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Chemistry Test
Class XII (ISC)
Chemical Kinetics, Chemical Equilibrium
Time 3 hours
Q.1(i)
(ii)
(iii)
(iv)
(v)
(vi)
(vii)
(viii)
(ix)
(x)
Q.2(i)
(ii)
(iii)
(iv)
(v)
MM 70 Marks
Q.3(i)
(ii)
(iii)
(iv)
(v)
Q.4-
For a chemical reaction 2A + B 2C + 3D, the rate of disappearance of A is 0.10 molL 1 sec1. Calculate the
rate of reaction and the rate of appearance of D.
For the reaction N2 (g) + 3H2 (g) 2 NH3 (g) the rate of reaction is found to be 2 104 molL1 sec. Calculate
the rate of disappearance of N2 (g) and that of H2 (g).
List any two factors that influence the rate of chemical reaction. Indicate whether the rate constant of the
reaction is dependent on or independent of these factor?
Q.5Q.6-
For the reaction 2x + y + z x2yz, the rate equation is Rate = k [x] [y] 2 with k = 3.0 10-6 mol-2 L2 sec-1 If
[x] = 0.1 mol L-1, [y] = 0.2 mol L-1, [z] = 0.7 mol L-1, determine
(i) the initial rate of reaction and also (ii) the rate after 0.02 mole of x has been reacted.
Q.8- For the reaction: N2 (g) + 3H2 (g)
2NH3 (g) at 400 K, Kp = 41. Find the value of Kp for each for the
following reaction at same temperature.
(i) N2 (g) + 3/2 H2 (g)
2NH3 (g)
(ii) 2N2 (a) + 6H2 (a)
4NH3 (g)
Q.9- Initially 0.9 moles of PCl5 and 0.12 moles of PCl3 are mixed in a 1 litre flask. At equilibrium, the flask
contains 0.72 moles of PCl5, what is Kc for the reaction.
PCl5
PCl3 + Cl2?
Q.10- A a certain temperature and a total pressure of 10 5 pa, iodine vapour contain 40% by volume of Iodine ahrms
I2 (g)
2I (g). Calculate Kp for the equilibrium.
Q.11- What is the effect of temperature, pressure concentration and addition of Argan at to the following
equilibrium?
(i) PCl5 (g) PCl3 (g) + Cl2 (g) -- heat
Q.7-
Q.14Q.15Q.16Q.17Q.18-
Q.19Q.20Q.21-
Q.22-
Q.23-
Volume of N2 (mL)
0
10
33
1.62
Find the order of reaction and calculate the value of rate constant.
Q.24- The optical rotation of sucrose in 1N HCl at various intervals was found as shown below:
Time (min)
0.00
7.18
18.00
27.05
Rotation (degrees)
+24.09
+21.41
+17.74
+15.00
10.74
Show that the inversion of cane sugar is a first order reaction.
Q.25- For the reaction 2NO(g) + Cl2 (g) 2NOCl (g), following data were obtained?
Experiment
1
2
3
initial Conc. of NO (mol L-1) initial Conc. of Cl2 (mol L-1) initial of rate (mol L-1 sec-1)
0.010
0.030
0.030
0.020
0.020
0.040
2.40 10-4
2.16 10-3
4.32 10-3