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DOI: 10.1039/c4cc04133j
www.rsc.org/chemcomm
Communication
ChemComm
Table 1
Cyrene
EN
T
a
b
p*
dD/MPa0.5
dP/MPa0.5
dH/MPa0.5
BP/1C
r/g mL 1
a
0.333
0.00
0.61
0.93
18.8a
10.6a
6.9a
203
1.25
NMP
Cyclohexanone
17
0.355
0.00
0.75
0.90
18.016
12.316
7.216
2021
1.0320
17
0.281
0.005
0.585
0.715
17.816
6.316
5.116
1551
0.95
DMF
DMAc
17
0.386
0.0018
0.7119
0.8819
17.416
13.716
11.316
1531
0.9420
17
0.377
0.0018
0.7319
0.8519
16.816
11.516
10.216
1651
0.9420
DMSO
17
0.444
0.0018
0.7419
1.0019
18.416
16.416
10.216
1891
1.1020
Sulpholane
0.41017
0.00
0.30
0.96
20.316
18.216
10.916
2821
1.2620
ChemComm
Communication
Fig. 2 (A) A LSER of the Menschutkin reaction and (B) rates of fluorination
in dierent solvents.