Escolar Documentos
Profissional Documentos
Cultura Documentos
COORDINATION CHEMISTRY
Setia Budi
Jurusan Kimia, Universitas Negeri Jakarta
sb/vbt
s, p and d orbitals
sb/vbt
Orbitals hybridization
Hybridization: Linear combination of
atomic orbitals on an atom
(goldbook-IUPAC), to form new hybrid
orbitals suitable for the qualitative
description of atomic bonding
properties
sb/vbt
Hybrid orbitals
sp
[Ag(CN)2]-
sb/vbt
Hybrid orbitals
sp2
[Cu(CN)3]2-
sb/vbt
Hybrid orbitals
sp3
[CoCl4]2-
sb/vbt
3d
4s
4p
4sp3
paramagnetic
sb/vbt
Hybrid orbitals
dsp2
[Cu(NH3)4]2+
sb/vbt
6s
6p
dsp2
square planar
sb/vbt
setia budi/inor3/vbt
10
Hybrid orbitals
sp3d
[SnCl5]2-
sb/vbt
setia budi/inor3/vbt
11
Hybrid orbitals
sp3d2
[Fe(H2O)6]2+
sb/vbt
setia budi/inor3/vbt
12
Example 1: [Co(NH3)6]3+
Co [Ar] 3d7 4s2
Co3+ [Ar] 3d6
Inner orbital complex
3d
4s
4p
4d
d2sp3
octahedral
Diamagnetic complexes
sb/vbt
setia budi/inor3/vbt
13
Example 2: [CoF6]3
Co [Ar] 3d7 4s2
Co3+ [Ar] 3d6
Outer orbital complex
3d
4s
4p
4d
4sp3d2
octahedral
Paramagnetic complexes
sb/vbt
setia budi/inor3/vbt
14
Electroneutrality principle
Electroneutrality principle expresses the tendency of all pure substances to carry a net
charge of zero
Complexes would be most stable when the electronegativity of the ligand was such that
the metal achieved a condition of essentially zero net electrical charge.
One difficulty with the VB assumption of electron donation from ligands to metal ions is
the build up of formal negative charge on the metal
sb/vbt
15
Electroneutrality principle
Explain briefly of the following fact:
[Be(H2O)4 ]2+ is stable, while [Be(H2O)6]2+ is not.
[AI(H2O)6 ]3+ is more stable than [AI(NH3)6]3+.
sb/vbt
16
Back bonding
Opposite to the electroneutrality principle,
Many complexes in which the metal exists in a low oxidation state and yet is
bonded to an element of fairly low electronegativity.
CO is the prominent ligand for such complex
When central atom is bound to atom carbon in the ligand, the source of
stability in these complexes is the capacity of the carbon monoxide ligand to
accept a "back donation" of electron density from the metal atom (described in
term of resonance)
sb/vbt
17
18
sb/vbt
setia budi/inor3/vbt
19
20
21
sb/vbt
setia budi/inor3/vbt
22