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Nama: _______________________________________________ Kelas: __________

PEPERIKSAAN PERTENGAHAN TAHUN

TAHUN 2016
TINGKATAN LIMA
CHEMISTRY
PAPER 2
Two hours and thirty minutes

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DO NOT OPEN THIS QUESTION PAPER UNTIL YOU ARE TOLD TO DO SO

This question paper consists of three sections: Section A,
For Examiners use only
Section B and Section C.
Sectio No Marka Markah
Answer all questions in Section A. Write your answers for
n
.
h
diperole
Section A in the spaces provided in the question paper.
penuh
hi
1
10
Answer one question from Section B and one question from
2
10
Section C. Answers questions in Section B and Section C in
A
3
10
detail. You may use equations, diagrams, tables, graphs and
4
10
other suitable methods to explain your answer.
5
10
Show your working. It may help you to get marks.
6
10
The diagrams in the questions are not drawn to scale unless
Total
stated.
B
7
20
Marks allocated for each question or part question are
8
20
shown in brackets.
Total
You may use a non-programmable scientific calculator.
C
9
20
Hand in your answer sheets at the end of the examination.
10
20
Total
Total marks

Disediakan oleh:

Disemak oleh:

Disahkan oleh:

Pn. Jumaiyah Salleh

En. Teoh Song Koon

En. Ho Nean Chan

Penolong Kanan
Pentadbiran

Ketua Panitia Kimia

This paper contains 25 printed pages

Section A
[60 marks]
[60 markah]
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Answer all questions

Jawab semua soalan
The time suggested to answer this section is 90 minutes.
Masa yang dicadangkan untuk menjawab bahagian ini ialah 90 minit

1. Diagram 1.1 shows part of the Periodic Table of the Elements. P, Q, R, S, T, U and V are not the actual sym
Rajah 1 menunjukkan sebahagian daripada Jadual Berkala Unsur. P, Q, R, S, T, U and V tidak mewakili si

P
Q
R

Using the letters in the Periodic Table of the Elements in Diagram 1.1, answer the following questions.
Dengan menggunakan huruf-huruf yang terdapat dalam Jadual Berkala Unsur pada Rajah 1.1, jawab soal
(a)

(i) Which element exists as a diatomic molecule?

Unsur yang manakah wujud sebagai molekul dwiatom?
....................
(ii) Which element forms coloured compound?
Unsur yang manakah membentuk sebatian berwarna?
..................

(b)

Elements P, Q and R are placed in the same group.

Unsur P, Q dan R terletak dalam kumpulan yang sama.
(i) Arrange the elements in descending order based on the reactivity towards oxygen.
Susun kereaktifan unsur terhadap oksigen dalam tertib menurun.
.....................

(ii) Write a balanced chemical equation when P reacts with oxygen.

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Tuliskan satu persamaan kimia apabila P bertindak balas dengan oksigen.

................

(c)

Diagram 1.2 shows an airship filled with helium gas.

Rajah 1.2 menunjukkan satu kapal udara yang diisi dengan gas helium.

Because helium is very light, helium is the gas of choice to fill airships.
Kerana helium sangat ringan, gas helium menjadi pilihan untuk mengisi
kapal udara.
Type of gas
Density (g/cm3)
Hydrogen
0.09
Helium
0.17

(i) Give justification why helium is more suitable to fill the airships compared to hydrogen.
Berikan justifikasi mengapa helium adalah lebih sesuai untuk mengisi kapal udara berbanding de
...................
..............
..........................

(ii) One of the characteristics of Group 18 gases is that they exist as monoatom. Explain why neon do
Salah satu ciri bagi kumpulan 18 adalah mereka wujud dalam monoatom. Jelaskan mengapa neo
.............
..........................
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2. Diagram 2.1 shows the relative atomic mass of silver atom is determined by comparing masses of silver ato
Rajah 2.1menunjukkan jisim atom relatif argentum ditentukan dengan membandingkan jisim atom argentu

(a)

Carbon-12 is assigned a mass of exactly 12 units. What is the mass of silver? Karbon-12 diberi jisim
......

(b)

(i) Silver reacts with oxygen gas to form silver oxide, Ag2O. Write a balanced chemical equation for t
Argentum bertindak balas dengan gas oksigen membentuk argentum oksida, Ag2O. Tuliskan persam

(ii) Calculate the volume of oxygen gas needed to produce 4.64 g silver oxide. [Molar mass Ag2O = 2
Hitung isipadu gas oksigen yang diperlukan untuk menghasilkan 4.64 g argentum oksida. [Jisim m

(c)

A compound consists of only C, H and O. When 1.0876 g of this compound burn completely in oxyge
Satu sebatian mengandungi C, H dan O sahaja. Apabila 1.0876 g sebatian ini terbakar sepenuhnya d
(i) Calculate the number of grams of C in the CO2 released.
Hitungkan jumlah grams of C in CO2 released.
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...............

(ii) Find the empirical formula of this compound.

Cari formula empirik untuk sebatian ini.

3.

(a) Diagram 3.1 shows the apparatus set up for the electrolysis of molten lead(II) bromide using car
Rajah 3.1 menunjukkan susunan radas bagi elektrolisis leburan plumbum(II) bromide menggunak

(i) What is meant by electrolysis?

Apakah yang dimaksudkan dengan elektrolisis?
...............
(ii) State the observation that occur at the anode.
Nyatakan pemerhatian yang berlaku dianod.
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..

(iii) Write the half equation at cathode.

Tuliskan persamaan setengah di katod.
................

(b)

Diagram 3.2 shows the apparatus set up for the electrolysis of silver nitrate solution using silver plat
Rajah 3.2 menunjukkan susunan radas bagi elektrolisis larutan argentum nitrat menggunakan keping

(i)

Write the formulae of all the ions present in the silver nitrate solution.
Tuliskan formula semua ion yang hadir dalam larutan argentum nitrat.
.................

(ii) State the ion selectively discharged at cathode. Give a reason to your answer. Nyatakan ion yang d
.........
.........
.........

(d)

A student investigated the electrolysis of copper (II) sulphate solution. The students method is show
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Seorang pelajar mengkaji elektrolisis bagi larutan kuprum(II) sulfat. Kaedah yang digunakan adala

(i) Explain why the electrode would dry faster when washed with propanone instead of water.
Jelaskan mengapa elektrod akan kering lebih cepat apabila di basuh dengan propanon berbandin
.............
The students results are given in the table 3.4.
Keputusan yang diperolehi oleh pelajar itu direkodkan dalam jadual 3.4.

Mass of electrode before electrolysis (g)

Jisim elektrod sebelum elektrolisis (g)
Mass of electrode after electrolysis (g)
Jisim elektrod selepas elektrolisis (g)

Positive electrode
Elektrod positif

Negative electrode
Elektrod negatif

16.41

15.46

16.10

15.75

The mass of the positive electrode decreased by 0.31g.

Jisim bagi elektrod positif berkurang sebanyak 0.31g.
(ii)What is the change in mass of the negative electrode?
Apakah perubahan jisim yang berlaku di elektrod negatif?
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(iii)The mass lost by the positive electrode should equal the mass gained by the negative electrode.
Jisim yang hilang di elektrod positif seharusnya sama dengan jisim yang bertambah di elektrod ne
Suggest two reasons why the results were not as expected.
Cadangkan 2 sebab mengapa keputusan yang diperolehi tidak seperti yang

diharapkan.

1..

2..

4.

A breath alcohol tester or alcometer is used to determine how much of alcohol is in a suspected drinkcolour depending on the alcohol content. The test is carried out 15 minutes after drinking an alcohol

The alcohol content of exhaled air accurately reflects the alcohol content of the blood.
When the amount of alcohol in the blood reaches 0.02 - 0.03%, the driver may feel a relaxing "high."
When that percentage reaches 0.05 - 0.10%, he will have reduced muscular coordination, a longer rea
A person with an alcohol level of 0.08% and above is considered legally intoxicated (drunk).

Alat penguji pernafasan alcohol atau alcometer digunakan untuk menentukan kandungan alcohol di d
kalium dikromat (VI), yang akan berubah warna bergantung kepada kandungan alcohol. Ujian dijala
Kandungan alkohol dalam hembusan nafas menggambarkan ketepatan kandungan alkohol di dalam
Sekiranya jumlah alkohol di dalam darah mencapai 0.02 0.03 , pemandu akan merasa khayal.
Sekiranya peratus mencapai 0.05 0.10%, pemandu akan mengalami kekurangan koordinasi otot.
Seseorang yang mencapai paras alkohol 0.08% dan keatas dianggap mabuk.
(a) Name the functional group of alcohol?
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(a( Namakan kumpulan berfungsi bagi alkohol?

) ......
(b) Draw the structural formula of ethanol.
Lukiskan formula struktur bagi etanol.

(c) (i) What is the colour change of potassium dichromate (VI) upon the presence of alcohol?
Apakah perubahan warna yang berlaku kepada larutan kalium dikromat (VI) dengan kehadiran alk
..........
(ii) Name the process occurs.
Namakan proses yang berlaku.
..............
(d)

Ethanol undergoes a process Q to produce substance X.

Etanol melalui proses Q dan menghasilkan sebatian X.
Uses of substance X

(i) Name the process Q and substance X.

Namakan proses Q dan sebatian X
..............

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(e)

Figure 2: Rubber tapping is a hard work.

Makcik Mina starts her daily routine as
Figure 1: The rubber trees plantation owned early as 4 a.m.
Rajah 2 : Menoreh getah adalah kerja
by Makcik Mina.
Rajah 1: Ladang getah milik Makcik Mina . keras. Makcik Mina bermula rutin
hariannya seawal pukul 4 pagi..

Figure 3: However, the tapping will

continue until late morning.
Rajah 3 : Walau bagaimanapun, menoreh
akan berterusan sehingga lewat pagi.

10

Figure 4: The latex flows into the cup

attached to the tree. By noon or early
afternoon, the latex will have stopped
flowing.
Rajah 4 : Susu getah yang mengalir ke
dalam cawan yang dilampirkan kepada
pokok itu. Menjelang tengah hari atau
awalpetang, susu getah berhenti mengalir.

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Figure 6:
The tins of latex will be carried to the
Figure 5: Makcik Mina will then go back to
factory.
each tree and empty the latex collected in
Rajah 6: Tin susu getah akan dibawa ke
the cups into the tin.
kilang.
Rajah 5 : Makcik Mina akan kembali ke
setiap pokok dan mengosongkan susu getah
yang dikumpul dalam cawan ke dalam tin
itu.

Figure 7: At the factory, the latex is poured

into moulds. At this process, a chemical
substance X is added into the liquid latex
to form a firm solid block of rubber.
Rajah 7 : Di kilang,susu getah dituang ke
dalam acuan . Pada proses ini, bahan
kimia X ditambah ke dalam susu getah cair
untuk membentuk blok pepejal getah.

Figure 8: The block of rubber is rolled by

the mangle machine to make into rubber
sheets. The finished rubber sheets are then
dry under the Sun.
Rajah 8 : Blok getah digulung
menggunakan mesin mangle untuk menjadi
kepingan getah. Lembaran getah siap
kemudian kering di bawah matahari.

Figure 9: The dry rubber sheets are sent to the factory for process Y to produce different
types of rubber products.
Rajah 9 : Lembaran getah kering dihantar ke kilang untuk proses Y untuk menghasilkan
pelbagai jenis produk getah.

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(i)A chemical substance X is added into the liquid latex as in Figure 7. Name the chemical substance
Bahan kimia X ditambah ke dalam susu getah cecair seperti dalam Rajah 7. Namakan bahan kimia
.........
(ii)Name the Process Y in Figure 9. Explain how this process is carried out in industry.
Namakan Proses Y dalam Rajah 9. Terangkan bagaimana proses ini dilakukan dalam industri .
.........
.........
(f)

State two differences in physical properties between natural rubber and the synthetic rubber.
Nyatakan dua perbezaan di dalam sifat-sifat fizikal antara getah asli dan getah sintetik.
......
......

5.

Three experiments, I, II and III are carried out to investigate the factors affecting the rate of reaction. Table
Tiga eksperimen, I, II dan III dijalankan untuk mengkaji faktor-faktor yang mempengaruhi kadar tindakba

(a)

State one suitable observable changes for measuring the rate of reaction.
Nyatakan satu perubahan yang sesuai diperhatikan untuk mengukur kadar tindakbalas.
......

(b)

Write an ionic equation for the reaction between magnesium and hydrochloric acid.
Tuliskan persamaan ion untuk tindakbalas antara magnesium dan asid hidroklorik.
.........

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(i) Compare the rate of reaction between Experiment I and Experiment II. Give
Bandingkan kadar tindakbalas antara Eksperimen I dan Eksperimen II.

a reason to your a

Berikan satu sebab kep

......
.......
......

(ii)Explain your answer in (c)(i) with reference to the collision theory.

Jelaskan jawapan anda di (c)(i)dengan merujuk kepada teori perlanggaran.
.........
.........
.........
.........
......

(d)

(i) The graph in Diagram 5.2 shows the curve obtained from Experiment II. Sketch the curve for exp
Graf dalam Rajah 5.2 menunjukkan lengkung yang diperolehi daripada Eksperimen II. Lakarkan len

Diagram 5.2 / Rajah 5.2

6

(a)

[2 marks / 2 markah]

Diagram 6.1 shows an industrial preparation of compound Y from the product of Contact Process a
Rajah 6.1 menunjukkan penyediaan sebatian Y secara industry daripada hasil Proses Sentuh dan Pr
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(i) State the name of compound X.

Nyatakan nama sebatian X.
.............
(ii)Write the formula of compound Y.
Tuliskan formula bagi sebatian Y.
.............
(iii) State the name of compound Y.
Nyatakan nama bagi sebatian Y.
................
(iv)What is the uses of compound Y?
Apakah kegunaan sebatian Y?
.......
(b)

Sulphuric acid is one of the raw materials to produce synthetic polymers. Synthetic polymers are diff
Asid sulfurik merupakan salah satu bahan mentah untuk menghasilkan polimer sintetik. Polimer sint
(i)Why it is not wise to dispose synthetic polymers by burning?
Mengapakah tidak wajar melupuskan polimer sintetik melalui pembakaran?
.................

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(ii)State one way to overcome the problem in (b)(i).

Nyatakan satu cara untuk mengatasi masalah di (b)(i).
..............

(c)

Diagram 6.2 shows two examples of manufactured substances in industry.

Jadual 6.2 menunjukkan dua contoh bahan buatan dalam industry.

(i)What is the type of glass used to make glass lid of the pot?
Apakah jenis kaca yang digunakan untuk membuat penutup kaca periuk itu?
......

(ii)The glove is made of polychloroethene. What are the structural formula and name of the monomer
Sarung tangan itu diperbuat dari polikloroetene. Apakah formula struktur dan nama bagi monomer

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Section B
[20 marks]
[20 markah]
Answer any one question from this section.
Jawab mana-mana satu soalan dalam bahagian ini.
The time suggested to answer this section is 30 minutes.
Masa yang dicadangkan untuk menjawab bahagian ini ialah 30 minit.

7.

Diagram 7.1/ Rajah 7.1

(a) (i)While in the midst of baking a cake, Suzy realised that she has placed the unlabelled
packet of sugar powder and salt powder on the same rack as shown in Diagram 1.
Without tasting, explain how you would help Suzy to differentiate the salt and sugar
powder by ONLY using the utensils found in the kitchen.
Semasa sedang membuat kek, Suzy telah menyedari dia telah meletakkkan
bungkusan gula halus dan garam halus yang tidak berlabel pada rak yang sama
seperti dalam Rajah 1. Tanpa merasa, jelaskan bagaimana anda menolong Suzy
untuk membezakan kedua-dua bungkusan tersebut dengan HANYA menggunakan
alatan yang terdapat di dapur.
[3 marks / 3 markah]
(ii) What is the type of bond present in table salt.
Apakah jenis ikatan yang terdapat pada garam .
(b
)

[1 mark / 1 markah]

Diagram 7.2 shows the atomic structure of aluminium, Al atom and oxygen, O atom.
Rajah 7.2 menunjukkan struktur atom bagi atom aluminium, Al dan oksigen, O.

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Diagram 7.2 / Rajah 7.2

Write the electron arrangements of the aluminium ion and oxide ion.
Tuliskan susunan electron bagi ion aluminium dan ion oksida.
[2 marks / 2 markah]
(c) Diagram 7.3 shows representative on three chemical elements: chlorine. Cl;
magnesium, Mg and carbon, C.
Rajah 7.3 menunjukkan perwakilan 3 unsur : klorin, Cl; magnesium, Mg dan karbon,
C.

Diagram 7.3 / Rajah 7.3

(i) Describe the formation of the following chemical bonds and draw the electron
arrangements of the compounds formed.
Huraikan pembentukan bagi ikatan kimia berikut dan lukis susunan electron bagi
sebatian yang terbentuk.
(ii) Ionic bond / ikatan ion
(iii)Covalent bond / ikatan kovalen

[5 marks / 5 markah]
[5 marks / 5 markah]

(iii) Explain why the compound formed in c(i) has high melting and boiling points
compared to compound formed in c(ii).
Terangkan mengapa sebatian yang terhasil di c(i) mempunyai takat lebur dan
takat didih yang tinggi berbanding sebatian yang terhasil di sebatian c(ii).
[4 marks / 4 markah]
8.

Diagram 8 shows a series of reaction starting from solid salt R.

Rajah 8 menunjukkan satu siri tindakbalas bermula dengan pepejal garam R.

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Based on Diagram 8:
Berdasarkan Rajah8
(a) Identify salt R, gas S, gas T, solution U, solid W and solution X.
Kenal pasti garam R, gas S, gas T, larutan U, pepejal W dan larutan X.
[6 marks / 6 markah ]
(b
)

State the type of Reaction I and write the chemical equation for the reaction between
solution U and sodium carbonate, Na2CO3 solution.
Nyatakan jenis Tindakbalas I dan tuliskan persamaan kimia bagi tindakbalas antara
larutan U dan larutan natrium karbonat, Na2CO3.
[3 marks / 3 markah ]

(c) A student heat strongly 5.43 g solid W. Solid W decomposed to produce a colourless
gas and a solid which is brown when hot and yellow when cool.
Seorang pelajar memanaskan dengan kuat 5.43 g pepejal W.Pepejal W terurai
menghasilkan gas tanpa warna dan suatu pepejal yang perang apabila panas dan
kuning apabila sejuk.
(i)

Write the chemical equation for the decomposition of solid W and state the
name of the products.
Tuliskan persamaan kimia bagi penguraian pepejal W dan nyatakan nama
hasil tindakbalas itu.
[4 marks / 4 markah ]

(ii)

Calculate the volume of the colourless gas produced in (c) at room

condition. [Molar mass solid W = 267 gmol-1; 1 mole of gas occupies 24
dm3at room condition]
Hitung isi padu gas tanpa warna yang di hasilkan di (c)pada keadaan bilik.
[Jisim molar pepejal W = 267 gmol-1; 1 mol gas menempati 24 dm3 pada
keadaan bilik]
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[3 marks / 3 markah ]
(d
)

What are the differences between solid salt R and solid W?

Apakah perbezaan antara pepejal garam R dan pepejal W?
[4 marks / 4 markah ]

Section C
[20 marks]
[20 markah]
Answer any one question from this section
Jawab mana-mana satu soalan dalam bahagian ini
The time suggested to complete Section C is 30 minutes
Masa yang dicadangkan untuk menjawab Bahagian C ialah 30 minit
9.

Table 9 shows the ionisation and the colour of phenolphthalein in solution P, Q and R.
Jadual 9 menunjukkan pengionan dan warna larutan fenolftalein dalam larutan P, Q
danR.
1.1 moldm-3 of
solution
Larutan 0.1
mol dm-3
P

Ionisation
Pengionan

Colour of phenolphthalein in the

solution
Warna fenolftalein dalam larutan itu

Ionises completely
Mengion lengkap

(a)

Colourless
Tanpa warna

Ionises partially
Colourless
Mengion separa
Tanpa warna
R
Ionises completely
Pink
Mengion lengkap
Merah jambu
Table 9 / Jadual 9
Suggest the name of solutions P, Q and R.
Cadangkan nama bagi larutan P, Q dan R.
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[3 marks / 3 markah]
(b)

Which solution has the lowest pH value? Explain your answer.

Larutan manakah mempunyai nilai pH paling rendah? Terangkan jawapan
anda.
[5 marks / 5 markah]

(c)

Based on your answer in (a), identify the anion in solution P. Describe a

chemical test to verify the anion in solution P.
Berdasarkan jawapan anda di (a), kenalpasti anion dalam larutan P. Huraikan
satu ujian kimia untuk menentusah anion dalam larutanP.
[5 marks / 5 markah]

(d)

By using 0.1 mol dm-3 solution R in Table 9, describe an experiment to prepare

250 cm3 of 0.02mol dm-3 of standard solution R. In your answer include the
apparatus used and the volume of solution R needed.
Dengan menggunakan larutan R 0.1 mol dm-3 dalam Jadual 9, huraikan satu
eksperimen untuk menyediakan 250 cm3 larutan R 0.02 mol dm3. Dalam
jawapan anda sertakan alatradas yang digunakan dan isipadu larutan R yang
diperlukan.
[7 marks / 7 markah]

10.

Ester can exist naturally and can be prepared artificially in the laboratory. Ester
is formed when a carboxylic acid reacts with an alcohol according to the
equation below.
Ester boleh wujud secara semulaja dan boleh disediakan dalam makmal. Ester
terbentuk apabila asid karboksilik bertindak balas dengan alkohol mengikut
persamaan berikut.
Alcohol + carboxylic acid ester + water
Alkohol + asid karboksilik ester +air
Esters are widely used as fragrances and food flavourings. The table below
shows some examples of artificial fruit flavourings.
Ester digunakan secara meluas sebagai pewangi dan perisa makanan. Jadual
berikut menunjukkan beberapa contoh perisa buah-buahan buatan manusia.

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(a)

(b)

Ester / ester

Odour / bau

Pentyl ethanoate /pentil etanoat

Banana / pisang

Ethyl butanoate / etil butanoat

Pineapple / nanas

Octyl ethanoate / oktil etanoat

Orange / oren

Pentyl butanoate / pentil butanoat

Apricot / aprikot

Name the process that produces ester.

Namakan proses untuk menghasilkan ester.

[1 mark /1 markah]

State and draw the functional group of ester.

Nyatakan dan lukiskan kumpulan berfungsi bagi ester.

[2 marks /2 markah]

(c)

Is ester a hydrocarbon? Explain your answer.

Adakan ester sejenis hidrokarbon? Jelaskan jawapan anda. [2 marks /2 markah]

(d)

Elise wants to make an apricot flavoured perfume for her friend as a birthday
present.
Elise hendak membuat minyak wangi berbau aprikot sebagai hadiah hari jadi
untuk kawannya.
(i) As a chemistry student, choose a suitable alcohol and a carboxylic acid
needed by her to produce artificial apricot fragrance.
Sebagai seorang pelajar kimia, pilih satu jenis alkohol dan satu jenis asid
karboksilik yang diperlukan oleh Elise untuk menghasilkan minyak wangi
berbau aprikot.
[2 marks / 2
markah]
(ii) Write a chemical equation for the reaction in d)i).
Tuliskan satu persamaan kimia bagi tindak balas dalam d)i).
[2 marks /2 markah]
(iii) Calculate the relative molecular mass of pentyl butanoate.
[Relative atomic mass: H, 1; C, 12; O, 16]
Hitungkan jisim molekul relatif bagi pentil butanoat.
[Jisim atom relatif: H, 1; C, 12; O, 16]
[1 mark /1 markah]
(iv)Describe briefly and include a labeled diagram to show how she can prepare
an artificial apricot fragrance in the laboratory.
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Huraikan secara ringkas dan sertakan gambarajah yang berlabel untuk

menunjukkan bagaimana Elise dapat menyediakan minyak wangi berbau
aprikot dalam makmal.
[6 marks / 6
markah]
(b)

Suggest two precautions that must be taken to ensure maximum production of

ester. Explain your answers.
Cadangkan dua langkah berjaga-jaga yang mesti dilaksanakan untuk menjamin
hasil ester yang maksima. Jelaskan jawapan anda.
[4 marks /4
markah]
END OF QUESTION PAPER
KERTAS SOALAN TAMAT

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4541/2

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