layer determines the dark current and photo current of
the device. The base layer doping in both structures must be below1016 cm-3 to avoid tunneling
current contribution, and the doping
Figure 7. Schematic of energy band diagrams of commonly used unbiased (a) n-on-p
homojunction and (b) P-on-n heterojunction photodiodes under backside illumination
values used are typically ~51015 cm-3 and ~51014 cm-3 for p-type and n-type layers,
respectively.
where
and npo and pno are the equilibrium electron and hole concentrations (cm-3) on the p- and n-sides
of the junction, respectively. These mechanisms, several of which are illustrated in Figure 9,
include generation-recombination (G-R) in the depletion region, band-to-band (BTB) tunneling,
trap-assisted tunneling (TAT), and surface recombination. The total dark current can be
expressed as the sum of all contributions
Materials with narrow bandgaps are especially susceptible to thermal G-R processes that
dominate the dark current at high temperatures. The dark current contribution to overall current
is illustrated in Figure 10.
10
Figure 9. Schematic of structure and energy band diagram of a HgCdTep-n junction DLPH
photodetector device under reverse bias and illumination.
Band-to-band tunneling occurs when electrons at a given energy level tunnel across the
bandgap from the valence band on one side of a junction to the conduction band on the other to
fill an unoccupied state at the same energy level. Band-to-band tunneling exhibits a strong
dependence on Eg and Efield, where the field strength depends on Vbias and the doping
concentration of the junction. Trap assisted tunneling is caused by carriers tunneling within the
depletion region via intermediate trap states created by impurities or defects. The tunneling
occurs in a two-step process involving one thermal transition from the valence band to the trap
state and a second transition from the trap state to the conduction band. Because the required
transition energies are smaller, trap-assisted tunneling occurs at lower fields than band-to-band
11
tunneling. The mechanism is heavily dependent on defect density Nt (cm-3) and the trap level
Etrap (eV) within the material bandgap.
Surface current contributions can create defects or trap states that affect detector
performance. Dangling bonds at the material surface can result in a large density of interface
states that generate current via the SRH mechanism. Moreover, the presence of a net surface
charge may invert or accumulate the bandedges near the surface creating current channels or
affect the position of the junction depletion regions which intersect the surface, facilitating
tunneling or field-induced G-R currents. Wide bandgap insulators typically used to neutralize the
material surface and reduce the density of surface states.
5.
5.1
Responsitivity
The responsivity of an infrared detector is defined as the ratio of the root mean square
(rms) value of the fundamental component of the electrical output signal of the detector to the
rms value of the fundamental component of the input radiation power. The units of responsivity
are volts per watt (V/W) or ampers per watt (amp/W).
5.2
signal output equal to the rms noise output, or the NEP is the signal level that produces a signalto-noise ratio of 1. The NEP for HgCdTe detectors is about two orders of magnitude better than
any other uncooled device and only a factor of three worse than devices cooled to 80 K[6].
5.3
Detectivity
The detectivity is the reciprocal of NEP. The advantage in material preparation of
HgCdTe and detector technology have led to devices approaching theoretical limits of
responsivity and detectivity over wide ranges of temperature and background[6].
6.
and high carrier concentrations, high mobility of electrons and low dielectric constant. The
12
extremely small change of lattice constant with composition makes it possible to grow high
quality layers and heterostructures. HgCdTe can be used for detectors operated at various modes,
and can be optimized for operation at the extremely wide range of the IR spectrum (130 m)
and at temperatures ranging from that of liquid helium to room temperature.
7.
density in narrow bandgap materials, fundamentally limiting the detector performance at higher
temperatures. Thus, high performance detectors are typically operated at cryogenic temperatures
(77 K or lower). These cooling systems are extremely bulky, require high input power, and are
prohibitively costly to implement. Increasing the detector operating temperature to a range where
the cooling requirements can be met by TE coolers (193 K-253 K) is advantageous as these
systems are smaller, simpler, and less expensive to integrate
At the processing level, achieving stable, well-controlled, extrinsic p-type doping
required for p-n junction PV structures by ex situ ion implantation or in situ doping via molecular
beam epitaxy (MBE) poses a significant challenge for HgCdTe detector technology. Ex situ
doping techniques (implantation, in-diffusion) cannot easily provide the level of control over
doping profiles necessary for abrupt junction, multi-layer structures and can introduce material
damage, reducing the carrier mobilities and minority carrier lifetimes.
8.
Conclusion
HgCdTe is an important material for high performance IR photodetectors and continues
13
Annexure A
Annexure B
14
References
[1]Donald
ISBN 0-07-232107-5
[2]Antoni
Rogalski, HgCdTe Infrared Detector Material: History, Status And Outlook, Reports
on Progress in Physics, Pages from 2269 to 2331, Rep. Prog. Phys. 68 (2005) 22672336,
Published 22 August 2005, Institute Of Physics Publishing.
[3]
[4]
P. Capper and J. Garland, editors. Mercury Cadmium Telluride, Growth, Properties and