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Sodium hydroxide is produced (along with chlorine and hydrogen) via the chloralkali
process. This involves the electrolysis of an aqueous solution of sodium chloride. The
sodium hydroxide builds up at the cathode, where water is reduced to hydrogen gas and
hydroxide ion:
2 Na+ + 2 H2O + 2 e- = H2 + NaOH .
To produce NaOH it is necessary to prevent reaction of the NaOH with the chlorine, this
is typically done in one of three ways, of which the membrane cell process is,
economically, the most viable.
An older method for sodium hydroxide production was the LeBlanc process, which
produced sodium carbonate, followed by roasting to create carbon dioxide and sodium
oxide. This method is no longer used, but it helped to establish sodium hydroxide as an
important commodity chemical.
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Major producers
In the United States, the major producer of sodium hydroxide is the Dow Chemical
Company, which has annual production around 3.7 million tonnes from sites at Freeport,
Texas and Plaquemine, Louisiana. Other major US producers include Oxychem, PPG,
Olin and Formosa. All of these companies use the chloralkali process.
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Uses
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General applications
Sodium hydroxide is the principal strong base used in the chemical industry. In bulk it is
most often handled as an aqueous solution, since solutions are cheaper and easier to
handle. It is used to drive for chemical reactions and also for the neutralization of acidic
materials.
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Experiment
Sodium hydroxide has also been used in conjunction with zinc for creation of the famous
"Gold pennies" experiment. A penny is boiled in a solution of NaOH together with some
granular zinc metal, the color of the penny will turn silver in about 45 seconds. The
penny is then held in the flame of a burner for a few seconds and it turns golden. The
reason this happens is that granular zinc dissolves in NaOH to form [Zn(OH)4]-2. This
zincate ion becomes reduced to metallic zinc on the surface of a copper penny. Zinc and
copper when heated in a flame form brass.
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Soap making
Soap making via saponification is the most traditional chemical process using sodium
hydroxide. The Arabs began producing soap in this way in the 7th century, and the same
basic process is still used today.
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Biodiesel
For the manufacture of biodiesel, sodium hydroxide is used as a catalyst for the
transesterification of methanol and triglycerides. This only works with anhydrous sodium
hydroxide, because water and lye would turn the fat into soap which would be tainted
with methanol.
It is used more often than potassium hydroxide because it costs less, and a smaller
quantity is needed for the same results. Another alternative is sodium silicate.
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Aluminum etching
Strong bases attack aluminium. This can be useful in etching through a resist or in
converting a polished surface to a satin-like finish, but without further passivation such as
anodizing or allodizing the surface may become corroded, either under normal use or in
severe atmospheric conditions.
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Food preparation
Food uses of lye include washing or chemical peeling of fruits and vegetables, chocolate
and cocoa processing, caramel color production, poultry scalding, soft drink processing,
and thickening ice cream. Olives are often soaked in lye to soften them, while pretzels
and German lye rolls are glazed with a lye solution before baking to make them crisp.
Specific foods processed with lye include:
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Domestic uses
Sodium hydroxide is occasionally used in the home as an agent for unblocking drains,
provided as a dry crystal (e.g. "Drno") or as a thick liquid gel. The chemical mechanism
employed is the conversion of grease to a form of soap, and so forming a water soluble
form to be dissolved by flushing; also decomposing complex molecules such as the
protein of hair. Such drain cleaners (and their acidic versions) are highly caustic and
should be handled with care (see precautions).
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Precautions
Gloves and eye protection should be worn when using sodium hydroxide, since there is a
high danger of causing chemical burns, permanent injury or scarring, and blindness. A
PVC apron is also recommended when concentrated solutions or the solid form are used.
It should be stored well away from strong acids such as battery acid. It can create enough
heat to ignite flammables (such as alcohols), so it should be added slowly in biodiesel
processors. Vinegar is a mild acid that will neutralize lye if it were to make contact with
the skin.
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See also
soda lime
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External links
Ammonia is a compound of nitrogen and hydrogen with the formula NH3. At standard
temperature and pressure ammonia is a gas. It is toxic and corrosive to some materials,
and has a characteristic pungent odor.
An ammonia molecule has a trigonal pyramid shape, as would be expected from VSEPR
theory. This shape gives the molecule an overall dipole moment and makes it polar so
that ammonia very readily dissolves in water. The nitrogen atom in the molecule has a
lone electron pair, and ammonia acts as a base. That means that, when in aqueous
solution, it can take a proton from water; this produces a hydroxide anion and an
ammonium cation (NH4+), which has the shape of a regular tetrahedron. The degree to
which ammonia forms the ammonium ion depends on the pH of the solutionat
"physiological" pH (~7), about 99% of the ammonia molecules are protonated.
The main uses of ammonia are in the production of fertilizers, explosives and polymers.
It is also an ingredient in certain household glass cleaners. Ammonia is found in small
quantities in the atmosphere, being produced from the putrefaction of nitrogenous animal
and vegetable matter. Ammonia and ammonium salts are also found in small quantities in
rainwater, while ammonium chloride (sal-ammoniac) and ammonium sulfate are found in
volcanic districts; crystals of ammonium bicarbonate have been found in Patagonian
guano. Ammonium salts also are found distributed through all fertile soil and in seawater.
Substances containing ammonia or that are similar to it are called ammoniacal.
General
Systematic name
Ammonia is a compound of nitrogen and
Trivial names
hydrogen with the formula NH3. At standard
temperature and pressure ammonia is a gas.
Molecular formula
It is toxic and corrosive to some materials,
and has a characteristic pungent odor.
Molar mass
An ammonia molecule has a trigonal
pyramid shape, as would be expected from
VSEPR theory. This shape gives the
molecule an overall dipole moment and
makes it polar so that ammonia very readily
dissolves in water. The nitrogen atom in the
molecule has a lone electron pair, and
ammonia acts as a base. That means that,
when in aqueous solution, it can take a
proton from water; this produces a
hydroxide anion and an ammonium cation
(NH4+), which has the shape of a regular
tetrahedron. The degree to which ammonia
forms the ammonium ion depends on the
pH of the solutionat "physiological" pH
(~7), about 99% of the ammonia molecules
are protonated.
http://en.wikipedia.org/wiki/NH3
The main uses of ammonia are in the
production of fertilizers, explosives and
polymers. It is also an ingredient in certain
household glass cleaners. Ammonia is found
in small quantities in the atmosphere, being
produced from the putrefaction of
nitrogenous animal and vegetable matter.
Ammonia and ammonium salts are also
found in small quantities in rainwater, while
ammonium chloride (sal-ammoniac) and
ammonium sulfate are found in volcanic
districts; crystals of ammonium bicarbonate
have been found in Patagonian guano.
Ammonium salts also are found distributed
through all fertile soil and in seawater.
Substances containing ammonia or that are
similar to it are called ammoniacal.
Content
Ammonia
Azane (see text)
Spirit of hartshorn
Nitrosil
Vaporole
NH3
17.03 g/mol
Appearance
CAS number
[7664-41-7]
Properties
-78.27 C (195.42 K)
Boiling point
-33.49 C (240.74 K)
Basicity (pKb)
4.75
Acidity (pKa)
approx. 34
Thermodynamic data
Std enthalpy of
formation fHgas
-45.92 kJ/mol
Standard molar
entropy Sgas
192.77 JK1mol1
Hazards
EU classification
Conc. dependent.
See text
R-phrases
Conc. dependent
See text
S-phrases
NFPA 704
Supplementary data page
Structure and
properties
n, r, etc.
Thermodynamic
data
Phase behaviour
Solid, liquid, gas
Spectral data
Regulatory data
Flash point,
RTECS number, etc.
s
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1 History
2 Synthesis and production
3 Biosynthesis
4 Properties
o 4.1 Formation of salts
o 4.2 Acidity
o 4.3 Formation of other compounds
o 4.4 Ammonia as a ligand
5 Uses
6 Liquid ammonia as a solvent
o 6.1 Solubility of salts
o 6.2 Solutions of metals
o 6.3 Redox properties of liquid ammonia
7 Detection and determination
8 Safety precautions
o 8.1 Toxicity
o 8.2 Household use
o 8.3 Laboratory use of ammonia solutions
o 8.4 Laboratory use of anhydrous ammonia
(gas or liquid)
9 See also
10 References
11 Bibliography
12 External links
COPPER SULFATE
(cupric sulfate; blue vitriol; blue stone; blue copperas)
CuSO4 5H2O
Properties: Blue crystals or blue, crystalline granules or powder; slowly efforescing in
air; white when dehydrated; nauseous metallic taste. Soluble in water, methanol; slightly
soluble in alcohol and glycerol; d 2.284.
Derivation: Action of dilute sulfuric acid on copper or copper oxide (often as oxide ores)
in large quantities with evaporation and crystallization.
Method of purification: Recrystallization.
Grade: Technical, CP, NF, also sold as monohydrate. Available as crystals of powder.
Use: Agriculture (soil additive, pesticides, Bordeaux mixture), feed additive, germicides,
textile mordant, leather industry, pigments, electric batteries, electroplated coatings,
copper salts, reagent in analytical chemistry, medicine, wood and ground pulp, process
engraving and lithography, ore flotation, petroleum industry, synthetic rubber, steel
manufacture, treatment of natural asphalts. The anhydrous salt is used as a dehydrating
agent.
http://search.opera.com/?search=CuSO4
Kloroform adalah nama umum untuk triklorometana (CHCl3). Kloroform dikenal karena
sering digunakan sebagai bahan pembius, meskipun kebanyakan digunakan sebagai
pelarut nonpolar di laboratorium atau industri. Wujudnya pada suhu ruang berupa cairan,
namun mudah menguap.
http://www.suaramerdeka.com/cybernews/harian/0601/06/nas8.htm
WHAT IS CHLOROFORM?
Chloroform is a clear liquid with an ether-like odor and a slightly sweet taste. It is
a naturally-occurring chemical, but most of the chloroform in the environment is
man-made. Chloroform is a member of a group of chemicals called
"trihalomethanes." It is used to make coolants, as a fumigant for grain, and as a
dry cleaning spot remover.
Chloroform can be formed during the break-down of chlorine-containing
compounds, and may be found in in small amounts in chlorinated drinking or
The following health effects can occur after several years of exposure to
chloroform:
Cancer: Chloroform is suspected of causing cancer. Liver and kidney tumors
have been reported in laboratory animals. Any exposure to a cancer-causing
chemical may increase your risk of developing cancer.
Reproductive Effects: The reproductive and developmental effects of
chloroform are not known. However, chloroform can enter the bloodstream of a
developing baby.
Organ Systems: Damaged liver or kidney function can result when levels of
chloroform reach 300 ppb in water or 0.25 ppm in air.
In general, chemicals affect the same organ systems in all people who are
exposed. However, the seriousness of the effects may vary from person to
person.
A person's reaction depends on several things, including individual health,
heredity, previous exposure to chemicals including medicines, and personal
habits such as smoking or drinking.
It is also important to consider the length of exposure to the chemical; the
amount of chemical exposure; and whether the chemical was inhaled, touched,
or eaten.
CAN A MEDICAL TEST DETERMINE EXPOSURE TO CHLOROFORM?
Chloroform is rapidly flushed from the body. Chloroform can be measured in
exhaled breath, urine, blood, and other tissues, but no reliable method exists to
determine the level of your exposure. Because chloroform can be formed in the
body following exposure to other substances, levels found in tests cannot always
be linked to just chloroform exposure. Doctors can use tests of liver, kidney, and
heart function to evaluate the health effects of chloroform exposure.
Seek medical advice if you have any symptoms that you think may be related to
chemical exposure.
(PPH 4355 Revised 3/2000)