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ISSN: 2320-2246
ABSTRACT
The ability of three different algal biomass (Sphaerococcus coronopifolius, Ulva lactuca and Jania rubens) to remove
mercury from aqueous solutions was investigated. The mercury biosorption process was studied through batch
experiments at 25 C with regard to the influence of contact time, initial mercury concentration, pH and salinity. The
maximum adsorption capacity was registered at pH 6, Sphaerococcus cornopifolius being the most efficient specie
(0,674 mmol/g regarding adsorbed mercury). The kinetics of adsorption was fast and a high capacity of adsorption
occurred within only 60 min. The presence of Na+ interfered significantly with the binding of mercury.
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Biosorbent preparation
Fresh algal biomass was gathered from Moroccan
Atlantic coast (Casabalnca region). The algal samples
were washed with double distilled water to remove salt
and extraneous particles, then air dried. The
protonated biomass was prepared by cleaning the algae
with 0.3N H2SO4 for 3h, then rinsed with distilled water
and dried at 50 C for 24h.
Raw
60%
54%
70%
Removal (%)
Pre-treated
86%
71%
90%
Figure1: Effect of contact time on the adsorption of mercury (500g) at pH 6 and 25C
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Figure 3: Effect of the initial concentration of Na+ on the removal of mercury (500g) at pH 6 and
Adsorption equilibrium
The experiment results are show in Figure 4. The
maximum adsorption capacity was obtained for
Sphaerococcus Coronopifolius (0,674 mmmol/g) in
comparison with Ulva Lactuca and Jania Rubens (0,419
and 0,399 mmol/g, respectively). Some author
http://crmb.aizeonpublishers.net/content/2014/6/crmb513-518.pdf
25C.
In-depth study
For a more substantial study and in order to investigate
the sorption isotherm, the obtained data were analyzed
referring to Freundlich and Langmuir models.
Freundlich isotherm
The Freundlich isotherm although criticized for lacking
a fundamental thermodynamic basis, is often used to
reckon the adsorption on heterogeneous surfaces and it
is not restricted to monolayer formation. It is expressed
by the following equation:
Where:
KF (mg1-n g-1 Ln) represents the sorption capacity and
n the Empirical parameter, depicting the energetic
heterogeneity.
Langmuir isotherm
Developed by Langmuir in 1916, it is probably the best
known and the most applied regarding sorption
isotherm, it is widely used for solute adsorption from a
liquid solution [17]. The data may be represented as
follows:
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Where:
Data analysis
Table 2 represents the obtained data following
Freundlich and Langmuir models. For all experimental
systems, the RL value was between 0 and 1 which
confirms a favorable uptakes, a value exceeding 1
would indicate an unfavorable uptake, and an
irreversible state if RL = 0. Taking into consideration
the correlation coefficient (R2), the obtained values
prove that the adsorption data are well depicted by
Langmuir model which indicate the formation of
monolayer coverage of the adsorbate on the outer
surface.
Algae
Species
Jania rubens
Ulva lactuca
Sphaerococcus coronopifolius
Langmuir parameters
Qm (mg.g-1) KL (L.mg-1)
90,9
0,24
90,9
0,1
111,11
0,27
RL
0,06
0,14
0,05
CONCLUSION
REFERENCES
1.
2.
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3.
4.
5.
6.
7.
8.
R2
0,990
0,947
0,915
Freundlich parameters
KF
1/n
R2
24,3
0,26
0,988
47,7
0,13
0,938
61,6
0,11
0,759
517
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