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John M. Guilbert
Professor Emeritus of Economic Geology
Department of Geosciences, The University of Arizona - USA
INTRODUCTION
It is my intent in this article to examine the remarkable improvements in our
understanding of the linkages among hydrothermal ore deposit types that are
developing as we enter the 21st century. Dramatic changes have occurred in our
perceptions of formative processes and genetic models for hydrothermal deposits
in the last 30 years that will profoundly change the techniques and methods
whereby exploration for those deposits will proceed in the next decades. As I will
suggest, we find ourselves much better equipped to evaluate processes and
genetic models related to hydrothermal ore deposits than we were even a couple
of decades ago, such that we need no longer focus unduly simply on temperature
and pressure. In short, we have what appears to be a much fuller understanding
of relationships among the many types of hydrothermal ore forming systems. Ore
deposit research is succeeding.
Part of the simplicity of Figure 1 stems from the fact that earlier classifications
have been improved by quantitative observations made since their publication,
observations that generally led to simplification and more satisfactory genetic
connections. Figure 3 shows Lindgren's brilliant classification of 1933 in which he
related many ore deposit types to their temperatures and pressures of formation.
This grouping was all pre-plate-tectonics and pre-fluid-inclusion-geothermometry
and geobarometry, and most of his assignments were inferential and based on the
best information available to him on mineral formation temperatures and
pressures. Lindgren considered hypothermal deposits to have formed at
temperatures roughly between 300 and 500 degrees Centigrade, temperatures
that we now consider to be solidly 'mesothermal'. As we will see, most of the
deposits that Lindgren classified as 'hypothermal' have in fact been reassigned to
other pigeonholes, such that the hypothermal classification can be considered to
have essentially disappeared. Few people use the terms 'telethermal' or
'xenothermal' any longer, and in fact the volcanogenic systems that were almost
incidental in Lindgren's classification have assumed huge importance since the
1970s. Figure 4 shows a revised Lindgren classification, with a number of new
entries, especially those under Solution-Remobilization. Emphases have changed,
genetic affiliations have changed, and deposit pigeonholing has changed, I think
much to the improvement of exploration parameters. Among other things, what has
certainly changed is the dynamics of our thinking of ore genesis and the
distribution of ore deposits. From the stabilist world of Lindgren and Emmons and
the early classifiers, we have moved into a global framework involving waters of
many different derivations (indicated in red in Figure 5) in many different tectonic
settings with many different melting environments and magma paths. It is also true
that the marvelously sophisticated research tools presently being brought to bear,
for example on fluid inclusions from ore-forming environments, are greatly
expanding our understanding of ore-forming processes and the interface between
magmas, hydrothermal fluids of several derivations, and their flowpaths.
So where did all the hypothermal deposits go? Figure 6 is a list of those deposits
that Lindgren included in his traditional hypothermal category. As shown, most of
those deposits have been reclassified into variations on a seafloor exhalation
model, with departures in tectonic settings, postformational tectonics, and
metamorphism. The classic Cornwall England tin deposits have been shown to be
better classified as spawned by S-type peraluminous High Heat Development
granites, and to differ from their I-type brethren in ways that we shall see.
classic
Cu-Au-Mo
porphyry
deposits,
and
that
the
S-type
systems
Lest it be thought that I might just be engaging in another level of speculation, let
me describe briefly one of the major breakthroughs in our understanding of
porphyry systematics that is carrying us to new levels of factual basis. Christopher
Heinrich and his students in Zrich, among others, have been developing new
techniques for single fluid inclusion quantitative chemical analysis. They have
been developing ultraviolet laser ablation and induction-coupled mass
spectrometric methods to open individual fluid inclusions (Figure 11) and to
vaporize their contents into a plasma that carries those contents directly into a
mass spectrometer. Heinrich and his team members are thus analyzing entire
individual fluid inclusions in terms of salinities and relative metal contents (Figure
12) that are interpreted to be micro-encapsulated samples of porphyry ore-forming
fluids. This work permits study of partitioning between the melt and its fluids, both
liquid brine and vapor, giving rise to the data in Figure 13, which shows palpable
CORDILLERAN VEINS
The Cordilleran Vein association was first set forth by Sawkins (1972), having
been depicted as part of the upper structural retinue of porphyry coppers by
Lowell and Guilbert (1970); the association is further described by Guilbert and
Park (1986). Figure 15 is a summary of W. H. Emmons' 1936 'Reconstructed
Vein', a description of the ideal composite vein mineralogy. I noted while
preparing a discussion of the reconstructed vein for Guilbert and Park that
although it was presented as descriptive of a typical vein system, I knew of no vein
in the world that contained the entire assemblage. It became apparent, with the
revelations of the various granitoid types, that Emmons had indeed telescoped
Cornwall and Butte-Casapalca-type vein systems to form one homogeneous but
unrealistic composite vein assemblage. Separating out Items 12-15 that are typical
of Cornwall leaves an assemblage (Items 1-11) that describes Butte, Magma, and
Casapalca almost perfectly. Sillitoe in his diagram (Figure 2) includes an interval
of these Massive Sulfide Cu-As-(Au-Ag) higher level veins above the potassic
alteration zone of the main porphyry system, which is now generally known as the
Cordilleran Vein environment. It is significant to the explorationist that there are
indeed different vein assemblages associated with different peraluminous,
metaluminous and calc-alkaline granitoid parent intrusions.
EPITHERMAL DEPOSITS
A great deal has been written in the last decade or two concerning connections
between porphyry systems and epithermal deposits. The association has long
been suspected, but only in the last few years has the linkage been firmly cast
both geologically and geochemically. Figure 16 shows the relationship between
the sericite-adularia low-sulfidation-type deposits and acid-sulfate high-sulfidationtype systems so well described by USGS geologists Heald, Foley, and Hayba
(1987) and further detailed by Richard Sillitoe in several publications (and Figure
2 again) and by White and Hedenquist (1995) and others. Figure 17 from Heinrich
et al. (1999) shows a generalized process and spatial connection between
porphyry and epithermal systems and similarity to the Lepanto - Far Southeast
Acid-Sulfate Epithermal - Porphyry Copper-Gold array, as depicted by Hedenquist,
Arribas, and Reynolds (1998) is quite clear. Linkages between epithermal deposits
and porphyry systems are becoming increasingly more convincingly documented
around the Rim of Fire, particularly with regard to Cu-Au rich porphyry systems.
Suffice it to say here that this linkage, at first only conceptually attractive, has now
been cemented by observation, process-model considerations, and geochemistry.
CU-AU-FE-REE SYSTEMS
The last category of hydrothermal deposits to be considered here may have
enormous impact on the progress of ore-deposit understanding and exploration.
Among others, Mark Barton and his students at the University of Arizona have
been investigating the Cu-Au-Fe-REE deposit type, with extraordinary results. One
of the key aspects that contributes to their formation appears to be the incursion
of meteoric fluids that have contacted evaporite sections and are thus Na-, Ca-,
and Cl-rich. The chloride dominance affects both dissolution and transport
characteristics of the hydrothermal fluids externally to and during transit through
the heat-source intrusive, again in what we have come to perceive as 'porphyry'
mesothermal pressure-temperature environments. David Johnson's dissertation
at the Humboldt Mafic Complex in Nevada affords comparison of the behavior of
briny hydrothermal fluids in both mafic and felsic contexts, as seen in Figure 21
from Johnson and Barton (2000). Figure 22 shows not only a rationalization for the
development of sodium-calcium metasomatism, but also it shows regimes of
dissolution, transportation, and deposition of metals in the brine-dominated
*Not available.
7
REFERENCES CITED
Barton, M.D., and D.A. Johnson, 1996. Evaporite-source model for igneousrelated Fe oxide-(REE-Cu-Au-U) mineralization. Geology 24:259-262.
Bastin, E.S., 1922. Primary native silver ores near Wickenburg, Arizona. USGS
Bull 735-E, pp. 131-155.
Bookstrom, A.A., 1977. The magnetite deposits of El Romeral, Chile. Econ. Geol.
72: 1101-1130.
Chappel, B.W., and A.J.R. White, 1974. Two contrasting granite types. Pac. Geol.
8: 173-174.
Dilles, J.H., M.T. Einaudi, J. M. Proffett, and M.D. Barton, 2000. Overview of the
Yerington porphyry copper district: magmatic to nonmagmatic sources of
hydrothermal fluids: their flow paths, and alteration effects on rocks and
Cu-Mo-Fe-Au ores. Pp.55-66 in Soc. Econ. Geol. Guidebook Series 32,
Part I. Contrasting styles of intrusion-associated hydrothermal systems, 162
pp.
Dilles, J.H., J. M. Proffett, and M.T. Einaudi, 2000. Field Trip Day 2, Magmatic and
hydrothermal features of the Yerington batholith with emphasis on the
porphyry Cu(Mo) deposit in the Ann-Mason area. Pp.67-89 in Soc. Econ.
Geol. Guidebook Series 32, Part I. Contrasting styles of intrusionassociated hydrothermal systems, 162 pp.
Emmons, W.H., 1936. Hypogene zoning in metalliferous lodes. 16th Internat.
Geol. Congr. Rpt., pt 1, 417-432.
Guilbert, J.M., and C.F. Park, Jr., 1986. The Geology of Ore Deposits. New York,
W.H. Freeman, 985 pp.
Giggenbach, W., 1997. The origin and evolution of fluids in magmatichydrothermal systems. In Barnes, H.L., ed., Geochemistry of Hydrothermal
Ore Deposits, 3rd. ed. New York, John Wiley, p. 737-796.
Gustafson, L.B. and J.P. Hunt, 1975. The porphyry copper deposit at El
Salvador, Chile. Econ. Geol. 70: 857-912.
Heald, P., N.K. Foley, and D.O. Hayba 1987. Comparative anatomy of volcanic hosted epithermal deposits: acid-sulfate and adularia-sericite types. Econ.
Geol. 82: 1-26
Hedenquist, J.W., A. Arribas Jr., and J.R. Reynolds, 1998. Evolution of an
intrusion-centered hydrothermal system: Far Southeast-Lepanto porphyry
and epithermal Cu-Au deposits, Philippines. Econ. Geol. 93: 373-404.
Hedenquist, J.W. and J.P. Richards, 1998. The influence of geochemical
10
FIGURES
Epithermal
High Sulfidation - Low Sulfidation
Volcanogenic
Sed-Ex
Cordilleran Vein
Cu-Au-Fe-REE
PORPHYRY
I-Type = Cu-Au-Mo
S-Type = Sn-W-Bi; Pegmatites
A-Type = Climax Mo
Alkalic = Cu-Au
Intrusion-Related Au
Five-Element
11
IN 2001
HYPOTHERMAL..GONE!
MESOTHERMAL..
Porphyry Copper, Moly, Gold, Tin, Climax Moly
Cordilleran Veins
Igneous Metamorphic
Cu-Au-Fe-REE / Five Metals
Intrusion-Related Gold
EPITHERMAL
High-Sulfidation - Low-Sulfidation
SOLUTION-REMOBILIZATION
Missippippi Valley Type
Western States / Athabasca Uranium
Cu-Au-Fe-REE / Five Metals
VOLCANOGENIC
Figure 4. A revised classification of some of the major
hydrothermal ore deposits for 2001.
12
13
THE PORPHYRIES
From the static models of the early1970s
to delineation of several subsets classified by
Metal content
Temperature-Pressure regimes
Alteration assemblages
Lithologic affiliation
Tectonic position
Fluid histories and sources
Mantle plumes to meteoric-dominated
Brine versus freshwater
Figure 7. A profile of the expansion of porphyry ore
deposit varieties as perceived in 2001.
Figure 8. An example of information detail available in current porphyry copper-gold studies. (Bajo
de la Alumbrera, after Proffett and/or Keough, in prep.).
14
Figure 9. Giggenbachs (1997) Process Focused schematic of Active Lowsulfidation porphyry copper deposit system genesis.
15
Figure 11. A sketch of the UV LA ICP MS (ultraviolet laser ablation induction-coupled plasma
mass spectrometric) method of total fluid inclusion analysis, after Ulrich (1998). The extraction
stages cover 36 seconds from left to right.
Figure 12. An example of the analytic data obtained from a single fluid inclusion from Bajo de la
Alumbrera with the UV LA ICPMS procedure (after Ulrich, 1998).
16
Figure 13. Partitioning of elements between brine and vapor derived from peraluminous (A),
metaluminous (B) and calc-alkaline magmas (D,E) (after Heinrich, et al., 1999).
200
400
800
17
18
Figure 17. A process-focused schematic of the linkage between porphyry and epithermal
environments, not accidentally echoing Figure 18. (After Heinrich, et al., 1999).
Figure 18. Hedenquist, Arribas, and Reynolds (1998) delineation of connections between the
acid-sulfate epithermal Lepanto deposit and the subjacent and contemporaneous Far
Southeast copper-gold porphyry system. See Figure 17.
19
Figure 20. Comparison of the porphyry environment shown in Figure 2 with that of IntrusionRelated Gold systems, which occur at similar lithostatic-hydrostatic depths and temperatures.
(After Lang, et al., 2000).
Figure 22. Geologic and chemical characteristics of systems affected by briny meteoric fluids. The
profound significance of the gain-loss arrows is discussed in text. (From Johnson and Barton,
2000).
Figure 23. Alteration zones, flowlines, and isotherms showing the effects of brine incursion at
Yerington, Nevada, particularly the sodium-calcium metasomatism zone. (After Dilles et al., 2000).
21
22