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Principles
of Heat treatment
The objective of annealing is primarily to soften the material to prepare it for further processing
such as coldforming and machining.
There are 3 stages of annealing which include
1. recovery,
2. recrystallization
3. grain growth.
Annealing/Normalizing
For steels, there are three annealing processes:
subcritical annealing / process annealing
intercritical annealing / spheroidizing annealing
full annealing.
The difference between the three are the temperatures at which the heat treatment is carried
out, with respect to the eutectoid part of the FeFe3 phase digram.
Normalizing is also a nonhardening process carried out on steels, where a faster cooling
rate (faster than annealing but much slower than the cooling rate applied during hardening)
is applied after austenitizing.
Annealing/Normalizing
Through hardening is produced by first heating in the austenitizing range, keeping it long enough
so that material is fully austenitized. The material is then quenched, i.e. cooled very fast.
Through hardening produces a martensitic ( ) structure, g g p ) , which is very hard and brittle.
TTT diagram
TTT termed as time-temperature transformation diagram, also known as SCurve, C-Curve, Bains
curve or Isothermal transformation diagram. This is particularly used in the assessment of
decomposition of austenite in a heat treatable steel.
The Fe-C diagram shows only the phases and the resulting microstructures corresponding to
equilibrium conditions, whereas, the principal source of information on the actual process of
austenite decomposition under non equilibrium conditions is the TTT diagram, which relates the
transformation of austenite to the time and temperature conditions to which it is subjected.
3) When austenitized, the samples are quickly transferred to an other molten salt bath held at
desire reaction temperature below A1, say 7050C.
4) After varying time intervals in the salt bath, each sample is quenched in cold water or iced brine.
5) After cooling, each sample is checked for hardness and studied microscopically
6) The above steps are repeated at different temp until sufficient points are determined to plot the
curves on the diagram.
Steps 3, 4 and 5 are shown schematically in Fig 4. Sample 1, after 30 s at 705 0C and quenched,
showed only Martensite at room temp. Sample 2, after 6 h at 7050C and quenched, showed about
95% Martensite and 5% coarse pearlite at room temp. Similarly other samples are also changed
from austenite to its respective structure based on the time and for const temp 7050C. The resultant
curve obtained for this isothermal treatment of samples at 7050C is shown in Fig 5 with its
microstructure, which is also called as reaction curve.
Fig 4. The progress of austenite transformation to coarse pearlite at 13000F as related to the structure at
room temp;
As a result of this experiment, two points may be plotted at 7050C or 13000F, namely the time for
the beginning and the time for the end of transformation.It is also common practice to plot the time
for 50% transformed.
The entire experiment is repeated at different subcritical temperatures (below A1 line) until
sufficient points are determined to draw one curve showing the beginning of transformation,
another curve showing the end of transformation, and a dotted curve in between showing 50%
transformed, shown in Fig 6 the resulting diagram know as TTT or IT diagram
The TTT diagram for eutectoid steel is shown in Fig. 7. Above the A1 or Ae1 line austenite is
stable. The area to the left of the beginning of transformation consists of unstable austenite. The
area to the right of the end of transformation line is the product to which austenite will transform at
const temp.
T
h
e
area between the beginning and the end of transformation labeled A+F+C consists of three phases,
austenite, ferrite and carbide.
The point on the beginning of the transformation line farthest to the left is known as the nose of the
diagram.
The Ms temperature is indicated as horizontal line, representing the Martensite start, arrows
pointing to the temp scale indicate the temp at which 50% and 90% of the total austenite will on
quenching have transformed to Martensite.
Cooling curves and the TTT diagram
The effect of cooling rate on the formation of different reaction products is shown in Fig 8.
Normalising
Also used to soften and relieve internal stresses after cold work and to refine the grain size and
metallurgical structure. It may be used to break up the dendritic (as cast) structure of castings to
improve their machinability and future heat treatment response or to mitigate banding in rolled
steel.
This requires heating to above the As temperature, holding for sufficient time to allow temperature
equalisation followed by air cooling. It is therefore similar to annealing but with a faster cooling
rate. Curve 3 in Figure 10 would give a normalised structure.
The Hardening Processes
Hardening
In this process steels which contain sufficient carbon, and perhaps other alloying elements, are
cooled (quenched) sufficiently rapidly from above the transformation temperature to produce
Martensite, refer Curve 1 in Figure 10.
Hardenability
It is the ability of a material to become uniformly hard or to harden in depth direction. It is noted
that the hardenability is not an indication of the hardness of a specimen; rather it is an index of the
depth to which Martensite can be formed in a given specimen as the result of quenching.
Methods to determine hardenability
a) The Grossmann method of hardness distribution curves: the heated round steel bars of
different
diameters to the austenitizing temp, quenched in oil and sectioned them and transverse readings of
hardness on the section to be taken to plot the hardness with the diameter of the bar. However this
method is not satisfactory due to (a) possible tempering during cutting of sections (b) the large
number of bars required to establish the hardness distribution curve and (c) the time and expense
consumed for only one heat of steel
b) Jominy test: the second and the most widely used method of determing hardenability is the endquench hardenability test or Jominy test. The testing procedure and the evaluation of hardenability
are discussed blow.
The Jominy Test
Application of hardenability
CCT diagrams are unavailable for most steels.
A plot of
hardness vs.
distance from
quenched end is
plotted to produce
a hardenability
curve.
This method of
quenching results in different rate of cooling along the length of the test piece. The quenched end
cools the most rapidly and exhibits the maximum hardness, since 100% martensite is formed.
The cooling rate at the opposite end can be considered to be air cooled, a very slow cooling rate,
producing a structure which is less hard.
We need to know the hardness at different cooling rates,
rather than the hardness at different distances.
The distance from quenched end is the Jominy distance & is
related to the cooling rate.
Each steel alloy has its own unique hardenability curve.
This standard quench process produces a common cooling
rate gradient along the Jominy bar, for all carbon and low
alloy steels. Thermal properties are nearly identical for these
ironcarbon alloys.
In this case, the supersaturated alpha solid solution is ordinarily heated to an intermediate temp T2
(Fig 12) within the _+_ two-phase region, at which temp diffusion rates become appreciable. The
beta precipitate phase begins to form as finely dispersed particles of composition, this process
sometime termed as aging. After the appropriate aging time at T2 the alloy is cooled to room
temperature.
Both solution and precipitation heat treatments are represented on the tempversus- time plot shown
in fig 13.
Processing Methods
In
the past the thermo-chemical processes were carried out by pack cementation or salt bath
processes. These are now largely replaced, on product\ quality and environmental grounds, by gas
and plasma techniques. The exception is boronising, for which a safe production scale gaseous
route has yet to be developed and pack cementation is likely to remain the only viable route for
some time to come.
The gas processes are usually carried out in the now almost universal seal quench furnace, and
any subsequent heat treatment is readily carried out immediately without taking the work out of
the furnace. This reduced handling is a cost and quality benefit.