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Paper Chemistry: Unit 9 & 10 (Objective)

Total marks: 14
Q.1

Time: 15 mints

Question

The
characteristics
of
reversible
reactions are the following except:

Producer
never
recombine
to from
reactants

They
never
complete

They
proceed in
both ways

Of high
temperatur
e

CaO is
more
stabe
than
CaCO3

CO2
escapes
continuou
sly

CaO is not
dissociated

[2 A][ B ]
[3C ]

[ A]2[ B]
[C ]3

[3C ]
[2 A][ B ]

[C ]3
[ A]2[ B]

Reaction
will go to
completio
n

The amount
of products
in negligible

Moderate
Ke value

None of
these

mol-1 dm3

mol dm3

Aqueous
ammonia

Sodium
chloride

Sodium
carbonate

Calcium
oxide

Salt and
water

Salt and
gas

Salt and
an acid

Salt and a
base

The conjugate acid of HPO42- is:

PO43-

H2PO42-

H2PO4-

H3PO4

10

Which one of the following is not


amphoteric?

H2O

NH3

HCO3

SO42-

11

You want to dry a gas which of the


following salt you will use

CaC12

NaC1

CaO

Na2SiO3

12

Dilute acids react with carbonates to


produced the given products excepts:

Salt

Water

Carbon
dioxide

Hydrogen

13

Which ion is the conjugate base of


sulphuric acid?

SO2-3

S2-

HSO-3

HSO-4

5
6
7
8
9

In the lime kiln, the reaction CaCO 3(s)CaCO(s) +CO2(g) goes to completion
because

For the reaction 2A(g) + B(g) ------- 3C(g)

When the magnitude of Ke is very


small it indicates

Reactions which have comparable


amounts of reactants and products at
equilibrium state have
For reaction between PCI3 and CI2 to
from PCI5 , the units of Ke are:
A base is substance which neutralizes
an acid, which of the substance is not
a base?
A reaction between an acid and a base
produces

Equilibrium
will never
establish

Very small
Ke value
mol dm-3

All
reactants
will be
converte
d to
products
Very
large Ke
value
mol-1 dm-

D
They have
a double
arrow
between
reactants
and
products

14

Which one of the following is Lewis


Base?

NH3

BF3

H+

A1C13

SUBJECTIVE (Unit: 9 & 10)


Time Allowed: 2:45 hours
Marks: 63
Part-1
Q. No. 2: Answer any FIVE parts from the followings:

What are irreversible reactions? Give a


few characteristics of them?
give the characteristics of reversible
3
reaction
1

[3 x 2 = 6]

2 Define chemical equilibrium state


4

Why at equilibrium state reaction does


not stop

Q. No. 2B: Answer any FIVE parts from the followings:


Name three common household substances
having

5 a- pH value greater than 7 b-pH value


less than 7
c- pH value equal than 7
Define the followings:
7
1- Normal Salt 2- Basic Salt

How is dynamic equilibrium


established?
Write the equilibrium constant
expression for following reactions:
1- H2(g) + I2(g)

2HI(g)

[3 x 2 = 6]

Define pH. What is the pH of pure


water?

Na2SO4 is a neutral salt while HaHSO4 is


an acid salt. Justify

Q. No. 3: Answer any THREE parts from the followings:

Total

[3 x 2 = 6]

What is relationship between active


mass and rate of reaction?

How direction of a reaction can be


predicted

2- CO(g) + 3H2(g)
CH4(g) +
H2O(g)
Why is equilibrium state attainable
5
from either way?
Q. No. 3B: Answer any THREE parts from the followings:

6
8
1
0

How are the insoluble salts prepared?

Which kind of bond forms between


9
Lewis acid and a base
Which salt is used to prepare plaster of
Paris?

Name two acids used in the


manufacture of fertilizers.
Why H+ ion acts as Lewis acid?

Q. No. 4: Answer any THREE parts from the followings:

If reaction quotient Qc of a reaction is


1 more than Kc. what will be the direction
of the reaction

[3 x 2 = 6]

[3 x 2 = 6]

When nitrogen reacts with hydrogen to


form ammonia, the equilibrium mixture
contains 0.31 mol dm-3 and 0.50 mol
dm-3 of nitrogen and hydrogen
respectively. If the Kc is 0.50 mol-2 dm6,
what is the equilibrium concentration
of ammonia?

What are the characteristics of a


3 reaction that establishes equilibrium
state at once?

How direction of a reaction can be


predicted?

Q. No. 4B: Answer any THREE parts from the followings:

5 Define acids and bases. Give examples. 6


7 Write four name and uses of salts

[3 x 2 = 6]

Write uses of sulphuric acid and


hydrochloric acid.
Fine out the pH and pOH of 0.1M
solution of KOH.

PART-II
Note :
3 = 21]

Attempt any THREE Questions.

[7 x

Q.5. (a)
State the law of Mass Action and derive the expression for equilibrium
constant for a general
reaction.
4
(b)

Q.6. (a)
(b)
Q.7. (a)
4
(b)
Q.8. (a)
(b)
Q.9. (a)
(b)

Define an acid and a base according to Bronsted-Lowry concept and justify


examples that water is an amphoteric compound?
3
What is the importance of equilibrium constant?
4
Give four uses of calcium oxide
3
Describe a reversible reaction with the help of an example and graph.
Define Neutralization reaction.
3
Write down the macroscopic characteristics of dynamic equilibrium.
4
Explain preparation of insoluble salts
3
Write down the General properties of Bases
4
How measure pH of a solution
3

Note :
2 = 10]

PART-III Practical

Attempt any TWO Questions.

[5 x

Q.10. (a) i. this simple pendulum completes on vibration in four seconds. Calculate its
length
When g = 10.0 ms-2.
3
ii Draw the diagram of simple pendulum and write its formula
2
(b) i. if 100 waves pass through a point of medium in 20 seconds. What is the
frequency? If its wavelength is 6cm,
3
ii Find the time period in the above statement
2
(c) i. the length of thread including hook is given in the table below. If the radius
of the bob is 0.6cm and the time for ten vibrations is given in the table,
then calculate the mean value of g.
5

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