Functional Chemicals Division: Product Information

fuenfwerken.com | EBR 5276 | 09.
2008
Clariant International Ltd.

Functional Chemicals Division
Marketing Metal Working
4132 Muttenz
Switzerland
Phone +41 61 46 978 11
Fax
+41 61 46 975 512
Clariant Produkte (Deutschland) GmbH
Research & Development Metal Working
65926 Frankfurt am Main
Germany
Phone +49 69 305 66 07
Fax
+49 69 303 299
Internet
http://www.clariant.com

Products for Metal Working Fluids
Product Information Update Summer 2008
Product Information
Update Spring 2008
Products for Metal Working Fluids
12 Glossary
Content

>
Page
Product names in alphabetical order
>
04
Introduction
Products at a glance
>
06
> 08 21
1

1.1
1.1.1
1.1.2

1.1.3

1.1.4
1.2
Anionic emulsifiers / Corrosion inhibitors

for soluble oils and semisynthetics
Alkenyl succinic acid derivatives
Alkenyl succinic acid anhydrides
Alkenyl succinic acid halfamides,
imidocaproic acids, halfesters
Alkenyl succinic acid derivative
packages
Packages / Others
Ether carboxylates
2
2.1
2.1.1
2.1.2
2.1.3
2.1.4
2.2
Nonionic emulsifiers
Nonionics
Nonylphenol oxethylates
Tristyrylphenol oxethylates
Fatty alcohol oxethylates
Fatty acid oxethylates
Fatty acid esters
>
31
>
32
>
32
>
32
> 32 35
>
36
>
36
3
3.1
3.2
Fatty acid alkanol amides

Fatty acid diethanolamides
Fatty acid alkanolamides / DEA free
>
>
>
>
>
>
23
24
24
>
24
>
>
>
26
26
28
39
40
40
Package
Abbreviations
A package is a stable pre-formulation

of different emulsifiers, corrosion inhibitors
and EP / AW additives if needed.
In combination with suitable mineral oils,
packages can be easily applied by enduser to formulate concentrates and / or
emulsions using a co-emulsifier for
adjustment.
MEA
DEA
TEA
EO
PO
APEO
TBN
m.p.
m.r.
HLB
Storage time
The standard storage time for the products
listed in this brochure is in general two
years. If special storage conditions are
necessary it is mentioned in the column
Remarks.
Monoethanolamine
Diethanolamine
Triethanolamine
Ethylene oxide
Propylene oxide
Alkylphenol ethoxylate
Total base number
melting point
melting range
Hydrophilic-lipophilic-balance
DEA-content
This remark refers to the column
DEA-content. The DEA content is given,
when DEA is used as a neutralizing or
reaction agent. If nothing mentioned there,
the product contains no DEA at all or other
neutralizing agents (e.g. MEA, TEA, alkali)
are used.
APEO-content
In general all products mentioned in
the brochure are free of alkylphenol
ethoxylates. Exceptions are marked in
the column Remarks with a notice:
APEO-containing.
Lime soap dispersing power, K-value

The lime soap dispersing power of some
products is listed as K-value (according to
the withdrawn DIN-method 53 903).
The K-value is a degree for the amount
of Ca-oleate which is dispersed by 1g of
resp. emulsifier. The higher the K-value, the
higher the lime soap dispersing power.
> 79
> Page
4

4.1
4.2
Water soluble corrosion inhibitors

and lubricants
Water soluble lubricants
>
43
> 44 47
>
46
Oil soluble corrosion inhibitors
> 49 51
6
6.1
6.2
6.3

Lubricants and EP-Additives

>
53
Esters
>
54
Phosphoric acid esters
> 56 59
Polyalkylene / Polyethylene glycols
see chapter 11 Brochures / Other ranges >
78
7
7.1
7.2
7.3

Cleaners
>
Fatty alcohol oxalkylates
>
Corrosion inhibitors / Specialities
>
Solvents
>
see chapter 11 Brochures / Other ranges >
Defoamers
> 67 69
Biocides
> 71 73
10
1 0.1
10.2
Others
Dewatering fluids
Amines
>
>
>
> Page
1 1
11.1

11.2
11.3
11.4
11.5
Brochures / Other ranges

Raw Materials for the
Chemo-Technical Industry
Fatty Amines and Derivatives
Glymes / glycol diethers
Polyalkylene / Polyethylene glycols
Hordaphos (phosphoric acid esters)
>
78
>
>
>
>
>
78
78
78
78
78
12
Glossary
>
79
61
62
64
64
78
75
76
76
This information is based on our present state of knowledge and is intended

to provide general notes on our products and their uses. It should not therefore
be construed as guaranteeing specific properties of the products described on
their suitability for a particular application. Any existing industrial property
rights must be observed. The quality of our products is guaranteed under our
General Conditions of Sale.
> 03
Product names in alphabetical order
Aicrobat N
Antimussol 3472 N
Antimussol 4459 liq.
Antimussol FN
Antimussol TIP
Antimussol ZJ
Appretan Defoamer 5084 liq.
Arkomon SO
Arkopal N 040
Arkopal N 060
Arkopal N 090
> Page E
> 74
Emulsogen CTS 160
> 68
Emulsogen EL 360
> 68
Emulsogen ELO 200
> 68
Emulsogen ENF
> 68
Emulsogen LP
> 68
Emulsogen M
> 68
Emulsogen MS 12
> 68
Emulsogen MT 050
> 68
Emulsogen OG
> 52
Emulsogen P
> 32
Emulsogen T
> 32
Emulsogen TS 100
> 32
Emulsogen TS 160
Dodicor 2565
Dodicor 2725 NF
Dodigen 95
Dispersogen SP 040
>
>
>
>
64
64
64
56
Emulsogen 3971
Emulsogen 3980
Emulsogen 4616
Emulsogen 4617
Emulsogen 5126 MW
Emulsogen 5690
Emulsogen A
Emulsogen A 060
Emulsogen CIO 050
Emulsogen CNH 030
Emulsogen CNO 080
Emulsogen COA 070
Emulsogen COL 020
Emulsogen COL 050
Emulsogen COL 080
Emulsogen COL 100
Emulsogen CTS 100
>
>
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26
26
28
28
24
24
36
36
28
28
28
28
28
28
28
28
28
>
Genagen IS 140
Genagen O 100
Genamin 3920
Genamin 8 R 100 D
Genamin CH 020
Genamin NO 050
Genamin SH 100 D P
Genapol B
Genapol BA 040
Genapol EP 0244
Genapol EP 2424
Genapol EP 2464
Genapol EP 2544
Genapol EP 2552
Genapol EP 2564
Genapol EP 2584
Genapol O 020
Genapol O 050
Genapol PN 30
Genapol PS
Genapol RX 065
> Page
> 28
> 36
> 36
> 76
> 34
> 34
> 34
> 40
> 36
> 34
> 26
> 32
> 32
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36
36
76
76
76
76
76
46
62
62
62
62
62
62
62
62
32
32
46
46
34
H
Hicor BAT
Hicor C
Hordaphos 124
Hordaphos 125
Hordaphos 145
Hordaphos 222
Hordaphos DEOD
Hordaphos MDAH
Hordaphos MDB
Hordaphos MDGB
Hordaphos MDHX
Hordaphos MDIT
Hordaphos MDO
Hostacor 1102
Hostacor 2732
Hostacor 3928
Hostacor 3981
Hostacor 4053
Hostacor 4053 SEO
Hostacor 4154
Hostacor 4221
Hostacor 4222
Hostacor 4323
Hostacor 4359
Hostacor B
Hostacor BI
Hostacor BIT
Hostacor DT
Hostacor IS
Hostacor IT
Hostacor L
Hostacor MT
Hostacor MTF
Hostacor PSO 300
Hostacor V 4188
Hostagliss A
> Page H
> 40
Hostagliss DHSZ
> 40
Hostagliss FN
> 56
Hostagliss H
> 56
Hostagliss L4
> 56
Hostagliss PA 135
> 56
Hostagliss PA 165
> 56
Hostaphat OPS 100
> 56
Hostaphat OPS 80 P
> 56
Hostaphat TBEP
> 58 N
> 58
Nipacide BIT 20
> 58
Nipacide CI
> 58
Nipacide FC
> 46
Nipacide HTP/2
> 44
Nipacide IPBC 20
> 24
Nipacide IPBC 30
> 24
Nipacide MBM
> 44
Nipaclean 3
> 44 S
> 26
Sodium Omadine 40%
> 24
> 26
> 24
> 26
> 44
> 46
> 46
> 40
> 44
> 44
> 24
> 40
> 40
> 50
> 40
> 54
> Page
> 54
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72
72
72
72
72
72
72
>
72
> 05
2
Introduction
Clariant is one of the worlds leading manufacturers of surfactants and auxiliaries.

Clariant is a global leader in the field of speciality chemicals. The Functional Chemicals Division
serves a wide range of industries e.g. Personal Care, Coating and Construction, Detergents and
Oil, Gas and the Mining industry. For Metal Working Clariant supplies:
< corrosion inhibitors
< emulsifiers
< lubricants
< cleaners
< defoamers
< dewatering fluids
< biocides
< ep / aw- additives
The base materials for these surfactants and raw materials are from both renewable and
petrochemical sources. What is common to all products is their high quality standard, which
is achieved through intensive research and development, modern production methods with
constant quality monitoring and customer-oriented applications technology, and this standard
is continuously improved.
Over and above the product range, we offer assistance to find specific solutions to solve
problems, either through advice or through related development work in the laboratory.
Biocides
For EEC (Europe):
Based on our information (status April 2008) all mentioned biocides are in compliance with the
BPD 98/8/EC and amendments/corrections. This information is based on the current situation and
Clariant reserves the right to modify the support if the data requirements change or the market
position alters.
See also: http://ecb.jrc.it/biocides/
For Germany:
Biozide sicher verwenden. Vor Gebrauch stets Kennzeichnung und Produktinformation lesen.
Antimussol, Appretan Defoamer, Arkomon, Arkopal, Dispersogen, Dodicor,

Dodigen, Emulsogen, Genagen, Genamin, Genapol, Genopur, Hordaphos,
Hostacor, Hostagliss, Hostaphat and Nipacide are registered trademarks in
numerous countries and licensed to Clariant.
Detergent Regulation EC 648/2004 and EC 907/2006
According to the Detergent Regulation Surfactants used in detergents (cleaners etc.) have to
show an ultimate biodegradation above given minimum limits according to EC648/2004. The determination methods, minimum ultimate biodegradation limits and test report quality requirements are
provided by the regulation. Producers state the compliance with the EU Detergent Regulation with
phrases in the EU safety data sheet (EU-SDS) Chapter 12 or 15.
Products with a compliance phrase in the EU-SDS show in the column remarks the abbreviation:
"DR +".
See also: http://eur-lex.europa.eu/LexUriServ/site/en/oj/2004/l_104/l_10420040408en00010035.pdf
Nonylphenol / Nonylphenol ethoxylate Directive 2003/53/EC

In general all products mentioned in the brochure are free of alkylphenols and alkylphenol ethoxylates (esp. nonylphenols and nonylphenol ethoxylates). Exceptions are marked in the column
"Remark" with notice: "APEO-containing" and are use restricted according to Directive 2003/53/EC
effective from 17 January 2005.
See also: http://eur-lex.europa.eu/pri/en/oj/dat/2003/l_178/l_17820030717en00240027.pdf
REACH
According to Regulation (EC) No. 1907/2006 (REACH), the manufacture or import of chemical
substances in volumes exceeding 1 ton per year must be registered at the European Chemicals
Agency (ECHA) in Helsinki. REACH registration is related to substances and not products, e.g.
preparations/formulations of substances. Production, import and marketing of a REACH-substance
will be restricted to those uses evaluated in its registration dossier.
The REACH process starts with preregistration (1st June 2008 until 1st December 2008), which
assures the availability of preregistered substances to the registration date. The date of registration
depends on the production volume of the substance and lies between 2010 and 2018.
We confirm that we will pre-register all substances manufactured by Clariant Division FUN in the
EU or imported in the EU, which are relevant for the products listed in this brochure. However,
no promise can be given that Clariant will offer all listed products over the 11 year phase of the
REACH implementation. If REACH registration requires unacceptable costs, Clariant will contact its
customers to find an appropriate solution.
New Products
> Page
< Antimussol 3472 N
>
68
< Genagen IS 140
>
36
< Hostagliss L4
>
54
< Appretan Defoamer 5084 liq.
>
68
< Genapol BA 040
>
62
< Nipaclean 3
>
72
< Appretan Defoamer 5342 liq.
>
68
< Genapol RX 065
>
34
< Nipacide BK
>
72
< Emulsogen 5690
>
24
< Hordaphos DEOD
>
56
< Nipacide HPT/2
>
72
< Genamin NO 050
>
76
< Hostaphat TBEP
>
56
< Sodium Omadine 40%
>
72
> Page
> Page
Changed products (from Update Winter 2004/2005)

< Aicamide N deleted
< Aicamide 2067 deleted
< Emulsogen SBL deleted
< Hostacor V 5233 deleted
< Emulsogen TS 050 deleted
< Hostacor 5428 deleted
< Aicamide 2131/B deleted

< Aicrobat N deleted and replaced
< Genamin 4048 deleted
< Hostacor GLA 1 deleted
< Genamin 5577 deleted
< Hostacor IPT deleted
by Nipacide BK
< Antimussol 3472 deleted and replaced
< Genamin 18 R 100 D deleted
< Hostacor IC deleted
< Genamin SH 100 D FLA modified and
< Hostagliss 1090 deleted
by Antimussol 3472 N
< Antimussol 4846 deleted and replaced by
renamed Genamin SH 100 D P (Pellets)

< Genapol 2822 renamed to Genapol EP 0244
< Hostagliss D deleted
Appretan Defoamer 5342

< Emulsogen 5171 deleted
< Hordaphos 123 deleted
< Hordaphos 185 renamed to
< Emulsogen AL deleted

< Emulsogen COL 090 deleted, recommended
< Genapol 3938 renamed Genapol EP 2464

Dispersogen SP 040
< Hordaphos AW 100 deleted
alternative Emulsogen COL 080 or COL 100

< Emulsogen E deleted and replaced
< Genapol EP 2454 deleted
< Hordaphos EP 300 deleted
< Genapol OA 020 deleted
< Hostamer AM deleted
by Emulsogen ENF
< Emulsogen MR deleted
< Genapol GX 030 deleted
< Nipacide HTP/3 replaced by Nipicide HTP/2
< Genapol X 020 deleted
< Nipacide SP replaced by
< Emulsogen PN extra deleted
< Genopurl ASA deleted
< Emulsogen PSP 123 deleted
< Highsorb GD deleted
Sodium Omadine 40%

< Nipaclean 2 replaced by Nipaclean 3
< Emulsogen SFO deleted
< Highsorb GF deleted
< Hostagliss DHV deleted
> 07

1.1
Alkenyl succinic acid derivatives
Function
Emulsifier
DEA-free
Corrosion
inhibitor
Lubricant
Boron-free
> Page
Applications
Neat
cutting oils
Cutting Fluids
milky
semisynthetic synthetic
Corrosion
Metal
protection oils cleaners
Dewatering
fluids
1.1.1 Alkenyl succinic acid anhydrides

Hostacor L
>
24
Emulsogen 5126 MW
>
24
Emulsogen 5690
>
24
Hostacor 3928
>
24
Hostacor 3981
>
24
Hostacor 4221
>
24
Hostacor 4323
>
24
Hostacor 4222
>
26
Emulsogen 3971
>
26
Emulsogen 3980
>
26
Hostacor 4154
>
26
Hostacor 4359
>
26
>
26
1.1.2 Alkenyl succinic acid halfamides,

1.1.3 Alkenyl succinic acid derivative

packages
1.1.4 Packages / Others

Emulsogen T
most suitable
> 08
suitable
> 09

1.2
Ether carboxylates
Function
Emulsifier
DEA-free
Corrosion
inhibitor
Lubricant
Boron-free
> Page
Applications
Neat
cutting oils
Cutting Fluids
milky
Corrosion
Metal
Dewatering
fluids
Emulsogen CIO 050
>
28
Emulsogen CNH 030
>
28
Emulsogen CNO 080
>
28
Emulsogen COA 070
>
28
Emulsogen COL 020
>
28
Emulsogen COL 050
>
28
Emulsogen COL 080
>
28
Emulsogen COL 100
>
28
Emulsogen CTS 100
>
28
Emulsogen CTS 160
>
28
Emulsogen 4616
>
28
Emulsogen 4617
>
28
Arkopal N 040
>
32
Arkopal N 060
>
32
Arkopal N 090
>
32
Emulsogen TS 100
>
32
Emulsogen TS 160
>
32
Genapol O 020
>
32
Genapol O 050
>
32
2.1
Nonionics
2.1.1 Nonylphenol oxethylates
2.1.2 Tristyrylphenol oxethylates
2.1.3 Fatty alcohol oxethylates
> 10
most suitable
suitable
> 11
2.1
Nonionics
Function
Emulsifier
DEA-free
Corrosion
inhibitor
Lubricant
Boron-free
> Page
Applications
Neat
cutting oils
Cutting Fluids
milky
Corrosion
Metal
Dewatering
fluids

Emulsogen M
>
34
Emulsogen LP
>
34
Emulsogen MS 12
>
34
Emulsogen P
>
34
Genapol RX 065
>
34
Emulsogen A
>
36
Emulsogen A 060
>
36
Genagen IS 140
>
36
Genagen O 100
>
36
Emulsogen EL 360
>
36
Emulsogen ELO 200
>
36
>
36
Hostacor DT
>
40
Hicor BAT
>
40
Hicor C
>
40
Hostacor V 4188
>
40
Hostacor MT
>
40
Hostacor MTF
>
40
Emulsogen MT 050
>
40
2.1.4 Fatty acid oxethylates
2.2
Fatty acid esters

Emulsogen OG
Fatty acid alkanolamides
3.1
3.2
> 12
Fatty acid alkanolamides / DEA free
most suitable
suitable
> 13

and lubricants
Function
Emulsifier
DEA-free
Corrosion
inhibitor
Lubricant
Boron-free
> Page
Applications
Neat
cutting oils
Cutting Fluids
milky
Corrosion
Metal
Dewatering
fluids
4.1 Water soluble corrosion inhibitors

Hostacor B
>
44
Hostacor 4053
>
44
Hostacor 4053 SEO
>
44
Hostacor IS
>
44
Hostacor 2732
>
44
Hostacor IT
>
44
Hostacor BI
>
46
Hostacor BIT
>
46
Hostacor 1102
>
46
Genapol B
>
46
Genapol PN 30
>
46
Genapol PS
>
46
Arkomon SO
>
50
Hostacor PSO 300
>
50
4.2 Water soluble lubricants
most suitable
> 14
suitable
> 15
Function
Emulsifier
DEA-free
Corrosion
inhibitor
Lubricant
Boron-free
> Page
Applications
Neat
cutting oils
Cutting Fluids
milky
Corrosion
Metal
Dewatering
fluids
6.1 Esters
Hostagliss FN
>
54
Hostagliss H
>
54
Hostagliss L4
>
54
Hostagliss A
>
54
Hostagliss DHSZ
>
54
Hostagliss PA 135
>
54
Hostagliss PA 165
>
54
Dispersogen SP 040
>
56
Hordaphos 124
>
56
Hordaphos 125
>
56
Hordaphos 145
>
56
Hordaphos 222
>
56
Hordaphos DEOD
>
56
Hordaphos MDAH
>
56
Hordaphos MDB
>
56
Hordaphos MDGB
>
58
Hordaphos MDHX
>
58
Hordaphos MDIT
>
58
Hordaphos MDO
>
58
Hostaphat TBEP
>
58
>
78
6.2 Phosphoric acid esters
6.3 Polyalkylene glycols / Polyethylene glycols

see chapter 11
most suitable
> 16
suitable
> 17
Cleaners
Function
Emulsifier
DEA-free
Corrosion
inhibitor
Lubricant
Boron-free
> Page
Applications
Neat
cutting oils
Cutting Fluids
milky
Corrosion
Metal
Dewatering
fluids
7.1 Fatty alcohol oxalkylates

Genapol EP 0244
>
62
Genapol EP 2424
>
62
Genapol EP 2464
>
62
Genapol EP 2552
>
62
Genapol EP 2544
>
62
Genapol EP 2564
>
62
Genapol EP 2584
>
62
Genapol BA 040
>
62
Dodigen 95
>
64
Dodicor 2565
>
64
Dodicor 2725 NF
>
64
Hostaphat OPS 100
>
64
Hostaphat OPS 80 P
>
64
>
78
>
68
Antimussol 3472 N
>
68
>
68
>
68
Antimussol FN
>
68
Antimussol TIP
>
68
Antimussol ZJ
>
68
>
68
>
68
7.2 Corrosion inhibitors / Specialities
7.3 Solvents

see chapter 11 Brochures / Other Ranges
Defoamers
most suitable
> 18
suitable
> 19
10
Biocides
Function
Emulsifier
DEA-free
Corrosion
inhibitor
Lubricant
Boron-free
> Page
Applications
Neat
cutting oils
Cutting Fluids
milky
Corrosion
Metal
Dewatering
fluids
Nipacide BK
>
72
Nipacide BIT 20
>
72
Nipacide CI
>
72
Nipacide FC
>
72
Nipacide HTP/2
>
72
Nipacide IPBC 20/IPBC 30
>
72
Nipacide MBM
>
72
Nipaclean 3
>
72
Sodium Omadine 40%
>
72
Emulsogen ENF
>
76
Genamin 8 R 100 D
>
76
Genamin SH 100 D P
>
76
Genamin 3920
>
76
Genamin NO 050
>
76
Genamin CH 020
>
76
Others
10.1 Dewatering fluids
10.2 Amines
most suitable
> 20
suitable
> 21
1 Anionic emulsifiers / Corrosion inhibitors


> Page
1.1 Alkenyl succinic acid derivatives
>
24

Hostacor L
Emulsogen 5126 MW
Emulsogen 5690
>
>
>
>
24
24
24
24

Hostacor 3928
Hostacor 3981
Hostacor 4221
Hostacor 4323
>
>
>
>
>
24
24
24
24
24
1.1.3 Alkenyl succinic acid derivatives

packages
Hostacor 4222
Emulsogen 3971
Emulsogen 3980
Hostacor 4154
Hostacor 4359
>
>
>
>
>
>
26
26
26
26
26
26
> Page

Emulsogen T
>
>
26
26
1.2 Ether carboxylates

Emulsogen CIO 050
Emulsogen CNH 030
Emulsogen CNO 080
Emulsogen COA 070
Emulsogen COL 020
Emulsogen COL 050
Emulsogen COL 080
Emulsogen COL 100
Emulsogen CTS 100
Emulsogen CTS 160
Emulsogen 4616
Emulsogen 4617
>
>
>
>
>
>
>
>
>
>
>
>
>
28
28
28
28
28
28
28
28
28
28
28
28
28
> 23
Appearance
Lubricant
Corrosion
inhibitor

Function
Emulsifier
Chemical description /
Ionicity
DEAcontent
(%)
pH (1%)
in water
Applications / Properties
General aspects
Special remarks
Hostacor L, Emulsogen 5126 MW and Emulsogen

5690 are soluble in mineral oils and insoluble in
water. They have to be converted to the corresponding alkali and / or amine / alkanolamine salts
by hydrolysis when used in water based metal
working fluids.
In this form they are stabilizing emulsions and are
used as hydrotropes (coupling agents). Contrary
to Emulsogen 5126 and Emulsogen 5690, Hostacor
L has pronounced wetting properties but is not
stable against water hardness.
Hostacor L shows good corrosion protection as

alkali and / or alkanolamine salt. Hostacor L may
become turbid after prolonged storage. The product gets clear again after homogenizing at 70C.

Hostacor L
Alkenyl succinic acid anhydride /

nonionic, anionic as salt
brown,
clear to turbid,
viscous liquid
Emulsogen 5126 MW

pale brown,
viscous liquid
Emulsogen 5690

brown, viscous
liquid
Hostacor 3928
Na / TEA mix salt of an alkenyl

succinic acid half amide / anionic
dark brown,
clear,
viscous liquid
8.2 9.2
Hostacor 3928 is used as emulsifier with corrosion

protecting properties for milky / transparent
metalworking fluids. The product is clearly soluble
in water, dispersible in mineral oils and compatible
with non / anionic products. Mineral oil based
formulations show no gelation tendency, form
spontaneously emulsions and are stable in hard
water.
Storage stability is max. 1 year.

Storage temperature should be below 30C.
Hostacor 3981
Alkenyl succinic imido carboxylic

acid / anionic as salt
dark brown,
clear,
viscous liquid
Hostacor 3981 is insoluble in water and slightly

turbid dispersible in mineral oil. Product should be
stored in a cool place.
Hostacor 4221
Alkenyl succinic imido carboxylic

acid / anionic as salt
brownish,
clear,
viscous liquid
Hostacor 3981 and 4221 are used as emulsifiers

with corrosion protecting properties for milky /
transparent metalworking fluids.
The free acids must be neutralized to the alkali
and / or alkanolamine salts. Mineral oil based
water. Both products are compatible with other
non / anionic additives. Hostacor 4221 is suitable
for formulations with low pH values (approx. 8).
Hostacor 4323
Alkenyl succinic acid half ester /

anionic as salt
light brown,
clear,
viscous liquid
Hostacor 4323 is used as emulsifier with corrosion

protecting properties for milky amine and nitrogen
free metalworking fluids. The product is insoluble
in water and soluble in mineral oil. Mineral oil
based formulations show no gelation tendency,
form spontaneously emulsions and are stable in
hard water. The product is compatible with other
non / anionic additives.
During the neutralization, for instance with 50%

aqueous KOH, temperatures above 60C and a
local excess of alkali should be avoided. Storage
temperature should be below 30C.
Emulsogen 5126 MW is solubilized in mineral oil

due to its high viscosity (high molecular weight).
Emulsogen 5690 is solubilised in a synthetic ester
due to its high viscosity (high molecular weight)

> 24
Hostacor 4221 is insoluble in water and clearly

soluble in mineral oil.
> 25
Appearance
Lubricant
Corrosion
inhibitor

Function
Emulsifier
Ionicity
DEAcontent
(%)
pH (1%)
in water
General aspects
Special remarks
Hostacor 4222 and Emulsogen 3971 are emulsifier

packages with good corrosion protecting
properties for milky, opaque and transparent metal
working fluids. Both products are soluble in water
and dispersible in mineral oil. Mineral oil based
water.
Hostacor 4222 and Emulsogen 3971 are very easy

and versatile to use for any kind of formulation.

1.1.3 Alkenyl succinic acid derivative

packages
Hostacor 4222
Package based on Na / TEA mix salt

of a complex amino carboxylic acid /
anionic
brownish,
clear,
oily liquid
8.5 9.5
Emulsogen 3971
Package based on Na / TEA mix salt

of a complex amino carboxylic acid /
anionic
dark brown,
clear,
oily liquid
7.5 9.0
Emulsogen 3980
Combination of alkenyl succinic acid

half amide with nonionics and alkanol
amides / anionic, nonionic
dark brown,
clear,
viscous liquid
approx. 10
9.4 9.8
Hostacor 4154
Corrosion inhibitor package

containing boric acid / anionic,
nonionic
dark brown,
clear,
viscous liquid
9 10
Hostacor 4359
Corrosion inhibitor package

containing boric acid / anionic,
nonionic
dark brown,
clear,
viscous liquid
9 10
yellow,
clear liquid
67
Product should be stored in a cool place.
Hostacor 4154 and Hostacor 4359 are corrosion

inhibitors and emulsifiers for water miscible metal
working fluids. They are largely unaffected by
water hardness and are used for milky, opaque
and transparent emulsions. Genapol O 020 can be
used as co-emulsifier.
Storage stability is max. 6 month in closed containers at temperatures below 30C. Due to the high
boron content the storage of Hostacor 4154 needs
certain precautions. Impurities, especially boric
acid crystals may lead to irreversible solidification
of the product.
Storage stability is max. 1 year. Storage temperature max.30 C.

Emulsogen T
> 26
Combination of polyglycol ether

and an anionic emulsifier / anionic,
nonionic
Emusogen T is an emulsifier for triglycerides.

Cloudiness in the concentrate can be eliminated
by adding small amounts of oleic acid.
> 27
Ether carboxylates
Appearance
DEAcontent
(%)
pH (1%)
in water
Applications / Function
Acid Value
mg KOH/g
Foaming
tendency
Corrosion
inhibiting
properties
Lime soap
dispersing
power 1
Ether carboxylic acids are based on

fatty alcohol oxethylates and exhibit
the benefits of anionic and nonionic
emulsifiers, especially when they are
converted to their salt form, eg. after
neutralisation with alkanolamines.
Therefore, the Emulsogen C-types are
versatile formulating agents, providing
high emulsion stability over the complete
pH-range, tolerating high content of
electrolytes and are stable against water
hardness. In general they are easily
biodegradable, show low toxicity and
excellent skin compatibility.
95 115
Low
Medium
Low
(<4)
140 155
Low
Medium
Low
(<4)
90 105
Low
Low
Low
(<4)
70 85
Medium
Low
Low
High
(25)
65 95
Medium
Low
High
Low
(8)
75 85
Medium
High
Medium
(12.5)
68 78
Medium
High
Low
High
(25)
64 78
Medium
High
Low
Excellent
(>25)
42 52
High
Medium
High
(20)
Lubricant
1.2
Corrosion
inhibitor

Function
Emulsifier
Ionicity
Emulsogen CIO 050
Ether carboxylic acid (5 EO),

nonionic / anionic (as salt)
yellowish,
clear liquid
2.0 3.5
Emulsogen CNH 030

colourless,
clear liquid
2.0 4.0
Emulsogen CNO 080 / 080 LC

colourless,
clear liquid
1.5 3.0
Emulsogen COA 070

yellowish,
clear liquid
2.0 4.0
Emulsogen COL 020

yellowish,
clear liquid
2.0 4.0
Emulsogen COL 050

yellowish,
clear liquid
2.0 4.0
Emulsogen COL 080

yellowish,
dull amber gel
1.5 3.0
Emulsogen COL 100 / 100 LC

yellowish,
clear liquid
2.5 3.5
Emulsogen CTS 100

yellowish,
clear liquid
2.0 4.0
Emulsogen CTS 160

yellowish,
clear liquid
2.0 4.0
39 49
High
Low
High
(20)
Emulsogen 4616
Ether carboxylic acid blend,

yellowish,
clear liquid
2.0 3.5
100 125
Low
Medium
Low
(<4)
Emulsogen 4617
Ether carboxylic acid blend,

yellowish,
clear liquid
2.0 4.0
83 90
Low
Low
High
(25)
Depending on their structure (type of

fatty alcohol, degree of oxethylation),
foaming properties, corrosion protection,
lime soap dispersing power may differentiate widely from product to product.
An overview about these properties is
given in the three columns on the right
side of this page.
As a result of the manufacturing process
the products contain max. 1% sodium
chloride-typically less.
Emulsogen CNO 080 and COL 100 are
avialable as low chlorid versions with a
sodium chloride content at max. 0,1%.
1)
> 28
Definition of K-value see glossary
> 29
2 Nonionic emulsifiers

> Page
2.1 Nonionics
>
32

Arkopal N 040
Arkopal N 060
Arkopal N 090
>
>
>
>
32
32
32
32

Emulsogen TS 100
Emulsogen TS 160
>
>
>
32
32
32

Genapol O 020
Genapol O 050
Emulsogen M
Emulsogen LP
Emulsogen MS 12
Emulsogen P
Genapol RX 065
>
>
>
>
>
>
>
>
32
32
32
34
34
34
34
34

Emulsogen A
Emulsogen A 060
Genagen IS 140
Genagen O 100
Emulsogen EL 360
Emulsogen ELO 200
>
>
>
>
>
>
>
36
36
36
36
36
36
36
> Page
2.2. Fatty acid esters

Emulsogen OG
>
>
36
36
Nonylphenol / Nonylphenol ethoxylate Directive 2003/53/EC

In general all products mentioned in the brochure are free of alkylphenols and alkylphenol ethoxylates
(esp. nonylphenols and nonylphenol ethoxylates). Exceptions are marked in the column Remark with notice:
APEO-containing and their use is restricted according to Directive 2003/53/EC effective from 17 January 2005.
See also: http://eur-lex.europa.eu/pri/en/oj/dat/2003/l_178/l_17820030717en00240027.pdf
> 31
Nonionics
Appearance
Lubricant
2.1
Corrosion
inhibitor
Nonionic emulsifier
Function
Emulsifier
Ionicity
DEAcontent
(%)
pH (1%)
in water
HLB
value
General aspects
Special remarks
Emulsifiers for mineral oil containing metal

working fluids based on naphthenic mineral oils
and metal cleaners.
Products contain APEO and are not allowed to be
used in EC effective from 17 January 2005.
Raw material for dewatering fluids.
Emulsifier for mineral oil containing metal working

fluids (esp. based on naphthenic mineral oils).
Excellent emulsifiers with good wetting properties

and outstanding lime soap dispersing power
(k = 20).
When stored at ambient temperatures the products

may become hazy or deposits are formed. Before
use, Genapol O 020 and Genapol O 050 has to be
homogenized at 50C.

Arkopal N 040
Nonylphenol polyglycol ether (4 EO)
yellowish liquid
Arkopal N 060
yellowish liquid
11
Arkopal N 090
yellowish liquid
68
12 13
Emulsogen TS 100
Tristyrylphenol polyglycol ether (10 EO)
yellowish,
clear liquid
approx. 7
10 11
Emulsogen TS 160
Tristyrylphenol polyglycol ether (16 EO)
yellowish,
clear liquid
approx. 7
Genapol O 020
Polyglycol ether (2 EO) based on

oleyl/cetyl alcohol
turbid,
yellowish liquid
approx. 7
Genapol O 020 is clearly soluble in naphthenic

and slightly turbid soluble in paraffinic mineral
oils. Genapol O 020 is a hydrotrope and a useful
coemulsifier for anionic products. Genapol O 020
stabilizes and clarifies oil concentrates and also
improves the dispersity and stability of emulsions.
Genapol O 020 is preferably used in combination
with emulsifiers like Hostacor 3928, Hostacor 3981
or Hostacor 4221.
Genapol O 050
Polyglycol ether (5 EO) based on

oleyl/cetyl alcohol
turbid,
yellowish liquid
approx. 7
Genapol O-050 is dispersible in mineral oils and

shows excellent emulsification properties for most
mineral oils. Stable emulsions are obtained in
soft and hard water. In metal working fluids good
compatibility to anionic formulation components is
given. It has a good stability against electrolytes
and excellent lime soap dispersing properties
(K value 17 20).
For alternatives to nonylphenol oxethylates / APEO

see chapter below and the brochure cited in
chapter 12.1.
> 32
> 33
Nonionics
Appearance
Lubricant
2.1
Corrosion
inhibitor
Function
Emulsifier
Ionicity
DEAcontent
(%)
pH (1%)
in water
HLB
value
General aspects
Special remarks
Emulsogen M / LP are excellent, low foaming

emulsifiers for mineral oils and are showing an
excellent compatibility to anionic components of
metal working fluids. As expressed by their
excellent lime soap dispersing power (K-value of
17 20) they are providing stable emulsions in
soft and hard water and stabilizing the emulsion
against increasing amounts of electrolytes.
Emulsogen M / LP are clearly soluble in most kinds
of mineral oils and are easy to formulate.
In solution of mineral oils they have a positive
impact to lubrication.
Emulsogen M and Emulsogen LP are stable and

homogeneous at room temperature. The pour point
for Emulsogen M / LP is between 0 and 5C.
> 34
Emulsogen M
Polyglycol ether (5 EO) based on oleyl /

cetyl alcohol
clear, yellow
liquid
approx. 7
Emulsogen LP
Polyglycol ether (5.5 EO) based on oleyl /

cetyl alcohol
clear, yellow
liquid
approx. 7
10
Emulsogen MS 12
Polyglycol ether (7 EO) based on oleyl /

cetyl alcohol
turbid,
yellowish liquid
approx. 7
11
Emulsogen MS 12 is dispersible in mineral oils and

shows excellent emulsification properties for most
mineral oils. Stable emulsions are obtained in soft
and hard water. In metal working fluids good compatibility to anionic formulation components. It has
a good stability against electolytes and excellent
lime soap dispersing power (K-value 17 20).
When stored at ambient temperatures the product

may become hazy or deposits are formed. Before
use, Emulsogen MS 12 has to be warmed up to
50C and homogenized.
Emulsogen P
Polyglycol ether (6,5 EO) based on

saturated fatty alcohol
yellow paste
approx. 7
Special emulsifiers for the preparation of liquid

emulsions from paraffin waxes melting between
38 and 56C. A homogenizer is not required.
Emulsogen P is used for preparation of stable,

easily dilutable, oil-in-water emulsions with a solid
content of up to 30%.
Genapol RX 065
Polyglycol ether based on synthetic

fatty alcohol
clear liquid
approx. 10 12 13
Genapol RX 065 is a water-free, mineral oil soluble,

emulsifier with excellent lime soap dispersing
power. It is especially suited for rolling fluids.
Genapol RX 065 becomes turbid with sedimentaion

at room temperature and must homogenised at
30C 40C before use.
> 35
Nonionics
Appearance
Lubricant
2.1
Corrosion
inhibitor
Function
Emulsifier
Ionicity
DEAcontent
(%)
pH (1%)
in water
HLB
value
General aspects
Special remarks
2.2
Emulsogen A
Fatty acid polyglycol ester (5,5 EO)

based on oleic acid
pale brown, clear

liquid
approx. 7
Emulsogen A is an emulsifier for many mineral oils.

It is clearly soluble in most kinds of mineral oils.
The emulsion forms spontaneously when the oil /
emulsifier mixture is stirred into water.
Emulsogen A 060
Fatty acid polyglycol ester (6 EO)

based on oleic acid
pale brown, clear

liquid
approx. 7
Emulsifiers for mineral oils. The emulsion forms

spontaneously when the oil / emulsifier mixture is
stirred into water.
Genagen O 100
Fatty acid polyglycol ester (10 EO)

based on oleic acid
yellow, clear to
turbid liquid
approx. 7
Genagen IS 140
Fatty acid polyglycid ester (14EO)

based isostearic acid
yellowish turbid,
pasty to liquid
approx. 7
Emulsifiers for cleaner formulations.
Genagen IS 140 is a waxy solid at room temperature.
Emulsogen EL 360
Polyglycol ester (36 EO) based on

castor oil
turbid, liquid or
pasty
approx. 7
Emulsifiers for triglycerides, oils of vegetable

origin, vegetable and synthetic ester oils to form
spontaneously milky emulsions.
Cloudiness of the concentrate can be adjusted by

adding small amounts of oleic acid.
Emulsogen ELO 200
Modified castor oil oxethylate
yellow brownish
clear liquid
approx. 7
Oleic acid polyglycerol ester
yellow liquid
approx. 7
Genagen O 100 is clearly soluble in paraffinic

mineral oils. Clear solutions in naphthenic mineral
oils are obtained at concentrations below 25% only.
Genagen O 100 is opaque dispersible in water.
Fatty acid esters

Emulsogen OG
> 36
Emulsogen A 060 is turbid soluble in mineral oils

and dispersible in water.
Coemulsifier in metal working fluids based on

paraffinic mineral oils. Concentrate and emulsion
stability are improved by addition of 23%. Emulsi
fier for high viscous water-in-oil emulsions based
on mineral oils, petroleum, fatty acid esters etc.
> 37
3 Fatty acid alkanol amides

3.1

> Page
Hostacor DT
Hicor BAT
Hicor C
3.2 Fatty acid alkanolamides / DEA free

Hostacor V 4188
Hostacor MT
Hostacor MTF
Emulsogen MT 050
>
>
>
>
40
40
40
40
>
>
>
>
>
40
40
40
40
40
> 39
3.1
Appearance
Lubricant

Corrosion
inhibitor
Fatty acid alkanol amides
Function
Emulsifier
Ionicity
DEAcontent
(%)
pH (1%)
in water
General aspects
Special remarks
Hostacor DT, and the Hicor types are clear soluble

in most mineral oils and are dispersible in water.
They are used as corrosion inhibitors for water
miscible metalworking fluids or neat oil applications respectively corrosion prevention oils.
Corrosion protection of used emulsion can be
generally adjusted by these products.
By varying the concentration of Hostacor DT it is

possible to adjust the corrosion inhibiting effect
of the emulsion to the special requirements of the
user. Hostacor DT is useful as corrosion inhibitor
in rust prevention oils.
Hostacor DT
Tall oil fatty acid diethanolamide
brown, clear,
oily liquid
approx. 30
approx. 10
Hicor BAT
Fatty acid diethanolamide based on

rapeseed oil
yellow, clear
liquid
0.5 0.6
8.9 9.5
Hicor C
Fatty acid diethanolamide based on

rapeseed oil
yellow, clear
liquid
57
Hostacor V 4188
Tall oil fatty acid monoisopropanolamide, formulated
brown, clear, oily

liquid
Hostacor MT
Tall oil fatty acid monoethanol amide,

ethoxylated
clear, brown
liquid
approx. 9.5
Hostacor MTF

ethoxylated, formulated
clear, brown
liquid
approx. 10.5
Emulsogen MT 050

ethoxylated
clear, brown
liquid
9.5 10
Hicor BAT is a corrosion inhibitor with an extremely low content of free DEA and free acid. As a
consequence formation of lime soaps is reduced
when mixed with water of high hardness. During
storage, the temperature should not drop below
20C, to avoid gelification and turbidity.
Hicor C is a corrosion inhibitor with a low content
of free DEA and free acid. As a consequence
formation of lime soaps is reduced when mixed
with water of high hardness. During storage, the
temperature should not drop below 20C, to avoid
gelification and turbidity.
3.2 Fatty acid alkanolamides / DEA free
> 40
approx. 9
Hostacor V 4188, Hostacor MT and Hostacor MTF

are clear soluble in most mineral oils and are
dispersible in water. They are used as corrosion
inhibitors for water miscible metal working fluids
or neat oil applications respectively corrosion
prevention oils.
Corrosion protection of used emulsion can be
generally adjusted by these products.
Hostacor V 4188 is useful as corrosion inhibitor in

rust prevention oils.
Hostacor MT is a corrosion inhibitor with a low

content of free acid and is very effective as an
emulsion stabilizer. By mixing MT with e.g. tall oil
fatty acid and alkanolamines, pH-values between
9.5 10.5 can be adjusted. HLB value: approx. 7.6
Hostacor MTF is based on Hostacor MT and
contains additionally fatty acid alkanolamine salts.
It is a DEA free alternative for products like
Hostacor DT (page 42).
Emulsogen MT 050 is a nonionic emulsifier based

on a fatty acid alkanol amide with low content of
acid and amine. Generally it is used for water
miscible metal working fluids providing an additional corrosion inhibition effect.
Emulsogen MT 050 is highly compatible with

anionic, cationic and nonionic surfactants. It is
showing very low foam tendency and is providing
an outstanding lime soap dispersing power
(k > 20).
> 41
4 Water soluble corrosion inhibitors

and lubricants

> Page
4.1 Water soluble corrosion inhibitors

Hostacor B
Hostacor 4053
Hostacor 4053 SEO
Hostacor IS
Hostacor 2732
Hostacor IT
Hostacor BI
Hostacor BIT
Hostacor 1102
>
>
>
>
>
>
>
>
>
>
44
44
44
44
44
44
44
46
46
46

4.2
> Page
Genapol B
Genapol PN 30
Genapol PS
>
>
>
>
46
46
46
46
> 43
> 44
Appearance
Lubricant
4.1
Corrosion
inhibitor
Water soluble corrosion inhibitors and

lubricants
Function
Emulsifier
Ionicity
DEAcontent
(%)
Boroncontent
(%)
pH (1%)
in water
General aspects
Special remarks
Hostacor B, Hostacor 4053 and Hostcor 4053 SEO

are suitable raw materials for the production of
mineral oil free metal working fluids. They are
water miscible in any ratio, hardwater stable and
extremely low foaming. In combination with
suitable emulsifiers (Emulsogen and Hostacor
grades) they can be used as corrosion inhibitors
for emulsifiable metal working fluids
The temperature should not drop below 0C, to

avoid gelification and turbidity
Hostacor B
Alkanolamine containing formulation

with boric acid
yellowish, clear,
viscous liquid
78%
approx.
2.7
9 10
Hostacor 4053

with boric acid
yellowish, clear,
viscous liquid
approx.
3.0
9 10
Hostacor 4053 SEO

with boric acid
yellowish, clear,
viscous liquid
approx.
7.0
9 10
Hostacor IS
Isononanoylamidocaproic acid/anionic
as salt
Crystalline
substance, m. r.
approx. 50 C
Hostacor 2732
Isononanoylamidocaproic acid partially

neutralized with cyclohexylamine/
anionic as salt
Yellow, clear
viscous liquid
Hostacor IT
TEA salt of Isononanoylamidocaproic

acid/anionic
Yellow, clear
viscous liquid
approx.
8.0
Hostacor 4053 SEO must be stored at 60C to avoid

crystallisation
Hostacor IS and Hostacor 2732 are insoluble in

water. Water soluble salts of Hostacor IS and
Hostacor 2732 are obtained by neutralization with
alkanolamines and hydroxides. They are used
alone or in combination with other water soluble
corrosion inhibitors or lubricants for cutting or
grinding fluids and in aqueous hydraulic fluids.
Hostacor IS and Hostacor 2732 are also suitable
for the formulation of aluminium working fluids. pH
value should be adjusted to approx. 8 to avoid
staining which is often observed at high pH values.
Hostacor IS is a raw material for manufacturing

water soluble corrosion inhibitors. Product must
be liquefied before use.
DR+
Hostacor IT is clearly soluble in water, stable

against water hardness and low foaming. It is used
alone or in combination with other water soluble
corrosion inhibitors or lubricants for cutting or
grinding fluids, in aqueous hydraulic systems and
in cleaners. For better lubricity Genapol B/PN30/
PS are suitable. Hostacor IT is also suitable for the
formulation of aluminium working fluids.
Hostacor IT is a ready to use product. It is darkening during storage to red brown colour. This does
not affect the application properties.
DR+
Hostacor 2732 is a liquefied version of Hostacor IS

which is easily pourable at room temperature.
DR+
> 45
4.2
> 46
Appearance
Lubricant
4.1
Corrosion
inhibitor
Water soluble corrosion inhibitors and

lubricants
Function
Emulsifier
Ionicity
DEAcontent
(%)
Boroncontent
(%)
pH (1%)
in water
Hostacor BI, Hostacor BIT and Hostacor 1102 are

used as corrosion inhibitors alone or in combination with other water soluble corrosion inhibitors,
glycols and EO/PO block- or copolymers for mineral oil free cutting and grinding fluids. Hostacor BI,
BIT and 1102 are water miscible, stable against
water hardness and low foaming.
Hostacor BI
Formulation based on alkanolamine,

boric acid and corrosion inhibitor/
anionic
Yellow, clear
viscous liquid
approx.
58%
approx.
2.1
9 10
Hostacor BIT
Formulation based on alkanolamine,

boric acid and corrosion inhibitor/
anionic
Yellow, clear
viscous liquid
approx.
2.5
9 10
Hostacor 1102
Mixture of alkanolamines, boric acid

and polycarboxylic acid salt/anionic
Slightly yellow,
clear viscous
liquid
approx.
56%
approx.
2.5
9.5
Genapol B
EO / PO blockpolymer based on
ethylenediamine
brown,
viscous liquid
approx.
11
Genapol PN 30
EO / PO blockpolymer based on
ethylenediamine
yellow,
viscous liquid
10 11
Genapol PS
EO / PO random copolymer
yellowish, highly
viscous liquid
57
General aspects
Special remarks

Genapol B / PN 30 / PS are low foaming lubricants
for synthetic metal working fluids. They are stable
against water hardness. In combination with corrosion inhibitors like Hostacor IT or Hostacor BIT,
clear water soluble metalworking fluids with good
lubricating and corrosion protecting properties are
obtained.
Water solubility increases from Genapol PN 30,

Genapol B to Genapol PS. Depending on the
amounts of boric acid esters, corrosion inhibitors
and solubilizing agents, the Genapol type of adequate solubility has to be selected to obtain stable
and clear concentrates resp. synthetic metal working fluids. Genapol PN 30 and Genapol B do not
contain free ethylene diamine.
> 47
5 Oil soluble corrosion inhibitors
> Page
Arkomon SO
Hostacor PSO 300
>
>
50
50
> 49
> 50
Appearance
Lubricant
Corrosion
inhibitor
Function
Emulsifier
Ionicity
DEAcontent
(%)
Boroncontent
(%)
pH (1%)
in water
General aspects
Special remarks
Arkomon SO
Oleic acid sarcoside
yellow to brown,
clear liquid
Arkomon SO is soluble in most kind of mineral oils. The strong foaming tendency of Arkomon SOsalts in aqueous emulsions should be taken in
Arkomon SO is used as corrosion inhibitor for oil
consideration.
based metal working fluids and corrosion protection oils. In neutralized form, e. g. as sodium salt it
can be used as corrosion inhibitor in water miscible metal working fluids.
Hostacor PSO 300
Calcium petroleum sulphonate,

overbased [TBN 300]
dark,
viscous liquid
In rust prevention oils Hostacor PSO 300 provides

long term rust protection to workpieces also under
unfavourable conditions such as storage under
open air. Hostacor PSO 300 is an oil soluble lubri
city and EP / AW additive with excellent corrosion
protection properties. As EP / AW additive it is
used in neat cutting oils, honing oils or deep
drawing oils alone or in combination with other
EP-additives.
Addition of acids to Hostacor PSO 300 containing

formulations must be avoided.
> 51
6 Lubricants and EP-Additives
> Page
> Page
6.1 Esters
Hostagliss FN
Hostagliss H
Hostagliss L4
Hostagliss A
Hostagliss DHSZ
Hostagliss PA 135
Hostagliss PA 165
>
>
>
>
>
>
>
>

Dispersogen SP 040
Hordaphos 124
Hordaphos 125
Hordaphos 145
Hordaphos 222
Hordaphos DEOD
Hordaphos MDAH
Hordaphos MDB
Hordaphos MDGB
Hordaphos MDHX
Hordaphos MDIT
Hordaphos MDO
Hostaphat TBEP
>
>
>
>
>
>
>
>
>
>
>
>
>
>
54
54
54
54
54
54
54
54
56
56
56
56
56
56
56
56
56
58
58
58
58
58
6.3 Polyalkylene glycols / Polyethylene glycols

see chapter 11
>
78
> 53
Appearance
Lubricant
Corrosion
inhibitor
Function
Emulsifier
Ionicity
DEAcontent (%)
Acid number
(mg KOH / g)
General aspects
Viscosity (mm2/s)
Viscosity Index
at 40C
at 100C
75 110
13 17
min. 150
3000 5000
250 500
approx. 180
approx. 45
approx. 169
80 120
approx. 180
2000 2700
180 220
approx. 210
270 330
31 37
min. 120
730 800
65 75
min. 120
6.1 Esters
> 54
Hostagliss FN
Polyester based on special fatty acids.
brown,
clear liquid
max. 5
Hostagliss H
Nitrogen containing complex polyester

based on fatty acids, dicarboxylic acids
and polyvalent alcohols.
brown, clear
viscous liquid
5.5 8.5
Hostagliss L4
Acid group containing complex ester

based on fatty acids.
clear viscous
liquid
50.5 55.5
Hostagliss A

brown, clear
viscous liquid
42 52
Hostagliss DHSZ

brown, clear
viscous liquid
29 35
Hostagliss PA 135
Copolymer of -olefin and maleic acid

di butyl ester.
clear liquid
max. 2
Hostagliss PA 165
Copolymer of -olefin and maleic acid

di butyl ester.
clear liquid
max. 2
Hostagliss FN and Hostagliss H are excellent

lubricity and AW additives and can be easily
incorporated into water miscible metalworking
fluids. In particular they show an outstanding
performance in formulations for aluminium cutting
fluids. Synergistic effects are obtained when
1 : 1 mixtures of Hostagliss FN / Hostagliss H
are applied.
approx.400
Hostagliss L4, Hostagliss A and Hostagliss DHSZ
are complex esters with a high residual acid number and can be easily incorporated into concentrates for water based emulsions despite their high
viscosities. They contribute to emulsion stability
900 1100
and corrosion protection when neutralized with
alkanolamines.
Hostagliss PA 135 and Hostagliss PA 165 are fully

saturated, liquid polymeric esters. The hydrolytic
stability is good so they can be applied in water
based metalworking fluids as well as lubricant in
various neat oil applications.
> 55
> 56
pH
(1% in water /
Isopropanol 1:3)
Acid number
(mg KOH / g)
P-content (%)
Phosphoric acid esters
Appearance
Lubricant
6.2
Corrosion
inhibitor
Function
Emulsifier
Ionicity
General aspects
Special remarks
Dispersogen SP 040
Phosphoric acid mono / di ester based

on alkylphenol ethoxylate
clear colourless
to yellowish
liquid
approx.
3.9
approx.
110
approx.
2.5
Dispersogen SP 040 is used in neutralized form as

emulsifier.
Product should be stored at ambient temperature.

Max. storage time is 1 year.
Hordaphos 124

on fatty alcohol polyglycol ether.
brownish
viscous liquid
approx.
4.4
approx.
130
approx.
2.8
Hordaphos 124 is suitable for low foaming

formulations and as a solubilizing agent.
Hordaphos 125

on fatty alcohol polyglycol ether.
yellowish to
brownish viscous
liquid
approx.
5.4
approx.
180
approx.
2.5
Hordaphos 125 is used in neutralized form for

water miscible metal working fluids.
Hordaphos 145

on fatty alcohol polyglycol ether
clear yellowish to
brownish liquid
approx.
5.0
approx.
160
approx.
3.0
Hordaphos 145 can be used as emulsifier or as

detergent in low viscous mineral oils when neutralized with suitable amines and / or alkanolamines.
The EP activity of Hordaphos 145 is influenced
by the amines chosen for neutralisation. It is
recommended to use Hordaphos 145 in mixtures
with esters, e.g. TMP-oleate.

Hordaphos 222

on alkyphenol ethoxylate
clear colourless
to yellowish
liquid
4.3 5.3
approx.
140
approx.
2.4
Hordaphos 222 is used in neutralized form

for water micible metal working fluids.

Hordaphos DEOD

on decanol, ethanol and octanol
clear colourless
to yellowish
liquid
approx.
12.0
approx.
220
approx.
2.5
In combination with Aluminium salts (Locron

types) and suitable surfactants Hordaphos DEOD
is a thickener for mineral oils

Max. storage time is 1 year
Hordaphos MDAH
Phosphoric acid mono / di

(2-ethylhexyl) ester
colourless to
yellowish liquid
approx.
11.5
approx.
308
approx.
2.3
Hordaphos MDAH is suitable additive for low

viscous mineral oils so it can be used in oil based
grinding fluids. Hordaphos MDAH has very strong
phosphatizing properties.

Hordaphos MDB
Phosphoric acid mono / di alkyl ester

based on short chain alcohol
clear acolourless
to yellowish
liquid
approx.
17.2
approx.
470
approx.
2. 2
Hordaphos MDB is used for synthetic and semi

synthetic metal working fluids after neutralization.
> 57
pH
(1% in water /
Isopropanol 1:3)
Acid number
(mg KOH / g)
P-content (%)
Appearance
Lubricant
Corrosion
inhibitor
Function
Emulsifier
Ionicity
General aspects
Special remarks

Hordaphos MDGB

glykol alkyl ester
clear colourless
to yellowish
liquid
approx.
19.5
approx.
548
approx.
1.7
Hordaphos MDGB is suitable for water miscible

cutting fluids. Due to its low decomposition
temperature it is a highly active EP-additive.
Hordaphos MDHX

glykol alkyl ester
clear colourless
to yellowish
liquid
approx.
13.1
approx.
375
approx.
2.3
Hordaphos MDHX is mainly used as

AW-additive in amine neutralized form.
Hordaphos MDIT
clear colourless
to yellowish
liquid
approx.
8.5
approx.
230
approx.
2.5
Hordaphos MDIT is used in neutralized form as

emulsifier. Due to the very low surface tension it
can be used in dewatering fluids.

Hordaphos MDO
clear colourless
to yellowish
liquid
approx.
11.5
approx.
330
approx.
2.7
Hordaphos MDO is used in neutralized form as

emulsifier. Due to its very low surface tension it
can be used in dewatering fluids.
Hostaphat TBEP
Phosphoric acid trialkylester
clear colourless
to turbid
yellowish liquid
< 0,5
Anti-Wear additive / lubricant for environmentally

sensitive applications
For short chain phosphoric acid esters suitable for surface treatment
and metal cleaners see brochures listed in chapter 11.5
> 58
> 59
7 Cleaners

7.1
> Page
Genapol EP 0244
Genapol EP 2424
Genapol EP 2464
Genapol EP 2552
Genapol EP 2544
Genapol EP 2564
Genapol EP 2584
Genapol BA 040
7.2 Corrosion inhibitors / Specialities

Dodigen 95
Dodicor 2565
Dodicor 2725 NF
Hostaphat OPS 100
Hostaphat OPS 80 P
>
>
>
>
>
>
>
>
>
62
62
62
62
62
62
62
62
62
>
>
>
>
>
>
64
64
64
64
64
64

7.3

> Page
Solvents see chapter 11.3
>
78
Detergent Regulation EC 648/2004 and EC 907/2006

According to the Detergent Regulation Surfactants used in detergents (cleaners etc.) have to
show an ultimate biodegradation above given minimum limits according to EC648/2004. The determination methods, minimum ultimate biodegradation limits and test report quality requirements are
provided by the regulation. Producers state the compliance with the EU Detergent Regulation with
phrases in the EU safety data sheet (EU-SDS) Chapter 12 or 15.
Products with a compliance phrase in the EU-SDS show in the column remarks the abbreviation:
"DR +".
See also: http://eur-lex.europa.eu/LexUriServ/site/en/oj/2004/l_104/l_10420040408en00010035.pdf
> 61
> 62
Appearance
Lubricant
7.1
Corrosion
inhibitor
Cleaners
Function
Emulsifier
Ionicity
DEAcontent
(%)
pH (1%)
in water
General aspects
Special remarks
These products are all soluble in water, stable against water hardness and stable against
aqueous acids and bases. They are mostly used
as low foaming cleaning agents mainly for mild
alkaline or neutral spray cleaners. These Genapol
types show excellent compatibility with anionic
corrosion inhibitors e.g. Hostacor IT.
The temperature should not drop below 20C to

avoid gelification and turbidity during storage.
If the products become opaque, thick or frozen it
can be thawed slowly at room temperature and
used after homogenization.
All products are DR+.
Genapol EP 0244
C10 / C12 Ziegler alcohol

EO PO adduct
turbid
68
Genapol EP 2424
C12 / C14 fatty alcohol
clear, liquid
68
Genapol EP 2464
C12 / C14 oxo alcohol EO PO adduct
turbid, liquid
68
Genapol EP 2552
clear, liquid
68
Genapol EP 2544
clear, liquid
68
Genapol EP 2564
turbid
68
Genapol EP 2584
turbid
68
Genapol BA 040
Benzyl alcohol-ethoxylate
clear liquid
68
Genapol BA 040 is an excellent solubilizer of low

volatility for cleaner formulations. It does not show
pronounced surfactant properties itself.
Genapol BA 040 can also be used in emulsifiable
metal working concentrates to improve spontaneity
of emulsion formation.
DR+
> 63
Corrosion inhibitors / Specialities
7.3
Appearance
Lubricant
7.2
Corrosion
inhibitor
Cleaners
Function
Emulsifier
Ionicity
DEAcontent
(%)
pH (1%)
in water
General aspects
Special remarks
All products are showing a pour point below

20C. Nevertheless, storage temperature should
not drop below 20C to avoid gelification and
turbidity. If products become opaque, thick or
frozen they can be thawed slowly at room
temperature and used after homogenization.
Dodigen 95
Mixture of an alkyl aryl ammonium

rhodanide and oxalkylated amine in
water / cationic.
brownish, liquid
8 10
Dodigen 95 is soluble in mineral / organic acids

and forms stable emulsions with water. Dodigen 95
is an inhibitor for oxo acids such as sulphuric acid,
phosphoric acid, sulphamic acid and organic acids
such as acetic, formic and citric acid.
Dodicor 2565
Solution of a quaternary chinolinium

compound in water / cationic.
brownish, liquid
3.5 5
Dodicor 2565 is soluble in water and acids. It is a

special inhibitor for zinc, but protects also steel
against the attack of mineral acids.
Dodicor 2725 NF
Mixture of quaternary chinolinium

compound, alkinol and nonionic
surfactant in glycol / cationic.
amber liquid
34
Dodicor 2725 NF is soluble in water and also

in diluted and concentrated hydrochloric acid.
It is used to inhibit the attack of hydrochloric /
hydrofluoric acid solutions on low carbon steels.
Dodicor 2725 NF also shows a good protection
to steel against sulfamic and sulfuric acid and
even to aluminium, if the acid concentrations
and treating temperatures are moderate.
Hostaphat OPS 100
Alkane phosphonic acid
white wax
Hostaphat OPS 100 is used in its neutralized

form as inhibitor in aluminium cutting fluids and
aluminium cleaner formulations. The surface
quality (staining) of certain Al alloys can be
improved significantly. Hostaphat OPS 100 shows
also corrosion protection for ferrous metals.
Hostaphat OPS 80 P
Alkane phosphonic acid in a mixture

of water / alcohol
clear, amber to
brownish liquid
The product is stable and do not show

Solubilized version of Hostaphat OPS 100 to
provide better handling. Used solvent offers a flash solidification or precipitation at storage
temperatures down to + 15C.
point > 100C
DR+
The product has to be warmed up above 60C to

get liquid . Suitable neutralisation agents are
alkali hydroxides and amines.
DR+
Solvents
Clariant offers a broad range of Glymes for cleaning applications, especially as replacement for toxicologically and environmentally problematic
solvents (chlorinated solvents, NMP). See chapter 11.3
> 64
> 65
Appearance
8 Defoamers
Lubricant
Corrosion
inhibitor
tab_head_1
Function
Emulsifier
Chemical description/
Ionicity
0.0 tab_head_2

0.0.0 tab_head_3
tab_products
>
64
tab_text
tab_text
> Page
Antimussol 3472 N
Antimussol FN
Antimussol TIP
Antimussol ZJ
>
>
>
>
>
>
>
>
>
68
68
68
68
68
68
68
68
68
> 67
> 68
Ionicity
Dilutability
in water
Flash
point
General aspects
Special remarks
Antimussol 3470 liq. and Antimussol 3472 N are

combined defoamers and foam suppressants, they
can be used in nonionic and anionic / nonionic
metal working fluids. They are suitable for oil containing, water miscible metal working fluids. For
the use in concentrates.
The products may precipitate at temperatures

below 10C, after heating to 40C and homogenisation they becomes clear and can be used
again without loss of performance.
Si-free
Silicone content
Silicone
free
Defoamers
Appearance
Si
Ionicity
Mixture of nitrogen containing, surface yellow liquid

active substances.
nonionic
yes
>100C
Antimussol 3472 N
Mixture of nitrogen containing, surface yellow liquid

active substances.
cationic
yes
>100C
Mixture of nitrogen and silicon

containing substances.
milky dispersion
cationic
yes
98C
Antimussol 4459 liq. is a combined defoamer

and foam suppressant, it can be used in anionic
and anionic / nonionic metal working fluids. It's
suitable for oil containing, water miscible metal
working fluids.
Sensitive to frost. After freezing the product is not

longer usable.
Storage stability is max. 6 months.
Aqueous dispersion of fat derivatives

with a low polysiloxane content.
milky dispersion
nonionic
yes
>100C
Antimussol 4752 liq. is an universal defoamer for

a wide range of metal working fluids.
Risk of separation after prolonged exposure to

temperatures above 40C. Sensitive to frost. After
freezing the product is not longer usable.
Storage stability is max. 6 months.
Antimussol FN
Mixture of sparingly water soluble

foam suppressing organic substances.
viscous liquid
nonionic
no
>100C
Antimussol FN is a defoamer for a wide range

of metal working fluids. It is suitable for oil
containing, water miscible metal working fluids.
For the use in concentrates. Product contains
fatty acid amide based on sec.-amine.
The product becomes turbid at temperatures

below 5C, after heating to 40C and
homogenisation it becomes clear and can be
used again without loss of performance.
Antimussol TIP
Solution of phosphoric acid ester

in alcohol
yellowish,
clear liquid
nonionic
no
27C
Antimussol TIP is a defoamer for all classes of

surfactants. It is suitable for a wide range of metal
working fluids and can be applied in concentrates.
Antimussol TIP keeps liquid below 25C. If it

becomes turbid, thick or frozen under exposure
of cold, thaw slowly at room temperature and
homogenize carefully.
Storage stability is max. 2 years.
Antimussol ZJ
Fatty acid amide
yellow liquid
nonionic
no
>100C
Antimussol ZJ is a raw material for defoamer

formulations and is suitable for a wide range of
metal working fluids. It can be applied in
concentrates.
Antimussol ZJ keeps liquid down to 25C. If it

becomes turbid, thick or frozen under exposure
of cold, thaw slowly at room temperature and
homogenize carefully.
Storage stability is max. 2 years.
Mixture of nitrogen containing substances with polyoxyalkylates
turbid dispersion
nonionic
yes
> 100 C Appretan defoamer 5084 liq. is a combination of

defoamer and a de-airing agent with good wetting
abilities. It is suitable for a wide range of metal
working fluids. For the use in Concentrates
Storage stability is max. 1 year
Water dispersible mixture of organic

compounds, aromatic free
turbid dispersion
nonionic
nonionic
> 150 C Appretan defoamer 5342 liq. is a universal for a

defoarmer wide range of metal working fluids
Risk of separation after prolonged exposure to

temperatures above 40C of after intensive
shearing. Stzorage stability is max 1 year
> 69
9 Biocides
> Page
Nipacide BK
Nipacide BIT 20
Nipacide CI
Nipacide FC
Nipacide HTP/2
Nipacide IPBC 20 / IPBC 30
Nipacide MBM
Nipaclean 3
Sodium Omadine 40%
>
>
>
>
>
>
>
>
>
72
72
72
72
72
72
72
72
72
Biocides
For EEC (Europe):
Based on our information (status April 2008) all mentioned biocides are in compliance with the
BPD 98/8/EC and amendments/corrections. This information is based on the current situation and
Clariant reserves the right to modify the support if the data requirements change or the market
position alters.
See also: http://ecb.jrc.it/biocides/
For Germany:
Biozide sicher verwenden. Vor Gebrauch stets Kennzeichnung und Produktinformation lesen.
> 71
> 72
Ionicity
Appearance
Formaldehyde
donor
pH (1%)
in water
General aspects
Special remarks
Nipacide BK
Tris(2-hydroxyethyl)-hexahydro-1,3,5- triazine
clear liquid
yes
10 11
Nipacide BK is a water soluble, wide spectrum

biocide, which can be used for disinfection and
preservation of metalworking fluids.
Storage time 1 year.

Max. storage temperature 40C.
Nipacide BIT 20
20% alkaline solution of benzisothiazoline
clear, yellow viscous liquid
no
89
Nipacide BIT 20 is used in formulations and

tankside addition. It is very effective at high pHs
and offers thermal stability.
Nipacide CI
Chlorinated and non chlorinated

isothiazolinones
yellow liquid
no
approx. 7,5
Nipacide CI is widely used for the post treatment

of metal working emulsions in large central
systems.
Nipacide FC
1,2-ethandiylbis(oxy)bismethanol
clear liquid
yes
approx. 7
Nipacide FC is used in formulations and tankside

dosing.It gives long term protection of emulsions
against bacteria and fungi.
Nipacide HTP/2
Tris(2-hydroxyethyl)-hexahydro-1,3,5-triazine
and Sodiumpyridinethiol-1-oxide.
colourless liquid
yes
approx. 11
Npacide HTP/2 is used in formulations and tank

side dosing. It is a combination of bactericide and
fungicide where additional fungicidal activity is
required.
Nipacide IPBC 20 / IPBC 30
3-Iodo-2-propinyl-butylcarbamate
colourless to yellow liquid
no
approx. 7
Nipacide IPBC grades are used in formulations

and tankside addition. Active levels 20% and 30%.
Nipacide MBM
N,N-methylene bismorpholine
clear liquid
yes
approx. 10
Nipacide MBM is used in formulations and tank

side dosing. It is an exceptionally good bactericide
with enhanced fungicidal qualities.
Nipaclean 3
Blend of biocides, cleaners and

surfactants
clear yellow
liquid
yes
approx. 12
Exceptional with synthetics and semi synthetics.

Used as a tankside treatment to remove contaminants, slimes and oil residues when emulsion
is changed. It ensures that the system is in good
microbial condition to accept new emulsion.
Sodium Omadine 40%
Sodium pyridinethiol-1 oxide
amber liquid
no
8,5 10
Nipacide SP is used as fungicide in formulations

and tankside addition
Biocides
> 73
10 Others
> Page
10.1 Dewatering fluids

Emulsogen ENF
Genamin 8 R 100 D
>
>
>
76
76
76
10.2 Amines
Genamin SH 100 D P
Genamin 3920
Genamin NO 050
Genamin CH 020
>
>
>
>
>
76
76
76
76
76
> 75
10.1
10.2
Appearance
Lubricant
Corrosion
inhibitor
Others
Function
Emulsifier
10
Ionicity
DEAcontent
(%)
pH (1%)
in water
General aspects
Special remarks
Emulsogen ENF is the nonylphenol ethoxylate free

replacement of Emulsogen E (deleted product)
Dewatering fluids
Emulsogen ENF
Corrosion inhibitor in combination with

fatty alkohol polyglycol ether
yellowish to
brown, clear
viscous liquid
approx. 7
Emulsogen ENF is clearly soluble in most organic

solvents. They are wetting agents with corrosion inhibiting properties for dewatering fluids.
Emulsogen ENF cause the rapid separation of the
water from the metal surface and prevent corrosion of the dewatered metal parts.
Genamin 8 R 100 D
Octylamine, dist.
colourless liquid
Raw material for corrosion inhibitors in dewatering

fluids. After neutralization with suitable fatty acids
like caprylic acid, Genamin 8 R 100 D is used in
combination with wetting agents as hydrophobic
and corrosion inhibiting component in dewatering
fluids.
Genamin SH 100 D P
Tallow fatty alkyl amine
white flakes
Genamin SH 100 D P is soluble in mineral oils. It is

used as corrosion inhibitor. Genamin SH 100 D P
is a useful component for oil-based formulations
e.g. for the neutralisation of acidic EP-additives to
generate oil soluble salts.
Genamin 3920
Caprylamine oxethylate
clear, colourless
to slight yellow
liquid
Genamin NO 050
Caprylamine ethoxylate
clear yellow
to brown liquid
Genamin 3920, Genamin NO 050 and Genamin CH

020 are used as neutralizing agents.
For emulsifiable (3920, NO 050, CH 020) and
synthetic (CH 020, NO 050) metal working fluids.
In many cases spontaneity of emulsion formation
is improved. Genamin CH 020 causes almost no
cobalt leaching.
Genamin CH 020
Cyclohexylamine oxethylate
clear, colourless
to slight yellow
liquid
Amines
Max. storage time 1 year
Clariant offers also a variety of fatty amines and amine derivatives like
fatty amine ethoxylates see brochure listed in chapter 11.2.
> 76
> 77
11 Brochures / Other ranges

1 1.1 Raw Materials for the Chemo-Technical Industry
< Fatty Amines and Derivatives

< Amine Oxides and Betaines

< Solubilizers

< Anionic Surfactants

< Nonionic Surfactants

< Low Foamers and Defoamers

< Emulsifiers

1 1.2 Fatty Amines and Derivatives
< Fatty Amines and Derivatives

< Amine Oxides, Betaines and Quaternary

Ammonium Compounds
< Amine Ethoxylates

1 1.3 Glymes Glycol diethers
< Ethylene glycol dimethyl ethers

< Polyethylene glycol dimethyl ethers

< Polyethylene glycol dibutyl ethers

< Polyethylene glycol monoallyl ethers

< Polyethylene glycol allylmethyl ethers

< Polyalkylene glycol monoallyl ethers

< Polyalkylene glycol diallyl ethers

1 1.4 Polyalkylene / Polyethylene glycols
< Polyethylene glycols (PEG)

< Polyglycole PR

< Polyglycole M

< Polyglycole P41

< Polyglycole B11

< Polyglycole B01 and T01

< Polyglycole D21

< special products

1 1.5 Hordaphos (phosphoric acid esters)
< General brochure

< Additives for Cleaners

< Additives for Industrial Cleaning

< Additives for Surface Finishing

Functional Chemicals Division: Product Information

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fuenfwerken.com | EBR 5276 | 09.

Clariant International Ltd.

Functional Chemicals Division

Products for Metal Working Fluids

Product names in alphabetical order

Anionic emulsifiers / Corrosion inhibitors

Fatty acid alkanol amides

A package is a stable pre-formulation

Lime soap dispersing power, K-value

Water soluble corrosion inhibitors

Oil soluble corrosion inhibitors

Lubricants and EP-Additives

Brochures / Other ranges

This information is based on our present state of knowledge and is intended

Product names in alphabetical order

Clariant is one of the worlds leading manufacturers of surfactants and auxiliaries.

Antimussol, Appretan Defoamer, Arkomon, Arkopal, Dispersogen, Dodicor,

Nonylphenol / Nonylphenol ethoxylate Directive 2003/53/EC

< Antimussol 3472 N

< Genagen IS 140

< Appretan Defoamer 5084 liq.

< Genapol BA 040

< Appretan Defoamer 5342 liq.

< Genapol RX 065

< Emulsogen 5690

< Hordaphos DEOD

< Nipacide HPT/2

< Genamin NO 050

< Hostaphat TBEP

< Sodium Omadine 40%

Changed products (from Update Winter 2004/2005)

< Emulsogen SBL deleted

< Hostacor V 5233 deleted

< Emulsogen TS 050 deleted

< Hostacor 5428 deleted

< Aicamide 2131/B deleted

< Genamin 4048 deleted

< Hostacor GLA 1 deleted

< Genamin 5577 deleted

< Hostacor IPT deleted

< Genamin 18 R 100 D deleted

< Hostacor IC deleted

< Genamin SH 100 D FLA modified and

< Hostagliss 1090 deleted

renamed Genamin SH 100 D P (Pellets)

< Hostagliss D deleted

Appretan Defoamer 5342

< Genapol 2808 renamed to Genapol EP 2564

< Hordaphos 123 deleted

< Genapol 2809 renamed to Genapol EP 2584

< Hordaphos 185 renamed to

< Emulsogen AL deleted

< Genapol 3938 renamed Genapol EP 2464

alternative Emulsogen COL 080 or COL 100

< Genapol EP 2454 deleted

< Hordaphos EP 300 deleted

< Genapol OA 020 deleted

< Hostamer AM deleted

< Genapol GX 030 deleted

< Nipacide HTP/3 replaced by Nipicide HTP/2

< Genapol X 020 deleted

< Nipacide SP replaced by

< Emulsogen PN extra deleted