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Declaration
I, Sagar Gupta student of XI-B is doing project report entitled Rusting of Iron being
submitted to our Chemistry Teacher Mr. N.K. Sharma is an original piece of work done by
me.
(Signature)
Rusting of Iron
INTRODUCTION
Ironisoneofthewidelydistributedelementsinthenature.Oneofits
strikingcharacteristicsisthatitundergoesrustingoncombiningwith
water,air&carbondioxideduetowhichitssurfacegetscoveredwith
aredbrownflakecoatingcalled"RUST".RUSTisaffectedbymoisture,
oxygen&carbondioxide.RUSTissoftandporousanditgradually
fallsofffromthesurfaceofironmaterial.Itisacontinuousprocessand
itgraduallyeatsupironduetowhichanironobjectlosesitsstrength.
Itisverywastefulprocessandshouldbeprevented.Itisveryveryslow
process.
ThusHatomseitherreactwiththedissolvedoxygenoroxygenfromair
tofromwater.
4H+O2======>2H2O(v)
Thecompletereactionmaybewrittenas:
O2+4H++4e======>2H2O(vi)
ThedissolvedoxygenmaytakeupelectronsdirectlytofromOHions
asfollows:
O2+2H2O+4e======>4OH(vii)
Theoverallreactionoftheminiaturecellwillbe:
2Fe(s)+O2(g)+4H+(aq)===>2Fe++(aq)+2H2O(l)
4.Theferrousionsformedreactwiththedissolvedoxygenoroxygen
fromairtofromferricoxidasfollows:
4Fe+++O2+4H2O======>2Fe2O3+8H+(aq)
FerricoxidethenundergoeshydrationtoformRUSTasfollows:
Fe2O3+xH2O=======>Fe2O3xH2O
Hydratedferricoxide(RUST)
Requirements
Apparatus:
i)Boilingtubes
ii)Rubberstopper
iii)Ironnails
iv)Burner
v)Testtube,Holder&Stand
Chemicals:
i)DistilledWater
ii)DiluteHCL
iii)DiluteNaClSolution
iv)AnhydrousCalciumChloride
v)Cotton
vi)MustardOil
Procedure - Iron Rusting
i)TakefivedrytesttubesandmarkthemA,B,C,DandE.Take10
piecesofironnailsfreefromrust.
ii)Moisttwoironnailswithdistilledwaterandslideitinthetesttube
markedAclosethemouthofthetube.
iii)InthetesttubeBtake5mlofwaterandboilitsoastoremove
dissolvedair.Slidetwonailsinthistesttubeandfewdropsofmustard
oilsoastocoverthesurfaceofH2O.
iv)InthetesttubeCtake5mlofdiluteNaClsolution.Slidetwonails
andcloseit.
v)InthetesttubeOaddtwopiecesofhydrouscalciumchlorideand
coveritwiththinlayerofcotton.Againslide3nailsandcloseit.
vi)leavethesetesttubesassuchfor45daysandobservecarefullyin
whichofthetubesrustisformed.
Observations
i)ItisobservedthatrustingtakesplaceinthetesttubeAandCwhere
asnotinB,D,andE.
ii)Moisture,oxygenandcarbondioxidepresentinairareresponsible
forrusting.
iii)Itappearsthatduringacompoundofironisformedbythe
combinationofironoxygen,carbondioxideandwater.
iv)Itisobservedthatwhentheprocesswasprolongedinthepresence
ofmoistairandacids,rustingspreadsquickly.
Methods of Prevention
i)
Rustingofironcanbepreventedbycoveringitssurfacewith
paints,greaseandlacquers.
ii)Galvanisation:Thisisoneofwidelypracticalmethodsusedforthe
preventionofrusting.ThelayerofZinconthesurfaceofiron,when
comesincontactwithmoisture,oxygenandcarbondioxideinair,
ferrousaprotectiveinvisiblethinlayerofbasiczinccarbonateZnCO3.
Zn(OH)2duetowhichthegalvanisedironsheetslosetheirlustureand
alsotendstoprotectitfromfurthercorrosion.
iii)Rustingofironcanalsobepreventedbycoatingitssurfacewith
iron(II,III)oxideFe3O4oriron(III)phosphateFePo4.
Conclusions
(i)Rustisformedbyprolongedactionofwateroxygenandcarbon
dioxideonanironunderothersuitableconditions.
(ii)Moisture,Oxygenandcarbondioxidepresentinair,allresponsible
forrusting.
ACKNOWLEDGEMENT