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Article history:
Received 31 January 2014
Received in revised form 15 May 2014
Accepted 23 May 2014
Available online 23 June 2014
Keywords: Composite
material Ceramicsilica matrix Fiber
reinforcement
Thermal conductivity
Cubic cell model
Anisotropy degree
Potential anisotropy
Anisotropic efciency
a b s t r a c t
The paper employs a theoretical model to evaluate the thermal conductivity of composites under two
thermal assumptions which allow to solve the heat conduction equation. The composite is made of a
ceramic-silica matrix and a ber reinforcement. Three different materials are investigated as reinforcement, i.e. asbestos, steel and copper. The theoretical effective thermal conductivity is calculated along
the three directions for a non-consumed composite and during its consumption. Numerical solutions
of heat conduction in the composite are carried out. The anisotropy degree of the composite is
investigated for the composite during its consumption. The anisotropic efciency of the composite is
dened as ratio between the anisotropy degree of the composite and the potential anisotropy of the
two materials, i.e. the ratio between the thermal conductivity of the ber and the matrix. The
theoretical model allows to evaluate, under the two thermal assumptions, the anisotropic efciency of
the compos- ites which decreases with the increase of the potential anisotropy reaching a minimum,
which is only dependent on the geometry of the composite.
2014 Elsevier Ltd. All rights reserved.
1. Introduction
The thermal behavior of composites, made of two materials
with different thermal properties is important in several applications as thermal protections, heat shields, heat guides and in
cases where anisotropy is requested. Several researchers have
investi- gated composites with different approaches.
Torquato and Kim [1] computed the effective properties of heterogeneous media with an efcient simulation technique. Havis
et al. [2] used the nite difference method to simulate the thermal
behavior of ber reinforced composites, with the conclusion that
these materials can be considered homogeneous and thermally
anisotropic. Graham and McDowell [3] evaluated the effective
thermal conductivity of a composite made of two different materials by means numerical simulations of the microscopic structure
of the composite. Islam and Pramila [4]
carried out
a
numerical analysis of the transverse thermal conductivity of
composites with imperfect interfaces. Dasgupta and Agarwal [5]
developed a 2-D thermal method based on
series/parallel
arrangement. Gu and Tao [6] studied a periodic composite with
contact resistance with the conclusion that the contact resistance
can change the effective conductivity dramatically. James and
Harrison [7] evaluated the effective thermal conductivity of
composites, made of two
Gori),
http://dx.doi.org/10.1016/j.ijheatmasstransfer.2014.05.047
0017-9310/ 2014 Elsevier Ltd. All rights reserved.
sandra.corasaniti@
142
F. Gori, S. Corasaniti / International Journal of Heat and Mass Transfer 77 (2014) 653661
Nomenclature
Latin
a
b
c
k
L
q
Q_
transfer
s
s1 , s 3
s2
T
Greek
D
n
thickness in x, y directions
thickness in x, y directions
specic heat
thermal conductivity
length
heat ux
heat
composite density
reinforcement volume fraction
anisotropic efciency
potential anisotropy
v
d
Subscripts
f
ber
m
matrix
max
maximum
min
minimum
x, y, z
directions
i, j, k
versors
nite difference
anisotropy degree
s1
s2
a
b
2. Theoretical models
s3
The elementary cubic cell of the material is presented, in threedimensions, in Fig. 1, with the ber reinforcement in the middle
s2
4a2
/
2
s1 s2 s3 2a b
1
qx
~q @B qAy C
qz
1
kx kxy kxz
B
C!
r T @ kyx ky kA
rT
yz
kzx kzy kz
0
1
kx
B
@0
0
0
ky
0
0
C
0A
kz
a
a
2a b
ki
Q_ i
Li
DT i Ai
F. Gori, S. Corasaniti / International Journal of Heat and Mass Transfer 77 (2014) 653661
The heat conduction equation can be solved under the two thermal
assumptions of parallel isotherms, or parallel isothermal lines (PIL),
Q_ x kx Ax
Dx
kx
T1
T4
2a b s1 s2 s3 2a b
143
km Am
T1
T2
a
T1
T2
kf Af
T1
km 2a b
T2
20
s1
Am s1 s2 s3 2a b b s2
7
n
2
Q_ II
2
km 4a kf 2a b
z
and
Af b s2
o T
2
4a
T3
21
s2
Q_z III km 2a
b
giving
Q_
Q_ zI
T3
T4
22
s3
x
km s1 s2 s3 2a b b s2 kf b s2
T1
T2
T1
km s1 s3 2a b kf 2a b s2
T2
T3
b
10
Qx_ III km s1 s2 s3 2a b b s2 kf b s2
T4
T2
T3
T3
_
s1
zQ
T4
2
km 2a b
Q_
a
x
T2
T2
_ II
xQ
T3
kf 2a b s2
km s1 s3 2a b
km s1 s2 s3 2a b b s2 kf b s2
24
4a2
2a b
12
25
T1
km 4a2 kf
III
11
_ II
Q
h z
s2
T3
23
km 2a b
Q_ z
s3
T2
T1
T4
s1
Q_ z
s3
2
km 2a b
Q_ z
s2
km 4a kf 2a b
26
4a
T3
T4
Q_
13
km s1 s2 s3 2a b b s2 kf b s2
14
T1
T4
Q_ x
s2
Q_ x
T4
kx s1 s2 s3
kx s1 s2 s3
s2
km 4a2 kf
s1
2a
Q_ x
km s1 s2 s3 2a b b s2 kf b s2
_
b
Q x
km s1 s3 2a b kf 2a b s2
17
Q_ z
2a b
4a2
28
kz
16
s3 Q_ z
km 2a b
15
27
s1
Q_ x
2a b
s3
kz 2a b
T1
km s1 s2 s3 2a b b s2 kf b s2
b
Q_ x
km s1 s3 2a b kf 2a b s2
s3 Q_ z
s1 s2
s 1
Q_ z
2a
T4
III
T1
s2
s3
29
2a b
s 1 s 3
2
km 2ab
4a2 k
s2
2
4a2
m kf 2ab
kx
2a s1 s2 s3
km s 1 s 2 s3 2a b b s2 kf b s2 b
b s1 s2 s3
2a b km s1 s3 kf s2
_ the matrix
transfer throughout the matrix, Q m ; the_ ber, Q f , and
_
and ber, Q ,
18
Q_z kz Az
DT
kz 2a b 2
Dz
T1
T4
s1 s2 s3
19
_ m _Q f _ Q
Q_ x Q
30
The heat transfer throughout the matrix, Q_ m ; with cross section
(s1 + s3) (2a + b) and thickness (2a + b) is
T 1 T
Q_m km s1 s3 2a b
2a b
31
T1
Q_ f kf s2 b
T4
32
2a b
Q_ km
T1
2s2 a
T2
33
h
Q_ 2a
b
T3
34
The heat transfer through the last layer of matrix, with cross section
(2s2 a) and thickness a is
Q_ km 2s2 a
T3
T4
35
Q_ s2 T 1
T4
1
b
km 2a kf
T
T 1
kx 2a b s1 s2 s3 4
2a b
Dx
37
kf
s2 b
s2
2a b
1
1
b
km 2a kf
38
kx
b s2
s
2ab 2
km s1 s3 kf
s1 s2 s3
km
b
2a kf
39
The total heat transfer in the z direction is the sum of the heat
trans- fer through the matrix, Q_ m , and the matrix and ber, Q_ ,
Q_ z Q_ m Q_
40
The heat transfer through the matrix, with cross section (4a2) and
thickness (s1 + s2 + s3), is
T1
Q_ m km 4a2
T4
41
s1 s2 s3
s1
sk3
2a
4a
T2
s
1
s2
2a b2
T 1
T 4
45
kf
"
4a
km 2a
s1 s2 s3
s1 s3
ks2
km
f
4a
46
Table 1 reports the thermo-physical properties (assumed constant with the temperature) used in the present theoretical model
and numerical simulations. The matrix is made of ceramic-silica
while three materials are assumed as ber, i.e. asbestos, steel
and copper.
The thermal conductivities of the ber differ by several orders
of magnitude, allowing to study the effect of the ratio between
the thermal conductivities of the ber and the matrix.
Numerical calculations have been performed with a housemade code for the same geometrical conguration. In order to estimate kx and kz heat transfer has been numerically computed by
setting a temperature gradient in the x direction (i.e. adiabatic
walls normal to y and z directions), and z direction.
Energy equation has been solved with a second order nite-differences scheme by using a non-iterative steady-state explicit
method in a grid of hexahedral cells
2
42
@ T @ T @ T
0
@ x2 @ y2 @ z2
47
kx
qx
DT x =Lx
48
qz
DT =L
z
T1
The heat transfer through matrix and ber, Q_ is the same throughout
each cross section, in steady state. The heat transfer through the
rst
layer of matrix, with cross section 2a 2 4a2 and thickness s1 is
b
i
h
Q _ km
4. Numerical simulations
DT x
kx s1 s2 s3 km s1 s3
s s
36
Q_ x kx Ax
T2
km
The heat transfer through the intermediate layer of ber, with cross
section (2s2 a) and thickness b is
Q_ kf 2s2 a
4a2
49
The heat transfer through the intermediate layer of ber, with the
same cross section 2a b2 4a2 but thickness s2 is
Q_ kf 2a
b
4a2
T2
T3
s2
43
The heat transfer through the last layer of matrix, with the same
cross section 2a b2 4a2 but thickness s3 is
Q_ km 2a
b
4a2
T3
T4
s3
44
Silica
Asbestos
Steel
Copper
2200
2000
7800
8930
[kg/m ]
c [J/(kg K)]
k [W/(m K)]
kf/km
1200
795
500
400
1.7
0.7
33.97
398
0.412
19.98
234.12
10
PIL
PFL
Num.
kx [W/mK]
0
0
3
s [mm]
100
5. Theoretical results
5.1. Effective thermal conductivities in the two directions
PIL
PFL
Num.
kx [W/mK]
80
60
40
20
0
0
s [mm]
1.8
1.8
1.7
1.7
k z[W/mK]
kx [W/mK]
1.6
1.6
PIL
PFL
Num.
1.5
PIL
PFL
Num.
1.5
1.4
1.4
1.3
1.3
1.2
0
3
s [mm]
3
s [mm]
PIL
PFL
Num.
kz [W/mK]
0
0
s [mm]
Fig. 7. Effective thermal conductivity in z direction, kz, for steel ber.
PIL
PFL
Num.
kz [ W/mK]
kx
kz
50
0
0
s [mm]
Fig. 8. Effective thermal conductivity in z direction, kz, for copper ber.
kf
km
51
v d
52
vPIL
d
kf =km
2
s1 s3 s2 2a b
n
b
2
2
4a d 2a
2a s1 s2 s32
s1 s2 s3 2ab b s2 =ds2 b
4a
b s1 s2 2 s3
2ab s1 s3 =ds2
53
tions are intermediate.
1.06
PIL
PFL
1.05
1.04
1.03
1.02
1.01
1.00
0.99
0.98
0
3
s [mm]
30
PIL
PFL
PIL
PFL
25
20
15
10
5
0
0
0
s1 s3
d
s1 s2 s3
2a b
b s2
s2
2ab
2
2
4a
s1 s2 s3
d
kf =km
s [mm]
s [mm]
vPFL
b
d
2a d
54
2.60
4a bbs2
s1 s3
PIL
PFL
2.55
2.50
2.45
2.40
0
s [mm]
Fig. 12. Anisotropic efciency v of the composite with asbestos ber.
0.20
100
PIL
PFL
PIL
PFL
10
0.15
0.10
0.05
0.1
0.00
0.01
0
0.01
10
100
1000
s [mm]
Fig. 15. Anisotropic efciencies, vPIL and vPFL, of the composite vs. the potential
anisotropy, d.
0.20
PIL
PFL
0.15
0.1
0.10
0.05
0.00
0
6. Conclusions
s [mm]
Fig. 14. Anisotropic efciency v of the composite with copper ber.
vPIL min
s2 s1
s3 2a
s2 s1
s3 2a
55
s1 s2 s3 2 2a2a b b2
kx
kz
vPFL min
s1 s2 s3 s1 s3 2a
b
s2 4ab b
56
Conict of interest
None declared.
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