SA 15 16 XII XII Chemistry Unit-4 Section-A

Miscellaneous Questions
UNIT
Section - A : Straight Objective Type

1.
Answer (2)
Change in angular momentum = (n 2 n1 )
2.
h
h
h
(2 1)
2
2 2
Answer (3)
m = +4
=4
n=5
for n = 5 number of waves will be 5

3.
Answer (3)
Molecular mass of MCln = 62.25 2 = 124.5
x + n 35.5 = 124.5
6n + 35.5 n = 124.5
n=3
4.
Answer (1)
NaOH + H2CO3 NaHCO3 + H2O
In this reaction only one H-atom is replaced from the acid H2CO3
n-factor of H2CO3 = 1
Equivalent mass of H2CO3 =

5.
molecular mass 62
62
n - factor
1
Answer (3)
vn = 2.18 106 m/s for H-atom, z = 1, n = 1
v = 2.18 106 = x
for Be3+ z = 4, n = 2
z
4
v Be3 2.18 10 6 2.18 10 6 2x
n

2
6.
Answer (1)
n 2 2r2
rn n2
2 = 2 4a
= 4a
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192
7.
Success Achiever (Solutions)
Answer (4)
K 2Cr2O 7 14 HCl 2 KCl 2 CrCl3 3 Cl2 7 H2O
In this reaction only 6Cl ions of HCl changes its oxidation number therefore n factor of HCl
equivalent mass of HCl
8.
6
3
14 7
M
7M
3/7
3
Answer (3)
3C Al 2O 3 4 Al 3 CO 2
3 12 g
9.
4 27 g
108 g Al is produced by consuming = 36 g carbon
270 103 is produced by consuming =
36
270 10 3 = 90 kg
108
Answer (4)
Average atomic mass =
P M Q(M 2) R(M 4)
PQR
where P, Q and R molar ratio of isotopes
P M Q(M 2) R(M 4)
(M 1)
(P Q R)
This equation is satisfied only when P : Q : R = 4 : 1 : 1

10. Answer (2)
Total number of spectrum =
n(n 1)
15
2
n=6
Electron should drop from higher level to 1st energy level therefore lines belongs to ultraviolet region are 5.
10a.
Answer (2)
[JEE (Main)-2014]
Let the mass of O2 = x

Mass of N2 = 4x
Number of moles of O2
x
32
Number of moles of N2
4x
x
=
7
28
Ratio
x x
: = 7 : 32
32 7
11. Answer (4)

nRT2 nRT1
Work done = PV = P
P
P
= nRT
= 2 8.314 1 = 16.628 J
193
12. Answer (3)

Since 1 mole of P4 gives 2 moles of P2O5
Mass of P2O5 = 2 142 = 284 g
13. Answer (4)
For gas A,
PV
P = 1 atm, W = 2 g
M = MA
W
RT
M
2
RT
MA
...(i)
For gas B, P = 0.5,
W=3g
1 V
0 .5 V
3
RT
MB
M = MB
...(ii)
Dividing equation (i) by (ii)

1
2 M
B
0 .5 3 M A
MA : MB = 1 : 3
14. Answer (2)
3R( t 273 )
M
3RT
(M = molecular mass of nitrogen)
Now then temperature becomes (2t + 273 + 273) K and molecules dissociates into atoms therefore atomic
mass becomes
v'
M
2
3R( t 273 )
3R(2t 546 )
2
2v
M
M/ 2
15. Answer (1)
Cp
Cv
0.125 5
1.67
0.075 3
Therefore gas is monoatomic therefore number of atoms present in 1 mole of gas is 6.023 1023
16. Answer (3)
PCl5(g)
Initial pressure
0.37 atm
Pressure at equlibrium (0.37 x) atm
PCl3(g)
0
x
Cl2(g)
1.73
(1.73 + x)
x(1.73 x )
0.082
(0.37 x )
Since Kp is very small x can be neglected compared to 0.37 and 1.73
x = 0.017
final pressure = (0.37 0.017) + 0.017 + (1.73 + 0.017)
= 2.12 atm
194
17. Answer (3)

2, 4, 6, - trinitrophenol is called picric acid. Although it is a phenol but it is highly acidic due to the presence
of three very strong electron withdrawing groups. So picric acid will liberate CO2 from NaHCO3.
18. Answre (3)
B(OH)3 in aqueous medium co-ordinate with a molecule of water to form the hydrated species H2O B(OH)3.
In the species B3+ ion because of its small size exerts a high polarising power thereby pulling sigma electron
charge of the co-ordinated oxygen atom toward itself co-ordinated oxygen in turn pulls the sigma electron
of OH bond toward itself. This facilitates the removal of H+ ion from OH bond.
B(OH)3 + H2O [B(OH)4] + H+
Therefore H+ ion does not come from acid molecule rather arises from water
So H3BO3 is not protonic acid.
19. Answer (2)
Normality =
Molarity =
1000 8 10 5
4 10 4 N
200
4 10 4
2 10 4
2
[Ba 2 ] [SO 24 ] 2 10 4 M
KSP = [Ba 2 ] [SO 24 ] = (2 104)2 = 4 108 M2
20. Answer (4)
Silicones are a group of condensation polymers formed as a chain of silicon and oxygen atoms
R
R
SiOSiO
R
R
all silicones are water repellant.
21. Answer (1)
From the given information it is clear that complex gives two ions per molecule of the complex as a result of
ionization of primary valency in solution. Thus complex should have the formula [CrCl2.xNH3]Cl further more
the C.N. of chromium is six. So it should be [Cr(NH3)4Cl2]Cl. Hence Cl, X is 4.
22. Answer (2)
CaCl2 cannot be used as it form alcohol solvated CaCl2 salt (CaCl2.5 ROH), anhydrous Na2SO4 is preferably
used but BaO and K2CO3 will serve to some extent.
23. Answer (2)
Angular momentum of an electron in 3rd orbit of an atom is given by
3h 1.5 h
mvr
24. Answer (2)

Mass of HCO3 in kg or 106 mg water = 244 mg
millimoles of HCO 3
244
4
61
Ca(HCO3)2 + CaO 2CaCO3 + H2O

millimoles of CaO = 2
mass of CaO = 56 2 = 112 mg
195
25. Answer (4)

All ionic carbides on hydrolysis will yield hydrocarbons while covalent carbides will not. SiC is covalent carbide.
26. Answer (4)
Being covalent compound HgCl2 cannot furnish Cl ion in water so it does not respond to chromyl chloride
test.
27. Answer (2)
In aqueous solution of both, forms a constant change in the value of specific rotation is observed for -D
glucose the specific rotation gradually falls from + 112o to + 52.7o while for -D glucose specific rotation
gradually increase from +19o to + 52.7o.
Such a change in rotation of each isomeric forms upto a constant value in aqueous solution is termed as
mutarotation.
28. Answer (1)
Out of four oxyacids of phosphorus given only H3PO2 has a H-atom directly bonded to phosphorus. This
hydrogen is not acidic but can reduce salts to metal, for example
H3PO2 + H2O H3PO3 + 2H
2 AgNO3 + 2H 2 Ag + 2 HNO3
29. Answer (3)
Nylon gives biuret test as it is the condensation product of hexanedioic acid and hexane, 1, 6 diamine but
cotton would not. Cotton is natural fibre basically made up of cellulose so it gives Molish test while nylon
respond negatively to this test.
29a.
Answer (1)
(AIEEE 2012)
30. Answer (2)

Boiling point of liquid =
H 50000
454.5 K
S
110
31. Answer (1)

According to Charles law, at constant pressure, the volume of a given sample of an ideal gas varies with
temperature as
t
v t v 0 1
273
32. Answer (1)
ONa
OH
(i) CO2 high P, T
COOH
(ii) H
Salicylic acid (major)
32a.
Answer (2)
(AIEEE 2009)
OH
OH
CO2
COOH
NaOH
Salicylic acid
196
32b.
Answer (1)
[JEE (Main)-2014]
O
O=C=O
H O
C
O
OH
OH
COOH
(CH3CO)2O
COO
(B)
OCOCH3
COOH
(C)
33. Answer (1)
Boron nitride BN has graphite like structure. It is known as inorganic graphite.
34. Answer (1)
HI
O CH 2
CH2I +
OH
35. Answer (1)

H+ has more reduction potential than Na+ there H2 gas evolves at cathode
2 H 2 e H2 (cathode )
In OH and SO 24 , OH has more oxidation potential therefore O2 gas is evolved at anode
4 OH 2H2O O2 4e (anode)
36. Answer (4)
H
C6H5NO2 6 [H]
C6H5NH2 2 H2O
6 F is needed to reduce = 123 g of nitrobenzene
24.6 g required =
6
24.6 1.2 F
123
37. Answer (1)

(CH3 )3 C MgBr D 2O (CH3 )3 CD Mg(OD)Br
38. Answer (2)
Carbanion is less stable in nucleophilic substitution reaction.
39. Answer (1)
Cl is weaker base amongst given leaving group therefore better leaving group.
197
40. Answer (3)
3 C(g) + D(g)
A(g) + 2 B(g)
Initial moles
At equilibrium
aX
2a
2a 2X
3X
According to condition
2a 2X = 3X
5X = 2a
2a
X
5
% of B reacted =
2X
2(2a / 5)
100
100 40%
2a
2a
41. Answer (1)
K P PCO2
PV = nRT
1.5 10 = n 0.082 400
n = 0.457 moles of CO2
Moles of CaCO3 remains unreacted = (0.5 0.457) = 0.043

% of CaCO3 remain unreacted =
0.043
100 = 8.6 %
0.5
42. Answer (3)

Shortest wavelength
1
1
R (2)2 4R
min
1
min
1
X
4R
Longest wavelength in Balmer series for Li2+

1
5
1 1
R (3)2 9R
36
4 9
1 5R
4
16 X
5R
5
43. Answer (3)

KE = h W
4h 4W = 2h W
x = h W
...(i)
3W = 2h
4x = 2h W
...(ii)
3.h0 = 2h
The value of X from eq. (i)

put into eq. (ii)
4(h W) = 2h W
2
3
198
44. Answer (4)

Q = i t = 10 965 = 9650 C
2 96500 C charge required for deposition of 1 mole Zn2+
9650 C charge required for deposition of
Initial moles = 1
300
0 .3
1000
Moles of Zn2+ remaining in solution = 0.3

Molarity of Zn2+ =
1
1
9650
mole of Zn2+
2 96500
20
1
0.25 mole
20
0.25
1000 M 0.833 M
300
45. Answer (3)

Reaction is Cu 2 2e Cu(s)
[OH] = 101
pH = 13
Cu2+ + 2OH
Cu(OH)2
Ksp = [Cu2+] [OH]2
1018 = [Cu2+] [101]2

[Cu2+] = 10 16
E cell Ecell
0.0591
1
log
2
[Cui2 ]
E cell 0.34
0.0591
1
log 16
2
10
Ecell = 0.34 0.4728

= 0.1328 V
46. Answer (4)
OH
NO2
conc. HNO3+H2SO4
Zn/
Zn+NaOH
NH
NH
(A)
47. Answer (2)
Cu2S + 2 Cu2O 6 Cu + SO2
(Self reduction)
48. Answer (1)

Tf = imKf
0.0193 = i 0.01 1.86
i = 1.037
CH3COOH
1
CH3COO + H+
i = 1 + = 1.037
% = 3.7 %
199
49. Answer (2)

The n = 4, = 2 represent 4d-orbital, 4d-orbital has highest energy amongst the given orbitals
50. Answer (3)
Ptotal X A PAo XB PBo

550 =
3 o 1 o
PA PB
4
4
3 PAo PBo 2200

560
...(i)
4 o 1 o
PA PB
5
5
4PAo PBo 2800
...(ii)
From equation (ii) and (i)
PAo 600 mm of Hg
51. Answer (3)
HCOOH evolves CO2 gas when treated with NaHCO3 but HCHO does not evolves CO2
HCOOH NaHCO 3 HCOONa H2O CO 2
52. Answer (3)
C6H5CHO does not give precipitate with Fehlings reagent.
53. Answer (1)
CH CH + H2O
HgSO4 + dil H2SO4
Tautomerise
CH2 = CH
O
CH3 C H
OH
54. Answer (2)
O
CH3
54a.
O
18
16
O C2H5 + H2O
CH3
16
18
O H + C2H5O H
Answer (3)
(AIEEE 2009)
H
Liquid + ethanol
Fruity smell compound
Carboxylic acid
Must be ester
H
CH3COOH + C2H5OH
CH3COOC2H5
200
55. Answer (1)
O
NaOH
CH3CHCH3
CH3CHCH3
Cl
I2(oxidation)
OH
CH3
CH3
I2+ NaOH
CH3COONa + CHI3
yellow ppt
56. Answer (2)
180
In BeCl2 the shape is linear Cl
Be
Cl
F
120o
In BF3 the shape is triangular planar
F
The bond angle in NH3 is less than CH4 because presence of one lone pair of electron at central atom.
57. Answer (2)
Mg2C3 exists as 2Mg2+ + C34
4
C=C=C
57a.
therefore 2 and 2 bonds are present
Answer (2)
[JEE (Main)-2014]
It contains Cs+ and I3 ions.

58. Answer (1)
W
= PV = 420 J = nRT
U = nCT
5
5
= n RT nRT
2
2
=
5
420 1050 J
2
59. Answer (1)

KP
2
PSO
3
2
PSO
P
2 O2
nSO3 nSO2
KP
1
PO2
PSO3 PSO2
PO2 0.1 atm
201
60. Answer (2)

2
1
O O+2 O
1
+1
+1
Cr
+1+1
Oxidation no. of Cr = + 6, two peroxylinkage are present.

61. Answer (3)
oxidation
+2 1
+3
FeS2
+4
3+
Fe + SO2
oxidation
n factor of FeS2 = 1 + 5 2 = 11
equivalent mass of FeS2 =
M
11
62. Answer (4)

In CH4, NH3 and H2O all have 10 electrons therefore isoelectronic.
In Na+, Mg2+, Al3+, F all have 10 electrons therefore isoelectronic

In CO32 , NO3 and SO2 all have 32 electrons therefore isoelectronic
62a.
Answer (1)
[JEE (Main)-2014]
Nitric oxide is paramagnetic in the gaseous state as it has one unpaired electron in its outermost shell.
The electronic configuration of NO is
2
2 * 2 *
1s
1s 2s 2s 22pz 22px 22py *2px
However, it dimerises at low temperature to become diamagnetic.

2NO
N2O2
Its bond order is 2.5 and it combines with O2 to give nitrogen dioxide.
63. Answer (1)
b
b
C C
this compound does not exhibit geometrical isomerism because in this compound there is two
identical group present on the same carbon.

63a.
Answer (2)
CH3
(AIEEE 2009)
C
CH3
H
H
cis-2-Butene
and
CH3
CH3
H
trans-2-Butene
202
64. Answer (2)
Cl
Cl
P
Cl
Cl
Cl
Shape-trigonal bipyramidal; dipole moment = 0
65. Answer (2)
Volume of hall = (5 102)3 = 1.25 108 cc = 1.25 105 litre
Total moles of air present in the hall =
The mass of air in the hall =
1.25 10 5
5580
22.4
3
1
5580 28 10 3 5580 32 10 3
4
4
= 160 kg
66. Answer (4)
+3
+5
3 BrF3 + 6 H2O
66a.
2HBrO3 + HBr + 9 HF
Answer (4)
[JEE (Main)-2014]
The reducing agent oxidises itself.

(a) H2O21 2H 2e
2H2O2
0
(b) H O1 2e
O2 2H
2 2
2
(c) H O 1 2e 2OH
2 2
0
(d) H O1 2OH 2e
O2 H2O
2 2
Note : Powers of 'O' are oxidation number of 'O' in the compound.
67. Answer (3)
Cl
I
Cl
Cl
68. Answer (1)
There are few biunit compound whose each unit contains two or more atoms of which at least one is nitrogen,
have similar property to that of halogen these are called Pseudohalogen such as (CN)2, (SCN)2
(Se CN)2 (OCN)2
69. Answer (4)
There are weak bonds between p orbitals of oxygen and d-orbital of silicons atoms.
203
70. Answer (3)
S 2O32 ion evolves SO2 with dil. H2SO4

S 2O 32 2H SO 2 H2O S
Precipitate
SO2 causes turbidity in baryta water

Ba(OH)2 + SO2 BaSO3 + H2O and also reduces acidified dichromate solution
71. Answer (2)
Polyamide and polyester are example of condensation polymer.
72. Answer (3)
OH
CHO
OH
CHO
OH
C
73. Answer (1)

The Lassaignes test for nitrogen infact is the test of CN ion formed in sodium extract since both (NH2 NH2) and
nitric acid HNO3 do not contain carbon alongwith nitrogen so these are unable to respond this test.
Diazocompound lose nitrogen even at moderate temperature hence do not respond to Lassaignes test.
74. Answer (1)
Equivalent of silver salt of monobasic acid = equivalents of Ag metal
100
59.6
Equivalent weight silver salt 108
Equivalent weight of Ag salt = 181.20

Equivalent weight of acid = Eq. wt. of Ag salt 108 + 1
Molecular weight of acid = 181.20 107 = 74.20 = 74
So, molecular formula of the acid will be CH3CH2COOH
75. Answer (3)
Zinc is volatile metal with low melting point. So it is purified by distillation process.
76. Answer (3)
Since net charge over cation is + 2. So ligand must contain 1 as the net charge over them. As H2O and NH3 are
neutral legand, So O2 must be in form of superoxo ion.
77. Answer (1)
Nesselers reagent K2HgI4 is infact K2 [HgI4]
78. Answer (3)
F
Cl
Al
Cl
Cl
Triangular planar
Al
F F F
Tetrahedral
204
79. Answer (3)

Langmuir adsorption isotherm is applicable to adsorption provided it is monolayer thick.
80. Answer (1)
As 0.1 mole of Cr (III) chloride in water gives 0.3 mole of AgCl and chromium shows co-ordination no. 6, therefore
most probable formula of complex is [Cr(H2O)6]3+.
81. Answer (3)
Ca(OH)2 + CO2 CaCO3 + H2O
100 g CaCO3 formed from = 22.4 litre CO2 at STP
0.5 g CaCO3 formed from
22.4
0.5 litre
100
= 0.112 litre
% of CO2 in carbogen
112
100
2000
= 5.6
82. Answer (4)
t1
2
1
Cn01
K
C 02
C02 T K
C 0 T = constant
order of reaction = 3
83. Answer (1)
At equilibrium
PCl5 (g)
PCl3(g) + Cl2 (g)
Total moles of equilibirium = 1 +

Kp =
=
2
1 2
Ptotal
1
2
1
4 P
Kp =
total
1
1
4
Kp =
Ptotal
3
Ptotal = 3 Kp
205
84. Answer (2)

1
(wave number) only one line observed in Paschen series it means upper level is n = 4
1
1 1 15 R
R 2
16
min
1 4
max
min
7R
1 1
R
9 16 16 9
max
max : min
15R 9 16
135 : 7
16
7R
85. Answer (2)

5
34
Molarity = 100
1000
50
1.47 M
34
86. Answer (2)
pH pK a log
Salt
Acid
Ka Kb = 1014
Ka = 105
pKa = 5
pH = pKa
[Salt] = [Acid]
=5
87. Answer (3)
K f 0.6932

t
1
2 f
K b 0.6932

t
1
2 b
K eq

t1
2 b
250
Kf
0.625
400
Kb

t1
2f
206
88. Answer (3)

Let the mass of X is a g
Molar mass of X4 O6 = (4a + 96) g
mass of X in 10 g X4 O6 =
4a 10 5.72
96 4a
40 a = 5.72 96 + 5.72 4a
a = 32 g
Atomic mass of X is 32 amu
89. Answer (1)
R u12 u 22 2u1u 2 cos

It is clear that is maximum when = 90
90. Answer (4)
Ksp = [Mg2+] [OH]2
1.2 10 11 = 0.1 [OH]2
[OH] = (1.2 1010)
[OH] = 1.1 105
pOH = 5 log 1.1 = 4.96
pH = 14 4.96 = 9.04
91. Answer (2)
According to Henry law
S = KH P
P
S
1.8 10 4
= 8.45 atm
K 2.13 10 5
92. Answer (3)

Effective no. of carbon atoms present at corners 8 1 1
8
Effective no. of carbon atoms present at face centres =
1
6 3
2
1
4
2
Total effective carbon atoms present in a unit cell of diamond is 8.
Effective no. of carbon atoms in tetrahedral holes = 8
93. Answer (3)

OH
In salicylic acid there is Intramolecular H-bonding is present
COOH
94. Answer (1)

Adsorption is always exothermic.
94a.
Answer (3)
(AIEEE 2009)
Physisorption is an exothermic process with H 20 kJ/mol

207
95. Answer (1)

The co-ordination no. and the charge on ions always balance out to give neutrality.
96. Answer (2)
Any symmetrical molecule will have zero dipole moment BF3 being the only symmetrical species as its shape is
trigonal planar will have zero dipole moment.
97. Answer (1)
Pb(NO3)2 + Na2SO4 PbSO4 + 2NaNO3
moles of Pb(NO3)2 = 20 0.1 103 = 2 103
moles of Na2SO4 = 30 0.1 103 = 3 103
Therefore Pb(NO3)2 is limiting reagent therefore mole of PbSO4 formed is 0.002 moles.
98. Answer (4)
1
eq. of Na2CO3 = eq. of HCl
2
moles of Na2CO3 = 0.2 50 103 = 10 103
equivalent of Na2CO3 = 20 103
1
20 103 = 20 103 x
2
x=
10
x = 0.5
20
99. Answer (4)

+3
+5
+6
Cr(OH)3 + OH + IO3 CrO4 + H2O + I
(n = 6)
Reduction
IO3 acts as a oxidising agent

100. Answer (1)
Kp depends only on temperature.
101. Answer (1)
Packing fraction in primitive cubic unit cell is
x (given)
6
4 3
r
16 r 3
3
2x
3
3 = 3 2
3
2
16
r
2 2r
4
Packing fraction in FCC =
102. Answer (2)

2CaCO3 + 2HCl
Ca(HCO3)2 + CaCl2 + H2O
In Presence of phenolphthalein
Let equivalent of CaCO3 = a
a
equivalent of CaCO3 = equivalent of HCl
2
equivalent of HCl =
0.005 =
50 0.1
1000
a
, a = 0.01,
2
0.005
wt. of CaCO3 = 0.5
208
103. Answer (3)

n1V1M1 = n2V2M2
2 100 x = 1 100 0.1
0.1
0.05
2
104. Answer (3)
x
2s
4r dr
2
2p
4r22dr
a
b
a<c<b
105. Answer (2)
Velocity is independent of mass.
106. Answer (1)
H
Heg
for
72

He
Li
Be
54
57
66
duplet is completed
107. Answer (4)

Fact
108. Answer (4)
BeCl2 exists as monomer, dimer and polymer.
109. Answer (3)
Due to deviation of electron bond angle decreases.
110. Answer (3)
111. Answer (3)
V
P
T
112. Answer (4)
Fact
113. Answer (2)
All statement are true but only option (2) is correct reason
114. Answer (4)
PCl5
PCl3
Cl2
At equilibrium y + 2a = 1.2
2
0.4
On solving we get, a = y = 0.4

Now
x
1
Pa,
0.5
209
115. Answer (1)

pH = pK a + log
Salt
Acid
as [Salt] = [Acid], pH = pKa

116. Answer (4)
2
+1
C O O H
+2
+1
1
+2
117. Answer (1)

Fact
118. Answer (4)
Factual
119. Answer (4)
All defects increase dielectric constant.
120. Answer (4)
Fact
121. Answer (4)
The value of would be measurable compared to other properties
122. Answer (1)
Area under curve = charge passed = 2 coulomb z
M
2
123. Answer (1)
NO 2 + H2O NO3 + 2H + 2e
o
EE
0.0591
lo g H
2
E increase by 0.24 V
124. Answer (3)
1 1
1
K
t A A 0 ... For 2nd order

t 1/2 =
2
kA 0
125. Answer (2)

Fact
126. Answer (2)
Every solid substance shows physisorption
127. Answer (4)
The catalysis is function of extent of adsorption
210
128. Answer (2)

Fact
129. Answer (2)
Diazo compounds give N2 readily, therefore, Duma's method is used.
130. Answer (2)
Fact
131. Answer (3)
Pka of alcohol is less than that of -hydrogen
132. Answer (4)
Cyclopropane has very high strain & gets ruptured very easily.
133. Answer (2)
For SN2, greater the nucleophilicity greater will rate of reaction.
134. Answer (4)
Cl
+ C2H5OH
Cl
Phosgene
O C
O C
C2H5
C2H5
Diethyl carbonate
non-toxic
135 Answer (3)

In absence of H+ ions esterification does not happen and conjugation in product makes it more stable
136. Answer (2)
Fact
137. Answer (3)
OH
R
CH
O
CN
CH3O
CH
O
CN
CN + R CH
138. Answer (1)

Fact
139. Answer (2)
Fact
140. Answer (2)
Nitro alkanes having -hydrogen give aldol condensation with aldehydes.
141. Answer (1)
HNO
2
R 2NH
R 2 N NO
142. Answer (4)

Fact
143. Answer (4)
Fact
211
144. Answer (4)

Fact
145. Answer (3)
1% phenol is used as disinfectant.
146. Answer (4)
Poling is done to remove impurity of oxides of Cu.
147. Answer (4)
Sn has impurity of heavier element which are removed by liquation.
148. Answer (2)
Fact
149. Answer (3)
Fact
150. Answer (2)
Fact
151. Answer (2)
Both are group II members.
152. Answer (3)
Fact
153. Answer (4)
Fact
154. Answer (4)
MgCl2.6H2O suffers hydrolysis on heating
155. Answer (1)
Fact
156. Answer (4)
Fact
157. Answer (1)
Hg2SO4 + 2NaCl Hg2Cl2 + Na2SO4
158. Answer (3)
CN is a strong field ligand cause pairing hence
159. Answer (3)
EAN = Atomic number oxidation number + (C.N 2)
28 2 + 8 = 34.


SA 15 16 XII XII Chemistry Unit-4 Section-A

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SA 15 16 XII XII Chemistry Unit-4 Section-A

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Miscellaneous Questions

Section - A : Straight Objective Type

for n = 5 number of waves will be 5

Equivalent mass of H2CO3 =

Success Achiever (Solutions)

108 g Al is produced by consuming = 36 g carbon

270 103 is produced by consuming =

where P, Q and R molar ratio of isotopes

This equation is satisfied only when P : Q : R = 4 : 1 : 1

Let the mass of O2 = x

11. Answer (4)

Success Achiever (Solutions)

12. Answer (3)

For gas B, P = 0.5,

Dividing equation (i) by (ii)

14. Answer (2)

(M = molecular mass of nitrogen)

15. Answer (1)

Pressure at equlibrium (0.37 x) atm

Success Achiever (Solutions)

17. Answer (3)

24. Answer (2)

Ca(HCO3)2 + CaO 2CaCO3 + H2O

Success Achiever (Solutions)

25. Answer (4)

30. Answer (2)

31. Answer (1)

32. Answer (1)

Salicylic acid (major)

Success Achiever (Solutions)

35. Answer (1)

6 F is needed to reduce = 123 g of nitrobenzene

37. Answer (1)

Success Achiever (Solutions)

40. Answer (3)

41. Answer (1)

Moles of CaCO3 remains unreacted = (0.5 0.457) = 0.043

42. Answer (3)

Longest wavelength in Balmer series for Li2+

43. Answer (3)

The value of X from eq. (i)

Success Achiever (Solutions)

44. Answer (4)

2 96500 C charge required for deposition of 1 mole Zn2+

9650 C charge required for deposition of

Moles of Zn2+ remaining in solution = 0.3

45. Answer (3)

1018 = [Cu2+] [101]2

Ecell = 0.34 0.4728

48. Answer (1)

Success Achiever (Solutions)

49. Answer (2)

Ptotal X A PAo XB PBo

3 PAo PBo 2200

4PAo PBo 2800

From equation (ii) and (i)

HgSO4 + dil H2SO4

Success Achiever (Solutions)

55. Answer (1)

In BeCl2 the shape is linear Cl

In BF3 the shape is triangular planar

therefore 2 and 2 bonds are present

It contains Cs+ and I3 ions.

59. Answer (1)