hernandez (sh28928) fsemAP04Ch6 Lachman (92881) 1

This print-out should have 35 questions. of the hotter water.

Multiple-choice questions may continue on Energy1 = Energy2
the next column or page find all choices
before answering. (4.18 J/g C) (86 g)(T 39) C

Hello everyone. Be sure to complete these = (4.18 J/g C) (280 g)(60 T ) C

by 9 p.m. Pacific time on the due date. Then, Solve for T :
be sure to go back the next day and look at 86 T (86 39) = (280 60) 280 T
the solutions for the ones you missed to help 86 T + 280 T = (280 60) + (86 39)
you study for the test. (86 + 280) T = (280 60) + (86 39)
(280 60) + (86 39)
001 10.0 points T =
The process of water freezing to form ice at 86 + 280
0 C is = 55 C

1. neither exothermic nor endothermic. 003 10.0 points

Refer to the potential energy diagram shown
2. an exothermic phase change. correct below.
10
3509
3. an exothermic chemical reaction. 8
7

Energy (kJ)
4. an endothermic chemical reaction. 6 B
3005
5. an endothermic phase change. 4
3
Explanation: 2 A
2501
Heat must be removed from the water for it
0
to freeze. This is exothermic. 0 1 2rxn
3 progress
4 5 6 7 8 9 101112

002 10.0 points What is the change in enthalpy (H) for

A 86 g sample of water with a temperature of the reaction
39 C is added to 280 g water at 60 C in an A B?
insulated container. What is the final temper-
ature after thermal equilibrium is reached? 1. 150 kJ
1. 50 C 2. 50 kJ
2. 0.0182C 3. 250 kJ
3. 55 C correct 4. +50 kJ correct
4. 72 C 5. +300 kJ
5. 44 C Explanation:
Hi = HA = 250 kJ
6. 234 C Hf = HB = 300 kJ
H = Hf Hi
Explanation:
= HB HA
Call T the final temperature. T is between
39 C and 60 C. The energy required to heat = (300 250) kJ
the cooler water is obtained from the cooling = 50 kJ
 hernandez (sh28928) fsemAP04Ch6 Lachman (92881) 2
Notice that H is positive. The reaction is Methane has a heat of combustion of about
endothermic. 50 kJ/g. About how much heat would be
produced if 12 moles of methane were burned?
004 10.0 points Methane has a molecular formula of CH4 .
A sample of 2.43 grams of Z is dissolved into
500 grams of water which is in a styrofoam 1. over 15,000 kJ
coffee cup. The temperature is monitored and
is found to rise from 24.663 C to 25.044 C. 2. 600 kJ
What is Hsolution for substance Z? Assume
no heat is lost/gained by the cup itself. The 3. 800 kJ
specific heat of water is 4.184 J/g C and the
molecular weight of Z is 118 g/mol. 4. 12,000 kJ

Correct answer: 38.7 kJ/mol of Z. 5. 9,600 kJ correct

Explanation: Explanation:
mZ = 2.43 g mwater = 500 g Hcomb = 50 kJ/g n = 12 mol
MWZ = 118 g/mol SH = 4.184 J/g C MWmethane = 16 g
T = 25.044 C 24.663 C = 0.381 C

Heat = (SH)(mwater )(T )  50 kJ  16 g 

(12 mol) = 9, 600 kJ
Then divide the heat by the number of moles, g mol
which is mass/MW.
007 10.0 points
005 10.0 points
Methane has a heat of combustion of about
A piece of chocolate cake is burned with oxy-
50 kJ/g. About how much heat would be
gen in a bomb calorimeter. The temperature
produced if 15 moles of methane were burned?
of 4175 grams of H2 O in the calorimeter is
raised by 0.32 K. What is E, including the
1. 12,000 kJ correct
sign, for the combustion of this piece ot choco-
late cake? Assume no heat is absorbed by the
2. over 15,000 kJ
calorimeter. The heat capacity of water is
1.0 cal/g K and the heat of vaporization of
3. 800 kJ
water is 540 cal/g.
4. 9,600 kJ
Correct answer: 1.336 kcal.
Explanation: 5. 750 kJ
T = 0.55 K m = 4175 g
HC = 1.0 cal/g K Hvapor = 540 cal/g Explanation:
1 cal Hcomb = 50 kJ/g n = 15 mol
(0.55 K) (4175 g) = 1336 cal MWmethane = 16 g
gK
is absorbed by the water.
Since the calorimeter does not absorb any Molar Hcomb = (50 kJ/g)(16 g/mol)
heat, the sample released 1336 cal. This reac- = 800 kJ/mol .
tion is exothermic and E is negative:
kcal The amount of heat produced from burning
1336 cal = 1.336 kcal 15 moles is
1000 cal

006 10.0 points (15 mol)(800 kJ/mol) = 12, 000 kJ .

 hernandez (sh28928) fsemAP04Ch6 Lachman (92881) 3
To do this, reaction 2 must be written as the
008 10.0 points reverse reaction, which changes the sign of
What would be the final temperature of the H2 :
system if 20 g of lead at 100 C are dropped Reaction Hf0
into 30 g of water at 20 C in an insulated (kcal/mol)
container? Cgraphite + O2 CO2 94.05
1
Correct answer: 21.6005C. CO2 CO + O2 +67.64
2
Explanation: 1
Cgraphite + O2 CO 26.41
2
009 10.0 points kcal
Total heat produced = 26.41
When 1 mol of methane is burned at constant mol
pressure, 890 kJ/mol of energy is released as
heat. If a 2.79 g sample of methane is burned 011 10.0 points
at constant pressure, what will be the value of The combustion reaction for Compound X is
H? (Hint: Convert the grams of methane given.
to moles. Also make sure your answer has the X(s) + 6 O2 (g) 8 CO2 (g) + 8 H2 O()
correct sign for an exothermic process.)
H for this reaction is equal to 5120
Correct answer: 155.194 kJ. kJ/mol. Hf for CO2 (g) is 393.5 kJ/mol
Explanation: and Hf for H2 O() is 285.8 kJ/mol.
CH4 : Hc = 890 kJ/mol m = 2.79 g Calculate Hf0 for Compound X.
H = ?
Correct answer: 314.4 kJ/mol.

mol CH4
 Explanation:
nCH4 = (2.79 g CH4 ) Reactants:
16 g CH4
Hf O2 (g) = 0 kJ/mol
= 0.174375 mol CH4 Products:
Hf CO2 (g) = 393.5 kJ/mol
H = 385.8 kJ/mol
H = (0.174375 mol)(890 kJ/mol) = 155.194 kJ f H2 O(l)
X X
Hrxn

= n Hf prod n Hf rct
010 10.0 points
The following reactions were carried out with Hrxn

= 8Hf CO2 + 8Hf H2 O Hf X
excess O2 (g) in the reaction vessels to ensure Hf X = 8Hf CO2 + 8Hf H2 O Hrxn

complete combustion: h
Experiment: H (kcal/mol rxn) = 8 (393.5 kJ/mol)
C(graphite) + O2 (g) CO2 (g) 94.05 i
1 +8 (285.8 kJ/mol)
CO(g) + O2 (g) CO2 (g) 67.64
2 (5120 kJ/mol)
It is not possible to alter the conditions in
= 314.4 kJ/mol
the reactor to produce pure CO(g). Calculate
Hf0 for 1 mol CO(g).
012 10.0 points
Correct answer: 26.41 kcals. Calculate the heat of formation of butane
Explanation: (C4 H10 ) using the following balanced chemi-
Sum the two equations in such a way so cal equation and information. Write out the
as to obtain the formation reaction for CO. solution according to Hesss law.
 hernandez (sh28928) fsemAP04Ch6 Lachman (92881) 4
C(s) + O2 (g) CO2 (g)
Hf0 = 396.8 kJ/mol U = q + w
1 = 396 kJ + (556 kJ)
H2 (g) + O2 (g) H2 O()
2 = 160 kJ .
Hf0 = 283 kJ/mol
13
4 CO2 (g) + 5 H2 O C4 H10 (g) + O2 (g) 014 (part 2 of 2) 10.0 points
2 Will the pressure of the gas be higher or lower
Hc0 = 2877.6 kJ/mol
when these changes are completed?
Correct answer: 124.6 kJ.
1. lower correct
Explanation:
Hf of butane (C4 H10 ) = ? 2. higher
The balanced equation is
Explanation:
If the heat added had exactly matched the
4 C(s) + 5 H2(g) C4 H10 (g)
amount of energy lost due to the work of the
Reaction Hf0 gas (i.e., if q had been equal but opposite
in sign to w), then U would have been 0
(kJ/mol)
and the temperature of the gas would not
4 C(s) + 4 O2 (g) 4 CO2 (g) have changed. Because less heat was added,
4(396.8) = 1587.2
however, and the gas was allowed to expand
5
5 H2(g) + O2 (g) 5 H2 O() further, the temperature of the gas would
2 have had to decrease, and consequently the
5(283) = 1415
4 CO2 (g) + 5 H2 O pressure of the gas would be lower at the end.
13
C4 H10 (g) + O2 (g) 015 10.0 points
2
2877.6 A truck at the top of a hill has higher gravita-
4 C(s) + 5 H2 C4 H10 (g) 124.6 kJ tional potential energy than when it is at the
Hf C4 H10 bottom of the hill. Why does it roll downhill?
= (124.6 kJ/mol)(1 mol) = 124.6 kJ
1. to lower its potential energy correct
013 (part 1 of 2) 10.0 points
A gas sample in a piston assembly expands, 2. to increase the entropy of the universe
doing 556 kJ of work on its surroundings at
the same time that 396 kJ heat is added to the 3. to decrease the entropy of the universe
gas. What is the change in internal energy of
the gas during this process? 4. to increase its kinetic energy
Explanation:
Correct answer: 160 kJ. Energy is required to keep a truck at the
Explanation: top of a hill. By rolling to the bottom of the
The change in internal energy U is given hill, the trucks potential energy is lowered.
simply by summing the two energy terms in-
volved in this process. We must be careful, 016 10.0 points
however, that the signs on the energy changes When separated from a water solution,
are appropriate; in this case, internal energy CuSO4 forms a hydrate with 5 water
will be added to the gas sample by heating molecules per formula unit. If 43 g of an-
(so q is positive), but the gas does work on its hydrous CuSO4 are dissolved in water, what
surroundings as it expands (so w is negative): mass of the hydrate could be recovered from
w = 556 kJ q = 396 kJ the solution?
 hernandez (sh28928) fsemAP04Ch6 Lachman (92881) 5

Correct answer: 67.2466 g. Correct answer: 101.669 g.

Explanation: Explanation:
water molecules per formula unit = 5 molec V = 11 cm3 density = 7.28 g/cm3
manhydrous CuSO4 = 43 g
First we find the mass of tin reacted:
The formula of the copper sulfate hydrate
would be CuSO4 5 H2 O.
We can use the formula weight of anhydrous 7.28 g Sn
copper sulfate to convert from grams CuSO4 ? g Sn = 11 cm3 Sn
1 cm3 Sn
to moles CuSO4 : = 80.08 g Sn

? mol CuSO4 = 43 g CuSO4 We use the molar mass of Sn to convert to

moles Sn. Each mole of SnO2 contains 1 mol
1 mol CuSO4
of Sn atoms. We use this ratio to convert to
159.608 g CuSO4 moles of SnO2 , and the molar mass of SnO2
= 0.269409 mol CuSO4 to convert to grams SnO2 :
For every one mole of copper sulfate there
1 mol Sn
are five moles of water molecules: ? g SnO2 = 80.08 g Sn
118.7 g Sn
1 mol SnO2 150.7 g SnO2

? mol H2 O = 0.269409 mol CuSO4 1 mol Sn 1 mol SnO2
5 mol H2 O = 101.669 g g SnO2

1 mol CuSO4
= 1.34705 mol H2 O
018 10.0 points
This is the number of moles of water. We For the reaction
can use the formula weight of water to convert
from mol H2 O to g H2 O: ? N2 + ? H2 ? NH3 ,
what is the maximum amount of NH3
18.02 g H2 O (17.0305 g/mol) which could be formed from
? g H2 O = 1.34705 mol H2 O
1 mol H2 O 8.42 mol (28.0134 g/mol) of N2 and 7.39 mol
= 24.2674 g H2 O of H2 (2.01588 g/mol)?
This is the mass of water, but we want the Correct answer: 83.9037 g.
mass of the entire hydrate. For this mass we
need to add the mass of the anhydrous copper Explanation:
sulfate to the mass of the water it will combine MWNH3 = 17.0305 g/mol nN2 = 8.42 mol
with: MWN2 = 28.0134 g nH2 = 7.39 mol
MWH2 = 2.01588 g
This is a limiting reactant problem because
? g CuSO4 H2 O = 43 g CuSO4 the amounts of more than one reactant are
+ 24.2674 g H2 O given. The balanced chemical equation is
= 67.2674 g
N2 + 3 H2 2 NH3 ,

017 10.0 points and either N2 or H2 will limit the amount of

How much SnO2 could be produced from NH3 that can form.
11 cm3 of tin metal (density 7.28 g/cm3 ) if Assume that N2 is the limiting reactant.
it all reacted? The amount of NH3 that can be produced is
 hernandez (sh28928) fsemAP04Ch6 Lachman (92881) 6
Explanation:
The unbalanced reaction is
2 mol NH3
? g NH3 = 8.42 mol N2
1 mol N2
HNO3 + KI KNO3 + I2 + NO + H2 O
17.0305 g NH3

1 mol NH3 Balance the half reactions:
= 286.794 g NH3 .
1 0
Assume that H2 is the limiting reactant. 2 I I2 +2 e

The amount of NH3 that can be produced is +5 +
+2
N O3 + 4 H + 3 e N O + 2 H2 O

2 mol NH3 Equate the e :

? g NH3 = 7.39 mol H2
3 mol H2
17.0305 g NH3 h 1 0 i
3 2 I I2 +2 e
1 mol NH3
= 83.9037 g NH3 . h +5
+
+2 i
2 N O3 + 4 H + 3 e
N O + 2 H 2 O
Since a smaller amount of NH3 can be pro-
duced with the given amount of H2 , H2 is the Add the balanced half reactions:
limiting reagent, and a maximum of 83.9037 g +
2 NO 3 + 8 H + 6 I

of NH3 can be produced. 3 I2 + 2 NO + 4 H2O
Neutralize the remaining charges with ex-
019 10.0 points isting counterions:
Write and balance the equation for the re- 8 HNO3 + 6 KI
action between nitric acid and potassium io- 6 KNO3 + 3 I2 + 2 NO + 4 H2O
dide. The products are potassium nitrate,
iodine, nitrogen monoxide, and water. What 020 10.0 points
is the coefficient of potassium nitrate in the Consider the combustion of 6.1 mol of liquid
balanced equation? ethanol (C2 H5 OH) to gaseous water and car-
bon dioxide. Calculate the enthalpy change
1. 6 correct for this reaction. The pertinent enthalpies of
formation (in kJ/mol) are
2. 7 Hf H2 O = 241.8 Hf CO2 = 393.5
Hf C2 H5 OH = 277.7
3. None of these
Correct answer: 7531.67 kJ.
4. 1
Explanation:
5. 4 nC2 H5 OH = 6.1 mol
The reaction is
6. 2
C2 H5 OH + 3 O2 3 H2 O + 2 CO2
7. 3
Reactants:
8. 12 Hf C2 H5 OH = 277.7 kJ/mol
Hf O2 = 0 kJ/mol
9. 5 Products:
Hf H2 O = 241.8 kJ/mol
10. 10 Hf CO2 = 393.5 kJ/mol
 hernandez (sh28928) fsemAP04Ch6 Lachman (92881) 7
T = 0 C = 273 K
X X
0
Hrxn = n Hf0prod n Hf0rct P V = nRT
   nRT
kJ V =
= 3 241.8 P
mol rxn Latm


  (0.0636607 mol) 0.08206 molK
kJ =
+2 393.5 1 atm
mol rxn (273 K)

kJ = 1.42615 L
277.7
mol rxn
 
kJ
+3 0
mol rxn 022 10.0 points
kJ 1 mol rxn Estimate the molar mass of a gas that ef-
= 1234.7 fuses at 2.60 times the effusion rate of carbon
mol rxn 1 mol C2 H5 OH
dioxide.
6.1 mol C2 H5 OH
= 7531.67 kJ Correct answer: 6.51 g/mol.
Explanation:
021 10.0 points rate of effusion of a gas = 2.60 CO2
A sample of oxygen collected over water at MWX = ?
32 C and 793 torr has a volume of 1.599 L. p
What volume would the dry oxygen occupy rate of effusion of X MWCO2
=
under standard conditions? The vapor pres- rate of effusion of CO2 MWX
sure of water at 32 C is 35.7 torr.

Correct answer: 1.42615 L.

p rate of effusion of CO2 p
MWX = MWCO2
Explanation: rateof effusion of X
1 p 
Sample: = 44 g/mol
2.6
V = 1.599 L T = 32 C = 305 K p
Ptotal = 793 torr PH2 O = 35.7 torr = 2.55125 g/mol
 p 2
Ptotal = PH2 O + PO2 MWX = 2.55125 g/mol
PO2 = Ptotal PH2 O = 6.51 g/mol
= 793 torr 35.7 torr
1 atm
= 757.3 torr = 0.996447 atm 023 10.0 points
760 torr
A piece of metal of mass 12 g at 114 C is
Applying the ideal gas law equation, placed in a calorimeter containing 54.1 g of
water at 20 C. The final temperature of the
P V = nRT mixture is 24.7C. What is the specific heat
PO 2 V capacity of the metal? Assume that there is
nO 2 =
RT no energy lost to the surroundings.
(0.996447 atm) (1.599 L)
= Latm

J
0.08206 molK (305 K) Correct answer: 0.992782 .
= 0.0636607 mol g C
Explanation:
Dry: mmetal = 12 g mH2 O = 54.1 g
n = 0.0636607 mol P = 1 atm TH2 O = 20 C Tfinal = 24.7 C
 hernandez (sh28928) fsemAP04Ch6 Lachman (92881) 8
J
Tmetal = 114 C CH2 O = 4.184
g C 1. NO2

qlost metal = qgained water 2. NO

mm Cm Tm = mH2 O CH2 O TH2 O
3. NO5
mH2 O CH2 O (Tfinal TH2 O )
Cmetal =
mmetal (Tfinal Tmetal ) 4. N2 O5
 
J
(54.1 g) 4.184 g C
= 5. N2 O4 correct
(12 g) (24.7 C 114 C)
(24.7 C 20 C) Explanation:
J mN = 0.606 g mO = 1.390 g
= 0.992782 . molar mass = 92 g/mol
g C
Composition in moles:
1 mol N
024 10.0 points 0.606 g N = 0.0433mol N
14.01 g N
Calculate H for the reaction 1 mol O
1 1.390 g O = 0.0869mol O
NO(g) + O2 (g) NO2 (g) 16.00 g O
2 Smallest whole-number ratio of atoms:
0.0433 mol N : 0.0869 mol O
if all products and reactants are under stan- 0.0433 0.0433
dard conditions. NO and NO2 are formed 1.00 mol N : 2.01 mol O
from their elements according to the follow- 1 mol N : 2 mol O
ing equations: The empirical formula is therefore NO2 .
molecular formula mass
Reaction Hf0 x=
1 1 empirical formula mass
N2 (g) + O2 (g) NO(g) +90.4 kJ/mol Empirical molar mass of NO2
2 2
1 = 14.01 g/mol + 2 (16.00 g/mol)
N2 (g) + O2 (g) NO2 (g) +33.9 kJ/mol
2 = 46.01 g/mol
Correct answer: 56.5 kJ/mol rxn. 92 g/mol
x= = 2.0 2
46.01 g/mol
Explanation: molecular formula: Nx O2x = N2 O4 .
Sum the 2 equations in such a way as to ob-
tain the reaction in question. To do this, rxn
026 10.0 points
1 needs to be written as the reverse reaction:
Slaked lime (Ca(OH)2 ) is formed from quick-
Reaction Hf0
lime (CaO) by the addition of water:
1 1
NO N2 + O2 90.4 kJ/mol
2 2 CaO(s) + H2 O() Ca(OH)2 (s) .
1
N2 + O2 NO2 +33.9 kJ/mol
2 What mass of slaked lime can be produced
1 from a mixture of 20.7 g of CaO and 11.6 g of
NO + O2 NO2 56.5 kJ/mol
2 H2 O?
kJ
Total heat produced = 56.5
mol Correct answer: 27.3515 g.
025 10.0 points Explanation:
The molar mass of a compound is 92 g/mol. mCaO = 20.7 g mH2 O = 11.6 g
Analysis of a sample of the compound indi-
cates that it contains 0.606 g N and 1.390 g
O. Find its molecular formula. FWCa(OH)2 = 40.08 g/mol
 hernandez (sh28928) fsemAP04Ch6 Lachman (92881) 9
+2 (16.0 g/mol) The e are equated, so add the balanced
+2 (1.0079 g/mol) half reactions:
= 74.0958 g/mol
Cu + SO2 +
4 + 4 H Cu
2+
+ SO2 + 2 H2 O

Neutralize the remaining charges with ex-

FWCaO = 40.08 g/mol + 16.0 g/mol isting counterions:
= 56.08 g/mol
Cu + 2 H2 SO4 CuSO4 + SO2 + 2 H2O
Calculate how much H2 O the 30 g CaO will
react with:

  028 10.0 points

1 mol CaO What pressure would a mixture of 3.2 grams
mH 2 O = (20.7 g CaO)
56.08 g CaO of O2 , 6.4 grams CH4 , and 6.4 grams of SO2
exert if the gases were placed in a 4.6 liter
  
1 mol H2 O 18.02 g H2 O
container at 127 C?
1 mol CaO 1 mol H2 O
= 6.65146 g H2 O
Correct answer: 4.28139 atm.
Because 11.6 g H2 O are present, the limiting Explanation:
reagent is CaO, and T = 127 C + 273 = 400 K V = 4.5 L

1 mol CaO
 mol
mCa(OH)2 = (20.7 g CaO) nO2 = 3.2 g = 0.1 mol
56.08 g CaO 32 g
mol
nCH4 = 6.4 g = 0.4 mol
 
1 mol Ca(OH)2
16 g
1 mol CaO mol
  nSO2 = 6.4 g = 0.1 mol
74.10 g Ca(OH)2 64 g
ntotal = 0.6 mol
1 mol Ca(OH)2
= 27.3515 g Ca(OH)2 Applying the ideal gas law equation,

P V = nRT
027 10.0 points nRT
P =
V
Latm


Copper reacts with hot, concentrated sulfuric (0.6 mol) 0.08206 molK (400 K)
acid to form copper(II) sulfate, sulfur dioxide, =
4.6 L
and water. What is the coefficient of Cu in = 4.28139 atm
the balanced equation?

Correct answer: 1. 029 10.0 points

Explanation: At a certain temperature and pressure, chlo-
The unbalanced reaction is rine molecules have an average velocity of
0.0610 m/s. What is the average velocity of
Cu + H2 SO4 CuSO4 + SO2 + H2 O sulfur dioxide molecules under the same con-
ditions?
Balance the half reactions:
0 Correct answer: 0.0642494 m/s.
Cu Cu2+ + 2 e
+6 2 +4 2 +1 2 Explanation:
+
S O2
4 +4 H + 2 e

S O2 +2 H2 O velocity of Cl2 molecules = 0.061 m/s
 hernandez (sh28928) fsemAP04Ch6 Lachman (92881) 10
velocity of SO2 molecules = ?
p Correct answer: 38.5354 kJ.
velocity of Cl2 MWSO2 Explanation:
= p
velocity of SO2 MWCl2 Hf Mn2 O3 = 962.3 kJ/mol
velocity of SO2 mMn2 O3 = 4.4 g
p
MWCl2
= (velocity of Cl2 ) p 3
MWSO2 2 Mn + O2 Mn2 O3
p 2
71 g/mol 962.3 kJ 1 mol rxn 1 mol Mn
= (0.061 m/s) p
64 g/mol mol rxn 2 mol Mn 54.938 g Mn
= 0.0642494 m/s 4.4 g Mn = 38.5354 kJ

030 10.0 points 033 (part 1 of 3) 10.0 points

The standard heat of formation for sulfur The oxidation of nitrogen in the hot exhaust
dioxide gas is 296.8 kJ/mol. Calculate the of jet engines and automobiles occurs by the
amount of energy given off when 29 g of reaction
SO2 (g) is formed from its elements.
N2 (g) + O2 (g) 2 NO(g)
Correct answer: 134.278 kJ.
Explanation:
Hf0 SO2 = 296.8 kJ/mol m = 29 g H = +180.6 kJ
0 How much heat is absorbed in the forma-
Hf for 29 g SO2 = ?  tion of 2.16 mol NO?
mol SO2
(29 g SO2 )
64.1 g SO2 Correct answer: 195.048 kJ.
= 0.452418 mol SO2
(0.452418 mol SO2 ) (296.8 kJ/mol) Explanation:
= 134.278 kJ n = 2.16 mol H = +180.6 kJ
given off.
 
180.6 kJ
031 10.0 points q = (2.16 mol)
One mole of carbon (12.0 g) in the form of 2 mol NO
crystalline graphite is burned at 25 C and = 195.048 kJ .
1.000 atm pressure to form CO2 (g). All of the
heat produced is used to heat a 2850 g bath
of liquid water, originally at 25 C. What is 034 (part 2 of 3) 10.0 points
the final temperature of the water bath? The How much heat is absorbed in the oxidation
heat of formation of CO2 (g) is 393.5 kJ/mol of 4.75 L of nitrogen gas measured at 1 atm
and the specific heat of water is 4.18 J/g/ C. and 273 K?

Correct answer: 58.0311C. Correct answer: 38.2928 kJ.

Explanation: Explanation:
P = 1 atm T = 273 K
032 10.0 points L atm
R = 0.08206 V = 4.75 L
The standard enthalpy of formation of K mol
Mn2 O3 is 962.3 kJ/mol. How much heat
energy is liberated when 4.4 grams of man- P V = nRT
ganese are oxidized by oxygen gas to Mn2 O3 PV
at standard state conditions? nN 2 =
RT
 hernandez (sh28928) fsemAP04Ch6 Lachman (92881) 11
(1 atm) (4.75 L)
= Latm


0.08206 Kmol (273 K)
= 0.212031 mol .

 
180.6 kJ
q = (0.212031 mol N2 )
1 mol N2
= 38.2928 kJ .

035 (part 3 of 3) 10.0 points

When the oxidation of N2 to NO was com-
pleted in a bomb calorimeter, the heat ab-
sorbed was measured as 525 J. What mass of
nitrogen gas was oxidized?

Correct answer: 0.0814535 g.

Explanation:
H = 180.6 kJ/mol MWN2 = 28.02 g/mol
qabsorbed = 525 J = 0.525 kJ

qabsorbed
nN 2 =
H
0.525 kJ
=
180.6 kJ/mol
= 0.00290698 mol , so

mN2 = n MWN2
= (0.00290698 mol) (28.02 g/mol)
= 0.0814535 g .