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Polymer Characterization
Polymer characterization is the analytical branch of polymer science which is concerned
with the characterization of polymeric materials on a variety of levels. The characterization
typically has as a goal to improve the performance of the material. As such, many
characterization techniques should ideally be linked to the desirable properties of the material
such as strength, impermeability, thermal stability, and optical properties. These properties,
however is achieved through polymer-solvent interaction in a solution.
It should be pointed out that not all polymers can be dissolved, and even though when
they can, the dissolution process may take up to several days or weeks. According to
Rosen (1982), there is an assembly of general rules for polymer solubility, based on
Molecular weight of polymers plays an important role in their solubility. In a given solvent
at a particular temperature, as molecular weight increases, the solubility of a polymer
decreases. This same behavior is also noticed as crosslinking degree increases, since
strongly crosslinked polymers will inhibit the interaction between polymer chains and
solvent molecules, preventing those polymer chains from being transported into solution.
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The dissolution of a polymer is generally a slow process, which can take even several
weeks, depending on the structure and the molecular weight of a given polymer.
When a low molecular weight solute such as sucrose is added to water, the dissolution
process takes place immediately. The sugar molecules leave the crystal lattice
dipole-dipole
induction,
and
interaction,
hydrogen
bonding
(Figure 1a).
behavior
shown
by
and
between
the
them,
attraction
polymer
forces
molecules
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G = H - TS
Where:
G - the change in Gibbs free energy in the process
A positive H solvent and polymer prefer their own company, the pure materials
Illustration:
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2. Solubility Parameter
s and p represent the cohesive energy density (CED) for solvent and polymer,
respectively. This magnitude is a measure of the strength of the intermolecular forces
keeping the molecules together in the liquid state, and it is known commonly with the
name of solubility parameter. Its units are (cal/cm3)1/2, and the equivalences to the SI
units are the following
The solubility parameters are particularly useful when studying how capable is a polymer to
being dissolved in a given solvent. However, it should be pointed out that above equation is
valid only for solutions where strong polymer-solvent interactions do not take place. Numerous
tables showing solubility parameters for both solvent and polymers have been published. Some
examples are detailed below.
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p ) in equation, must be
smaller than 4.0. Thus, for example, according to the data shown from the, if we are trying to
dissolve nylon 6.6 in water, we will see that it is not possible thermodynamically, since ( water -
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Solvent
Effect
Application
Sodium
carboxymethyl
cellulose
Soapy water
Selective precipitation
onto clothing
fibers
Diblock
copolymers
Motor oil
Colloidal suspensions
dissolve at
high temperatures,
raising viscosity
Poly(ethylene
oxide)
Water
Proteins
Wine
Clarification of wines,
removes
colloidal matter
Polystyrene,
various
Triglyceride oils
Viscosity control,
phase-separates
during oil
polymerization
Poly urethane,
various
Esters, alcohols,
various
Poly(vinyl
chloride)
Polystyrene
Dibutyl phthalate
Solvent vehicle
evaporates, leaving
polymer film for glues,
solvent
enters mating surfaces
Plasticizes polymer
Poly(2,6-dimethyll,4-phenyl oxide)
Mutual solution;
toughens polystyrene
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soften polymer,
makes "vinyl"
Impact-resistant objects,
such as
Poly(methyl
methacrylate)
Poly(vinylidine
fluoride)
appliances
Automotive applications,
parts that might contact
gasoline
***
In many of these applications, the phase separation behavior of a polymer solution is manipulated in
order to create a desired effect.
References
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