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ACS
111
COLLEGE
FINAL
EXAM
CHEMISTRY
PRACTICE
II
SHEET
1. Atomic Structure
A. Which statement is true ?
1. Protons and neutrons are relatively heavy, but occupy relatively little
volume.
2. Electrons are relatively heavy, but occupy relatively little volume.
3. Protons and neutrons are relatively heavy, and occupy a relatively large
volume.
4. Electrons are relatively heavy, and occupy a relatively large volume.
B. Which of the following could be an isotope of the element X, represented by
14
7 X ?
1.
14
2.
15
3.
15
4.
14
Si
2. Ca
3. Ba
4. Al
2. K
3. Mg
4. Ar
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2. Br
3. Kr
4. I
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2. Molecular Structure
A. Which of the following molecules exhibits resonance?
1. NH3
2. CH4
3. NBr3
4. SO3
.. ..
..
: F : Br : F :
.. ..
..
: F :
..
2. trigonal pyramid
3. square pyramid
4. T-shape.
90.
2.
120.
3.
180.
4.
109.5.
Cl Be Cl
2. H O
\
H
3.
H
|
N
/ \
H H
4.
N = N = 0
2. Ca
3. Fe
4. C
B. Which of the following elements forms an oxide X2O3, and a phosphate XPO4 ?
1. Na
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2. Ca
3. Al
4. C
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H = 4.0%,
O = 64.0%.
2. CH12O12
3. C4H6O6
4. CH2O4
2.hydrogen sulfate.
3. hydrosulfuric acid.
4. hydrogen sulfide.
4. Stoichiometry
A. How many grams of chlorine can be produced from the complete reaction of
100 g of MnO2 ?
MnO2
4 HCl
MnCl2 +
Cl2
2 H2O
2. 81.7 g
3. 123 g
4. 6.16 x 105 g
13 O2
(Molecular weights:
1. 11 g
8 CO2
10 H2O
2. 179 g
3. 359 g
4. 494 g
C. How much of the excess reactant remains when 90 g of SO2 reacts with 100 g
of O2 in the reaction :
2 SO2
O2
(Molecular weights:
1. 11.5 g
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2 SO3
SO2 = 64.1, O2 = 32.0, SO3 = 80.1)
2. 22.5 g
3. 67.5 g
4. 77.5 g
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5. Solutions
A. What is the concentration of NaCl in 0.50 L of aqueous solution which
contains 96 g of NaCl ?
(Molecular weight:
1. 3.3 M
NaCl = 58.5)
2. 0.03 M
3. 1.2 M
4. 1.6 M
B. A precipitate will form from an aqueous solution of Ca(NO 3)2 upon the
addition of :
1. HCl.
2. HNO3.
3. H2SO4.
4. FeCl3.
2. NaCl
3. NH3
4. Br2
2. 0.5 L
3. 0.8 L
4. 1.2 L
6. Acid-Base Reactions
A. Which of the following is a product of the reaction between acetic acid,
CH3COOH, and potassium hydroxide ?
1. CH3COOH
2. CH3COOH
3. KCH3COO
4. K2CO3
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NH3
NH3
NH3
NH3
(g)+
(g)+
(g)+
(g)+
H 2O
H 2O
H 2O
H 2O
(l)
(l)
(l)
(l)
H3O+1 (aq) +
NH3O (aq) +
NH4+1 (aq) +
NH2OH (aq)
NH21 (aq)
H2 (g)
OH1 (aq)
+ H2 (g)
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2. 7.0.
3. 10.0.
4. 12.0.
2. 3.97
3. 4.19
4. 4.83
3. H3PO4.
4. H2PO41.
2. PO43.
7. Equilibrium
A. An equilibrium mixture for the reaction
2 H2S (g)
2 H2 (g)
S2 (g)
was found to contain 1.0 moles of H2S, 4.0 moles of H2, and 0.80 moles of S2 in
a 4.0 liter vessel. The value of the equilibrium constant for this reaction
is :
1. 0.64.
2. 0.8.
3. 1.6.
4. 3.2.
The
The
The
The
2 O2 (g)
CO2 (g) +
2 H2O (l)
8. Thermodynamics
A. If the values of S are SO3 = 256.2 J/K mol, H2O = 69.9 J/K mol, and
H2SO4 = 156.9 J/K mol, the value of S for the reaction
SO3
H2O
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H2SO4
is :
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CO (g)
+
C (s) + O2 (g)
CO2 (g)
2 H2O2 (l)
2 H2O (l) +
O2 (g)
(a)
(b)
(c)
3 H2 (g)
1. a > b > c ?
2. a > c > b ?
3. c > b > a ?
C. A spontaneous reaction will never occur when :
1.
2.
3.
4.
H
H
H
H
is
is
is
is
positive,
negative,
positive,
negative,
S
S
S
S
is
is
is
is
4. c > a > b ?
positive.
negative.
negative.
positive.
9. Kinetics
A. For the reaction
2 H2S (g)
O2 (g)
2 S (s)
2 H2O (l)
2. 12 years
3. 24 years
4.
48 years
Electrochemistry
A. Is the standard potential for a galvanic cell made up from the two
half-reactions
Fe (s)
2e
Fe+2 (aq)
Sn+2 (aq)
1. 0.58V ?
2 e
E =
Sn (s)
E = -0.14V
2. 0.30V ?
3. 0.30V ?
0.44V
4. 0.58V ?
2 Fe+2 (aq)
Ni (s)
2 Fe+3 (aq)
the value of E when [Ni +2] = 2.0 M, [Fe+2] = 2.0 M, [Fe+3] = 0.1 M, is :
1. 1.11V.
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2. 1.07V.
3. 0.97V.
4.
0.93V.
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Electrons will flow from the lead electrode to the platinum electrode.
Copper will be deposited on the platinum electrode.
Reduction occurs at the platinum electrode.
The concentration of Cu+2 will decrease.
2. +5.
3. +7.
4. +9.
+
1.
2 H2SO4
Cu
CuSO4
2.
SO2
3.
2 H2O
H
4.
HNO3
2.
SnO2
NO2
3.
H2O
4.
2. 29 C
3. 288 C
4. 561 C
B. If the moles of a gas are doubled, and the volume is tripled, at constant
temperature, the pressure of the gas will :
12.
1. decrease by a factor of 1.
2. decrease by a factor of
3. decrease by a factor of 6.
4. increase by a factor of 1.
1/
3
General
1. 0.5 M.
2. 1.0 M.
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3. 1.5 M.
4. none of these.
the
the
the
the
2. freezing.
3. evaporation.
4. condensation.
2. molarity.
3.mole fraction.
4.
volume.
2. NaNO3
3. KCN
4. CuSO4
2. liters of solution.
3. kilograms of solution.
4. kilograms of solvent.
G. If KSP = 6.6 x 1011 for CrF3, what is the molar solubility of CrF3 in water ?
1. 1.3 x 103 M
2. 2.9 x 103 M
3. 4.0 x 104 M
4. 8.1 x 106 M
H. Sulfur dioxide emitted into the air is absorbed by rain droplets, which will
then typically have a pH of:
1. 0.10.
1. Atomic Structure
A - 1
B
2. 4.0.
3. 7.0.
4. 10.0.
7. Equilibrium
A - 4
B
8. Thermodynamics
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A
2. Molecular Structure
A
9. Kinetics
A
10. Electrochemistry
3. Chemical Formulas/Reactions
A
4. Stoichiometry
A
5. Solutions
12. General
A. -
6. Acid-Base Reactions
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