NEET Model Papers Free Practice Set 1 Chemistry

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8 of 45 questions answered correctly
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1. 1. Question
The conversion of methyl chloride into dimethyl ether takes place by

Wolf Kishner reaction

Williamsons Synthesis

Hydroboration reaction

Kolbes reaction

Correct

2. 2. Question
Stephens reduction is used to prepare aldehyde from

Incorrect

3. 3. Question
The correct order of thermal stability of alkali metal follows the order

Incorrect

Thermal stability increases from lower member to higher member of alkali metal.
4. 4. Question
Which of the following is formed when acetophenone reacts with (C 6H5)3P = CH2?

Correct

The reaction is known as Wittig reaction

5. 5. Question
Which of the following is the correct order of basic strength of the following compounds?

I > IV > III > II

I > III > II > IV

II > IV > I > III

III > II > I > IV

Incorrect

Basic strength depends on the availability of lone pair of electron over Nitrogen atom. In I &
III structure, the lone pair is easily available but in II & IV, the electrons are displaced by the
resonance.
6. 6. Question

and its derivatives are used as

Analgesics

Antipyretics

Antihistamine

Hypnotics

Incorrect

The structure is barbituric acid. The derivatives are luminal, seconals etc which are used as
tranquilizers.
7. 7. Question
Propionic acid when heated in presence of P 2O5 gives

Acetic anhydride

Propyne

Propanoic anhydride

None of the above

Incorrect

8. 8. Question
Which of the following is not tetrahedral?

Incorrect

In case of carbonate radical,

H = [V + M C + A]
= [4 + 0 0 +2] = 3(sp2)
So the shape is trigonal.
9. 9. Question

If a and b are the initial moles of N 2 & H2 respectively in the reversible reaction N2 + 3H2
2NH3 of volume V then which of the following relation explains the K C of the reaction?

Correct

10.

10. Question

Which of the following is a wrong statement?

For a reaction of nth order, a graph of

vs t must be a straight line.

The general expression for the half life period is given by

where n is the

order of reaction.

The plot for on explosive reaction will be

A negative catalyst decreases the activation energy of the reaction.

Incorrect

A negative catalyst increases the activation energy of reaction by forming a new

intermediate of high energy. Due to increase in activation energy active molecules become
inactive. So rate decreases.
11.

11. Question

The heat of reaction for the hydrogenation of acetylene is at 25C is 42 kcal to form
ethylene. Calculate the internal energy of the reaction at the same temperature.

41kcal

42.6 kcal

40 kcal

43 kcal

Incorrect

The required equation

We know that H = E + nRT

Here n = 1 2 = 1
R = 2 cal or 2 10-3 kcal
T = 298 K
E = HnRT
=42 (1). 2 10-3 298
= 42 + 0.596 = 41.404 kcal
12.

12. Question

A metal carbonyl has the formula Cr(CO)x. What is the value of x if the effective atomic
number of Cr metal is 36?

Incorrect

Atomic number of Cr = 24.

Oxidation number of Cr = 0
Effective atomic number rule = Atomic number oxidation state + 2 Coordination number
36 = 24 0 + 2 x
Or 2x = 12
x=6
13.

13. Question

For the redox reaction

The correct coefficients of the following will be

Incorrect

14.

14. Question

The ionic radii of P3+, Sb3+, As3+, & Bi3+ is in the order of

Incorrect

The atomic sizes and ionic sizes increases along the group due to successive addition of
new shells. So Bi3+ is biggest in size and P3+ is smallest in size.
15.

15. Question

When 2 moles of NH3 are present in 1.5 litre vessel at 13 and 25 atm pressure, then

Compressibility factor of

Ideal pressure of

Compressibility factor of

Ideal pressure of

is 1.879

is 20 atm

is 0.879

is 35 atm

Incorrect

Compressibility factor

16.

16. Question

Which of the following is not a correct statement?

Asbestos is a silicate mineral.

Anglesite is a sulphate mineral.

Corundum is a carbonate mineral.

Dolomite is a carbonate mineral.

Incorrect

Corundum is an oxide mineral Al2O3.

17.

17. Question

Which of the following molecules displaces the other three from their compounds?

Incorrect

Fluorine is the strongest oxidizing power among all. So it can displace other three from their
compound as
2NaCl + F2 NaF + Cl2
18.

18. Question

Isomerisation of butane to 2-methyl propane is carried out in presence of

Incorrect

Rearrangement reaction takes place through hydride ion shift in carbonium ion.
19.

19. Question

Which of the following statements is not correct for a noble gas?

Neon gas is used in discharge tube for advertisement.

Half life of Rn is 3.8 days.

Xe is obtained by radioactive disintegration.

mixture is used for deep sea divers.

Incorrect

Radon is obtained by the radioactive disintegration due to radioactive in nature.

20.

20. Question

IUPAC name of the compound

4 Amidoethylbenzoate

Ethyl 3 carbamoyl benzoic acid

is

3 Ethoxycarbonyl benzamide

Ethyl 3 carbamoyl benzoate

Incorrect

21.

21. Question

Toluene reacts with chlorine in presence of light produces

Chlorobenzene

Benzyl chloride

Methyl chloride

o- and p chloro toluene

Incorrect

Clorination of toluene in presence of sunlight undergoes free radical substitution reaction. So

side chain reaction takes place.

22.

22. Question

In the sequence of the reaction, identify the compound B.

Propylamine

N methyl propanamine

N- methyl ethanamide

Ethanamide

Correct

23.

23. Question

In H2S, the hybrid state of sulphur is

Incorrect

The hybridization
H = [ V + M C + A]
= [6 + 2 0 + 0]
=4
So it is sp3 hybridised.
24.

24. Question

Which has maximum number of atoms?

36 gm of Fe

36 g of Carbon

36g of Al

36g of Silver

Incorrect

In (a) 56 g contains 6.023 1123 atoms

So 36 contains < 6.023 1023 atoms
(b)
12 g 6.023 1023 atom
36 g 3 6.023 1023 atoms.
(c)
27g 6.023 1023
36g 8.03 1023

(d)

25.

108 g 6.023 1023

36 g less than 6.023 1023 atoms.
25. Question

Which of the following is wrongly matched?

Elastic gel Gelatin

Butter gel

Fog Solid sol

Cord liver oil emulsion

Incorrect

Fog is aerosol. Dispersed phase Liquid,

Dispersion medium gas.
26.

26. Question

For the formation of tert butyl ethyl ether by Williamsons synthesis, the reactants used are

Sodium methoxide and sodium butoxide

Sodium methoxide and tert butyl bromide

Sodium tert butoxide and ethyl Iodide

None of the above

Incorrect

27.

27. Question

A compound is optically active but gives oxime with hydroxyl amine and also gives a positive
Fehling solution test. Give the structure of the compound.

Incorrect

The compound is aldehyde as it responds Fehling solution. The compound contains chiral
carbon atom at C2 position (*).
28.

28. Question

In which of the following compounds, the electrophilic reaction will not be in meta-position?

Incorrect

All other structures show R resonance effect so the electron density is lower in ortho and
para position. Thus first, second and fourth structures show m substitution. But the lone
pair of nitrogen in third structure can resonate to the ring to create high electron density in o
& p position.

29.

29. Question

Which one of the following represents an impossible arrangement?

n
l
m
s

2 0 0 +1/2

3 1 1 1/2

4 2 +3 +1/2

4 3 2 1/2

Incorrect

The subshell is 4d.

But l 3, l value = 2
30.

30. Question

Amide are weaker bases than amine. This can be explained by

Inductive effect

Electromeric effect

Mesomeric effect

Hyperconjugation

Incorrect

Due to resonance, the lone pair of amide is displaced to carbonyl group which decreases the
basic characters. But in amine, alkyl group increases the density of electron due to +I effect.
31.

31. Question

Match the following:

List I
(A) Antihistamine
(B) Azo dye
(C) Antibiotic
(D) Direct dyes

List II
(I) Azithromycin
(II) Martius yellow
(III) Promethazine
(IV) Methyl orange

Incorrect

Self Explanatory.
32.

32. Question

The weakest acid amongst the following is

Incorrect

CH3COOH show +I effect which decreases the acidic strength.

33.

33. Question

What will be the work done by 3 mole of an ideal gas at 27C in reversible isothermal
expansion from 3 litres to 15 litres?

10.49 KJ

12.039 J

12.039 kJ

13.3 kJ

Incorrect

Work done in isothermal expansion

W = 2.303 nRT log (V2/V1)
= 2.303 3 8.31 300 log (15/3)
= 2.303 3 8.31 300 0.6990
= 12039.6 J
= 12.039 kJ
34.

34. Question

The formula of dichlorobis(urea) Nickel (II) is

Correct

Bis means di for bidentate ligand. As it is a neutral ligand, so no special ending. All are inside
square bracket.
35.

35. Question

Which of the following elements shows highest oxidation state?

Ti

Cr

Fe

Incorrect

The oxidation state of Cr = +6( K2Cr2O7)

The oxidation state of V = +5 (V2O5)
The oxidation state of Ti = +4 (TiO2)
The oxidation state of Fe = +2 or +3 (FeCl3)
36.

36. Question

In acidic medium potassium dichromate changes to Cr 3+ ion. What will be the equivalent
weight of potassium dichromate in acidic medium (K = 39, Cr = 52)?

96

49

147

294

Incorrect

37.

37. Question

Which of following is most basic in nature?

Incorrect

Basic nature depends on the availability of lone pair of electron over nitrogen atom (Lewis
concept). All other examples (except NH3) contain electronegative halogens which
decreases the electron density over nitrogen. In
Hence more basic.
38.

, the lone pair is easily available.

38. Question

Which of the following methods is not used for the extraction of Al metal?

Bayer process

Serpek Process

Van-Arkel Process

Hall Process

Correct

Van-Arkel process is used for the extraction of zirconium and titanium.

39.

39. Question

The hybridization of interhalogen compound like ICl 7 is

Incorrect

The hybridization
H = [ V + M C + A]
= [7 + 7] = 7. So sp3d3.
The shape is pentagonal bipyramidal.
40.

40. Question

20 ml of ethane burnt with 70 ml of oxygen. The volume of gas left after cooling to room
temperature will be

70 ml

60 ml

50 ml

40 ml

Correct

Ratio of their volume is 2:7:4

2 vol =20 ml
4 vol of CO2 = 2 20 = 40 ml
41.

41. Question
Which of the following elements shows highest 1st ionization potential?

Nitrogen

Oxygen

Magnesium

Helium

Correct

Ionization potential decreases along a group & increases along a period. Helium shows
highest ionization potential in the periodic table. This shows due to smallest atomic size.
42.

42. Question

The IUPAC name of

3 Oxo 5, 5 dimethylcyclohexanal

4, 4-Dimethyl 2 oxo cyclohexane 1 carbaldehyde

5, 5-Dimethyl cyclohex 1, 3 dione

3, 3-Dimethyl 6 formyl cyclohexan 1 one

Incorrect

43.

43. Question

The correct order of decreasing SN2 reactivity is

Incorrect

3 follows SN1 reaction

1 follows SN2 reaction
2 follows either SN1 or SN2
So decreasing order follows 1 > 2 > 3
44.

44. Question

Which of the following is most basic?

Incorrect

Methyl amine shows +I effect which increases the basic strength due to high density of lone
pair of electron over the nitrogen atom.
45.

45. Question

A reaction cannot take place spontaneously at any temperature when

both H and S are positive

both H and S are negative

H is ve and S is positive

H is +ve and S is negative

Incorrect

Gibbs equation is G = H TS
(i) The reaction is spontaneous if G = ve
(ii) The reaction is non spontaneous If G = +ve
(iii) The reaction is in a state of equilibrium if G = 0
If H is +ve and S is ve than
G = +ve T(ve)
= +ve
So option d is correct.