Safety Data Sheet: SECTION 1: Identification of The Substance/mixture and of The Company/undertaking

Safety Data Sheet
according to Regulation (EC) No 1907/2006
Alkadur P 82 Additive
Print date: 23.01.2014
Page 1 of 10
Product code: 91040131
SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Further trade names
valid for all package sizes
REACH Registration Number:

CAS No:
EC No:
01-2119980027-26-0001
52408-42-1
257-900-3
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Coatings and paints, fillers, putties, thinners, Additive.

Uses advised against
The product is intended for professional use.

1.3. Details of the supplier of the safety data sheet
Company name:
STEULER-KCH GmbH
Siershahn
Street:
Place:
Post-office box:
Telephone:
e-mail:
Berggarten 1
D-56427 Siershahn
1163
D-56425 Siershahn
+49 2623 600 0
info@steuler-kch.de
Contact person:
e-mail:
Labor COS/RUL
msds@steuler-kch.de
Internet:
Responsible Department:
www.steuler-kch.de
+49 2624 13 507
+49 2623 600 535
1.4. Emergency telephone

number:
Telefax: +49 2623 600 513
(001) 352 3233500 Emtel-Customer-No. 99496
SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Indications of danger: Xn - Harmful, Xi - Irritant

R phrases:
Harmful if swallowed.
Risk of serious damage to eyes.
May cause sensitisation by skin contact.
Harmful to aquatic organisms.
May cause long-term adverse effects in the aquatic environment.
GHS classification
Hazard categories:
Acute toxicity: Acute Tox. 4
Serious eye damage/eye irritation: Eye Dam. 1
Respiratory/skin sensitization: Skin Sens. 1
Hazardous to the aquatic environment: Aquatic Chronic 3
Hazard Statements:
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Causes serious eye damage.

May cause an allergic skin reaction.
Harmful to aquatic life with long lasting effects.
2.2. Label elements
Hazardous components which must be listed on the label
1,4-butanediylbis[oxy(2-hydroxy-3,1-propanediyl)] diacrylate
Signal word:
Danger
GHS05-GHS07
Pictograms:
Hazard statements
H302
H317
H318
H412
Precautionary statements
P270
P280
P301+P312
P301+P330+P331
P302+P352
P305+P351+P338
Do no eat, drink or smoke when using this product.
Wear protective gloves/protective clothing/eye protection/face protection.
IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
IF ON SKIN: Wash with plenty of water.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
Special labelling of certain mixtures

EUH208
Contains 4-methoxyphenol, hydroquinone monomethyl ether, mequinol. May produce an
allergic reaction.
2.3. Other hazards
Causes mild skin irritation.
Harmful to algae. Harmful to fish. Not readily biodegradable (according to OECD criteria)
Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil. Keep away
from food, drink and animal feeding stuffs.
SECTION 3: Composition/information on ingredients

3.1. Substances
Chemical characterization
Substance related information:
Additive
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Hazardous components
EC No
CAS No
Index No
REACH No
257-900-3
52408-42-1
Chemical name
Classification
GHS classification
Quantity
Xn - Harmful, Xi - Irritant R22-41-43-52-53
> 99,8 %
Acute Tox. 4, Eye Dam. 1, Skin Sens. 1, Aquatic Chronic 3; H302 H318 H317 H412
01-2119980027-26-0001
205-769-8
150-76-5
4-methoxyphenol, hydroquinone monomethyl ether, mequinol

Xn - Harmful, Xi - Irritant R22-36-43
604-044-00-7
Acute Tox. 4, Eye Irrit. 2, Skin Sens. 1; H302 H319 H317
< 0,2 %
Full text of R and H phrases: see Section 16.
SECTION 4: First aid measures

4.1. Description of first aid measures
General information
In case of accident or unwellness, seek medical advice immediately (show directions for use or safety
data sheet if possible). First aider: Pay attention to self-protection!
After inhalation
Provide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice.
After contact with skin
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. Medical treatment necessary.
After contact with eyes
In case of contact with eyes, rinse immediately with plenty of flowing water for 10 to 15 minutes holding
eyelids apart. Subsequently consult an ophthalmologist.
After ingestion
Rinse mouth immediately and drink plenty of water. Do NOT induce vomiting. In all cases of doubt, or
when symptoms persist, seek medical advice.
4.2. Most important symptoms and effects, both acute and delayed
Eye contact: Risk of serious damage to eyes.
Skin contact: May cause sensitisation especially in sensitive humans.
Ingestion: Harmful if swallowed.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media
Water spray. Carbon dioxide (CO2). Dry extinguishing powder. Foam.
Co-ordinate fire-fighting measures to the fire surroundings.
Unsuitable extinguishing media
High power water jet.
5.2. Special hazards arising from the substance or mixture
In case of fire may be liberated: Carbon monoxide. Carbon dioxide. Gas/vapours, toxic.
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5.3. Advice for firefighters

In case of fire and/or explosion do not breathe fumes. Wear a self-contained breathing apparatus and
chemical protective clothing.
Additional information
Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.
Use water spray jet to protect personnel and to cool endangered containers.
SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment. Avoid contact with skin, eyes and clothes. Remove all sources of
ignition. Avoid breathing dust/fume/gas/mist/vapours/spray. Provide adequate ventilation.
6.2. Environmental precautions
Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil.
6.3. Methods and material for containment and cleaning up
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents).
Treat the recovered material as prescribed in the section on waste disposal.
6.4. Reference to other sections
See protective measures under point 7 and 8.
Disposal: see section 13
SECTION 7: Handling and storage

7.1. Precautions for safe handling
Advice on safe handling
Wear personal protection equipment. Provide adequate ventilation. Avoid contact with skin, eyes and
clothes. Do no eat, drink or smoke when using this product. Spontaneous ignition possible through
autoxidation of cloths soaked in the product.
Advice on protection against fire and explosion
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Take precautionary measures
against static discharge.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Keep container tightly closed in a cool, well-ventilated place.
Conditions to avoid: UV-radiation/sunlight. heat.
Keep only in the original container at temperature not exceeding 45 C.
Unsuitable materials for Container: copper. Iron.
Advice on storage compatibility
Do not store together with:
Gases under presussure. Oxidizing agents. Organic peroxides:
Further information on storage conditions
Floors should be impervious, resistant to liquids and easy to clean. Observe in addition any national
regulations!
Storage class:
storage stability: 6 months storage temperature: < 45 C
7.3. Specific end use(s)
Restricted to professional users. Observe technical data sheet.
SECTION 8: Exposure controls/personal protection

8.1. Control parameters
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Additional advice on limit values
DNEL/DMEL and PNEC values:

DNEL worker:
DNEL long-term inhalative (systemic): 4,7 mg/m
DNEL long-term dermal (systemic): 0,67 mg/kg
PNEC type:
PNEC aquatic, freshwater:0,0616 mg/L - PNEC aquatic, marine water:0,00616 mg/L
PNEC sediment, freshwater: 0,283 mg/kg - PNEC sediment, marine water: 0,0283 mg/kg
PNEC aquatic, intermittent release:0,616 mg/L - PNEC sewage treatment plant (STP): 10 mg/L
PNEC Soil: 0,0205 mg/kg
8.2. Exposure controls
Appropriate engineering controls
If local exhaust ventilation is not possible or not sufficient, the entire working area must be ventilated by
technical means.
Protective and hygiene measures
Remove contaminated, saturated clothing immediately. Protect skin by using skin protective cream.
After work, wash hands and face. When using do not eat or drink.
Eye/face protection
Tightly sealed safety glasses.
Hand protection
Tested protective gloves are to be worn:
Breakthrough times and swelling properties of the material must be taken into consideration.
Suitable material: NBR (Nitrile rubber).
Skin protection
Suitable protective clothing: Single-use suit.
Respiratory protection
With correct and proper use, and under normal conditions, breathing protection is not required.
Environmental exposure controls
Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil.
SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state:
Colour:
Odour:
liquid
light yellow
characteristic
Test method
pH-Value (at 20 C):
not determined
Changes in the physical state

Melting point:
not determined
> 150 C slow decomposition.
Initial boiling point and boiling range:
not applicable
Sublimation point:
-58 C
Softening point:
Flash point:
> 100 C DIN EN ISO 2719
Flammability
Solid:
not relevant
not relevant
Gas:
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Explosive properties
The product is not: Explosive.
Lower explosion limits:

Upper explosion limits:
not applicable
not applicable
not determined
Ignition temperature:
365 C
Auto-ignition temperature
Solid:
Gas:
Oxidizing properties
The product is: Not oxidizing.
Vapour pressure:
(at 20 C)
Density (at 20 C):
Bulk density:
Water solubility:
(at 20 C)
Solubility in other solvents
Soluble in: ester/ketone.
Partition coefficient:
1 hPa
1,1642 g/cm ISO 2811
not applicable
partially soluble
0,3 - 2,5
Viscosity / dynamic:
(at 25 C)
Viscosity / kinematic:
Flow time:
650 - 850 mPas DIN 53015
Vapour density:
No data available
0%
not determined
not determined
Solvent content:
9.2. Other information
Solid content:
0,19 %
SECTION 10: Stability and reactivity

10.1. Reactivity
No ignition, explosion, self-heating or visible decomposition.

10.2. Chemical stability
The product is stable under storage at normal ambient temperatures.
10.3. Possibility of hazardous reactions
Stabiliser can lose its effectiveness if stored over a long period of time.
10.4. Conditions to avoid
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Take precautionary measures
against static discharge.
10.5. Incompatible materials
acid. Base. Oxidizing agents. Reducing agent.
10.6. Hazardous decomposition products
In case of fire may be liberated: Pyrolysis products, toxic. Carbon monoxide. Carbon dioxide.
Burning produces heavy smoke.
SECTION 11: Toxicological information

11.1. Information on toxicological effects
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Acute toxicity
Acute toxicity, dermal.
CAS No
Chemical name
Exposure routes
52408-42-1
Dose
Species
Source
Rat
OECD 423
oral
150-76-5
Method
LD50
> 300 2000 mg/kg

oral
LD50
1600 mg/kg
Rat
Irritation and corrosivity

Irritating to eyes. Risk of serious damage to eyes.
Sensitising effects
May cause sensitization by skin contact.
STOT-single exposure
No data available
Severe effects after repeated or prolonged exposure
May cause sensitisation especially in sensitive humans.
Carcinogenic/mutagenic/toxic effects for reproduction
This substance does not meet the criteria for classification as CMR category 1 or 2.
Specific effects in experiment on an animal
The product has not been tested. Toxicological data are not available.
SECTION 12: Ecological information

12.1. Toxicity
The product has not been tested. Toxicological data are not available.
CAS No
Chemical name
Aquatic toxicity
52408-42-1
150-76-5
Method
Dose
[h] | [d] Species
Source
Acute fish toxicity
LC50
66,8 mg/l
96 h Brachydanio rerio
(zebra-fish)
OECD 203
Acute algae toxicity
ErC50
61,6 mg/l
72 h Pseudokirchneriella
subcapitata
OECD 201
Acute crustacea toxicity
EC50
> 100 mg/l
48 h Daphnia magna (Big water

flea)
OECD 202
96 h
GESTIS

Acute fish toxicity
LC50
84,3 mg/l
12.2. Persistence and degradability
Not easily bio-degradable (according to OECD-criteria).

CAS No
Chemical name
Method
Value
Source
40- 50 %
28
OECD 301 F
Evaluation
52408-42-1
Biological degradation:
Product is not easily biodegradable.
12.3. Bioaccumulative potential
There are no data available on the preparation/mixture itself.

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Partition coefficient n-octanol/water

CAS No
Chemical name
52408-42-1
150-76-5
Log Pow
0,3-2,5
1,34
12.4. Mobility in soil

Adsorption/Desorption:
log Koc: 1 (Methode: calculated.)
12.5. Results of PBT and vPvB assessment
This substance does not meet the criteria for classification as PBT or vPvB.
12.6. Other adverse effects
No information available.
SECTION 13: Disposal considerations

13.1. Waste treatment methods
Advice on disposal
Do not allow to enter into surface water or drains. Dispose of waste according to applicable legislation.
Evidence for disposal must be provided.
Waste disposal number of waste from residues/unused products
WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the MFSU of plastics, synthetic
070208
rubber and man-made fibres; other still bottoms and reaction residues
Classified as hazardous waste.
Waste disposal number of contaminated packaging
WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE
150110
CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately collected municipal
packaging waste); packaging containing residues of or contaminated by dangerous substances
Classified as hazardous waste.
Contaminated packaging
Water (with cleaning agent). Completely emptied packages can be recycled. Handle contaminated
packages in the same way as the substance itself.
SECTION 14: Transport information

Land transport (ADR/RID)
14.2. UN proper shipping name:
No dangerous good in sense of these transport regulations.
Inland waterways transport (ADN)

No dangerous good in sense of these transport regulations.
Marine transport (IMDG)

Not a hazardous material with respect to these transportation regulations.
Air transport (ICAO)

Not a hazardous material with respect to these transportation regulations.
14.5. Environmental hazards
ENVIRONMENTALLY HAZARDOUS:
no
14.6. Special precautions for user

Keep away from food, drink and animal feeding stuffs.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not classified for this carrier.
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SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information
1999/13/EC (VOC):
100 % (1164,2 g/l)
National regulatory information
Employment restrictions:
Water contaminating class (D):
Skin resorption/Sensitization:
Observe employment restrictions for young people.

2 - water contaminating
Causes allergic hypersensitivity reactions.
15.2. Chemical safety assessment
For the following substances of this mixture a chemical safety assessment has been carried out:
SECTION 16: Other information

Changes
This data sheet contains changes from the previous version in section(s): 2,3,5,6,7,8,9,10,11,12,15,16.
Abbreviations and acronyms
ADR: Accord europen sur le transport des marchandises dangereuses par Route
(European Agreement concerning the International Carriage of Dangerous Goods by Road)
RID: Rglement international concernant le transport des marchandises dangereuses par chemin de
fer
(Regulations Concerning the International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
GefStoffV: Gefahrstoffverordnung (Ordinance on Hazardous Substances, Germany)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
VOC: Volatile Organic Compounds (USA, EU, CH)
DNEL: Derived No-Effect Levels
PNEC: Predicted No-Effect Concentration
Full text of R phrases referred to under Sections 2 and 3
22
36
Irritating to eyes.
41
Risk of serious damage to eyes.
43
May cause sensitisation by skin contact.
52
Harmful to aquatic organisms.
52/53
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
53
May cause long-term adverse effects in the aquatic environment.
Full text of H statements referred to under Sections 2 and 3
H302
H317
H318
H319
Causes serious eye irritation.
H412
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Further Information
The above information describes exclusively the safety requirements of the product and is based on
our present-day knowledge. The information is intended to give you advice about the safe handling of
the product named in this safety data sheet, for storage, processing, transport and disposal. The
information cannot be transferred to other products. In the case of mixing the product with other
products or in the case of processing, the information on this safety data sheet is not necessarily valid
for the new made-up material.
Revision No: 1,01
GB - EN

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Safety Data Sheet

according to Regulation (EC) No 1907/2006

Product code: 91040131

SECTION 1: Identification of the substance/mixture and of the company/undertaking

REACH Registration Number:

Coatings and paints, fillers, putties, thinners, Additive.

The product is intended for professional use.

1.4. Emergency telephone

Telefax: +49 2623 600 513

(001) 352 3233500 Emtel-Customer-No. 99496

SECTION 2: Hazards identification

Indications of danger: Xn - Harmful, Xi - Irritant

Revision date: 23.01.2014