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Summary
Members of a special class of interfacially active
chemicals were injected into wells in Kern County, CA,
immediately before and during the huff 'n' puff steaming
cycle. The chemical treatment was found to give significant increases in oil production.
Introduction
Earlier work in this laboratory and in the field 1,2 indicated that injection of water-soluble demulsifiers into
the steam used in cyclic steam stimulation operations
often gave improved oil production. This work extends
this earlier application to the use of a broader range of
compounds that we call thin film spreading agents
(TFSA) and that, while still acting to prevent emulsification, are found to aid in oil displacement and waterwetting of rock surfaces. 3 These compositions frequently have higher oil solubilities and higher oil/water
distribution ratios than the formerly used products.
DECEMBER 1982
Well
-
Field
Producing
Formation
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
MS
KF
KF
KF
KF
Potter
Potter
Potter
Spellacy
Spellacy
Spellacy
Spellacy
Speilacy
Spellacy
Spellacy
Spellacy
Chanac
Chanac
Chanac
Chanac
--
F148
F200
G99
R277
R437
R517
R557
R677
R787
R977
R1087
Y48R
Y70
Y72
Y87
(tt)
Producing
Interval
(tt)
1,400
1,500
1,028
1,158
1,255
1,130
1,172
1,100
1,072
1,600
875
2,017
2,028
2,012
2,067
285
200
203
99
176
78
75
90
100
120
107
210
280
321
240
Approximate
Depth
Steam Injected
(bbl of water)
Without TFSA
With TFSA
10,161
7,509
9,400
14,160
12,590
9,756
4,163
12,082
11,004
9,257
10,326
9,220
9,800
9,690
10,000
10,251
11,930
10,985
12,780
12,618
11,582
10,847
13,590
15,490
11,390
13,114
12,480
Steam Quality
(%)
Without TFSA
With TFSA
62
68
65
62
66
63
58
71
69
60
71
60'
60'
60'
60'
61
59
65
70
62
65
55
66
'Estimated.
60
-------i' Oil-WATER
:I
40
INTERFACIAl.. TENSION
50
~
Z
>
ow
40
J>----- _----D-----------.-----------ji
.......
20
~
w
g:
LTFSA_t
~"o''''
/
r'/
10
til
-'
30
oa::
Q.
...J
(5
" ,"
20
1+:::'"
...J
~
o
iii
w
a::
oR
I~
.,~
~~~~_~-o
j.-----
"
0'
10
",.,
""
/'
0 - - - - 0 UNTREATED FLOOD WATER
-- -_ _ THERMOFLOOD 805 IN FLOOD WATER
PORE
2758
3BBBr--------------------------,
4BBB'r--------------------------,
.J
II
II
MS-G99
CYCLE 2
KF-Y87
CYCLE 5=
IU
JSBBBr--------------------------.
16BBBr - - - - - - - - - - - - - - - - - - - - - - - - - ,
o
o
I[
D.
.J
MS-F148
CYCLE 11
MS-F2BB
CYCLE 2
B'~~----------------------_2
MONTHS
ON
1
PRO~UCTION
Fig. 3-0il production volumes before and after use of Thermoflood-803 in steam.
6BBBr-----------------~~-----,
4BBBr--------------------------,
.J
II
II
-I-
steam only
MS-R 1.087
CYCLE 3
S'77
CYCLE 7
B
J 6BBBr--------------------------,
4BBBr---------------------~---,
I[
D.
4--
.J
steam only
t"1S-R277
t-1S-RSJ.7
CYCLE 8
CYCLE 9
12
M 0 N TH S
ON
PRODUCTION
Fig. 4-0il production volumes before and after use of Thermoflood-805 in steam.
6BBB~-------------------------.
4BBBr--------------------------.
oJ
..ou
steam... onIYMS_R437
MS-R557
e 1-~~~======::::~~L:E~6~-1
12
~8BBBr--------------------------.
o
o
CYCLE 7
4000r--------------------------,
IE
Do
oJ
steam only
CYCLE 1B
CYCLE 6
~-----------R~S-R787
MONTHS
MS-R677.
ON
PROOUCTION
Fig. 5-0il production volumes before and after use of Thermoflood-805 in steam.
4BBB~--------------------~---.
oJ
m
m
2
.u
hsteam only
KF-Y48R
I-<F- 'T'70
CYCLE
CYCLE 5"
B~------------------~----~12
o
o
:12
"~.O""
IE
"+
Do
oJ
o
VF-'T'72
CYCLE 5
MONTHS
ON
12
PRODUCTION
Fig. 6-0il production volumes before and after use of Thermoflood-801 in steam.
Observed Cycle
to Preceding Cycle
Field
Number
of Wells
Mean
Well Ratio
VolumeWeighted
Ratio
Mean
Well Ratio
VolumeWeighted
Ratio
MS
KF
combined
11
4
15
4.53
1.41
3.70
2.49
1.30
2.19
6.47
2.01
5.28
3.56
1.86
3.13
34,296
24,007
75,058
51,051
1,123,122
24,750
1,098,372
73,225
jected was 0.535 for the last cycle with TFSA compared
with 0.233 for the preceding cycle with steam alone.
Of the 4 wells in the KF field treated with either
Thermoflood-801 (Fig. 6) or -803 (Fig. 3), 3 had
substantial increases in production ratio, and 1 had a
reduction. The mean well production ratio was 1.41,
with an SD of 0.57. The volume-weighted mean ratio
was 1.30. Fig. 7 shows the cumulative oil production for
the entire 15 wells during the last cycle with TFSA and
during the preceding cycle with steam alone.
The preceding individual well and total production
ratios understate the benefits of TFSA use because they
compare last-cycle results of using the chemical agent to
next-to-Iast cycle results of using steam alone. Studies of
cyclic steam production in other fields including Huntington Beach 9 and Duri 10 show average cycle-to-cycle
decline rates well above 30%. From the decline rate we
can estimate the expected, last-cycle, steam-only production volume from the observed production during the
next-to-Iast cycle. This, in tum, permits estimation of effective, same-cycle production ratios resulting from
TFSA use.
Table 2 presents the effective, same-cycle production
ratios for the various well groups calculated on the basis
of a conservative 30% decline rate. Also shown for the
same groups are the observed ratios oflast-cycle production with TFSA to next-to-Iast cycle production with
steam alone.
Table 3 gives a simplified analysis of the economic
benefit of TFSA use. This does not take into account the
greater present value of the production resulting from
higher production rates.
Conclusions
The use of properly selected TFSA compounds with the
steam injected in huff 'n' puff operations leads to large
DECEMBER 1982
Acknowledgment
We thank Ronald G. Sampson for important help in data
processing and computer graphics generation.
8BBBB~----------------------~
o
T
ste.1m only
oJ
ID
ID
1
MDNTHS
DN
PRDDUCTIDN
2761
References
1. Muggee, F.D.: "Process for Recovery of Petroleum by Steam
Stimulation," U.S. Patent No. 3,396,792 (1968).
2. Rohiback, G.: "New Additive Promises Revised SteamStimulation Economics," Oil and Gas 1. (Oct. 10, 1966) 207-09.
3. Blair, C.M. Jr.: "Method of Recovering Petroleum From a
Subterranean Reservoir," U.S. Patent No. 4,260,019 (1981).
4. Blair, C.M. Jr.: "Interfacial Films Affecting the Stability of
Petroleum Emulsions," Chern. and Ind. (May 1960) 538-44.
5. Csaszar, A.K.: "Solvent-Waterflood Oil Recovery Process,"
U.S. Patent No. 3,163,214 (1964).
6. Treating Oil Field Emulsions, C.F. Kruse (ed.), API and
Petroleum Extension Service, U. of Texas, Austin (1974) 33-45.
7. DeGroote, M. and Keiser, B.: "Process for Breaking Petroleum
Emulsions," U.S. Patent No. 2,557,081 (1951).
8. Blair, C.M. Jr.: "Micellar Solutions of Thin Film Spreading
Agents," U.S. Patent Nos. 4,309,306 and 4,326,985 (1982).
9. Adams, R.H. and Khan, A.M.: "Cyclic Steam Injection Project
Performance Analysis and Some Results of a Continuous Steam
2762
E-Ol
E+OO
E-Ol
m3
mN/m
m
J.tm
JPT
Original manuscript received in Society of Petroleum Engineers office Feb. 10, 1982.
Paper accepted for publication July 30,1982. Revised manuscript received Oct. 12,
1982. Paper (SPE 10700) first presented at the 1982 SPEIDOE Joint Enhanced Oil
Recovery Symposium held in Tulsa April 4-7.