81.

Arrange the following in increasing ionization energy: Ga, Sg, La, Sb, Sr
a. La Sg Sb Sr Ga
b. Sg La Sr Sb Ga

c. Ga Sr Sb Sg La
d. Ga Sb Sr La Sg

82.A 0.0040-mole sample of S2 (g) is allowed to dissociate in a 0.500-L flask at

1000 K. When equilibrium is established, 2.0 x 10 -11 moles of S (g) is present.
What is the concentration equilibrium constant for the reaction?
a. 1.97 x 10-21
c. 1.6 x 106
-17
b. 1.64 x 10
d. 2.0 x 10-19
e.
83.Which natural products have structures derived from cholesterol?
a.
I. Vitamin A
b.
II. Vitamin D
c.
III. Cholic acid
d.
IV. Cortisone
e.
V. Squalene
f.
g. I, II III
i. III, IV, V
h. II, III, IV
j. I, III, V
k.
84.Calculate the amount of silica produced from 250 grams of silane. (Si = 30
g/mol)
a. 300 g
c. 150 g
b. 142 g
d. 441 g
e.
85.Which conditions will convert pentanoic acid to pentanoyl chloride?
a. HCl
c. SOCl2
b. NaCl
d. LiAlH4 followed by HCl
e.
86.Which oxidation conditions are used in the industrial transformation of
cyclohexanone to adipic acid?
a. K2Cr2O7 / H2SO4
c. HNO3
b. KMnO4
d. AgNO3 / NH3
e.
87.Which of the following does not contain a stereocenter?

a.

(I)

(II)

(III)
b.
c. I and II
d. II and III

Property of Billones, Fulgencio, Layug, Lopez, Sampaga

e. I only
f. III only

g.
88.The acid dissociation constant of phenol red indicator is 1.259 x 10 -8. What is
its pH range?
a. 3.8 5.4
c. 7.8 8.5
b. 4.8 6.0
d. 6.8 8.4
e.
f.
89.What is the pH of 0.1 M of NH4Cl? KA = 5.6 x 10*10
a. 5.63
c. 2.87
b. 5.13
d. 8.87

Property of Billones, Fulgencio, Layug, Lopez, Sampaga

90.
91.What is the product formed when 45Ti decays by positron emission?
a. Scandium
c. Calcium
b. Vanadium
d. Chromium
e.
92.Calculate the energy change of Uranium given by the fission reaction:
a.
b.

235
92

94

140

U + 0n 40 Zr + 58Ce +6 +1e +2 0 n

The atomic masses are:

93.9061 g/mol,

140
58

Ce

235
92

= 235.0439 g/mol,

94
40

Zr

= 139.9053 g/mol.

a. -1.98 x 1016 J/amu

c. -3.29 x 10-11 J/amu
13
b. -1.98 x 10 J/amu
d. -1.40 x 10-13 J/amu
e.
93.An electrode consisting of a platinum electrode that is immersed in a 1 M H +
solution and that has H2 gas bubbled over it at 1 atm pressure. It is defined as
the reference electrode.
a. Standard electrode
c. Standard
hydrogen
b. Standard
electrode
electrode
potential
d. Glass electrode
e.
94.Calculate the reduction potential for hydrogen ion in a system having a
perchloric acid concentration of 2.00 x 10 -4 M and a hydrogen pressure of
2.50 atm at 25oC.
a. -0.46 V
c. -0.21 V
b. -0.12 V
d. -0.23 V
e.
95.The amount of water in human blood plasma.
a. 80%
c. 60%
b. 90%
d. 8%
e.
96.Calculate the final temperature of carbon dioxide of mass 16.0 g with a
specific heat capacity of 0.844 J/gK that is expanded reversibly and
adiabatically from 500 cm3 at 298.15 K to 2.00 dm3.
a. 32.33 K
c. 126.99 K
b. 218.60 K
d. 199.88 K
e.
97.Determine the change in internal energy when 2.0 mol CO 2 is heated at a
constant pressure of 5.0 atm and its temperature increases from 250 K to 277
K.
a. 1556.39 J
c. 2454.30 J
b. 2005.34 J
d. 1780.87 J
e.
98.It gives the probability that the electron will be found anywhere between the
two walls of a spherical shell.
a. Radial Wavefunction
b. Radial
Distribution
Function

Property of Billones, Fulgencio, Layug, Lopez, Sampaga

c. Radial
Function

Hydrogenic

d. Radial Quantum Function

e.
f.
99.It is the ratio of pressure to the fractional change in volume.
a. Youngs Modulus
c. Shear Modulus
b. Bulk Modulus
d. Poissons Ratio
e.
100.
Calculate the theoretical oxygen demand of 200 ppm of glucose acid.
a. 160 ppm
c. 107 ppm
b. 213 ppm
d. 205 ppm
e.
f. 100. The pH of a water sample was found to be 7.0. The bicarbonate was
measured to be
g.
2.1 x 10-3 M. Assuming that the sample was isolated from the
atmosphere, calculate the total carbonate if Pk a1 and pKa2 are equal to 6.3
and 10.33, respectively.
a. 2.2 x 10-3 M
c. 2.8 x 10-3 M
b. 2.5 x 10-3 M
d. 3.0 x 10-3 M
e.

Property of Billones, Fulgencio, Layug, Lopez, Sampaga