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NATIONAL
CHEMISTRY OLYMPIAD
LOCAL SECTION EXAM
Prepared by the American Chemical Society Chemistry Olympiad Examinations Task Force
Property of ACS USNCO Not for use as USNCO Local Section Exam after March 31, 2016
Distributed by the American Chemical Society, 1155 16 th Street, N.W., Washington, DC 20036
All rights reserved. Printed in U.S.A.
amount of substance
ampere
atmosphere
atomic mass unit
Avogadro constant
Celsius temperature
centi prefix
coulomb
density
electromotive force
energy of activation
enthalpy
entropy
equilibrium constant
n
A
atm
u
NA
C
c
C
d
E
Ea
H
S
K
CONSTANTS
M
mol
h
P
k
Q
s
c
T
t
VP
V
V
R = 8.314 Jmol K
1
1
R = 0.0821 Latmmol K
1
F = 96,500 Cmol
1
1
F = 96,500 JV mol
1
h = 6.626 1034 Js
c = 2.998 108 ms
0 C = 273.15 K
1 atm = 760 mm Hg
Specific heat capacity of H2O =
1
1
4.184 Jg K
1
EQUATIONS
E Eo
1
1A
1
H
RT
ln Q
nF
H o 1
ln K
constant
R T
k E 1 1
ln 2 a
k1 R T1 T2
18
8A
2
He
3
Li
2
2A
4
Be
13
3A
5
B
14
4A
6
C
15
5A
7
N
16
6A
8
O
17
7A
9
F
6.941
9.012
10.81
12.01
14.01
16.00
19.00
20.18
11
Na
12
Mg
13
Al
14
Si
15
P
16
S
17
Cl
18
Ar
22.99
24.31
26.98
28.09
30.97
32.07
35.45
39.95
19
K
31
Ga
32
Ge
33
As
34
Se
35
Br
36
Kr
1.008
4.003
10
Ne
20
Ca
3
3B
21
Sc
4
4B
22
Ti
5
5B
23
V
6
6B
24
Cr
7
7B
25
Mn
8
8B
26
Fe
9
8B
27
Co
10
8B
28
Ni
11
1B
29
Cu
12
2B
30
Zn
39.10
40.08
44.96
47.88
50.94
52.00
54.94
55.85
58.93
58.69
63.55
65.39
69.72
72.61
74.92
78.96
79.90
83.80
37
Rb
38
Sr
39
Y
40
Zr
41
Nb
42
Mo
43
Tc
44
Ru
45
Rh
46
Pd
47
Ag
48
Cd
49
In
50
Sn
51
Sb
52
Te
53
I
54
Xe
85.47
87.62
88.91
91.22
92.91
95.94
(98)
101.1
102.9
106.4
107.9
112.4
114.8
118.7
121.8
127.6
126.9
131.3
55
Cs
56
Ba
57
La
72
Hf
73
Ta
74
W
75
Re
76
Os
77
Ir
78
Pt
79
Au
80
Hg
81
Tl
82
Pb
83
Bi
84
Po
85
At
86
Rn
132.9
137.3
138.9
178.5
180.9
183.8
186.2
190.2
192.2
195.1
197.0
200.6
204.4
207.2
209.0
(209)
(210)
(222)
87
Fr
88
Ra
89
Ac
104
Rf
105
Db
106
Sg
107
Bh
108
Hs
109
Mt
110
Ds
111
Rg
112
Cn
113
115
118
(Uup)
116
Lv
117
(Uut)
114
Fl
(Uus)
(Uuo)
(223)
(226)
(227)
(261)
(262)
(263)
(262)
(265)
(266)
(281)
(272)
(285)
(284)
(289)
(288)
(293)
(294)
(294)
58
Ce
59
Pr
60
Nd
61
Pm
62
Sm
63
Eu
64
Gd
65
Tb
66
Dy
67
Ho
68
Er
69
Tm
70
Yb
71
Lu
140.1
140.9
144.2
(145)
150.4
152.0
157.3
158.9
162.5
164.9
167.3
168.9
173.0
175.0
90
Th
91
Pa
92
U
93
Np
94
Pu
95
Am
96
Cm
97
Bk
98
Cf
99
Es
100
Fm
101
Md
102
No
103
Lr
232.0
231.0
238.0
(237)
(244)
(243)
(247)
(247)
(251)
(252)
(257)
(258)
(259)
(262)
Page 2
Property of ACS USNCO Not for use as USNCO Local Section Exam after March 31, 2016
DIRECTIONS
When you have selected your answer to each question, blacken the corresponding space on the answer sheet using a soft, #2
pencil. Make a heavy, full mark, but no stray marks. If you decide to change an answer, erase the unwanted mark very carefully.
There is only one correct answer to each question. Any questions for which more than one response has been blackened will not
be counted.
Your score is based solely on the number of questions you answer correctly. It is to your advantage to answer every question.
1. A 20.0 g sample of mercury(II) oxide (HgO, M = 216.6)
is heated strongly, causing it to decompose to metallic Hg
and O2 gas. What volume of O2 gas is produced
(measured at STP)?
(A) 1.03 L
(B) 2.07 L
(C) 4.14 L
(D) 14.0 L
(B) 6.64 g
(C) 9.97 g
(D) 13.3 g
(B) C3H3O
(C) C6H3O2
(D) C6H6O
(B) NaC2H3O2
(C) K2CO3
(D) CH2O
(B) Sodium
(C) Potassium
(D) Copper
(B) Ni2+
(C) Cu2+
(D) Zn2+
(B)
(C)
(D)
(B) 0.602 m
(C) 1.20 m
(D) 4.17 m
(B) NaOH
(C) AlCl3
(D) NH4NO3
Property of ACS USNCO Not for use as USNCO Local Section Exam after March 31, 2016
Page 3
(B) 1.79 g L1
(C) 1.96 g L1
(D) 2.60 g L1
(A) I only
(B) II only
(B) N2
(C) F2
(D) Cl2
Hf, kJ mol1
400
(A) 41 J
P, mm Hg
350
OH(aq)
230
HCO3(aq)
692
CO3 (aq)
677
H2O(l)
286
(B) 74 J
(C) 330 J
(D) 820 J
300
250
200
20
40
60
80
100
(A) 18.0 C
(B) 20.6 C
(C) 22.0 C
(D) 28.0 C
120
V, mL
(A) There are more ways of arranging the Ca2+ and SO42
ions in aqueous solution than in the crystal lattice.
(A) I only
(B) II only
17. How many nearest neighbors does each silicon atom have
in solid Si?
(A) 4
Page 4
(B) 6
(C) 8
(D) 12
Property of ACS USNCO Not for use as USNCO Local Section Exam after March 31, 2016
(B) 96 kJ mol1
28. What are the units of k if the rate law of a reaction is rate
= k[X]0[Y]0?
(A) M s1
(B) s1
(C) M1 s1
(D) k is dimensionless
(B) 0.503 M
(C) 0.335 M
(D) 0.128 M
CaO(s) + CO2(g)
[B]0, M
0.050
0.100
Initial rate,
M s1
0.085
0.050
0.200
0.170
0.100
0.300
0.510
(B) P = 30.0 mm Hg
(D) P = 60.0 mm Hg
32. Nitrous acid, HNO2, has Ka = 4.5 104. What is the best
description of the species present in a 0.1 M solution of
nitrous acid?
(A) HNO2(aq) is the predominant species; much smaller
amounts of H+(aq) and NO2(aq) exist.
(B) H+(aq) and NO2(aq) are the predominant species;
much smaller amounts of HNO2(aq) exist.
(C) Only H+(aq) and NO2(aq) are present in measurable
amounts.
(D) HNO2(aq), H+(aq), and NO2(aq) are all present in
comparable amounts.
Property of ACS USNCO Not for use as USNCO Local Section Exam after March 31, 2016
Page 5
(B) 1.7 g
(C) 2.4 g
(D) 7.7 g
(B) II only
Half-Reaction
+
E, V
Ag (aq) + e Ag(s)
+0.80
Cu2+(aq) + 2e Cu(s)
+0.34
(A) 9 1014 M
(B) 9 1011 M
(C) 8 104 M
(D) 3 103 M
(B) 2 : 1
(C) 3 : 1
(D) 3 : 2
(B) I2
(C) K
(D) H2O
Page 6
(B) 3300 s
(C) 6600 s
(D) 13000 s
(B) FrO
(C) Fr2O3
(D) FrO2
Property of ACS USNCO Not for use as USNCO Local Section Exam after March 31, 2016
(B) decrease
(C) increase, then decrease
(B) 2, 0, 0, +
(C) 3, 1, 0, +
(D) 4, 3, 2,
232
Th
(B)
234
Th
(C)
237
Np
(D)
231
Pa
(B) HCN
(C) NH3
(D) P4
(B) 6
(C) 9
(B) CH3CH2CH(OH)CH3
(C) (CH3)2CHCH2OH
(D) (CH3)3COH
(B) CH3COOH
(C) CH3CHO
(D) Cl3CCHO
(A) I only
(B) II only
(B) NF5
(C) PF3
(D) PF5
(D) 11
(B) C and T
(C) C and U
(D) G and U
(C) T-shaped
(D) Tetrahedral
END OF TEST
Property of ACS USNCO Not for use as USNCO Local Section Exam after March 31, 2016
Page 7
Olympiad 2016
USNCO Local Section Exam
KEY
Number
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
Answer
A
A
A
B
D
A
D
D
B
A
D
D
B
D
C
B
A
C
B
C
A
C
A
D
C
C
C
A
D
A
Number
31.
32.
33.
34.
35.
36.
37.
38.
39.
40.
41.
42.
43.
44.
45.
46.
47.
48.
49.
50.
51.
52.
53.
54.
55.
56.
57.
58.
59.
60.
Answer
B
A
D
C
B
D
B
B
C
A
B
D
A
A
B
C
A
B
A
C
B
C
C
B
C
D
B
D
A
B