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Answer All Questions :

1 Which of the following formula of the compound is true?


 
Compound Formula
A Lead(II) sulphate Pb2SO4
B Ammonium nitrate (NH4)2NO3
C Aluminium oxide AlO3
D Barium nitrate Ba(NO3)2
   
2
Table 1 shows the results to determine the empirical formula of a substance. What is
the empirical formula of the substance?

X Y

Ratio of moles 1 1.5

Table 1
A XY C X3 Y

B XY3 D X2Y3

3 Which of the following is not matched correctly?

Substance Formula
Bahan
Sodium Na
Natrium
Copper(II) sulphate CuSO4
Kuprum(II) sulfat
Potassium oxide K2O
Kalium oksida
Ammonium nitrate NH4(NO3)2
Ammonium nitrat
4 Diagram 4 shows the set –up of apparatus in an experiment to determine the
emperical formula of a metal oxide.
Rajah 4 menunjukkan susunan radas bagi menentukan formula empirik bagi satu oksida
logam.
Diagram 4
Rajah 4

Which of the following metals oxide is suitable to be used in the experiment?


Oksida logam yang manakah paling sesuai di gunakan di dalam eksperimen tersebut?
A Magnesium oxide C Calcium oxide
Magnesium oksida Kalsium oksida

B Aluminium oxide D Copper(II) oxide


Aluminium oksida Kuprum(II) oksida

5 The equation shows a reaction between silver nitrate solution and sodium chloride
solution .
Persamaan di bawah menunjukkan tindak balas antara larutan argentum nitrat dan larutan
natrium klorida.
AgNO3 (aq) + NaCl(aq) → NaNO3 (aq) + AgCl(s)

Calculate the mass of silver chloride formed when 0.2 mol of silver nirate solution
is added to 0.1 mol of sodium chloride ?[ Relative atomic mass : Cl = 35.5 ,Ag =
108]
Hitung jisim argentum klorida yang terbentuk apabila 0.2 mol larutan argentum nitrat
ditambahkan kepada 0.1 mol larutan natrium klorida?{ Jisim atom relatif : Cl = 35.5, Ag
=108}
A 28.7 g C 21.5 g

B 14.35g D 43.05g

6 Which of the following contains 3 moles of atoms?


[S, 32; C, 12 ; Cu , 64 ;O, 16; Avogadro constant= 6.0 X 1023.]

I 96 g of sulphur
II 36 g of carbon
III 18 x 1023 atoms of copper
IV 132 g of carbon dioxide
A I and II only C II and III only
B I and IV only D I ,II and III only

7 How many grams of carbon dioxide would contain the same number of atoms as
in 2 moles of sulphur dioxide, SO2 ?
[ S , 32 ; O , 16; C, 12]

A 11 C 44
B 22 D 88
8 The equation below shows the decomposition of copper(II) nitrate on heating.

2Cu( NO3)2 → 2 CuO + 4NO2 + O2

What is the total volume of gas produced at room temperature when 9.4 g of
copper(II) nitrate is decomposed completely?
[ Relative atomic mass : Cu ,64; N, 14; O,16; 1 mole of gas occupies 24 dm3
at room temperature]

A 0.6 dm3 B 1.2 dm3 C 2.4 dm3 D 3.0 dm3

9 Calculate the mass of carbon dioxide that will be produced at room temperature
when 10 g of calcium carbonate is reacted with excess hydrochloric acid
according to the equation below. :

CaCO3 (s) + 2HCl(aq) → CaCl2 (aq) + H2O( l )+ CO2(g)

[ Relative atomic mass :Ca, 40; O, !6:C, 12]

A 0.44 g B 2.2 g C 4.4 g D 44 g

10 Which of the following is the correct element and symbol ?

Element Symbol
A Nitrogen Ni
B Potassium P
C Copper C
D Magnesium Mg

11 The empirical formula of the carbonate of metal X is X2 CO3 .


Its relative molecular mass is 16. What is the relative atomic mass of X ?
[Relative atomic mass: C, 12; O , 16 ]

A. 11 B. 22 C. 23 D. 44

12
An element W forms a chloride with the formula of WCl3.
What is the formula of sulphate , SO4-2 formed by W ?

A WSO4 B W2SO4
C W2 (SO4)3 D W3 (SO4 )2
12 Calculate the volume occupied by 16.0 g of oxygen gas at stp
[ Ar of O = 16, 1 mol gas occupies a volume of 22.4 dm3 at stp ]

A 1.4 dm3 B 2.8 dm3 C 5.6 dm3 D 11.2 dm3

13 Calculate the number of molecules present in 0.56 dm3 of carbon dioxide gas at stp. [
1 mole of gas occupies a volume of 22.4 dm3 at stp, NA = 6.0 X 1023 mol-1 ]

A 1.2 X 1022 B 1.5 X 1022 C 1.2 X 1023 D 1.5 X 1023

14 What is the mass of carbon dioxide, CO2 gas that contains the same number of
molecules as 2.2 g of propane gas, C3H8 ?
[ Use the information that the relative atomic mass of H = 1, C = 12, O = 16 ]
A 2.2 g B 3.3 g C 4.4 g D 5.5 g
Answer all the question in this section:
Part A : Structure questions
1. Figure 1 shows the set-up of apparatus for an experiment to determine the
empirical formula of magnesium oxide

Figure 1
Results :
Mass of crucible + lid = 24.0 g
Mass of crucible + lid + magnesium ribbon = 26.4 g
Mass of crucible + lid + magnesium oxide = 28.0 g

(a) What is meant by empirical formula ?.

………………………………………………………………………………………
[ 1 marks ]
(b) What is meat by molecular formula ?

………………………………………………………………………………………
[ 1 marks ]
(c) Based on the above results,
(i) determine the empirical formula of magnesium oxide [4 marks]

[ Relative atomic mass : O , 16 ; Mg, 24 ]


(i) write the chemical equation for the reaction in the experiment

………………………………………………………………………………
[ 1 mark ]
(d) Why was the crucible lid opened once in a while during the experiment?.

………………………………………………………………………………………
[ 1 mark ]

e) Why was the magnesium ribbon cleaned with sand paper before heating ?.

………………………………………………………………………………………
[ 1 marks ]
f) Why was the crucible covered with the lid as soon as the magnesium started
burning ?

……………………………………………………………………………………..
[1 marks ]
g) How does to make sure that the reaction is complete ?

……………………………………………………………………………………
[ 1 marks ]

(e) Metal X is placed below hydrogen in the reactivity series. How does the above
experiment suitable for determining the empirical formula of metal X ?.
Explain the reason and suggest the experiment .

……………………………………………………………………………………
[ 3 marks ]
2. A student carried out an experiment to determine the empirical formula of aluminium
oxide. The steps and set-up of apparatus of the experiment are shown in the figure below.
Step Set-up of apparatus
1. Crucible and lid are weighed.

2. Crucible, lid and aluminium strip are weighed.

3. Aluminium strip is heated until the reaction is


complete.

4. Crucible, lid and aluminium oxide are weighed


when cooled.
(a) Complete the following table by stating the observations and related inferences in the
experiment.
Observations Inferences
(i) (i)

(ii) (ii)

[6 marks]

(b) The mass of crucible and lid: g


The mass of crucible, lid and aluminium strip: g
The mass of crucible, lid and aluminium oxide when cooled: g
[3 marks]
(c) (i) What is the mass of aluminium that has been used?

(ii) What is the mass of oxygen which reacted with aluminium?

(iii) Determine the empirical formula of aluminium oxide.


Use the information that relative atomic mass, Al = 27 and O = 16.

[3 marks]

(d) Based on your answer in (c)(iii), how many moles of aluminium and oxygen atoms
have reacted?

[3 marks]
3.
(a) Find the relative molecular mass and chemical formula. Then, complete the table
below.
Substance Chemical formula Relative molecular mass
  Sodium carbonate    
  Copper sulphate    
  Potassium carbonate    
  Aluminium nitrate    
Aluminium Sulphate
Zinc Nitrate
[Relative atomic mass: C = 12; N = 14; O = 16; Na = 23; Al = 27; S = 32; K = 39;
Cu = 64 ; Zn = 35.5 ]

[6 marks]

(b) How many molecules are found in:


(i) 16.2 g of carbon dioxide?

(ii) 22.5 dm³ carbon dioxide at s.t.p.?


[Avogadro constant = 6.02 × 10²³; 1 mol of gas occupies 22.4 dm³ at s.t.p.]

[2 marks]

(c) Calculate the mass of


(i) sodium carbonate that contains the same number of molecules in 21.3 g of
carbon dioxide.

[2 marks]
(ii) copper sulphate that contains the same number of molecules in 12.5 g of
hydrogen.
[2 marks]

4.
a) Calculate the number of molecules present in 0.56 dm3 of carbon dioxide gas at stp.
[ 1 mole of gas occupies a volume of 22.4 dm3 at stp, NA = 6.0 X 1023 mol-1 ]
[ 3 marks ]

b)
Calculate the volume occupied by 16.0 g of oxygen gas at stp
[ Ar of O = 16, 1 mol gas occupies a volume of 22.4 dm3 at stp ]
[ 3 marks ]

c)
The empirical formula of the carbonate of metal X is X2 CO3 .
Its relative molecular mass is 16. What is the relative atomic mass of X ?
[Relative atomic mass: C, 12; O , 16 ]
[ 3 marks ]

d)
The equation below shows the decomposition of copper(II) nitrate on heating.

2Cu( NO3)2 → 2 CuO + 4NO2 + O2

What is the total volume of gas produced at room temperature when 9.4 g of
copper(II) nitrate is decomposed completely?
[ Relative atomic mass : Cu ,64; N, 14; O,16; 1 mole of gas occupies 24 dm3 at
room temperature]
[ 4 marks]

e)
Calculate the mass of carbon dioxide that will be produced at room temperature when
10 g of calcium carbonate is reacted with excess hydrochloric acid according to the
equation below. :

CaCO3 (s) + 2HCl(aq) → CaCl2 (aq) + H2O( l )+ CO2(g)

[ Relative atomic mass :Ca, 40; O, !6:C, 12]


[ 4 marks ]

Part B : Essay Question

1.
(b) The figure below shows the standard representation for an atom of element Na

State three types of information that can be deduced ?


Draw the electron arrangement for an atom of element Na
[5 marks]
(c) The information below is regarding substance X

 Carbon 85.70%

 Hydrogen 14.30%

 Relative molecular mass = 56

(i) Determine the empirical formula of substance X.


[Given that the relative atomic mass of C = 12 , H = 1]
(ii) Determine the molecular formula of substance X.

(iii) Based on the answers in (a)(i) and (a)(ii) , compare and


contrast the empirical formula and the molecular formula.
SULIT NAME : ………………………………………..
4541/2 [ 8 marks]
APRIL TEST
1 HOUR

FORM : ……………………………..

SMK SIMPANG BEKOH


ASAHAN , MELAKA

APRIL TEST 2009

CHEMISTRY

FORM 4

TIME : 1 HOUR

Prepared By : Verified By :

(……………………….) (……………………)
Pn.Rozilah Yunus Pn.Normah Abd Kadir
Chemistry teacher GKMP Science and Mathematic

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