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  • OChem 4

    Enviado por

    mememe123123
    14 visualizações49 páginas
    The document is a transcript of an online organic chemistry lecture covering various topics including: organic acidity; carbonyl reactivity including tautomerization, enolate nucleophilicity, and electrophilicity; nucleophilic additions and their mechanisms such as hydride reductions, acetal reactions, imine formation, and aldol reactions; properties of carboxylic acids and their derivatives like esters; and sample organic chemistry problems and their solutions. The transcript spans 49 pages and discusses these topics in detail over the course of the lecture.

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    OChem-4---

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    The document is a transcript of an online organic chemistry lecture covering various topics including: organic acidity; carbonyl reactivity including tautomerization, enolate nucleophilicity, and electrophilicity; nucleophilic additions and their mechanisms such as hydride reductions, acetal reactions, imine formation, and aldol reactions; properties of carboxylic acids and their derivatives like esters; and sample organic chemistry problems and their solutions. The transcript spans 49 pages and discusses these topics in detail over the course of the lecture.

    Direitos autorais:

    © All Rights Reserved
    Baixe no formato PDF, TXT ou leia online no Scribd
    Sinalizar o conteúdo como inadequado
    14 visualizações49 páginas

    OChem 4

    Enviado por

    mememe123123
    The document is a transcript of an online organic chemistry lecture covering various topics including: organic acidity; carbonyl reactivity including tautomerization, enolate nucleophilicity, and electrophilicity; nucleophilic additions and their mechanisms such as hydride reductions, acetal reactions, imine formation, and aldol reactions; properties of carboxylic acids and their derivatives like esters; and sample organic chemistry problems and their solutions. The transcript spans 49 pages and discusses these topics in detail over the course of the lecture.

    Direitos autorais:

    © All Rights Reserved
    Baixe no formato PDF, TXT ou leia online no Scribd
    Sinalizar o conteúdo como inadequado
    de 49

    Elluminate Live!

    - MCAT119EARLY-O CHEM 4
    Introduction

    Page 1.

    Jan 11, 2012 12:06:44 PM

    Elluminate Live! - MCAT119EARLY-O CHEM 4


    review organic acidity

    Page 2.

    Jan 11, 2012 12:06:44 PM

    Elluminate Live! - MCAT119EARLY-O CHEM 4


    acidity summary

    Page 3.

    Jan 11, 2012 12:06:44 PM

    Elluminate Live! - MCAT119EARLY-O CHEM 4

    Jan 11, 2012 12:06:44 PM

    carbonyl reactivity - tautomerization

    Page 4.

    Elluminate Live! - MCAT119EARLY-O CHEM 4

    Jan 11, 2012 12:06:44 PM

    carbonyl reactivity - nucleophilicity of enolates

    Page 5.

    Elluminate Live! - MCAT119EARLY-O CHEM 4

    Jan 11, 2012 12:06:44 PM

    carbonyl reactivity - electrophilicity

    Page 6.

    Elluminate Live! - MCAT119EARLY-O CHEM 4

    Jan 11, 2012 12:06:44 PM

    nucleophilic additions - general mechanism

    Page 7.

    Elluminate Live! - MCAT119EARLY-O CHEM 4

    Jan 11, 2012 12:06:44 PM

    nucleophilic additions - hydride reductions

    Page 8.

    Elluminate Live! - MCAT119EARLY-O CHEM 4

    Jan 11, 2012 12:06:44 PM

    nucleophilic additions - organometallic reagents

    Page 9.

    Elluminate Live! - MCAT119EARLY-O CHEM 4

    Jan 11, 2012 12:06:44 PM

    nucleophilic additions - acetal reaction

    Page 10.

    Elluminate Live! - MCAT119EARLY-O CHEM 4

    Jan 11, 2012 12:06:44 PM

    nucleophilic additions - acetal mechanism

    Page 11.

    Elluminate Live! - MCAT119EARLY-O CHEM 4

    Jan 11, 2012 12:06:44 PM

    acetal/hemiacetal structure

    Page 12.

    Elluminate Live! - MCAT119EARLY-O CHEM 4

    Jan 11, 2012 12:06:44 PM

    acetal identification problems

    Page 13.

    Elluminate Live! - MCAT119EARLY-O CHEM 4

    Jan 11, 2012 12:06:44 PM

    original carbonyl compounds

    Page 14.

    Elluminate Live! - MCAT119EARLY-O CHEM 4

    Jan 11, 2012 12:06:44 PM

    nucleophilic additions - imine formation

    Page 15.

    Elluminate Live! - MCAT119EARLY-O CHEM 4

    Jan 11, 2012 12:06:44 PM

    nucleophilic additions - aldol reaction

    Page 16.

    Elluminate Live! - MCAT119EARLY-O CHEM 4


    how many enolates?

    Page 17.

    Jan 11, 2012 12:06:44 PM

    Elluminate Live! - MCAT119EARLY-O CHEM 4

    Jan 11, 2012 12:06:44 PM

    relative acidities of alpha protons

    Page 18.

    Elluminate Live! - MCAT119EARLY-O CHEM 4

    Jan 11, 2012 12:06:44 PM

    kinetic vs. thermodynamic enolates

    Page 19.

    Elluminate Live! - MCAT119EARLY-O CHEM 4

    Jan 11, 2012 12:06:44 PM

    reactivity and resonance structures

    Page 20.

    Elluminate Live! - MCAT119EARLY-O CHEM 4

    Jan 11, 2012 12:06:44 PM

    nucleophilic additions - Michael addition

    Page 21.

    Elluminate Live! - MCAT119EARLY-O CHEM 4


    ICC P9 text

    Page 22.

    Jan 11, 2012 12:06:44 PM

    Elluminate Live! - MCAT119EARLY-O CHEM 4


    ICC P9 Q1&2

    Page 23.

    Jan 11, 2012 12:06:44 PM

    Elluminate Live! - MCAT119EARLY-O CHEM 4


    ICC P9 Q3

    Page 24.

    Jan 11, 2012 12:06:44 PM

    Elluminate Live! - MCAT119EARLY-O CHEM 4


    ICC P9 Q4

    Page 25.

    Jan 11, 2012 12:06:44 PM

    Elluminate Live! - MCAT119EARLY-O CHEM 4


    ICC P9 Q5

    Page 26.

    Jan 11, 2012 12:06:44 PM

    Elluminate Live! - MCAT119EARLY-O CHEM 4


    ICC P9 Q6

    Page 27.

    Jan 11, 2012 12:06:44 PM

    Elluminate Live! - MCAT119EARLY-O CHEM 4


    ICC P10 text

    Page 28.

    Jan 11, 2012 12:06:44 PM

    Elluminate Live! - MCAT119EARLY-O CHEM 4


    ICC P10 Q1&2

    Page 29.

    Jan 11, 2012 12:06:44 PM

    Elluminate Live! - MCAT119EARLY-O CHEM 4


    ICC P10 Q3

    Page 30.

    Jan 11, 2012 12:06:44 PM

    Elluminate Live! - MCAT119EARLY-O CHEM 4


    ICC P10 Q4

    Page 31.

    Jan 11, 2012 12:06:44 PM

    Elluminate Live! - MCAT119EARLY-O CHEM 4


    ICC P10 Q5

    Page 32.

    Jan 11, 2012 12:06:44 PM

    Elluminate Live! - MCAT119EARLY-O CHEM 4


    ICC P10 Q6

    Page 33.

    Jan 11, 2012 12:06:44 PM

    Elluminate Live! - MCAT119EARLY-O CHEM 4


    carboxylic acids

    Page 34.

    Jan 11, 2012 12:06:44 PM

    Elluminate Live! - MCAT119EARLY-O CHEM 4

    Jan 11, 2012 12:06:44 PM

    COOH acid derivatives - synthesis from COOH

    Page 35.

    Elluminate Live! - MCAT119EARLY-O CHEM 4

    Jan 11, 2012 12:06:44 PM

    COOH acid derivatives - relative reactivities and LGs

    Page 36.

    Elluminate Live! - MCAT119EARLY-O CHEM 4

    Jan 11, 2012 12:06:44 PM

    nucleophilic addition-eliminations

    Page 37.

    Elluminate Live! - MCAT119EARLY-O CHEM 4

    Jan 11, 2012 12:06:44 PM

    COOH acid derivatives - ester formation overall

    Page 38.

    Elluminate Live! - MCAT119EARLY-O CHEM 4


    ester mechanism

    Page 39.

    Jan 11, 2012 12:06:44 PM

    Elluminate Live! - MCAT119EARLY-O CHEM 4

    Jan 11, 2012 12:06:44 PM

    COOH acid derivatives - saponification

    Page 40.

    Elluminate Live! - MCAT119EARLY-O CHEM 4

    Jan 11, 2012 12:06:44 PM

    COOH acid derivatives - predict the product

    Page 41.

    Elluminate Live! - MCAT119EARLY-O CHEM 4


    ICC P11 text

    Page 42.

    Jan 11, 2012 12:06:44 PM

    Elluminate Live! - MCAT119EARLY-O CHEM 4


    ICC P11 Q1

    Page 43.

    Jan 11, 2012 12:06:44 PM

    Elluminate Live! - MCAT119EARLY-O CHEM 4


    ICC P11 Q2

    Page 44.

    Jan 11, 2012 12:06:44 PM

    Elluminate Live! - MCAT119EARLY-O CHEM 4


    ICC P11 Q3

    Page 45.

    Jan 11, 2012 12:06:44 PM

    Elluminate Live! - MCAT119EARLY-O CHEM 4


    ICC P11 Q4

    Page 46.

    Jan 11, 2012 12:06:44 PM

    Elluminate Live! - MCAT119EARLY-O CHEM 4


    ICC P11 Q5

    Page 47.

    Jan 11, 2012 12:06:44 PM

    Elluminate Live! - MCAT119EARLY-O CHEM 4


    ICC P11 Q6

    Page 48.

    Jan 11, 2012 12:06:44 PM

    Elluminate Live! - MCAT119EARLY-O CHEM 4


    Public Screen 2

    Page 49.

    Jan 11, 2012 12:06:44 PM

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