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TPG4170
Rock Acoustics
Rune M. Holt
Table of Contents:
1. Summary of poroelasticity.
The elastic behaviour of porous media (such as reservoir rocks) is described by so-
called poro-elastic theory. The prime developer of this theory was Maurice A. Biot, and
it is therefore often referred to as Biot theory.
The main difference between poroelastic and standard solid elastic theory is that
because of the two material phases (solid s; fluid f), one needs to account for
Biot introduced the zeta-parameter because it is convenient for describing fluid flow in
a porous medium. The time derivative of is directly related to the flow rate in Darcys
law. is a measure of the ratio of displaced fluid volume to total volume; i.e.
V f V p pf
= = ( ) (1.1)
V Vp Kf
The displaced fluid volume is resulting from the change in pore volume (as indicated by
the subscript p), and the compressibility (1/Kf) of the pore fluid.
The relationship between stress and strain in linear elasticity is linear. The simplest
linear form that includes both stress and strain parameters above is:
= K v C
(1.2)
p f = C v M
This is Biot Hookes law for isotropic stress conditions. Let us now consider two
basic tests as examples:
In this case, the pore pressure is kept constant (or zero; or the sample is tested in dry
conditions). Since the stresses in Eq. (1.2) have an absolute meaning, whereas the
strains are only relative, one can write differentials in and pf while keeping v and
; i.e. for the drained test
p f = 0
C2
= ( K ) v = K fr v (1.3)
M
C
= v
M
In the first equation we define the framework bulk modulus Kfr as the drained bulk
modulus, and relate it to the coefficients K, C & M. The latter equation means that the
ratio C/M controls the relation between pore and bulk volume change in this
experiment:
C
V p = V = V (1.4)
M
The parameter is called the Biot coefficient. If only the pore space deforms and the
solid grains are considered incompressible, then the volume change and the pore
volume changes are equal, and =1. If the grains are also compressible, then V p < V
and <1.
Now the pore fluid is kept within the sample with no possibility to escape; i.e.
=0
= K v (1.5)
C
p f =
K
We see that physically K is the undrained bulk modulus. The pore pressure increase is
given by the ratio C/K.
In general, any situation where external stress and / or pore pressure is changing will
produce the same strain as long as the so-called effective stress change is the same:
C
' = p f = K fr v (1.6)
M
This can be seen by eliminating from Eqs. (1.2). This leads to the effective stress
principle, which states that a rock sample deforms as if it is exposed to an effective
stress
ij' = ij p f ij (1.7)
ij is the Kronecker- =1 when i=j and 0 when ij. In practice it means that we can use
Hookes law as in elasticity of solids, but the stress changes must be effective stress
changes, and the elastic moduli must the framework moduli. K is the bulk modulus of
the undrained rock (no fluid expelled; =0), while C and M are other poroelastic
coefficients. These parameters can be related to the elastic properties of the ingredients
of the porous medium, plus the porosity. These relationships can be derived from simple
thought experiments, which are presented in textbooks like Fjr et al. (1992). The
results are:
K fr 2
(1 )
Kf Ks
K = K fr +
Kf K fr
1+ (1 )
Ks Ks
K fr
(1 )
Kf Ks
C= (1.8)
K K
1 + f (1 fr )
Ks Ks
1
M =C
K
1 fr
Ks
Thus;
C K
= = 1 fr (1.9)
M Ks
The upper of the equations above is known as the Biot-Gassmann equation. It can also
be written as
K K fr Kf
= + (1.10)
K s K K s K fr ( K s K f )
Biot hypothesised that the shear modulus is not influenced by the presence of the pore
fluid; i.e.:
Notice that the framework moduli Kfr and Gfr depend on the microstructure of the rock,
in particular on the porosity. Various models exist for these relationships, from
Wave velocities:
The velocities of P- and S-waves in a poroelastic material (in the low frequency limit)
are also expressed in the same way as for a solid material, except that the bulk modulus
now is the undrained bulk modulus K as given by Eqs. (1.8) or (1.10):
4
K + G fr
vP = 3
(1.12)
G fr
vS =
The bulk density is found by adding the fluid and the solid contributions:
= f + (1 ) s (1.13)
If the material is air saturated at room conditions, then K Kfr in the Biot-Gassmann
equation (since the bulk modulus of air is negligible compared to that of the rock
framework). The density is also reduced, because the gas density is negligible compared
to the solid density. As a result of this, the S-wave velocity decreases slightly when a
dry sample is saturated with fluid, while the P-wave velocity normally (but not
necessarily!) increases.
The Reuss model assumes a uniform state of stress, so that the strains of each
component are added, i.e.
1 N
i
= (2.1)
M R i =1 M i
where i is the volume concentration and Mi is the elastic (bulk or shear) modulus of
component i. A well-known example where the Reuss model gives a correct prediction
is a suspension of particles (solid; s) in a fluid (f). The undrained bulk modulus of the
suspension is given by
1 1
= + (2.2)
KR K f Ks
where is the porosity (fluid volume divided by total volume). This is also known as
Woods equation.
In general, the Reuss modulus MR gives a lower bound for the elastic moduli of the
composite. The Reuss bound for the shear modulus GR=0 because the fluid does not
have any shear modulus. Likewise, the drained (frame) Reuss bulk modulus is zero,
since Kf=0 for evacuated pores.
The Voigt model assumes a uniform state of strain, so that the associated stresses are
additive. Thus,
N
M V = M i i (2.3)
i =1
where M again can be K or G. The Voigt modulus represents an upper bound for the
elastic moduli of a composite. It is used to describe the elastic properties of e.g. a
polycrystalline material. The drained (frame) Voigt bulk modulus is
KV = (1 ) K s (2.4)
4
K s + Gs ( K s K f )
+
K HS = Ks 3 (2.5)
4
K s + Gs (1 ) ( K s K f )
3
Ks K f
K HS = ( KR ) (2.6)
K s + (1 ) K f
4
5 K s + Gs Gs
+
GHS = Gs 3
; GHS =0 (2.7)
4
5 K s + Gs 2 (1 )( K s + 2Gs )
3
The potential use of the bounds is to find the permitted intervals for elastic properties of
the composite. Adding more information about the structure of the medium, bounds
may be found which are sufficiently close together that one may use them to actually
predict properties of the effective medium. One assumption which has been made
without actually incorporating microstructural knowledge, is the so-called Hills
average e.g. that elastic moduli may be estimated in a rough way as the average value
between the upper (e.g. Voigt) and lower (e.g. Reuss) bounds.
One model for wave velocity vs. porosity which has been (and still is) used quite often
by the oil industry is the time-average equation. It relates the P-wave velocity vp to
porosity and P-wave velocities of the solid (vp,s) and fluid (vf) phases is an empirical
equation:
1 1
= + (2.8)
Vp Vp,s V f
The theoretical basis for this equation is to assume that the sound wave shares its time
passing through the rock in volumetric proportion in the solid and pore fluid. This is
strictly valid only if the wavelength is much shorter than the grain and pore size, i.e. in
the limit of very high frequency. The fact that dispersion has been found normally to be
quite low in porous rocks may explain the success of this empirically based approach.
When the porosity is lower than c, there will be a fintite framework bulk modulus and
a finite shear modulus. The actual values will depend on porosity, and on the structural
details of the rock, e.g. on the degree of cementation between the grains. With no
further knowledge, a simple assumption is that the framework stiffnesses will vary
linearly from zero at the critical porosity to the values of the solid constituent at zero
porosity, i.e.
K fr = K s (1 ) <c (3.1)
c
G fr = Gs (1 ) <c (3.2)
c
K = K s (1 ) + Kc <c (3.3)
c c
where
1 1 c
= c + (3.4)
Kc K f Ks
The weaknesses of this model are that the critical porosity is not a universal constant -
not even for a given class of rocks, such as sandstones, and that the linear relationship
between moduli and porosity is a very rough approximation. The strength is that the
model is very simple, and does not require any other assumptions about microstructure
than the knowledge of a critical porosity. We will use it further in the course to gain
insight into e.g. effects of lithology, effects of clay content etc. One should however be
careful to use it uncritically in field data analysis.
A modification that can be made to account for the observed diversity of behaviours is
to modify Kfr and Gfr in Eqs. (3.1) and (3.2) by introducing an exponent :
M fr = M s (1 ) <c (3.5)
c
A low value of will describe behaviour of a well cemented rock, while a higher value
will describe the behaviour of a less cemented rock. This is illustrated in Figure 3.2.
It is possible to employ the critical porosity concept also to other rock properties, like
strength parameters. It turns out, for instance, that the unconfined strength of clean
sandstones is described quite well by an equation of the same form as Eq. (3.5) with an
exponent = 2.
Figure 3.1 Undrained bulk modulus vs. porosity for Reuss, Voigts and Nurs
Critical Porosity model.
40
35
30
Bulk modulus [GPa]
25 =1/2
20
=1
15
10
5
=2
0
0.00 0.10 0.20 0.30 0.40 0.50
Porosity
Several more microscopically based theories exist in the literature. They can be divided
into two main groups:
While the inclusion models appear most realistic for hard rocks with low porosity, they
find significant application within sedimentary rock physics. One reason for this is that
they explicitly express elastic moduli as function of porosity, while porosity plays a
more implicit role in the grain pack models.
Figure 4.1 shows the basic idea of an inclusion model: The elastic properties of a sphere
of solid material containing a spherical void are calculated. Then, as a next step, the
effect of adding several inclusions is calculated by simply adding their influence
independently. This impies that the voids are sufficiently far apart from each other not
to interact; i.e. that the inclusion density is small. For spherical pores in a solid host
material, it has been found:
Ks, Gs
Vc
V
1 1 3K s
= 1 + 1 + (4.1)
K * K s 4Gs
1 1 15 K s + 20GS
= 1 + (4.2)
G * Gs 9 K S + 8GS
These expressions are strictly valid only for low porosity. One way to make them more
general is to make the effective medium self consistent: this is done by replacing
(mathematically) the solid material surrounding the inclusion with the resulting
effective medium. The solutions can not in general be expressed analytically. They do
however have a form that leads the elastic moduli to 0 at a certain porosity., hence,
not unlike the critical porosity model.
In most cases the spherical porosity model overestimates the elastic stiffness of real
rocks. The main reason for this is that the pore shapes found in natural rocks deviate
strongly from spherical. Rather, a significant amount of low aspect ratio pores normally
exists. Such pores are much more compliant than spherical pores, and play a more
important role in controlling the wave velocities. Although there are models that may
incorporate inclusions of various shapes, we will here only mention the so-called crack
models: A penny-shaped crack is defined as an ellipsoid with a short axis = 2c and a
c
long axis = 2a, so that the crack aspect ratio is = . Cracks affect the elastic moduli
a
through a parameter called crack density ():
N
= < a3 > (4.3)
V
The crack porosity is related to the crack density as
4
C = (4.4)
3
Since the aspect ratio for a crack is small, the crack porosity is usually also small. It
does however, as said above, have a significant impact on the elastic moduli. For non-
interacting cracks with a random spatial and orientational distribution, one finds:
2a
2c
1 16 1 s
2
1
= 1 + (4.5)
K * Ks 9 1 2 s
1 1 32 (1 s )( 5 s )
= 1 + (4.6)
G * Gs 45 ( 2 s )
16 1 fr 2
K fr = K s 1 (4.7)
9 1 2 fr
32 (1 fr )( 5 fr )
G fr = Gs 1 (4.8)
45 ( 2 fr )
where
16
fr s 1 (4.9)
9
We see that the elastic moduli 0 as the crack density becomes large enough. For such
large crack densities, one would however not expect the basic assumption behind the
theory to be valid anymore: Cracks tend to coalesce and not be randomly distributed in
space when a material approaches the failure limit.
We may add the effects of pores and cracks in the case of reasonably low porosities and
cracke densities, i.e.
M fr M s (1 a p p bc ) (4.10)
M represents bulk or shear modulus, ap and bc are constants (depending on the solid host
material properties), and p is the spherical (equant) porosity. Since cracks are much
more compliant than spherical pores, the last term gives rise to stress dependency.
When an external stress is applied, the lowest aspect ratio cracks are closed first, and
then subsequently higher aspect ratio cracks are closed as the stress increases. This leads
to a relatively rapid increase in moduli until all cracks are closed. From then on, further
stress increase will give rise to increase in moduli by reduction of porosity.
The second class of effective medium theories for porous media is grain pack
descriptions. The basic element in these models is the elastic contact between two
grains in contact. For two equally sized spheres in contact, the elastic contact law has
been derived by Hertz and Mindlin.
Figure 4.3 shows a sketch of such a grain contact. The two spheres have radius a. The
contact area between the spheres is a circle with radius b. s represents the displacement
as a result of a compressive force F applied to the pair of spheres. Following the
arguments of deGennes (1996) (Note: This is not a mathematical proof, buthandwaving
arguments of a Nobel prize winner in physics), the contact stress is then of the order
(F/b2). The contact strain is of the order (s/b). From geometrical considerations, s/b
b/a. Thus;
F s
;
b2 b
3 1
(4.11)
s 32 2
F sb s a a ( )
2 2
a
The global stress is of the order (F/a2) , and the global strain is of the order (s/a).
Thus;
3
2 (4.12)
We see that this is a nonlinear elastic element, since stress is not directly proportional to
strain. The stiffness is
d 1 1
M 3
2
(4.13)
d
Hence, the wave velocities, which are proportional to the square root of M, should
1
increase with external stress as . For a random packing of equally sized spheres, the
6
1
(1 ) 2 n 2Gs2 3
K fr = (4.14)
18 (1 s )
2 2
This result is often referred as the Hertz-Mindlin model, or the Walton model. n is the
coordination number, being defined as the average number of spheres in contact with a
given sphere. Typically n decreases with increasing porosity, from around 12 at closest
packing (porosity 26%) to 6 at most open packing (porosity 48%).
The shear modulus depends on wether the spheres are considered rough or smooth. The
results are:
1
1 12(1 ) 2 n 2Gs2 3
G fr ;smooth = (4.15)
10 2 (1 s ) 2
1
5 4 s 3(1 ) 2 n 2Gs2 3
G fr , rough = (4.16)
5(2 s ) 2 2 (1 s ) 2
Table 5.1: P- and S-wave velocities in rocks and some common materials.
A main message to be learnt from these numbers is that there are large variations within
each class of rocks. Natural rocks like sandstone, shale or limestone should not be stated
to have a typical P- or S-wave velocity. Rather the velocities depend on a number of
factors, like the the composition and the microstructure of the rock itself (lithology,
porosity, degree of cementation, fluid saturation, saturating fluid, etc.), and the
boundary conditions under which the measurement is performed (w.r.t. stress, pore
pressure, temperature). In the following chapters we will describe observed wave
velocities in different rocks and see how these factors influence on the velocities. The
results will be compared to theoretical models where available. We will use the Biot
Gassmann model as our macroscopic basis, and because of its simplicity, we will use
the critical porosity model to illustrate some of the observed relationships.
The reader is also referred to the more extensive Rock Physics Handbook by Mavko et
al. (1998).
Figure 6.1 shows measured P- and S-wave moduli in dry, clean sandstones (after
Murphy et al., 1993). They show a nice almost linear trend, and were probably
instrumental in guiding the Stanford Rock Physics group led by Amos Nur to suggest
their critical porosity model (see also Chapter 3). Based on such a model, we would
write for the wave velocities in a dry porous medium
4
( K s + Gs )(1 )
3 c
vp = (6.1)
(1 ) s
Gs (1 )
c
vs = (6.2)
(1 ) s
where Ks and Gs are the solid mineral bulk and shear modulus, s is solid mineral
density, is porosity, and c is critical porosity. The exponent inserted here is usually
taken = 1, but there is evidence from laboratory data that weak rocks would have > 1,
and strong rocks have < 1. Critical porosity in sandstone seems to be 0.4, whereas in
chalk it is 0.6 0.7. In shale, nobody knows (yet).
Figure 6.1: High pressure laboratory measurements of the bulk and shear frame
moduli (i.e. of dry rock) for clean quartz sandstones (from Murphy et al.,
1993).
7000
6000 vp
5000 =2
Velocities [m/s]
=2 =1/2 =1
4000
=1
3000
vs =1/2
2000
1000
0
0.00 0.10 0.20 0.30 0.40 0.50
Porosity
Figure 6.2: P- and S-wave velocities in dry sandstone with a critical porosity of 0.40,
modelled for different values of the exponent .
Clearly, the porosity dependence will change with fluid saturation. We will discuss the
effects of a saturating fluid in a subsequent chapter, but the general effect is to increase
i) the bulk modulus, according to the Biot-Gassmann theory, and ii) the density, by
adding a contribution f. Normally this leads to an increase in P-wave velocity,
because the bulk modulus increases more with fluid saturation than the density. The
result is also a different porosity dependence of vp than would be predicted from Eq.
(6.1). This is seen in Figure 6.3, which also contains traditional empirical relations used
by the industry. The most common of these is the socalled time-average (Wyllie's)
equation, which simply states that the travel time through a rock is a volume weighted
average of the travel times in the solid and in the fluid phase:
1 1
= + (6.3)
vp v f v p,s
Fundamentally, one should not expect this equation to be valid, except maybe at very
high frequencies (since it is a kind of a ray approximation). For shear waves, it is
obviously not valid, since there is no S-wave velocity in the fluid. In addition, let us
briefly mention Raymer's equation, which also may be applied to fluid saturated rocks:
Figure 6.4shows wave velocities in water saturated sandstones with different porosities.
The figure has two distinct features: There is a clear trend of decreasing velocity with
increasing porosity. The best fit by Wang & Nur (1992), from whom these data are
taken, was (velocity in [km/s]; porosity as fraction):
7000
6000
4000
Time Average
3000 Raymer
2000
0
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00
Porosity
Figure 6.3: P-wave velocity vs. porosity in water saturated sandstone; calculated
using the Biot-Gassmann model with a critical porosity; with the time-
average, and with Raymers equation.
We have focussed on sandstones in the examples above, but the models are of course
applicable to other types of rock as well. In Figure 6.5 we show the trend found in North
Sea shales. We notice that in this case, the data lie close to the prediction of the
suspension model.
6000
P-wave velocity (normal) (m/s)
5000
4000
3000
2000
1000
0
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70
Porosity
Figure 6.5: P-wave velocity normal to bedding vs. porosity (derived from water
content) in shales from the North Sea. The curve is a modified suspension
model, where the P-wave modulus is used for the solid modulus. The data
clouds represent measurements performed during rock mechanical tests
with each sample (from Holt et al., 1997).
The vp/vs ratio can in some circumstances be a better lithology indicator than the
velocities themselves. For example vp/vs is normally higher in shale than in sandstone;
thus, it is possible from seismics to distinguish between e.g. cap rock and reservoir rock.
Theoretically, using a critical porosity approach, the vp/vs ratio in a dry rock is governed
by the elastic moduli of the solid minerals, and independent of porosity:
4
vp K s + Gs
( ) dry = 3 (7.1)
vs Gs
Typical bulk and shear modulus values for sand (quartz), chalk (calicite) and shale are
given in Table 7.1. The values for shale are extrapolated to zero porosity from
measurements with shale samples, since isolated clay minerals are hardly available for
measurement. The low values indicate that bound water is included in the values of the
solid material moduli. From these values, Eq. (7.1) predicts
Table 7.1: Solid mineral bulk and shear modulus for sand, chalk and shale.
If we account for fluid saturation, e.g. by using the Biot-Gassmann equation for the bulk
modulus
Kf 2
K = K fr + (7.2)
Kf
1+ ( )
Ks
K fr
with = (1 ) , then we find that the vp/vs ratio increases slightly with porosity. In
Ks
case of a critical porosity law:
vp 4 Ks K f 1
= + + (7.3)
vs 3 Gs c Gs Kf
[c + (1 c )][1 ]
Ks c
Since Kf is usually significantly smaller than Gs, the 3rd term under the square root is
usually also small; excepth when the porosity is near the critical porosity. Thus; vp/vs
will still be a good lithology indicator. Using brine as pore fluid (Kf=2.7 GPa), we find
for porosities well below c:
vp/vs ~ 1.5 1.6 for water saturated sandstone with moduli as given in Table 2
vp/vs ~ 1.9 2.0 for water saturated chalk with Ks=70; Gs=30 GPa
vp/vs ~ 2.1 2.3 for water saturated shale with Ks=22.5; Gs=7.5 GPa
Figure 7.1: vp/vs vs. porosity for a brine saturated sandstone; calculated using Eq.
(7.3). Critical porosity = 0.40. illustrates the vp/vs behaviour for brine saturated
sandstone.
8.0
7.0
6.0
5.0
vp/vs
4.0
3.0
2.0
1.0
0.0
0.00 0.10 0.20 0.30 0.40
Porosity
Figure 7.1: vp/vs vs. porosity for a brine saturated sandstone; calculated using Eq.
(7.3). Critical porosity = 0.40.
Data from laboratory core experiments and sonic logs are summarized by Mavko et al.
They report the following typical vp/vs values
In addition:
We have here looked at vp/vs as a main parameter for lithology identification. Another
may be linked to anisotropy. In particular, shale at depth is lithologically anisotropic.
We have however assumed in the theoretical predictions that the solid phase is mono-
mineralic. This is of course not true: Most sedimentary rocks contain many minerals,
and thus, the solid bulk and shear moduli need to be refined. A particular example is
given in the next Chapter, where we consider effects of clay on velocities of sandstone.
If clay is part of the load bearing framework, then the clay minerals contribute to the
solid modulus Ks (and to Kfr). This may be modelled e.g. by using a Voigt average for
the solid (bulk and shear) moduli:
Vcl
vcl = (8.3)
Vcl + Vqtz
Figure 8.1 shows the predicted P-wave velocity vs. porosity for different clay fractions
according to this model. We see that increasing clay content reduces the P-wave
velocity.
On the other hand, if clay occur as pore fill, it can be modelled as part of the pore fluid,
using a suspension model.
1 1 cl
= cl + (8.4)
K f K cl Kw
Vcl
cl = (8.5)
+ Vcl
The result is that increase in clay content leads to an increase in P-wave velocity. Thus;
by observing trends in sonic logs for areas where an independent clay indicator exists,
one may be able to distinguish between clay as pore fill (which is detrimental to
permeability) and clay as part of the solid matrix.
6000
vcl = 0.05
vcl = 0.15
vcl = 0.25
vcl = 0.35
5000
P-wave velocity [m/s]
4000
3000
2000
0.00 0.10 0.20 0.30
Porosity
Figure 8.1: Calculated P-wave velocity vs. porosity for water saturated sandstone
with different clay contents. The plot was derived using Biot-Gassmann
and a critical porosity model, where the solid modulus is given by a
Voigt average of clay and quartz contributions.
Based on experimental results, Han and later Vernik (1994) distinguished between
sandstones according to their clay content C and made empirical fits based on a
classification of siliclastics, representing clean arenites, arenites, wackes, and shales:
Figure 8.2 shows a presentation of such data reproduced from Hans Thesis by Mavko
et al. (1998). The resemblance with Figure 8.1 is striking.
Han, Nur & Morgan derived empirical fits for water saturated sandstone (at 40 MPa
confining stress) with porosity below 30% and clay content C below 50%:
Marion, Nur, Yin & Han measured with samples made by mixing sand and clay
(kaolinite) powder, with clay contents ranging from 0 to 100%. They found that there is
a maximum in velocity (associated with a porosity minimum) on the transition between
shaly sand and sandy shale. This is shown in Figure 8.3.
Figure 8.3: P-wave velocity vs. clay content in sand-clay mixtures at different
stresses. From Marion et al., 1992.
In addition, the framework moduli (Kfr and Gfr) are normally assumed unaffected by the
saturating fluid (neglecting possible chemical interactions).
4
K+ G
Thus; P-wave velocity v = 3 may increase or decrease, depending on whether
p
G
the fluid contribution to K or is the larger. S-wave velocity vs = will decrease
upon saturation, since G is assumed unaffected. At high frequencies, fluid induced
dispersion may cause an increase in both velocities.
The Biot Gassmann theory can be used to predict the effect of liquid saturation in the
low frequency limit. Figure 9.1 shows the predicted effect of brine saturation on P- and
S-wave velocities. As above, typical parameters for sandstone have been used, together
with a critical porosity model with c = 0.40. We see that the P-wave velocity increases
upon saturation at high porosities; or when the P-wave velocity is below 3500 m/s. At
higher velocities, the rock stiffness is so high that the fluid contribution to it becomes
less significant than the density increase. The S-wave velocity is seen to decrease as a
result of saturation in all cases, as expected.
7000
6000 vp sat
vs sat
vp dry c-p
Wave Velocities [m/s]
vs dry c-p
5000
4000
3000
2000
1000
0
0.00 0.10 0.20 0.30 0.40
Porosity
Figure 9.1: Wave velocities for dry and saturated sandstone, based on Biot-
Gassmann theory with a critical porosity law.
The effect of partial saturation depends on the distribution of the fluid phases in the pore
space. If mixed at a fine scale, the fluid properties may be estimated through a Reuss
(isostress) average, i.e.
1 S
= i (9.1)
Kf i K f ,i
Si represents the concentrations of fluid phase i. For water containing air bubbles, the
suspension model is appropriate. Since air has a bulk modulus (1.410-4 GPa) which is
negligible compared to that of water (2.2 GPa), the fluid bulk modulus is governed by
the gas modulus, except when the water saturation approaches 1. This is also seen in
laboratory experiments: Only when the water saturation exceeds 95% or more is the P-
wave velocity of the rock found to increase. Acoustic wave measurements are therefore
good indicators of gas (shallow gas, gas zones in reservoirs).
It is worthwhile to notice that for very low water saturation levels, such as when the
rock is ovendried before measurements are performed, a strong increase in P-wave
velocity may also be seen. This observation implies that the water has a certain
softening effect on the grain contact. Since most rocks in the Earth have a certain water
saturation, this means that laboratory experiments for wave velocity measurement
should not be performed with oven dried cores.
The basis for Equation (9.1) is that the various fluid phases feel the same stress; in order
words, that the fluid pressure is in equilibrium between the different phases. This
implies that pressure diffusion may take place during the passage of the wave, say in the
course of one period. Hence, from standard diffusion theory, the size of the patches
should be related to the time scale as
Kf k 1
l Dt (9.2)
f
Here D denotes a diffusion coefficient, which depends on the permeability k and the
fluid viscosity , in addition to the bulk modulus of the pore fluid, and the porosity. For
the seismic frequency range (10 100 Hz) we find that the patches must be smaller than
10 30 cm in order for the Reuss average to be used. If this condition is not fullfileld,
other mixing rules than Eq. (9.1) are required. One obvious alternative is the Voigt
average, which gives an upper bound to the fluid bulk modulus:
K f = S i K f ,i (9.3)
i
More realistic averages require more detailed knowledge about the patchiness. If this is
not available (which is the normal case), one may for instance use the following
approach for the bulk modulus of the rock:
1 1 1
= (9.4)
K 4 G fr
K + G fr
3
Figure 9.2: P-wave velocity vs. water saturation in a gas-water saturated porous
rock. The uniform saturation case is modelled with the Reuss average,
and the patchy case denoted by the upper limit Voigt model Laboratory
data are also shown. The figure is taken from the Rock Physics course by
Gary Mavko at Stanford University.
http://pangea.stanford.edu/courses/gp262/Notes.htm
The calculation leading to Figure 9.1 is performed with fluid properties typically seen at
room conditions. The density and bulk modulus of fluids (both liquid and gas) are
however sensitive to pressure as well as to temperature, and will therefore be quite
different under reservoir conditions than at atmospheric conditions. The bulk and shear
modulus of the rock framework is also stress and pore pressure dependent, so to obtain
realistic values from core measurements in the laboratory is a tedious task.
Table 9.1: Characteristic elastic properties and densities of typical pore fluids
under different pressure and temperature conditions.
Let us now look in some detail at the fluid properties: In an ideal gas, the pressure P is
proportional to the number of molecules per volume unit (N/V), to Boltzmanns
constant k and to absolute temperature Ta (in [K]):
PV = NkTa (9.5)
P
( )T = P (9.6)
V / V
The density is
N
= mm (9.7)
V
kTa
v= (9.8)
mm
This is of course a huge oversimplification for real gases and liquids. Some realism is
added by considering the process of acoustic wave propagation as adiabatic, not
isothermal as was implicit in the derivation of Eq. (9.8). Thus the bulk modulus in Eq.
(9.6) has to be multiplied by , which is equal to the ratio of the heat capacities
measured under constant pressure (Cp) and constant volume (Cv) conditions:
kTa
v= (9.9)
mm
The ideal gas law is also not a good approximation for a real gas or liquid. An
improvement can be made by multiplying the right hand side of the ideal gas law by a
pressure and temperature dependent so-called compressibility factor Z;
PV = ZNkTa (9.10)
In addition, the variable composition of natural gases adds further complexity. We will
here only give the following empirical relationships (from Batzle & Wang, 1992) for
natural gases under pressures and temperatures that are common in petroleum
exploration and production:
Gas density is
28.8GP
(9.11)
ZRTa
where G is the specific gravity, i.e. the ratio of gas density to air density at 15.6 C and
atmospheric pressure. G is 0.5 0.6 for methane, and 1.5 2 for gases with heavy
components or high carbon numbers. P is given in [MPa].R is the gas constant (=8.31 J /
g mole C).
1 2 Ppr
1.2
where the pseudopressure Ppr and pseudocritical temperature Tpr both should not be
0.1 or more.
P
Ppr = (9.14)
4.892 0.4048G
Ta
Tpr = (9.15)
94.72 + 170.75G
P
Ks 0 (9.16)
Ppr Z
1
Z Ppr T
where 0 is
5.6 27.1
0 = 0.85 + + 8.7 exp 0.65( Ppr + 1) (9.17)
( Ppr + 2) ( Ppr + 3.5) 2
The equations show that bulk modulus and density both increase with increasing
pressure and increasing gravity, and decrease with increasing temperature. This is
illustrated in the examples in Table 3 and further in Batzle & Wangs Paper.
The (P-) wave velocity in brine can be fitted to the following empirical relation:
vbrine = vwater + S(1170 9.6T + 0.055T 2 8.5 105T 3 + 2.6P 0 0029TP 0.0476P2 )
(9.18)
+S1.5 (780 10P + 0.16P2 ) 1820S 2
4 3
vwater = wijT i P j (9.19)
i =0 j =0
The coefficients wij are given in Table 9.2. When applying Eqs. (9.18) and (9.19) the
velocities are given in [m/s], S is the salinity in weight fraction [ppm/1000.000], T is
temperature in [C], and P is pressure in [MPa].
In addition, the densities of brine and water (in [g/cm3]), respectively are given by:
brine = water + S{0.668+0.44S +1106 [300P 2400PS +T(80 + 3T 3300S 13P+ 47PS)]} (9.20)
Table 9.2: The coefficients wij for calculation of wave velcoity vs. pressure and
temperature in water (taken from Batzle & Wang; 1992).
3.5
Salinity 20 % Bulk modulus of brine
P = 1 atm.
3.0
Bulk Modulus [GPa]
2.5
0.5
0.0
0 50 100 150 200 250 300
Temperature [C]
Figure 9.3: Calculated bulk modulus of brine vs. temperature under different
conditions of pressure, salinity, and dissolved gas content.
Predicted velocities for brines under different conditions of pressure and temperature
are shown in Figure 9.3. The following main features should be noticed:
When saturation is partial, then the effect of gas on the fluid modulus must be
estimated. If gas is dissolved, then one generally assumes a slight reduction of fluid
modulus with respect to that of the gas free pore fluid. The bulk modulus of brine with
dissolved gas is thought to follow a relationship of the form
K brine
K brine ( with dissolved gas ) = (9.22)
1 + 0.0494 RG
1.5
log10 RG = log10 (0.712 P T 76.71 + 3676 P 0.64 ) 4 7.786 S (T + 17.78) 0.306 (9.23)
The (P-wave) velocity in oil (Figure 9.4) is also temperature and pressure dependent.
There is a strongly decreasing trend of bulk modulus (and velocity) with increasing
temperature, and increasing modulus (and velocity) with pressure. The equations
leading to this plot are also based on no compositional changes as a function of pressure
and temperature. These equations are (for dead oil):
1
0 2 1
1
v = 2096 3.7T + 4.64 P + 0.0115 4.12(1.08 0 1) 1 TP (9.24)
2
2.6 0
where 0 is the density of the oil measured at 15.6 C and atmospheric pressure. The
density under pressure and temperature conditions is
P
= (9.25)
0.972 + 3.81 104 (T + 17.78)1.175
Again, dissolved gas, which is present in live crude oil, reduces the bulk modulus (and
velocity), more so than in brine. This means that laboratory measurements on dead
oils can be quite misleading. Again the effect of dissolved gas is incorporated through a
1.205
( 4.072
RG = 0.02123G Pe 0 0.00377T
(max)
(9.27)
The velocity is now calculated with Eq. (9.24), but replacing the density 0 with a
pseudodensity :
0
'= (1 + 0.001RG ) 1 (9.28)
B0
where
1.175
G 1
B0 = 0.972 + 0.00038 2.49 RG ( ) 2 + T + 17.8 (9.29)
0
0 + 0.0012GRG
liveoil = (9.30)
B0
Clearly the velocity behaviour is sensitive to the composition of the oil, and the plot in
Figure 9.4 is given for one fixed composition.
2.5
Bulk Modulus of Oil
P = 1 atm.
2.0 P = 50 MPa
Bulk modulus [GPa]
1.5 P = 25 MPa
1.0
0.0
0 50 100 150 200 250 300
Temperature [C]
Figure 9.4: Calculated bulk modulus of oil vs. temperature for different conditions of
pressure. Also shown is the result for a live oil, containing dissolved gas.
Figure 10.1 shows predicted temperature dependence in dry and liquid saturated
sandstone using the temperature dependence found in quartz in a critical porosity law
for the frame moduli, and the temperature dependence of fluid properties described
above in the Biot-Gassmann equation. The expected trend, which is in agreement with
observations, is thus that the velocities decrease with temperature, and more so in
saturated than in dry sandstone.
4000
Pressure: 25 MPa
vp dry
vp brine
P-wave Velocity [m/s]
3500 vp oil
3000
Figure 10.1: Calculated temperature dependence of P-wave velocity in dry, oil- and
brine-saturated sandstone.
In most rock cores, wave velocities increase strongly with increasing stress at low stress
levels, and level off at high stresses. This is commonly observed in sandstone. An
example is shown in Figure 11.1.
First, let it be pointed out that the often made basic assumption of linear elasticity
implies that elastic moduli are constants independent of stress. The observation of
stress dependence therefore indicates violence of the basic assumption. This may
happen through stress changes sufficiently large to alter porosity (which is assumed
constant in the linear poroelastic theory), or it may happen because of a nonlinearity in
the stress strain relationship.
The obvious physical explanation for such nonlinearities is that an external stress
improves the grain to grain contacts and / or closes microcracks / microfissures in the
rock, thereby increasing the stiffness. This means that a well cemented rock with
welded grain contacts is expected to show less stress sensitivity than a poorly cemented
rock with many Hertzian grain contacts. It also implies that a cored rock, which has
been unloaded from its in situ stress state and therefore contains microcracks, is
expected to show much stronger stress sensitivity than the same rock under virgin
conditions in situ. The effect of such core damage on wave velocities and their stress
dependence have been discussed elsewhere (e.g. Fjr & Holt, 1999; Nes et al, 2002).
2750
2700
P-wave velocity [m/s]
2650
2600
2550
2500
0 5 10 15 20 25 30 35
Figure 11.1: Characteristic stress dependence of wave velocities as seen in most rock
cores.
A few exceptions to the general behaviour illustrated in Figure 11.1 can be mentioned.
In high porosity shales, the stress dependence effect is often quite small. This is thought
to be because water always covers clay particles. Grain contacts are then often
constituted by water, which in itself is thought to be stress insensitive. In chalk,
increasing hydrostatic stress may lead to pore collapse which causes a velocity
reduction because the breaking of grains and grain bonds leads to a weakening of the
chalk structure. This is illustrated in Figure 11.2.
Figure 11.2: Measured velocities vs. stress in Red Wildmoor sandstone, Fullers Earth
(claystone) and outcrop chalk. From Holt et al., 1991.
Velocities depend on an effective stress ', which is the external stress minus a certain
contribution from the internal (pore) pressure pf:
' = p f (11.1)
The coefficient is normally assumed to be close to 1, but values < (and >) 1 may be
found. From Eq. (11.1) one sees that a high pore pressure plays the same role as a low
external stress, causing the sound velocity to be reduced. This is used in the estimation
of abnormal pore pressures from logs (and may also be used in seismics). Since the
expected trend in a homogeneous formation would be a monotonous increase of
velocity with depth (because the effective stress increases with depth), an overpressured
zone shows up as a low velocity zone breaking the expected trend.
It is however important to underline that the effective stress law above is not the same
as the Biot effective stress law from linear poroelasticity. Here we consider the stress
dependence of an elastic parameter, which already means that we are beyond linear
elasticity. Further, as seen above, the pore pressure has an intrinsic effect on the bulk
modulus and density of the pore fluid, without affecting the rock framework. This is
illustrated in Figure 11.3, which shows calculated P-wave velocities for a rock saturated
with brine and with oil, for a case where the framework is modelled as stress
insensitive. If the effective stress principle applied, we would expect the same stress
sensitivity independent of fluids, and if =1 (as is conventionally thought), there would
not be any stress dependency of the saturated rock in this case.
2900
T=150 C
Brine Saturated Rock
3.5% salinity
2800
P-wave velocity [m/s]
2500
0 10 20 30 40 50
Figure 11.3: Calculated P-wave velocity vs. external stress (=pore pressure) in a
sandstone where the framework is assumed stress insensitive.
When a rock sample is stressed in anisotropic stress conditions, the wave velocities
become anisotropic. This is particularly the case near failure (Figure 11.4), where the
velocities with propagation direction and / or polarisation along the minor principal
stress direction are found to decrease substantially. This is result of opening of
microcracks (grain bond breakage) in this direction. It is also the case for a core sample
retrieved from the Earth, where stress release has caused development of an oriented
microcrack distribution, which carries a memory of the in situ stress state.
The presence of fractures or cracks smaller than the wavelength will significantly
reduce sound velocities. This essentially happens because the stiffness is strongly
reduced by the presence of cracks. The stress dependence discussed above is related to
closing of microcracks. If the fractures are larger than the wavelength, they will act as
reflectors.
Figure 11.4: P- velocities along (axial) and prependicular (radial) to the major
principal stress during a triaxial test with sandstone (failure strain:
0.015).
Let us finally look at the stress changes that may occur in a depleting reservoir. Clearly,
these stress changes may produce effects that can be seen in time-lapse seismics. For a
reservoir which is relatively large in extent compared to thickness, one may assume that
(i) there is no horizontal strain during depletion; and (ii) the reservoir feels the full
weight of the overburden at all times (no shielding; or stress arching). Hookes law
may now be used to estimate the stress change, as well as the compaction and porosity
change associated with depletion. From Hookes law we write
1
x = x y z
E E E (11.2)
1
z = x y + z
E E E
We now associate the z-direction with the in situ vertical (v) direction, and the x- and y-
directions with the in situ horizontal (h) directions. Here we assume the in situ stress to
be isotropic (=h) in the horizontal plane, but that assumption does not affect the results
below)According to poroelasticity theory, we need to replace the stresses with the
effective stress changes occurring during depletion. The elastic parameters to be used
are those of the drained rock framework. Hence:
1
h = 0 = h' fr h' fr v'
E fr E fr E fr
(11.3)
h 1
z = = fr h' fr h' + v'
h E fr E fr E fr
Since the total vertical stress is not changing, the effective vertical stress change in the
reservoir is directly given by the pore pressure change:
v' = p f (11.4)
From the first of the two equations under (11.3) we then find the horizontal effective
stress change as
fr
h' = v' = fr (p f ) (11.5)
1 fr 1 fr
For a Poisson ratio of 0.25, the effective horizontal stress increase will be 1/3 of the
effective vertical stress increase. Since the total vertical stress is constant, the total
horizontal stress is actually decreasing during depletion. Notice that depletion implies
that the pore pressure change pf is negative.
The second equation under (11.3) permits us to compute the compaction h (in meters),
given the initial thickness h of the reservoir. Combining with Eq. (11.5) we find that
(1 + fr )(1 2 fr ) 1
h = (p f ) h = (p f ) h (11.6)
E fr (1 fr ) 4
K fr + G fr
3
The porosity change during depletion can also be calculated (more tedious). The result
is:
1
= 1 ( p f ) (11.7)
K fr
1 2 fr
= v + 2 h = p f (11.8)
1 fr
The porosity changes during depletion are usually small, and the direct effect of a
porosity change on wave velocities will normally also be small. The stress changes may
however be sufficiently large to exceed the elastic limits, so that new faults or fractures
are made within the reservoir (or in the overburden!), or old faults are activated. In
those cases one would expect a significant effect of the stress change on the 4D seismic
response. One would also expect a significant 4D effect when the reservoir is very soft
(Hertzian contacts) or when it is fractured.
Sound velocities are slightly frequency dependent, increasing with frequency from
seismic to ultrasonic frequencies. Typically the total increase in velocity is a few %. The
transition between low and high frequency behaviour depends on pore fluid viscosity ,
and on the dispersion mechanism. If dispersion is caused by global viscous flow of pore
fluid (Biot flow), then
fc (12.1)
If dispersion is caused by local flow (squirt flow) between pores and cracks / pore
throats, then
1
fc (12.2)
The latter mechanism is often thought be the most important in sedimentary rocks.
For most rocks, the seismic frequency range is thought to be well below the transition
frequencies given above. Thus; the seismic velocities are assumed frequency
independent, although they may be smaller than laboratory measured (ultrasonic)
velocities, and also possibly smaller than those measured with a sonic logging tool.
A final note at the end: When computing elastic stiffnesses from wave velocities, one
generally finds that the dynamic elastic moduli are larger than thos measured in a static
experiment. Although part of that can be related to the frwequency dependence
discussed here, the major contribution to the discrepancy comes from the fact that the
amplitude of an elastic wave is too small to trigger non-elastic processes, such as crack
sliding and grain contact plastification. Such processes do however usually contribute to
the static deformation of rock. Thus; for instance, using the P-wave modulus of a dry
rock directly to estimate reservoir compaction (Eq. (11.6)) gives a lower limit to the
actual compaction that will occur in the field during depletion.
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