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Group B elements are transition elements. Metals, metalloids, and nonmetals can be
identified by their location on the periodic table.
These groups are number from 1 - 18, left to right and groups have their Roman
numbers and A or B classification..
Name
Elements
Common Valence
Electron Configuration
Group 1 (IA) -
Alkali metal:
ns1
Group 2 (IIA) -
ns2 3p1
Group 14 (IVA) -
No specific name
ns2 3p2
Group 15 (VA) -
No specific name
N, P, As, Sb, Bi
ns2 np3
O, S, Se, Te, Po
ns2 np4
Cl, Br, I, At
ns2 np5
In addition to groups in the periodic table there are three blocks of elements called
transition elements (which are labeled with B), Lanthanides and Actinides ( placed
bottom of the table.
Metals, Nonmetals and Metalloids
Most of the elements in the periodic table are metals. Note the stair step line in the
periodic table. Elements to the left of the line are metals. Elements to the right of the
line are nonmetals. In between metal and non-metals there are semi-metals or
metalloids. Metals lose electrons and nonmetals gain electrons.
Ionic Compounds are formed when electrons are exchanged in this way between
metals and nonmetals.
Covalent or Molecular Compounds are formed between non metals and non metals
react by sharing electrons.
Atomic Number and Atomic Mass
The atomic number (Z) of an element represents the number of protons in the
nucleus of atoms of that specific element. No two element has that same number of
protons. Atomic number after it was discovered proved to be the best order without any
discrepancies to arrange the elements in the periodic table and is shown on top of the
space for each element. The atomic number will always be a whole number value
without decimals. At the bottom average atomic mass calculated based on isotopes of
each elements is written.
Look on a periodic chart at the elements listed below. Do you know how to find an
elements atomic number?
Problem: Use your periodic table to find the symbol, atomic number and atomic mass
rounded to two decimal place of each of the following elements:
a) Magnesium b) Neon c) Selenium d) Gold
Answer
Mg, atomic number = 12, mass = 24.31 amu
Orbital Shapes
Shape
s
spherical
p
dumbbell
d
complex
f
very complex
n=1
one
s
1s (1)
1
n=2
two
s and p
2s(1) 2p(3)
4
n=3
three
s, p and d
3s(1) 3p(3) 3d(5)
9
2(2n2)
2 + 6= 9(2n2)
n=4
four
s. p, d and f
4s(1) 4p(3) 4d(5) 4f(7)
16
maximum number of
electrons
in an Energy Level
2
8
18
32
# of
sublevels
Sublevels names
1
2
3
4
2
2, 6 =8
2, 6, 10 =18
2, 6, 10, 14 =32
s
s, p
s, p, d
s, p, d, f
Problem:
How many electrons are found:
Within principle shells? a) n = 1 b) n = 2 c) n = 3 d) n =4 e) n = 5
Answer:
a. n = 1; 2n2 = 2(1)2 = 2
b. n = 2; 2n2 = 2(2)2 = 8
c. n = 3; 2n2 = 2(3)2 = 18
d. n = 4; 2n2 = 2(4)2 = 32
e. n = 5; 2n2 = 2(5)2 = 50
Problem: With in a sub-shells: a) s, b) p c) d,
Answer: a) s = 2, b) p=6 c) d=10, d) f= 14
d) f
Elements in the last family, the noble gases, have either two or eight valence
electrons. Their most important properties are their extreme stability and lack of
reactivity. A full energy level is responsible for this unique stability.
The Octet Rule
Noble gases are non-reactive because they all have a complete outer shell. An
atom chemically reacts to fill its valance shell. A full valance shell contains eight
electrons there fore the name octet. The octet rule tells us that in chemical reactions
atoms of elements will gain, lose or share the minimum number of electrons necessary
to achieve the electron configuration of the nearest noble gas.
octet rule - the rule which predicts that atoms form the most stable molecules or ions
when they are surrounded by eight electrons in their highest occupied energy (valance)
level.
Electronic configuration of ions
Series of negative ions, noble gas atom, and positive ions with the same number
electrons and electronic configuration. Electron configuration of ions is obtained by
adding more electrons (anions) or removing electrons (cations) from a neutral atom. In
the process atoms achieves a noble gas electron configuration.
Group 1 (or IA), Alkali Metals have one valence electron.
They all form +1 cations when the single valence electron is lost.
Metals lose electrons and achieve electron configuration of preceding noble gas.
E.g. Potassium (K):
K K+ (cation) + eOxygen (O):
O + 2e- O2- (anion)
Metallic elements tend to form cations and nonmetals form anions that are isoelectronic
with their nearest noble gas neighbor.
Isoelectronic electronic configurations
If atom and a cation or anion have same number of electrons they are called
isoelectronic.
E.g. K+ and Ar
O2- and Ne
Problem: Which of the following are isoelectronic: F,Cl, K+, Ar
Answer:
a. F, 10e; Cl, 18 e; Not isoelectronic
b. K+, 18 e; Ar, 18e; Isoelectronic
Ion Formation and the Octet Rule
Metals lose electrons and achieve a an octet of valance electrons similar to electron
configuration of preceding noble gas.
E.g. Potassium (K): [Ar] 4s1
K ([Ar] 4s1) K+ ([Ar]) + eOxygen (O): [He] 2s2 2p4
O ([He] 2s2 2p4) + 2e- O2- ([Ne])
I (54 e) = Xe= 1s2, 2s2, 2p6, 3s2, 3p6, 4s2, 3d10, 4p6, 5s2, 4d10, 5p6
b. Ba2+ (54 e)= Xe= 1s2, 2s2, 2p6, 3s2, 3p6, 4s2, 3d10, 4p6, 5s2, 4d10, 5p6
c. Se2 (36 e) =Kr = 1s2, 2s2, 2p6, 3s2, 3p6, 4s2, 3d10, 4p6
d. Al3+ (10 e)=Ne = 1s2, 2s2, 2p6
a.
c. S, O, Se
Answer:
a.
b.
c.
Ion Size
Ions follows same trends as for atomic radius in a group, fro example taking oxide and
sulfide ion: radius of O2- < S2-.
Cation or positive ions have fewer electrons than neutral atom and nuclear charge being
same attract remaining electrons strongly making cation smaller than the neutral atom
Anions or negative ions larger than neutral atom. Anions are larger than the atoms from
which there are formed. Adding electrons to an atom increases the repulsion between
electrons. Anion has a harder time holding on to the electrons.
1. Which two scientists in 1869 arranged the elements in order of increasing atomic masses to form a
precursor of the modern periodic
table of elements?
Ans. Mendeleev and Meyer
2. Who stated that the elements, when arranged according to their atomic masses, showed a distinct
periodicity of their properties?
Ans. Dimitri Mendeleev
3. In the modern periodic table, the elements are arranged according to what system?
Ans. increasing atomic number
4. The modern periodic law states that the physical and chemical properties of the elements are periodic
functions of what property?
Ans. atomic number
5. What do we call the horizontal row of elements on the periodic table?
Ans. periods
6. How many periods are found on the periodic table?
Ans. seven
7. Which period contains the element sodium?
Ans. three
8. What do we call the columns of elements on the periodic table?
Ans. groups
9. What number for an atom gives the number of electrons and protons found in that atom?
Ans. atomic number
10. Where are the alkaline earth metals located on the periodic table?
Ans. Group IIA (2)
11. What is the general name given to the elements of Group VIIA (17)?
Ans. Halogens
12. What term is used for the elements straddling the "staircase" boundary between the metals and
nonmetals?
Ans. Metalloids or semi-metals
13. For a representative element, how can we deduce the number of valence electrons in a neutral atom
from the position of the element in the
Periodic Table?
Ans. the group number (Roman numbers with Bs) is also the number of valence electrons
14. How many orbitals are in an s sublevel? How many in a p sublevel?
Ans, 1; 3
15. In what way(s) are the three orbitals in the 2p sublevel similar; in
what way(s) are they different?
Ans. they have the same shape and the same energy; they are oriented
differently in space
16. What requirement must be met in order for two electrons to coexist in
the same orbital?
Ans. they must have opposite spins
D. neutron number
E. density
Ans. A. atomic number
33. What do we call a complete horizontal row of elements on the periodic
table?
A. group
B. period
C. family
D. representative elements
E. transition elements
Ans, B
34. What are all the elements in the A-groups often called?
A. transition elements
B. lanthanides
C. metals
D. non-metals
E. representative elements
Ans. E
35. Which of the following elements is a metalloid?
A. C B. Ge C. Pb D. N E. P
Ans. B
36. Where are the alkali metals located on the periodic table?
A. representative elements
B. transition metals
C. Group IA (1)
D. Group IIA (2)
E. Group IIIA (3)
Ans. C
37. How many valence electrons are in an atom of carbon?
A.8 B. 6 C. 4 D. 1 E. 0
Ans. C
38. What is the lowest energy sublevel of a principal level?
A. d B. e C. f D. s E. p
Ans. D
39. How many sublevels are there in the third principal energy level?
A. 3 B. 2 C. 1 D. 0 E. 4
Ans. A
40. How many orbitals are there in a p sublevel?
A. 2 B. 3 C. 1 D. 0 E. 4
Ans. B
41. Which of the following correctly gives the electron capacity of a
principal energy level in terms of the number n?
A. n B. 2n C. 2n + 2 D. n2 E. 2n2
Ans. E
42. What is the electron configuration of sulfur, atomic number 16?
A. 1s21p62s22p6
B. 1s22s22p62d6
C. 1s22s22p63s23p4
D. 1s22s22p63s23d4
E. 1s22s22p63s22d4
Ans. C
43. Which one of the following electron configurations is appropriate for a
normal atom?
A. 1s12s1
B. 1s22s1
C. 1s22s22p8
D. 1s22s22p43s1
E. 1s22s22p63d1
Ans. B
44. Which of the following elements is most likely to form a 3+ ion?
A. Li B. K C. Al D. N E. Cu
Ans. C
45. Give the complete electronic configuration of a sodium ion.
A. 1s22s22p5
B. 1s22s22p6
C. 1s22s22p63s1
D. 1s22s22p63s2
E. 1s22s22p63s23p64s1
Ans. B
46. Which of the following ions does not follow the octet rule?
A. Na+ B. Ca2+ C. Al3+ D. N3- E. Cl2Ans. E
47. Which of the following atoms has the biggest size (radius)?
A. Na B. Al C. Cl D. Rb E. I
Ans. D
48. Which of the following elements has the highest ionization energy?
A. Li B. B C. O D. F E. Ne
Ans. E
49. Which of the following elements has the lowest ionization energy?
A. Li B. B C. O D. F E. Ne
Ans. A
50. The electron affinity is
A. the energy required to remove an electron from an isolated atom
B. the force between two electrons in the same orbital
C. the force between two ions of opposite charge
D. the energy released when an isolated atom gains an electron
E. the attraction of an atom for an electron in a chemical bond
Ans. D
51. Which one of the following elements has the highest electron affinity?
A. Li B. K C. Kr D. O E. Cl
Ans. E
52. T F In Mendeleev's table, the elements were arranged according to
their atomic numbers.
Ans. F
53. T F There are nine periods on the periodic table.
Ans. F
54. T F Sulfur (S) is one of the representative elements.
Ans. T
55. T F Platinum (Pt) is a lanthanide element.
Ans. F
56. T F Tin (Sn) is a metalloid.
Ans F
Mg3N2
a.
b.
d.
The shared pair of electrons provides each hydrogen atom with two
electrons in its valence shell (the 1s) orbital.
In a sense, it has the electron configuration of the noble gas
helium
When two chlorine atoms covalently bond to form Cl2, the following
sharing of electrons occurs:
Each chlorine atom shared the bonding pair of electrons and achieves
the electron configuration of the noble gas argon.
In Lewis structures the bonding pair of electrons is usually displayed
as a line, and the unshared electrons as dots:
The shared electrons are not located in a fixed position between the
nuclei. In the case of the H2 compound, the electron
Polar Covalent Bonding and Electronegativity
Hetero-nuclear covalent bonds- Covalent bond between two different atoms leads to
polar covalent bonds with a charge separation depending of the electronegativities of
atoms.
Electronegativity
"Electronegativity is the power of an atom when in a molecule to
attract electrons to itself." The electronegativity will depend upon a
number of factors including other atoms in the molecule. There are a
number of ways to produce a set of numbers which represent
electronegativity scales. The Pauling scale is perhaps the most
famous.
-> Atomic radius decreases -> Ionization energy increases ->
Electronegativity increases ->
Group
10 11
12 13 14
15
16
17
18
Period
1
H
2.1
He
Li Be
1.0 1.5
B
C
N
O
F Ne
2.0 2.5 3.0 3.5 4.0
Na Mg
0.9 1.2
Al Si
P
S
Cl
1.5 1.8 2.1 2.5 3.0
Ar
K Ca Sc Ti
V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br
0.8 1.0 1.3 1.5 1.6 1.6 1.5 1.8 1.9 1.8 1.9 1.6 1.6 1.8 2.0 2.4 2.8
Kr
Rb Sr Y ZrZr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te
I
0.8 1.0 1.2 1.4 1.6 1.8 1.9 2.2 2.2 2.2 1.9 1.7 1.7 1.8 1.9 2.1 2.5
Xe
Cs Ba
Lu
0.7 0.9
Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
1.3 1.5 1.7 1.9 2.2 2.2 2.2 2.4 1.9 1.8 1.9 1.9 2.0 2.2
Fr Ra Lr
0.7 0.9
Rf
Polar Covalent bonds: Electron negativity difference between 0.5 1.6 to indicate polar covalent. This type of bond occurs when there is
Name
Symbol
Name
H+
Hydrogen ion
H-
Hydride ion
Li+
Lithium ion
F-
Fluoride ion
Sodium ion
Cl
Chloride ion
K+
Potassium ion
Br-
Bromide ion
Be2+
Beryllium ion
I-
Iodide ion
Na
Mg
2+
Ca2+
2-
Magnesium ion
calcium ion
S2-
Oxide ion
Sulfide ion
Ba2+
barium ion
N3-
Nitride ion
Zn2+
zinc ion
P3-
Phosphide ion
(Stock system)
Common
Symbo
l
(Stock
system)
Common
Cu+
copper(I)
cuprous
Hg22+
mercury(I)
mercurous
mercury(II)
mercuric
2+
2+
Cu
copper(II)
cupric
Hg
Fe2+
iron(II)
ferrous
Pb2+
lead(II)
plumbous
Fe3+
iron(III)
ferric
Pb4+
lead(IV)
plumbic
cobalt(II)
cobaltous
2+
2+
Sn
tin(II)
stannous
Co
Sn4+
tin(IV)
stannic
Co3+
cobalt(III)
cobaltic
Cr2+
chromium(II)
chromous
Ni2+
nickel(II)
nickelous
nickel(IV)
nickelic
3+
Cr
chromium(III)
Mn2+
Mn3+
4+
Ni
manganese(II)
chromic
manganou
s
Au+
gold(I)
aurous
manganese(III)
manganic
Au3+
gold(III)
auric
Name
Formula
Name
NO3-
nitrate
CO32-
carbonate
NO2-
nitrite
SO42-
sulfate
CN-
cyanide
SO32-
sulfite
MnO4-
permanganate
PO43-
phosphate
OH-
hydroxide
PO33-
phosphite
O22-
ClO4-
perchlorate
HCO3-
peroxide
hydrogen carbonate(bi
carbonate)
ClO3-
chlorate
HSO4-
ClO2-
chlorite
HSO3-
ClO-
hypochlorite
HPO42-
hydrogen phosphate
CrO42-
chromate
H2PO4-
dihydrogen phosphate
Cr2O72-
dichromate
C2H3O2-
acetate
followed by the name of the negative ion (anion). There for conversion of name to
formula is easy if you know the metal and nonmetal ion symbols and charges. Use the
periodic table to decide the charge on both the cation and anion (or the tables) and
determine the formula of the compound(s) formed in each case. For transition metals
the common ionic charges are given in after the metal name in parenthesis.
Writing basic ionic compound formulas.
Examples: lithium sulfidelithium =Li+1 ; sulfide =S-2
Write ions on a line: Li+1 S-2
Then remove cation and anion charges and exchange them without charge as subscripts
on the metal and nonmetal
Li+1 S-2 becomes Li2S1
Remember we omit "1" from the subscript formula becomes Li2S
Problem: What is the formula of the following compounds given their names?
a. Potassium chloride
b. Magnesium bromide
c. Magnesium nitirde
Answer: First get the formula of ions in the compound. Potassium consists of cation K +
and chloride Cl-. Look in the table to get charges on the ions and one need to balance
the opposite charges. If charges are equal already formula has 1:1 anions and cation like
in K+ and Cl-, therefore formula become KCl. If charges are different like in Mg 2+
and N3- to get the formula usually cross multiply with charges to obtain 3 Mg 2+ and
2 N3-) and drop the charges and write formula Mg3N2.
a.
b.
a) sodium chloride
b) aluminum phosphate
c) magnesium fluoride
d) potassium nitrate
e) calcium sulfate
f) mercury(II) chloride
g) iron(II) chloride
h) cobalt(III) nitrate
i) potassium chromate
Answers:
a) NaCl
b) AlPO4
c) MgF2
d) KNO3
e) CaSO4
f) Hg Cl2
g) FeCl3
h) Co(NO3)3
i) KmnO4
b) copper(II) sulfate
c) Sodium phospate
d) Sodium sulfite
f) lithium carbonate
h) calcium bisulfate
i) potassium bicarbonate
Answers:
a) FeBr2
b) CuSO4
c) Na3PO4
d) Na2SO3
e) Fe(NO3)2
f) Li2CO3
g) AuCl2
h) Ca(HSO4)2
i) KHCO3
Covalent Compounds
Most covalent compounds are formed by the reaction of non-metals. Covalent
compounds exist as molecules and are named using prefixes that denote the number of
each element present in the compound.
Many familiar covalent compounds have common names. It is useful to
correlate both systematic and common names with the corresponding molecular
formula.
Properties of Ionic and Covalent Compounds
In the solid state, covalently bonded molecules are discrete units and have less
tendency to form an extended structure, while ionic compounds form a crystal lattice.
The melting and boiling temperatures for ionic compounds are generally higher than
those of covalent compounds. Ionic solids are crystalline, whereas covalent solids may
be either crystalline or amorphous. Many ionic solids dissolve in water, dissociating into
positive and negative ions (an electrolytic solution). Because these ions can carry
(conduct) a current of electricity, they are called electrolytes. Covalent solids in solution
usually retain their neutral character and are nonelectrolytes.
Physical State
Melting and Boiling Points
Structure of Compounds in the Solid State
Solutions of Ionic and Covalent Compounds
Drawing Lewis Structures of Molecules and Polyatomic Ions
Lewis Structures of Molecules
Lewis Structures of Polyatomic Ions
The electronic structure of atoms, ions, and molecules, which is closely allied to the
properties of these substances, can conveniently be represented using Lewis structures,
or electron-dot diagrams based on the octet rule.
Concepts of stability and polarity are better understood when viewed from the
perspective of a Lewis structure. The stability of a covalent compound is related to the
bond energy. The magnitude of the bond energy increases and the bond length decreases
in the order: single bond > double bond > triple bond.
The valence shell electron pair repulsion (VSEPR) theory helps to explain (or
predict) molecular geometry, including linear, trigonal planar, and tetrahedral
arrangements of attached atoms. Exceptions to the octet rule exist.
2. Hydrogen Bonding
Hydrogen bond---an oxygen or nitrogen with a lone pair of electrons
attracts a "hydrogen" covalently bonded to another oxygen or
nitrogen.
The O or N with the lone pair, the hydrogen, and the other O or N
must be in a straight line.
This attraction is highly directional.
3. Dipole-Dipole Interactions
Two molecules with permanent NET dipoles can approach each other
and "align their permanent NET dipoles"
The + end of one molecule becomes attracted to the - end of the
other molecule.
Relative Scale
C-C covalent
83.0
100
Electrostatic
20.6
25
Hydrogen Bond
4.8
Dipole-Dipole
2.2
London Forces
0.1
less than 1
Problem: Give the names of following formulas from the names of following covalent
compunds names:
H2S
a.
CS2
b.
PCl5
c.
P2O5
d.
Answer:
a. hydrogen sulfide
b. carbon disulfide
c. phosphorus pentachloride
d. diphosphorus pentoxide
Problem: Give the formula of following covalent compounds:
a. Nitrogen trifluoride
b. Carbon monoxide
Answer:
a. NF3
b. CO
Draw Lewis structure of a. Ethane( CH3CH3 b. Nitrogen (N2)
H H
C C H
H H
b. :N:::N:
Draw Lewis structure of a. cyanide ion (CN-) b. carbonate ion (CO32-)
a.
CN
[:C:::N:]
[Note: 5 valence electrons from nitrogen, 4 from carbon, and one from the
-1 charge equals 10 valence electrons total.]
b. CO32
2-
O
O C O
[Note: 4 valence electrons from carbon, 6 from each of three oxygen atoms,
and two for the -2 charge equal 24 valence electrons total.]
4.16
a. The hydrogen atom is less electronegative than the sulfur atom, so a likely
skeletal structure is:
HS
The total number of valence electrons in the hydrogen sulfide ion is:
1 hydrogen atom x 1 valence electron
1 sulfur atom x 6 valence electrons
and 1 negative charge
= 1 electron
= 6 electrons
= 1 electron
OO
= 12 electrons
= 2 electrons
O O
4.18
:N:::N:
b. Cl2
Cl Cl
The bond strength parallels the bond order. N2 has a bond order of 3, and is a
stronger bond than that found in Cl2, a single bond, bond order of 1.
4.20
Since both S and Se are in the same family (Group VIA), they have the same
number of valence electrons, and therefore, should form the same kinds of
bonds.
4.22
a. C2H4
H
C
H
C
H
Three groups around each carbon; trigonal planar around each carbon.
b. H:C:::C:H
HCCH
4.24
4.26
a. Si Cl
b. S Cl
c. H C
d. C C
a. CO2
O
There are two identical groups around the central atom. The molecule has
linear geometry and the polarity of the groups cancel. The molecule is
nonpolar.
b. SCl2
Cl
Cl
Sulfur and oxygen are in the same group of the periodic table. SCl2 is
analogous to H2O: a bent molecule. The effect of two lone pairs causes the
molecule to be polar.
c. Br-Cl
Br Cl
The Br-Cl bond is polar due to the electronegativity difference between
bromine and chlorine. Since Br-Cl is the only bond in the molecule, the
molecule is polar.
d. CS2
S
There are two identical groups around the central atom. The molecule has
linear geometry and the polarity of the groups cancel. The molecule is
nonpolar.
4.28
a.
b.
c.
d.
4.32
a.
2 Na +
2 Na
b.
2-
2 Na +
4.34
2 Na
a. HNO3
H
= 1 valence electron
N
= 5 valence electrons
O x 3 = 6 x 3 = 18 valence electrons
Total of 24 valence electrons
O
This structure satisfies the octet rule for N and O.
N O H
O
b. CCl4
C
= 4 valence electrons
4 x Cl = 4 x 7 = 28 valence electrons
Total of 32 valence electrons
Cl
Cl C Cl
Cl
c. PBr3
P
= 5 valence electrons
3 x Br = 3 x 7 = 21 valence electrons
Total of 26 valence electrons
Br
Br
Br
4.36
a.
b.
c.
d.
e.
4.38
a. SO42
c. PO43
b. NO3
d. HCO3
4.40
sulfide ion
chloride ion
carbonate ion
ammonium ion
acetate ion
a. AgCN
b. NH4Cl
c. Ag2O
d. MgCO3
e. Mg(HCO3)2
4.42
a. Nitrogen dioxide
b. Sulfur trioxide
c. Phosphorus trichloride
d. Dinitrogen tetraoxide
e. Carbon tetrachloride
4.44
4.46
4.48
a. CO or CO2
c. CaO
b. SO2 or SO3
d. SiH4
a. NH4I
c. NH4C2H3O2
b. (NH4)2SO4
d. NH4CN
a. sodium hypochlorite
c. sodium chlorate
b. sodium chlorite
d. sodium perchlorate
4.50
The attractive forces among positive and negative ions are quite strong; a great
deal of energy is needed to overcome these forces. As a result, the melting
points of ionic compounds are quite high when compared to those of covalent
compounds that have weaker attractive forces among the uncharged molecules.
4.52
Water will have a higher boiling point. Water is a polar molecule with strong
intermolecular attractive forces, whereas carbon tetrachloride is a nonpolar
molecule with weak intermolecular attractive forces. More energy, hence, a
higher temperature is required to overcome the attractive forces among the water
molecules.
4.54
a.
Be
b.
c.
d.
2-
4.56
a. Be2+
b. Al3+
c.
d.
2-
S
4.58
and
N O
If resonance did not occur, the bond lengths between N and O would not be
identical. The nitrogen oxygen double bond length would be shorter than the
nitrogen oxygen single bond length. Experimentally, we find the nitrogen
oxygen bond lengths to be identical. This is attributed to the resonance hybrid.
O
4.60
formaldehyde
H C H
H H
H
C C
H H
H
N
H
4.62
ethylamine
4.64
a. Cl and Cl
b. H and H
c. C and H
d. Li and F
e. O and O
4.66
a. Cl and Cl
b. H and H
c. C and H
H
Cl Cl
H
H H
C H
H
4.68
The rule of "like dissolves like" applies to the question of solubility. Molecules
of similar polarity will be mutually soluble. Water is a polar molecule; therefore
one would predict that polar molecules would dissolve in water.
4.70
B. mass number
C. atomic mass
D. neutron number
E. density
33. What do we call a complete horizontal row of elements on the periodic
table?
A. group
B. period
C. family
D. representative elements
E. transition elements
34. What are all the elements in the A-groups often called?
A. transition elements
B. lanthanides
C. metals
D. non-metals
E. representative elements
35. Which of the following elements is a metalloid?
A. C B. Ge C. Pb D. N E. P
Page 2
36. Where are the alkali metals located on the periodic table?
A. representative elements
B. transition metals
C. Group IA (1)
D. Group IIA (2)
E. Group IIIA (3)
37. How many valence electrons are in an atom of carbon?
A. 8 B. 6 C. 4 D. 1 E. 0
38. What is the lowest energy sublevel of a principal level?
A. d B. e C. f D. s E. p
39. How many sublevels are there in the third principal energy level?
A. 3 B. 2 C. 1 D. 0 E. 4
40. How many orbitals are there in a p sublevel?
A. 2 B. 3 C. 1 D. 0 E. 4
41. Which of the following correctly gives the electron capacity of a
principal energy level in terms of the number n?
A. n B. 2n C. 2n + 2 D. n2 E. 2n2
42. What is the electron configuration of sulfur, atomic number 16?
A. 1s21p62s22p6
B. 1s22s22p62d6
C. 1s22s22p63s23p4
D. 1s22s22p63s23d4
E. 1s22s22p63s22d4
43. Which one of the following electron configurations is appropriate for a
normal atom?
A. 1s12s1
B. 1s22s1
C. 1s22s22p8
D. 1s22s22p43s1
E. 1s22s22p63d1
44. Which of the following elements is most likely to form a 3+ ion?
A. Li B. K C. Al D. N E. Cu
Page 3
45. Give the complete electronic configuration of a sodium ion.
A. 1s22s22p5
B. 1s22s22p6
C. 1s22s22p63s1
D. 1s22s22p63s2
E. 1s22s22p63s23p64s1
46. Which of the following ions does not follow the octet rule?
A. Na+ B. Ca2+ C. Al3+ D. N3- E. Cl247. Which of the following atoms has the biggest size (radius)?
A. Na B. Al C. Cl D. Rb E. I
48. Which of the following elements has the highest ionization energy?
A. Li B. B C. O D. F E. Ne
49. Which of the following elements has the lowest ionization energy?
A. Li B. B C. O D. F E. Ne
50. The electron affinity is
A. the energy required to remove an electron from an isolated atom
B. the force between two electrons in the same orbital
C. the force between two ions of opposite charge
D. the energy released when an isolated atom gains an electron
E. the attraction of an atom for an electron in a chemical bond
51. Which one of the following elements has the highest electron affinity?
A. Li B. K C. Kr D. O E. Cl
52. T F In Mendeleev's table, the elements were arranged according to
their atomic numbers.
53. T F There are nine periods on the periodic table.
54. T F Sulfur (S) is one of the representative elements.
55. T F Platinum (Pt) is a lanthanide element.
56. T F Tin (Sn) is a metalloid.
57. T F Valence electrons are involved when atoms form bonds.
58. T F There are a maximum of 50 electrons in principal energy level
number five.
59. T F Atoms of the noble gas elements, Group VIII A (18), do not form
bonds with any other elements.
60. T F There are eight valence electrons in a chloride ion.
61. T F The ions formed from Group IIA (2) atoms have charges of 2+.
Page 4
62. T F Cations tend to be formed from metal atoms, while anions are
formed from non-metal atoms.
63. T F The atoms of smallest radius are those of elements in top left
hand part of the periodic table.
64. T F The halogens (Group VII A (17)) have the lowest ionization
energies of any group in the periodic table.
Page 5
3 37 37 C
3 38 38 D
3 39 39 A
3 40 40 B
3 41 41 E
3 42 42 C
3 43 43 B
3 44 44 C
3 45 45 B
3 46 46 E
Page 1
Answer Key for Test "chapter3.tst", 8/17/04
No. in
Q-Bank
No. on
Test Correct Answer
3 47 47 D
3 48 48 E
3 49 49 A
3 50 50 D
3 51 51 E
3 52 52 F
3 53 53 F
3 54 54 T
3 55 55 F
3 56 56 F
3 57 57 T
3 58 58 T
3 59 59 F
3 60 60 T
3 61 61 T
3 62 62 T
3 63 63 F
3 64 64 F
Page 2
1. In a Lewis structure, what do the dots represent?
2. Draw the Lewis structure of the bromine atom.
3. How many dots are shown in the Lewis structure for the sulfur atom?
4. What are the two principal types of bonding called?
5. Name the two classes of element which are most likely to form an ionic
compound if they are allowed to react with each other.
6. Draw the Lewis structure of the Pb2+ ion.
7. What constitutes a covalent bond between two atoms?
8. In what way is a polar covalent bond similar to a nonpolar covalent
bond? In what way are they different?
9. What does it mean if an atom is said to have a high electronegativity?
10. The elements with the lowest electronegativities are found in the
_______ _______ region of the periodic table.
covalent bond?
42. What do the letters VSEPR stand for?
43. If the shape of a molecule is trigonal planar, what are the values of
the bond angles?
44. In the molecule AX2, the central atom A has two lone pairs of electrons
in addition to the two bond pairs in the A-X bonds. What is the shape
of this molecule?
45. The ammonia molecule, NH3, is polar. Why does this fact suggest that its
shape is trigonal pyramidal, rather than trigonal planar?
Page 2
46. Which of the following Lewis structures of neutral atoms is correct?
K Sn O Ba Al
ABCDE
A. A B. B C. C D. D E. E
47. Which of the following Lewis structures of ions is incorrect?
Na Ca Sn N I
2+ 3- - + 2+
ABCDE
A. A B. B C. C D. D E. E
48. Which of the following has the greatest electronegativity?
A. H B. Cl C. O D. F E. Na
49. Which of the following has the greatest electronegativity?
A. Si B. P C. Cl D. Ar E. Br
50. In the compound CH3Cl the bond between carbon and chlorine is
A. intermolecular B. ionic
C. nonpolar covalent D. polar covalent
51. Which one of the following is NOT true about elements that form
cations?
A. The atoms lose electrons in forming ions.
B. The elements are metals.
C. They are located to the left of the periodic table.
D. They have low ionization energies.
E. They have high electron affinities.
1.
2.
Which of the following pairs of atoms are least likely to form an ionic compound?
a.
Ni, O
b.
Na, F
c.
Cu, Cl
d.
Li, Mg
e.
Li, F
double bond.
b.
single bond.
c.
triple bond.
3.
4.
d.
lone pair.
e.
Which of the following formulas are incorrect on the basis of simple Lewis dot structures?
a.
LiCl
b.
MgO
c.
Na2O
d.
CO2
e.
none of these
H-F
b.
H-Cl
c.
H-H
d.
F-F
e.
H-I
52. Assuming reactions between the following pairs of elements, which pair
is most likely to form an ionic compound?
A. copper and tin
B. chlorine and oxygen
C. cesium and iodine
D. carbon and chlorine
E. fluorine and iodine
53. What kind of bond results when electron transfer occurs between atoms
of two different elements?
A. ionic
B. covalent
C. nonpolar
D. single
E. double
Page 3
54. What is the old name of Cu+?
A. cupric ion
B. cuprous ion
C. copper(I) ion
D. copper(II) ion
E. ferrous ion
55. Give the name of FeSO4 in the Stock system.
A. iron monosulfuric acid
B. iron(II) sulfate
C. iron(III) sulfate
D. ferrous sulfate
E. ferric sulfate
56. Assuming reactions between the following pairs of elements, which pair
is most likely to form a covalent compound?
A. lithium and iodine
B. sodium and oxygen
C. calcium and chlorine
D. copper and tin
E. carbon and oxygen
57. A double bond between two atoms, A and B
A. is longer than a single bond between the same two atoms
B. has a lower bond energy than a single bond between the same two
atoms
C. arises when two electrons are transferred from A to B
D. consists of two electrons shared between A and B
E. consists of four electrons shared between A and B
58. What is the correct formula of phosphorus pentachloride?
A. PCl B. PCl3 C. PCl5 D. P2Cl5 E. P5Cl
59. What term describes the temperature at which a solid is converted into
a liquid?
A. critical point
B. flash point
C. sublimation point
D. melting point
E. boiling point
60. What term describes a solution of a compound in water that conducts an
electric current?
A. amorphous solution
B. an electrolyte solution
C. a nonelectrolyte solution
D. superconducting solution
E. isoelectric solution
Page 4
61. How many bonding electrons are in CO2?
A. 1 B. 2 C. 3 D. 4 E. 8
62. How many nonbonding electrons are in CH4?
A. 0 B. 1 C. 2 D. 3 E. 8
63. How many valence electrons are in SO42-?
A. 2 B. 64 C. 32 D. 12 E. 16
64. According to VSEPR theory, if the valence electrons on a central atom
are 3 bond pairs and one nonbonding (lone) pair, the geometry (shape)
at this atom will be
A. linear
B. bent (angular)
C. trigonal planar
D. trigonal pyramidal
E. tetrahedral
65. T F In Lewis structures, the chemical symbol of an element represents
both the nucleus and the lower energy (nonvalence) electrons.
4 12 12 crystal lattice
4 13 13 Na2S
4 14 14 Ba3N2
4 15 15 iron(II) ion
4 16 16 lower positive charge
4 17 17 polyatomic
4 18 18 SO424 19 19 hydrogen carbonate
4 20 20 ammonium
4 21 21 sodium phosphate
4 22 22 copper(I) oxide
4 23 23 Na2CO3
4 24 24 covalent
4 25 25 Covalent
4 26 26 SO3
4 27 27 NH3
4 28 28 carbon tetrachloride
4 29 29 dinitrogen pentoxide
4 30 30 boiling point
4 31 31 amorphous
4 32 32 electrolyte
4 33 33 nonelectrolyte
4 34 34 covalent
4 35 35 ten
4 36 36
CN
HH
H
HH
4 37 37 H S H
4 38 38
Page 1
Answer Key for Test "chapter4.tst", 8/17/04
No. in
Q-Bank
No. on
Test Correct Answer
The structure shows 26 valence electrons, but there should only be 24.
4 39 39
OOOOOO
4 40 40 bond energy
4 41 41 bond length
4 42 42 Valence Shell Electron Pair Repulsion
4 43 43 120
4 44 44 bent or angular
4 45 45 If the molecule were trigonal planar, the symmetry would result
in a nonpolar molecule. The centers of positive and negative
charge would coincide.
4 46 46 C
4 47 47 C
4 48 48 D
4 49 49 C
4 50 50 D
4 51 51 E
4 52 52 C
4 53 53 A
4 54 54 B
4 55 55 B
4 56 56 E
4 57 57 E
4 58 58 C
4 59 59 D
4 60 60 B
4 61 61 E
4 62 62 A
4 63 63 C
4 64 64 D
4 65 65 T
4 66 66 F
4 67 67 F
4 68 68 F
4 69 69 T
4 70 70 F
4 71 71 F
4 72 72 F
4 73 73 F
4 74 74 T
4 75 75 T
4 76 76 T
4 77 77 F
4 78 78 F
4 79 79 T
4 80 80 F
4 81 81 F
Page 2