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(Received 6 October 2014; accepted 26 December 2014; published online 20 January 2015)
In this study, we create a multifunctional metal surface by producing a hierarchical
nano/microstructure with femtosecond laser pulses. The multifunctional surface exhibits combined
effects of dramatically enhanced broadband absorption, superhydrophobicity, and self-cleaning. The
superhydrophobic effect is demonstrated by a falling water droplet repelled away from a structured
surface with 30% of the droplet kinetic energy conserved, while the self-cleaning effect is shown
by each water droplet taking away a significant amount of dust particles on the altered surface.
C 2015
The multifunctional surface is useful for light collection and water/dust repelling. V
AIP Publishing LLC. [http://dx.doi.org/10.1063/1.4905616]
I. INTRODUCTION
Nature provides many examples of multifunctional properties on a biological surface.1,2 One of the examples is the
water-repelling lotus leaves.1,3,4 The lotus leaves have a number of functionalities, such as superhydrophobicity, selfcleaning, and defense against pathogens.1,3 Studies have
shown that the lotus leaf surface has a hierarchical structure
containing a larger micro-scale structure in the range of
1050 lm and a finer structure in the range of 200 nm2 lm.1,3
This hierarchical structure along with a hydrophobic epicuticular wax coating imparts the superhydrophobicity to lotus
leaves. Furthermore, the hierarchical surface structure significantly reduces the adhesion of contaminants to the surface.3
Both enhanced hydrophobicity and reduced contaminant adhesion produce the lotus self-cleaning effect, often referred as
the lotus effect.3 The lotus self-cleaning is achieved when
water drops roll over the leaves, pick up the dust particles, and
carry them away when rolling off the leaves. Another example
of the multifunctional biological surface is the Morpho butterfly wing. The surface structures of the wings produce a blue
color and also make the wing surface superhydrophobic and
self-cleaning.5,6
Recently, studies have shown that femtosecond laser
surface processing can produce surface structures that can
significantly modify optical712 or wetting1215 properties of
metals. However, the metal blackening711 and wetting
effect1315 were each demonstrated individually. Here, we
demonstrate a laser nano/microstructuring technique to create a combined black, superhydrophobic, and self-cleaning
effect on a metal surface. The enhanced light absorption is
useful whenever light collection is needed, for example, in
sensors and solar energy absorbers. The superhydrophobicity
and self-cleaning effects will repel water and dust, and
improve the performance and reduce the maintenance of the
devices that utilize these surfaces. Furthermore, the superhydrophobicity should also enable other highly desirable
functionalities, such as anti-corrosion,16 anti-icing,1719 antibiofouling,19,20 anti-microbial,21 low flow resistance,21,22
a)
b)
0021-8979/2015/117(3)/033103/5/$30.00
and platelet anti-adhesion,23 which are intrinsically associated with the superhydrophobicity. Using anti-icing as an
example, water drops do not have enough time to freeze on a
superhydrophobic surface before they roll off the surface.24
Some potential applications for anti-icing surfaces include
protection of aerofoils, power transmission lines, pipes of air
conditioners and refrigerators, and radar or telecommunication antennas.24,25
II. EXPERIMENTAL SETUP
In this study, we use an amplified Ti:sapphire laser system that generates 65-fs pulses with a central wavelength of
800 nm and at a maximum pulse repetition rate of 1 kHZ.
The laser beam is focused onto the sample surface by a lens
onto a sample mounted on a computerized XY-translation
stage. The samples in our study are platinum, titanium, and
brass. Each sample is textured with an array of parallel
microgrooves covered by extensive nanostructures. The
platinum sample is processed at laser fluence of 9.8 J/cm2.
The titanium sample is processed at laser fluence of 7.6 J/
cm2. Brass is processed at laser fluence of 3.9 J/cm2. The
orientation of microgrooves is controlled by the scan direction. A scanning electron microscope (SEM) and a 3D laser
scanning microscope are used to examine the surface structures. Superhydrophobic properties are studied by measuring both water contact angle and the surface tilt angle for
water sliding. The self-cleaning properties are studied with
real-life dust particles collected from a vacuum cleaner. For
cleaning, we use rolling and falling water drops. The rolling
drops with nearly zero kinetic energy are produced by
pipetting water drops near the sample surface, while the
falling drops are produced by pipetting drops at a height of
38 cm above the sample surface. The diameter of the
pipetted water drops is in the range of 25 mm. The selfcleaning action is recorded with a video camera. To characterize the optical properties, we measure the total hemispherical optical reflection of the samples using a PerkinElmer Lambda 900 spectrophotometer and Bruker IFS 66/S
FTIR spectrometer, each equipped with an integrating
sphere. The two spectrometers allow us to measure the
117, 033103-1
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FIG. 1. (a) Photograph of superhydrophobic black platinum; (b) laser microscopy image showing micro-structures on the platinum surface; (c) and (d) SEM
images showing the detailed hierarchical structures on the platinum surface; (e) and (f) laser microscopy images showing surface structures on brass and
titanium.
characterize the hydrophobicity of the treated platinum surface, we measure the water contact angle on the surface to be
158 , and a water drop will slide on the treated surface at a tilt
angle of only 4 . More remarkably, when a drop of water is
released and falls towards the treated surface, the water droplet is repelled by the treated surface to such a degree that it
bounces off the surface, lands again due to gravity, and bounces again and off the treated surface area, as shown in Fig. 2.
Here, the water drop is released 19 mm above the surface,
reaches a height of 5.3 mm after the first bounce, and lands
13.75 mm away from the first bounce before bouncing off the
surface. About 30% of the water droplet kinetic energy is conserved from the first bounce. The two bouncing motions last
less than 0.5 s, and the laser-treated surface remains completely dry afterwards [Fig. 2(f)].
FIG. 2. (a)(f) Video clips showing a water droplet bouncing off a superhydrophobic black platinum surface. The surface has a tilt angle of 8 .
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FIG. 3. (a)(e) Video clips showing a superhydrophobic platinum surface self-cleaned by water droplets. The surface has a tilt angle of 8 ; (f) an untreated
platinum surface accumulates a puddle of water with floating dusts.
with dust particles. In contrast to our superhydrophobic surface, water remains on the untreated surface with all the dust
particles floating inside [Fig. 3(f)]. After water vaporizes, all
the dust particles will remain on the surface. In our study, we
repeatedly perform 20 cleanings on the superhydrophobic
surface and did not observe any degradation of the
self-cleaning effect.
Self-cleaning surfaces should have the following properties: (i) large water contact angle exceeding 150 , (ii) small
sliding angle (<10 ) to cause water drops easily roll off the
surface, and (iii) the adhesion between the surface and dust
particles on the surface should be smaller than that between
the dust particles and water.3,27,3133 The surface structures
we produced benefit self-cleaning in two ways. First, the surface structures turn a metal surface superhydrophobic; second, the surface structures also reduce the adhesion of dust
particles to the solid surface.3 We also produce
FIG. 4. Supplementary video demonstrating the self-cleaning effect of the platinum sample. (Multimedia view) [URL: http://dx.doi.org/10.1063/1.4905616.1]
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FIG. 5. Spectral reflectance of the black brass, black platinum, and black titanium as a function of wavelength. Spectral reflectance of three mechanically polished metals without laser treatment is also shown for a
comparison. Dashed line shows the spectral reflectance of an ideal solar
absorber.
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absorption, superhydrophobicity, and self-cleaning. This surface also has other highly desirable functionalities such as
anti-corrosion, anti-icing, anti-biofouling, and self-sanitation,
since these properties are directly related to
superhydrophobicity.
ACKNOWLEDGMENTS
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2
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