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Module 2.5
Cement Kiln
Process Chemistry
Module 2. Cement clinker quality and composition.
2.5 Deviation from Bogue compound
composition.
In the preceding two sessions of the course we saw that the clinker
mineral composition, i.e. the C3S, C2S, C3A and C4AF content, is
controlled by proportioning the raw materials to lime saturation,
silica modulus and alumina modulus targets. ..and that
the clinker mineral composition can be calculated from the oxide
composition using the Bogue methodology.
This is considered sufficient by most cement companies.
However, the clinker mineral composition according to Bogue is
only another way of expressing the oxide composition.
The real clinker mineral composition can differ quite widely
.the reasons for
from the Bogue composition.
that deviation will be explored in this session of the course.
This document is for the sole use of students enrolled on course CKPC01 and cannot be reprinted, reproduced or distributed without prior written consent from Tradeship Publications Ltd
http://Training.CemNet.com
Module 2.5
This document is for the sole use of students enrolled on course CKPC01 and cannot be reprinted, reproduced or distributed without prior written consent from Tradeship Publications Ltd
http://Training.CemNet.com
Module 2.5
This document is for the sole use of students enrolled on course CKPC01 and cannot be reprinted, reproduced or distributed without prior written consent from Tradeship Publications Ltd
http://Training.CemNet.com
Module 2.5
The following corrections are made to the C3S and C2S content
of the clinker:
%C3S = Bogue Value + 1.8 x %Al2O3 - 2.8 x %Fe2O3
%C2S = Bogue Value - 2.1 x %Al2O3 + 1.9 x %Fe2O3
This document is for the sole use of students enrolled on course CKPC01 and cannot be reprinted, reproduced or distributed without prior written consent from Tradeship Publications Ltd
http://Training.CemNet.com
Module 2.5
SiO2
A2S
CS
CAS2
C3S2
C2S
C2AS
C3S
Al2O3
CaO
CA
C3A
Al2O3
C12A7
SiO2
A2S
CS
CAS2
C3S2
C2S
C2AS
C3S
Al2O3
CaO
C3A
CA
Al2O3
C12A7
This document is for the sole use of students enrolled on course CKPC01 and cannot be reprinted, reproduced or distributed without prior written consent from Tradeship Publications Ltd
http://Training.CemNet.com
SiO2
A2S
CS
CAS2
C3S2
C2S
.but at the
ternary eutectic
between C2S, CaO
C3A and C12A7.
Module 2.5
C2AS
C3S
Al2O3
CaO
CA
C3A
Al2O3
C12A7
3 2
12
SiO2
A2S
CS
CAS2
C3S2
C2S
.but at the
ternary eutectic
between C2S, CaO
C3A and C12A7.
C2AS
C3S
Al2O3
CaO
C3A
CA
Al2O3
C12A7
This document is for the sole use of students enrolled on course CKPC01 and cannot be reprinted, reproduced or distributed without prior written consent from Tradeship Publications Ltd
http://Training.CemNet.com
Module 2.5
This document is for the sole use of students enrolled on course CKPC01 and cannot be reprinted, reproduced or distributed without prior written consent from Tradeship Publications Ltd
http://Training.CemNet.com
Module 2.5
Cement Kiln
Process Chemistry
Module 2. Cement clinker quality and composition.
2.5 Deviation from Bogue compound
composition.
This document is for the sole use of students enrolled on course CKPC01 and cannot be reprinted, reproduced or distributed without prior written consent from Tradeship Publications Ltd
http://Training.CemNet.com