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10
(2)
(4)
Mass
Volume
The anomaly is in the densities of K and Na. This is because as we move from Na to K the mass is increased
but volume has increased unusually more. So, the volume of K is lower than Na.
2.
(2)
Na
(3)
(4)
Cs
22
4.
Which one of the following ions has the largest size in aqueous solution?
(1) Rb+
(2)
Na+
(3)
K+
(4)
Li+
(2)
Na
(3)
Al
(4)
Mg
Sodium chloride gives a golden yellow colour to the bunsen flame, which is due to
(1) Sublimation of metallic sodium to give yellow vapour
(2) Photosensitivity of sodium
(3) Low ionization potential of sodium
(4) Emission of excess of energy absorbed as a radiation in the visible region
(2)
BeO
(3)
Li2O
(4)
H2O
(2)
KH
(3)
NaH
(4)
CsH
Na2CO3 can be manufactured by Solvays process but K2CO3 cannot be prepared because
(1) K2CO3 is more soluble
(2)
(4)
Na 2CO 3 + H 2O + CO 2
2NaHCO 3
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23
(2)
KOH
(3)
LiOH
(4)
RbOH
2LiOH(s)
Li 2O(s) + H 2O(g)
(2)
Washing soda
(3)
Bleaching powder
(4)
Quick lime
(2)
Cl2
(3)
Na2CO3
(4)
NaCl
Anode : Cl
1
Cl + e
2 2
(2)
KHCO3
(3)
CsHCO3
(4)
NaHCO3
(2)
Sodium
(3)
Potassium
(4)
Cesium
(2)
Brine
(3)
Quick lime
(4)
Sodium hydroxide
24
16. Which of the following halides has the highest melting point?
(1) NaCl
(2)
NaBr
(3)
NaF
(4)
NaI
(2)
Mg
(3)
Ca
(4)
Ba
(2)
Mg
(3)
Ca
(4)
Sr
(3)
CaCO3
(4)
CaSO4
(4)
LiCl
(2)
Ca(OH)2
(2)
NaCl
(3)
MgCl2
25
(2)
(3) Dehydration
(4)
Hydration
(1) CaCO3
(2)
1
CaSO4 H2O
2
(3)
CaSO42H2O
(4)
CaSO4
(2)
Ca(OH)2
(3)
CaO
(4)
CaCO3
(3)
2CaSO4H2O
(4)
CaSiO3
(4)
Ba(OH)2
(1) CaSO42H2O
(2)
CaSO4
1
HO
2 2
(2)
Sr(OH)2
(3)
Ca(OH)2
(2)
Calcium
(3)
Caesium
(4)
Francium
26
(2)
NaOH
(3)
BeO
(4)
LiOH
SECTION - B
Objective Type Questions
1.
(2)
NaNO3
(3)
KNO3
(4)
RbNO3
(2)
Mg
(3)
Be
(4)
Ba
Which one of the following statements is correct? The chlorides of group II metals
(1) Are all hygroscopic in nature
(2)
(4)
4.
27
(2)
(4)
(2)
(4)
The thermal stability of alkaline earth metal carbonates increases from Be to Ba. This is because
(1) Covalent nature decreases and Ionic nature increases
(2) Lattice energy increases
(3) Electropositive nature decreases
(4) None of these
The solubility of sulphates in water decreases from MgSO4 to BaSO4. It is due to the fact that
(1) Ionic nature increases
(2)
(4)
(2)
(4)
28
9.
Which one of the following statements concerning the compounds of Lithium is false?
(1) The hydroxide, carbonate, nitrate, decompose to give the oxide on heating
(2) It is the most electronegative among alkali metals
(3) The hydrogen carbonate cannot be isolated as a stable solid
(4) It forms a peroxide but not superoxide
(2)
NaH2PO3
(3)
NaH2PO4
(4)
Na2HPO4
H 3PO 2 + NaOH
NaH 2PO 2
Normal salt
(2)
NaHCO3
(3)
Na2SO4
(4)
Na2CO3
Kerosene oil
(3)
Water
(4)
Petrol
(2)
(4)
29
15. Chemical A is used for water softening to remove temporary hardness. A reacts with sodium carbonate to
generate caustic soda. When carbon dioxide is bubbled through A, it turns cloudy. What is the chemical
formula of A?
(2)
(1) CaCO3
CaO
(3)
Ca(OH)2
(4)
Ca(HCO3)2
(3)
Na
(4)
Cs
(2)
(2)
Mg(OH)2
(3)
2CaSO4 H2O
(4)
BaSO4
(3)
FeSO4 7H2O
(4)
Na2SO4 10H2O
(4)
Mg and Cl2
(2)
CuSO4 5H2O
(2)
K only
(3)
K and Mg only
MgCl2 Mg
2+
+ 2Cl
Mg
Cl2
(Cathode) (Anode)
KCl is unaffected by the applied voltage and amperage.
20. Alkaline earth metals form hydrated crystalline solids such as MgCl2 6H2O and CaCl2 6H2O. This is due to
(1) Smaller ionic size
(2)
(4)
30
21. Compared with the alkaline earth metals, the alkali metals show
(1) Greater hardness
(2)
Higher m.p.
(4)
(2)
Salt petre
(3)
Glauber's salt
(4)
Soda ash
23. CaCO3
A + B(gas)
H2O
Cl2
40C
Product D is
(1) CaCl2
(2)
Ca(OH)2
(3)
CaCl2.6H2O
(2)
(4)
All of these
(4)
CaOCl2
CaCO3
1200 K
CaO + CO2
HO
2
Ca(OH)2
(2)
CaO
(3)
SrO
(4)
BaO
31
(2)
Be3N2
(3)
(4)
BeC
(2)
Yellow colour
(3)
Orange colour
(4)
No colour
(4)
All of these
(2)
Ca(H2PO4)2
(3)
NaHCO3
(2)
Na2CO3 + CO2
(4)
Na2CO3 + H2O
SECTION - C
Previous Years Questions
1.
[NEET-2016]
32
2.
(2)
CaCO3
(3)
K2CO3
[Re-AIPMT-2015]
(4)
Na2CO3
Polarising power of Mg2+ is maximum amongst Ca2+, Mg2+, K+ and Na+, thus on heating, MgCO3 releases CO2
most easily.
3.
The function of "Sodium pump" is a biological process operating in each and every cell of all animals. Which
of the following biologically important ions is also a constituent of the pump?
[AIPMT-2015]
(1) Fe2+
(2)
Ca2+
(3)
Mg2+
(4)
K+
Solubility of the alkaline earth's metal sulphates in water decreases in the sequence
(1) Ba > Mg > Sr > Ca
(2)
(3)
[AIPMT-2015]
Sr > Ca > Mg > Ba
Which one of the alkali metals, forms only, the normal oxide, M2O on heating in air?
(1) Li
(2)
Na
(3)
Rb
(4)
[AIPMT (Prelims)-2012]
K
Equimolar solutions of the following substances were prepared separately. Which one of these will record the
[AIPMT (Prelims)-2012]
highest pH value?
(1) LiCl
(2)
BeCl2
(3)
BaCl2
(4)
AlCl3
(2)
CaCl2
(3)
CaBr2
[AIPMT (Prelims)-2011]
(4)
CaI2
Which one of the following is present as an active ingredient in bleaching powder for bleaching action?
[AIPMT (Prelims)-2011]
(1) CaCl2
(2)
CaOCl2
(3)
Ca(OCl)2
(4)
CaO2Cl
9.
33
[AIPMT (Mains)-2011]
List-II
(Substances)
(Composition)
(i) CaSO4.2H2O
(B) Epsomite
(ii) CaSO4.
(C) Kieserite
(D) Gypsum
(A)
(B)
(C)
(D)
(1) (i)
(ii)
(iii)
(iv)
(2) (iv)
(iii)
(ii)
(i)
(3) (iii)
(iv)
(i)
(ii)
(4) (ii)
(iii)
(iv)
(i)
1
HO
2 2
1
CaSO 4 H 2O
2
Epsomite
MgSO47H2O
Kiesertie
MgSO4H2O
Gypsum
CaSO42H2O
11. Which of the following alkaline earth metal sulphates has hydration enthalpy higher than the lattice enthalpy ?
[AIPMT (Prelims)-2010]
(1) CaSO4
(2)
BeSO4
(3)
BaSO4
(4)
SrSO4
[AIPMT (Prelims)-2010]
(2)
(4)
Electronegativity
34
(2)
BaO2
[AIPMT (Prelims)-2010]
(3)
MnO2
(4)
NO2
(1) CaCO3
Na2CO3
(3)
K2CO3
(4)
CaSO4.2H2O
CaCO 3
CaO + CO 2
Colourless gas
(A)
CaO + H 2O
Ca(OH) 2
Residue
(B)
Ca(OH) 2 + 2CO 2
Ca(HCO 3 ) 2
(B)
excess
(C)
Ca(HCO 3 ) 2
CaCO 3 + CO 2 + H 2O
(C)
(A)
15. Which of the following oxides is not expected to react with sodium hydroxide ?
(1) CaO
(2)
SiO2
(3)
BeO
[AIPMT (Prelims)-2009]
(4)
B2O3
(2)
(4)
(2)
BaSO4
(3)
MgSO4
[AIPMT (Prelims)-2007]
(4)
RaSO4
1
Size
18. The correct order of increasing thermal stability of K2CO3, MgCO3, CaCO3 and BeCO3 is
[AIPMT (Prelims)-2007]
(1) K2CO3 < MgCO3 < CaCO3 < BeCO3
(2)
(4)
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35
(2)
(3)
[AIPMT (Prelims)-2006]
+
(2)
(4)
2Na/Hg
Sodium amalgam
+ 2H 2O
2Na + + 2OH + H 2 + 2Hg
Cl + MF
CF + MI
(2)
(3)
Rb
(4)
Li
(2)
(4)
(2)
(4)
36
(2)
(4)
CaCl 2
Ca + 2Cl
At cathode : Ca2+ + 2e Ca
At anode : 2Cl Cl2 + 2e.
26. When a substance (a) reacts with water it produces a combustible gas (b) and a solution of substance (c) in
water. When another substance (d) reacts with this solution of (c), it also produces the same gas (b) on
warming but (d) can produce gas (b) on reaction with dilute sulphuric acid at room temperature. Substance
(a) imparts a deep golden yellow colour to a smokeless flame of Bunsen burner. Then (a), (b), (c) and (d)
respectively are
(1) Ca, H2, Ca(OH)2, Sn
(2)
K, H2, KOH, Al
(4)
2Na + 2H 2O
2NaOH(aq) + H 2 (g)
2NaOH + Zn
Na 2 ZnO 2 + H 2
Zn + H 2SO 4
ZnSO 4 + H 2
SECTION - D
Assertion Reason Type Question
1.
NaN3 and Na3N are both unstable. The reaction shown is the laboratory method for preparation of nitrogen.
Strong triple bond has a small bond length that makes the above compounds unstable.
2.
3.
37
A : Lithium is less reactive but the strongest reducing agent in aqueous solution.
R : Lithium shows positive reduction potential.
38
Be(OH) 2 + 2OH
Be(OH) 4
Beryllate ion
Be(OH) 2 + 2HCl + 2H 2O
Be(OH) 4 Cl 2
Beryllium hydroxide is amphoteric in nature.
14. A : Aq. solution of washing soda is alkaline in nature.
R : It is salt of weak acid and strong base.
Sol. Answer (1)
Aq. solution of washing soda is alkaline in nature because it is a salt of weak acid and strong base.
15. A : Be is sp hybridized in BeCl2 at room temperature.
R : Be is sp3 hybridized above 1200 K in BeCl2.
Sol. Answer (4)
The hybridisation of Be in BeCl2 is sp in vapour phase.
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