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P Block elements ANS- Nitrogen has a tendency to form pp multiple bonds with itself.
Nitrogen thus forms a very stable diatomic molecule, N 2.
Q8 Why does nitrogen show catenation properties less than
phosphorus?
ANS- This is because of the relative weakness of the NN single bond as
Q1 Why does the reactivity of nitrogen differ from phosphorus? compared to the PP single bond. NN single bond is weaker because there
ANS- the two nitrogen atoms form a strong triple bond. This triple bond is greater repulsion of lone pairs of two nitrogen atoms,
has very high bond enthalpy and strength,
Q9 Can PCl5 act as an oxidising as well as a reducing agent? Justify.
Q2 Why does NH3 form hydrogen bond but PH3 does not? ANS- PCl5 can only act as an oxidizing agent not a reducing agent . The
ANS- ANS Nitrogen is highly electronegative as compared to phosphorus.. highest oxidation state that P can show is +5. In PCl5, phosphorus is in its
highest oxidation state (+5). now, it can only decrease its oxidation state and
Q3The HNH angle value is higher than HPH, HAsH and HSbH angles. act as an oxidizing agent.
Why?
ANS- Hydride NH3 PH3 AsH3 SbH3 Q10 Bond angle in is higher than that in PH3. Why?
the electronegativity of the central atom is highest in NH 3due to which bond ANS- In PH3, . Three bond pair and one lone pair. As lone pair-bond pair
pairs are closer to cetre N and repel more that leads to more separartion of repulsion is stronger than bond pair-bond pair repulsion, shape is changed to
bond pairs . pyramidal.
Due to the absence of lone pair in PH4+, there is no lone pair-bond pair
repulsion. Hence, the bond angle in is higher than the bond angle in PH3.
[structure must ]
Q 4 Some metals (e.g., Cr, Al) do not dissolve in concentrated nitric Acid
ANS- because of the formation of a passive film of oxide on the surface.the
single
Q11:Why are pentahalides more covalent than trihalides?
Q5:Why does R3P=O exist but R3N=O does not (R = alkyl group)? ANS In pentahalides, the oxidation state is +5 and in trihalides, the oxidation
ANS- N (unlike P) lacks the d-orbital. This restricts nitrogen to make 5 state is +3. Since the ion with a high charge has more polarizing power,
bond . Hence, R3N=O does not exist.
Q6 Explain why NH3 is basic while BiH3 is only feebly basic. Q12: Why is BiH3 the strongest reducing agent amongst all the hydrides
. ANS- Nitrogen valence shell has a small size due to which the lone pair of of Group 15 elements?
electrons is concentrated in a small region. This means that the charge ANS- because Bi-H bond is weakest and is most un stable hydride in
density is high. group 15 from NH3[most stable] to BiH3.[least stable ]
Q15 Though nitrogen exhibits +5 oxidation state, it does not form Q22. Give reasons for the following:
pentahalide. Give reason. (a) CN ion is known but CP ion is not known.
ANS- It does not has vacant d orbitals to expand its covalence beyond four. (b) NO2 dimers to form N2O4
ANS (a) Nitrogen being smaller is size forms p- p multiple bonding with
Q16Why does NH3 act as a Lewis base ? carbon, So ion is known, but phosphorus does not form p- p bond as it is
ANS- Nitrogen atom in NH3 has one lone pair of electrons which larger in size.
is available for donation. (b) NO2 is an odd electron molecule and there fore gets dimerised to stable
N2O4.
Q17 Why does NO2 dimerise ? Q23. (a) What is the covalence of nitrogen in N2O5?
ANS- NO2 contains odd number of valence electrons which make it (b) Explain why both N and Bi do not form pentahalides while
unstable . On dimerisation, it is converted to stable N 2O4 molecule with even phosphorus does.
number of electrons. ANS- (a) 4
(b) unlike P, N has no vacant d-orbitals in its valence shell.
Q`18In what way can it be proved that PH3 is basic in nature? Bi prefers +3 oxidation state is more stable because of inert pair effect.
ANS- PH3 has alone pair and reacts with acids like HI to form PH 4I which
shows that it is basic in nature. Q24 In which one of the two structures, NO2+and NO2-, the bond angle
has a higher value and why ?
Q19Why does PCl3 fume in moisture ? ANS- The bond angle in NO2+ is greater than that in. NO2- As in NO2+ there
PCl3 hydrolyses in the presence of moisture giving fumes of HCl. are two bond pairs at nitrogen which make it linear where as in NO 2-
there are two bond pairs and one lone pair which make it bent shape
Q 25 Assign a reason for each of the following statements:Ammonia is a
Q20Are all the five bonds in PCl5 molecule equivalent? Justify your stronger base than phosphine.
(iii) H3PO2 and H3PO3 act as as good reducing agents while H3PO4
ANS-. does not
Due to resonance in NO2, the two bonds are equivalent. This leads to
Q26 How would you account for the following? a decrease in bend length. Thus, the N O bond length in NO2resembles a
(i) The value of electron gain enthalpy with negative sign for double bond Now, the resonating structures for NO3 can be drawn as:
phosphorous is higher than that for nitrogen
(ii) NF3 is an exothermic compound but NCl3 is endothermic compound.
(iii) The stability of + 5 oxidation state decreases down the group in
group 15 of the periodic table.
(iv) Solid phosphorus pentachloride behaves as an ionic compound.
(v) Tendency to form pentahalides decreases down the group in group 15 As seen from the above resonating structures of NO 3, the three oxygen
of the periodic table atoms are sharing two single bonds and one double bond. So, the real
ANS- (i) . Because of the electron-electron repulsions in 2p sub-shell are N O bond length resembles a single bond closely. This explains the
quite high. Hence, the incoming electron is not accepted as easily in nitrogen existence of shorter bond length of the N O bond in
as it is in phosphorous . Hence, the negative electron gain enthalpy for NO2 than in NO3.
phosphorous is higher than that of nitrogen .
(ii) In gaseous and liquid state, PCl5 has a trigonal bipyramidal structure. In
(ii) The instability of NCl3 is due to the weak NCl bond. This is due to. On this structure, the two axial P Cl bonds are longer and less stable than the
the other hand, N-F bond is stronger as size are similar three equatorial P Cl bonds. This is because of the greater bond pair bond
Q 33[i]Why PCl5 has two types of bond length for P-Cl bond
[ii] Why PCl3 on hydrolysis forms H3PO3 but NCl3 does not give H3NO3 NO2- < NO2< NO2+
ANS-This is due to the fact that the axial bond pairs suffer more repulsion 35 A translucent white waxy solid (A) on heating in an inert atmosphere
is converted to its allotropic form (B).Allotrope (A) on reaction with
ANS-
ANS-
(i)
44
Complete the reaction
(ii)
(iii) ANS-
(iv)
(v) catches fire in air to give dense white fumes of P4O10.
45 Draw the structures of white phosphorus and red phosphorus. Which
one of these two types of phosphorus is more reactive and why?
[c]Why does O3 act as a powerful oxidising agent? Q 58Which form of sulphur shows paramagnetic behaviour ?
ANS- [c]Ozone is unstable and decomposes readily to give a nascent ANS- In vapour state sulphur partly exists as S2 molecule which has two
oxygen. Nascent oxygen, being a free radical, is very reactive. unpaired electrons in the antibonding * orbitals like O2 and, hence,
exhibits paramagnetism.
ANS-
This oleum is then diluted to obtain H2SO4 of
the desired concentration..
Q 69
[ii]SO2 is a colourless and pungent smelling gas.It can be detected with the
help of potassium permanganate solution. When SO2 is passed through an
acidified potassium permanganate solution, it decolonizes the solution as it
reduces
(i) It forms only one oxoacid as compared to other halogens that form a
number of oxoacids. 92 With what neutral molecule is ClO isoelectronic? Is that
(ii) Ionisation enthalpy, electronegativity, and electrode potential of fluorine molecule a Lewis base?
are much higher than expected. ClO is isoelectronic to ClF. Also, both species contain 26 electrons in all as
shown.
87 Sea is the greatest source of some halogens. Comment.
ANS- Sea water contains chlorides, bromides, and iodides of Na, K, Mg, and Total electrons ClO = 17 + 8 + 1 = 26 In ClF = 17 + 9 = 26
Ca. However, it primarily contains NaCl. The deposits of dried up sea beds
contain sodium chloride and carnallite, KCl.MgCl2.6H2O. Marine life also ClF acts like a Lewis base as it accepts electrons from F to form ClF 3.
contains iodine in their systems. For example, sea weeds contain upto 0.5%
Electronic structure of Cl The bond dissociation energy of H-X molecules where X = F, Cl, Br, I,
(excited state) decreases with an increase in the atomic size. Since H-I bond is the weakest,
HI is the strongest acid.
(ii) XeOF4 can be prepared using XeF6. (ii)XeF2 is isoelectronic to and has a linear structure.
(iii) XeO3 is isostructural to and has a pyramidal molecular structure. 105 Write down the equations for hydrolysis of X F4 and XeF6. Which
of these two reactions is a Redoxreaction?
ANS-
(ii) All noble gases have full s and p outer electron shells, so they do not form
chemical compounds easily. However, in heavier members like Xe, the
outermost electrons experience a shielding effect from the inner electrons, so
they are comparatively easily ionised. Hence, the first ionisation energy is
roughly equivalent to that of molecular oxygen. Xe reacts with
electronegative elements like fluorine and oxygen to form stable compounds.
111 Why has it been difficult to study the chemistry of radon? xix O2 F2, O F2, Cl2O Br2O [thermal stability]
ANS-It is difficult to study the chemistry of radon because it is a radioactive xx Cl2O, ClO2, Cl2O6, Cl2O7 [thermal stability]
substance having a half-life of only 3.82 days. Also, compounds of radon - ANS-
such as RnF2 have not been isolated. They have only been identified.