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TAIBAH UNIVERSITY
Introduction to Crystallography
and Mineral Crystal Systems
Geol 101
By
Dr. Hana Salem
Gypsum
Monoclinic
Dolomite
Crystallography
Emerald
Andalusite
Orthorhombic
Garnet
Isometric
Triclinic
Hexagonal
Definition of Crystallography
Crystal Morphology
Space groups for atom symmetry
Point groups for crystal face symmetry
Crystal Faces = limiting surfaces of growth
Crystal Morphology
Nicholas Steno (1669): Law of Constancy of Interfacial
Angles
Quartz
120o
120o
120o
120o
120o
120o
120o
related by a mirror
or a 2-fold axis
prism
pyramid
related by n-fold
axis or mirrors
dipryamid
Zone
Any group of faces || a common axis
Use of h k l as variables for a, b, c
intercepts
(h k 0) = [001]
If the MIs of 2 non-parallel faces are
added, the result = MI of a face between
them & in the same zone
ELEMENTS OF SYMMETRY
PLANES OF SYMMETRY
Any two dimensional surface that, when passed through the center of
the crystal, divides it into two symmetrical parts that are MIRROR
IMAGES is a PLANE OF SYMMETRY
A cube has 9 planes of symmetry, 3 of one set and 6 of another.
In the left figure the planes of symmetry are parallel to the faces of the cube form, in
the right figure the planes of symmetry join the opposite cube edges.
90o
Symmetry
AXES OF SYMMETRY
4-fold axes (90o)
http://home.planet.nl/~bartdw/sphalerite.htm
Symmetry
3-fold axes (120o)
AXES OF SYMMETRY
FOR EXAMPLE:
Crystal Form
There are only 7 symmetry classes; each mineral belongs to only ONE symmetry
class, and thus all crystals exhibit that symmetry only!
isometric
tetragonal
orthorhombic
hexagonal
monoclinic
triclinic
http://members.aol.com/jmichaelh/part1.html
Introduction to Mineral
Identification Basics
Welcome to the fascinating world of
Minerals. The purpose of this is to
present you with some of the basic
techniques used to identify minerals.
HEXAGONAL
TETRAGONAL
ORTHORHOMBIC
MONOCLINIC
TRIGONAL
TRICLINIC
Crystal Forms
During the process of crystallization, crystals assume various
geometric shapes dependent on the ordering of their atomic
structure and the physical and chemical conditions under which
they grow. These forms may be subdivided, using geometry, into
six systems.
CRYSTALLOGRAPHIC
AXES
(1) CUBIC
(2) TETRAGONAL
(3) ORTHORHOMBIC
(4) HEXAGONAL
(5) TRIGONAL
(6) MONOCLINIC
(7) TRICLINIC
ISOMETRIC CRYSTALS
a3
ISOMETRIC or CUBIC
In this crystal system there are 3
axes. Each has the same length (as
a2 indicated by the same letter a).
They all meet at mutual 90o angles
in the center of the crystal.
a1
ISOMETRIC
Basic Cube
are
ISOMETRIC CRYSTALS
ISOMETRIC CRYSTALS
a3
a3
a2
a1
a2
a1
ISOMETRIC CRYSTALS
Number of Faces
(1) Cube
6
(2) Octahedron
8
(3) Dodecahedron
12
(4) Tetrahexahedron
24
(5) Trapezohedron
24
(6) Trisoctahedron
24
(7) Hexaoctahedron
48
Cubic System
Spinel
Octahedron
Garnet
Trapezohedron
Fluorite
Cube
Garnet - Dodecahedron
Pyrite
Cube with
Pyritohedron
Striations
TETRAGONAL CRYSTALS
a
1
a
2
TETRAGONAL
Crystal Axes
TETRAGONAL CRYSTALS
TETRAGONAL
TETRAGONAL Crystal
Model
TETRAGONAL CRYSTALS
Form
(1) Pinacoid
Number
of Faces
2
4
8
16
TETRAGONAL CRYSTALS
WULFENITE
Same crystal seen edge on.
TETRAGONAL CRYSTALS
APOPHYLLITE on Stilbite
HEXAGONAL CRYSTALS
a3
a2
a1
HEXAGONAL SYSTEM
These 3 axes, labeled a1, a2, and a3, are the same
length. The fourth axis, termed c, may be longer
or shorter than the a axes set. The c axis also
passes through the intersection of the a axes set at
right angle to the plane formed by the a set.
HEXAGONAL CRYSTALS
HEXAGONAL
This model represents a hexagonal PRISM (the
outside hexagon - six sided shape). The top and
bottom faces are called PINACOIDS and are
perpendicular to the vertical c axis.
Within this model is the SCALENOHEDRAL
form. Each face is a scalenohedron. Calcite
often crystallizes with this form.
HEXAGONAL Crystal
Model
HEXAGONAL CRYSTALS
Form
(1) Pinacoid
Number
of Faces
2
12
12
6
12
24
HEXAGONAL CRYSTALS
These hexagonal
CALCITE crystals
nicely show the six
sided prisms as well as
the basal pinacoid.
TRIGONAL CRYSTALS
TRIGONAL FORMS
Form
Number
of Faces
(1Rhombohedrom
6
(2) Scalenohedron
12
Prism
RHOMBOHEDRON
Faces
Pyramid
Face
Quartz
SCALENOHEDRON
Rhodochrosite
ORTHORHOMBIC CRYSTALS
ORTHORHOMBIC
c
ORTHORHMOBIC Crystal
Axes
ORTHORHOMBIC CRYSTALS
ORTHORHOMBIC
This model shows the alternative axes
where the vertical c axis is not the
longest axis.
ORTHORHMOBIC
Crystal Model
ORTHROMBIC FORMS
Form
Number
of Faces
ORTHORHOMBIC CRYSTALS
ORTHORHOMBIC CRYSTALS
ORTHORHOMBIC CRYSTALS
Pinacoid View
Prism View
STAUROLITE
ORTHORHOMBIC CRYSTALS
MONOCLINIC CRYSTALS
MONOCLINIC
In this crystal form the axes are of
unequal length.
c
b
a
MONOCLINIC Crystal
Axes
MONOCLINIC CRYSTALS
MONOCLINIC
In this model the outside shape is
the PRISM. It looks like a
distorted brick - flattened out of
shape.Inside is the DIPYRAMID.
MONOCLINIC Crystal
Model
MONOCLINIC FORMS
Form
Number
of Faces
Mono. . Dipyramid
2
2
2
8
MONOCLINIC CRYSTALS
Top View
Mica
Gypsum
Orthoclas
TRICLINIC CRYSTALS
TRICLINIC CYSTAL
a
TRICLINIC Crystal
Axes
TRICLINIC CRYSTALS
TRICLINIC
Again in this model the outside
shape is the PRISM.
Located within the prism is the
DIPYRAMID.
TRICLINIC Crystal
Model
TRICLINIC FORMS
Form
Number
of Faces
TRICLINIC CRYSTALS
Thank You