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2003 Semicond. Sci. Technol. 18 S59

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INSTITUTE OF PHYSICS PUBLISHING SEMICONDUCTOR SCIENCE AND TECHNOLOGY
Semicond. Sci. Technol. 18 (2003) S59S66 PII: S0268-1242(03)34363-9

Diamond diodes and transistors


A Aleksov1, A Denisenko1, M Kunze1, A Vescan1, A Bergmaier2,
G Dollinger2, W Ebert1 and E Kohn1
1
Department of Electron Devices and Circuits, University of Ulm, Albert-Einstein-Allee 45,
89081 Ulm, Germany
2
Department E12, Technische Universitaet Muenchen, 85748 Garching, Germany

Received 28 February 2002


Published 7 February 2003
Online at stacks.iop.org/SST/18/S59

Abstract
Over the past few years a variety of diamond electron devices have been
fabricated, analysed and simulated. This includes Schottky diodes on
boron-doped p+ diamond substrates, boron/nitrogen pn-junction diodes,
bipolar transistors based on this pn-junction and field effect transistors
(FETs) with boron delta-doped channels and hydrogen-related surface
conductive layers. Many of the fabricated devices considered here represent
the current state-of-the-art in this field. This includes the operation of
diamond Schottky diodes at temperatures of up to 1000 C, as well as
diamond FET devices with a cut-off frequency of 30 GHz and channel
current densities of 300 mA mm1. Simulations show that diamond boron
delta-doped FETs might yield an RF-output power density of up to
30 W mm1.

1. Introduction [2] this fact is not detrimental. Two methods are available in
order to establish a p-type conductivity. The first is by boron
The interest in diamond as a material for electronic doping, allowing the formation of various doping profiles and
applications was triggered by the unique physical/chemical concentrations. The acceptor level of boron is 0.38 eV above
properties of this material as well as the capability to grow the valence band edge. However, the activation energy of
diamond homoepitaxially with low dislocation density by the conductivity drops to zero as the doping level approaches
microwave plasma chemical vapour deposition (MPCVD). 1020 cm3 [3].
Due to the large bandgap and the high hole mobility diamond The other method utilizes diamond hydrogen-related
is predestined for the devices with high power handling surface conductive layers. Such layers show a room-
capability at microwave frequencies and for operation at high temperature-activated p-type conduction in a near surface
temperatures and in harsh environments. In this paper, we region [4].
focus on such diamond electron devices developed in our
Devices fabricated on boron-doped layers are Schottky
laboratory leaving aside the potential for sensing applications.
diodes, metalsemiconductor FETs (MESFETs) and junction
Recently, diamond electron devices have made steady
FETs (JFETs). The fabricated Schottky diodes presented here
progress in meeting the expectations set by the ideal material
were the first diamond devices showing a clear breakdown
properties; however, they perform still well below estimated
limits. Thus, the devices presented need still to be understood behaviour allowing for the first time the extraction of the
as proof of concept structures pinpointing towards further breakdown field in a diamond CVD layer for electronic
development. applications [5].
This is especially the case with bipolar transistors (BJTs) The diamond JFETs discussed below utilize boron
using boron/nitrogen pn-junctions since the nitrogen donor delta-doped channels with enhanced activation at moderate
level has an activation energy of 1.7 eV [1] and nitrogen- temperatures [6]. The devices have been operated in a
doped layers, therefore, represent a lossy dielectric with high temperature range from 20 K to 473 K. Operation down to
sheet resistance. However, despite this serious drawback BJT 20 K was possible due to reduced activation energies [4]. In
operation at room temperature (RT) was observed pointing out the FET gate diode advantage was drawn from the high built-
the potential of this device, if a shallow donor can be found. in voltage of the boron/nitrogen pn-junction. Here, the high
Otherwise, diamond electronic devices are unipolar activation energy of nitrogen is not detrimental to the device
devices utilizing p-type hole conduction. Since the hole operation. For the first time diamond FET devices utilizing
mobility in diamond can be as high as p = 1800 cm2 V1 s1 recessed gates for reduction of parasitic resistances and with

0268-1242/03/030059+08$30.00 2003 IOP Publishing Ltd Printed in the UK S59


A Aleksov et al

C H4+ H2 + N2 1000C
Waveguide 10 3

RF-Source
10 1 700C

J (A/cm2)
(ASTEX 5000TM )
10 -1

Plasma 500C
Substrate Feed-through 10 -3

10 -5
R.T.
Boron rod as a solid-state
10 -7
doping source: 300 m -10 0 10 20 30 40 50
boron rod on W-kernel
V (V)
Thermocouple
Figure 2. Operation of diamond Schottky diode from RT to
Figure 1. Diamond MPCVD system with a solid B-doping source 1000 C.
(B-rod).
0
gate-field plates for enhanced breakdown fields were
fabricated and simulated [7]. = 1.7eV
-10
Regarding hydrogen-related surface conductive layers,
diamond MESFETs were fabricated, analysed and modelled
[8, 9]. These devices show high output currents, high break- ln(I0 /T 2) -20
down voltages and high transconductances resulting in high
cut-off frequencies in the microwave regime for devices with
sub-m gate lengths below 0.5 m. -30

2. Technology
-40
The active layers are grown by microwave plasma chemical
1,5 2,0 2,5 3,0 3,5
vapour deposition (MPCVD). The methane concentration in
the gas phase ranges from 0.125% to 1.5%, resulting in growth 1000/T (K-1)
rates from 8 nm h1 to 450 nm h1. The low growth rate is
used for nanometre-precise growth of thin high quality Figure 3. Barrier height of a quasi-metallic highly p-type-doped
diamond layers. Figure 1 shows the MPCVD set-up used Si Schottky contact to diamond.
in these experiments. Reactive ion etching is mostly used for device isolation.
In situ boron doping is obtained by using a solid boron In recent device structures RIE is also used to etch the gate
doping source. Here, a boron rod (with a thin tungsten kernel) recess trench. The etch rate and the morphology of the etched
is introduced into the plasma during growth. This doping surfaces depend mainly on the Ar/O2 ratio. This ratio varies
technique enables the formation of steep doping profiles and
from 0.3 to 10, with an etch rate varying from 1.5 nm min1 to
also the growth of heavily boron-doped metal-like diamond
35 nm min1. Small etch rates are used for nanometre-precise
with NA > 1020 cm3 [10], where the activation energy reaches
etching, which is necessary to adjust the depth of the gate
zero [3]. The chemical doping concentrations were determined
recess trench with nanometre-precision close to the channel.
by elastic recoil detection (ERD) measurements.
In general, structures are patterned by optical (UV)
Nitrogen-doped diamond layers are obtained by
introducing N2 into the gas mixture [6]. The concentration lithography, both for mesa and contacts. For the sub-m gates
of nitrogen in the gas phase is process dependent in between e-beam lithography is used with a standard three-layer resist
1% and 5%, resulting in nitrogen concentrations in diamond of process obtaining T-gate metal structures with gate lengths
about 1 1018 cm3 to 5 1018 cm3 as determined by ERD. down to 200 nm [7, 12].
The electrical analysis of devices with nitrogen-doped layers Contact metals are deposited by sputtering with an ion
confirmed that most of the chemical doping concentration acts beam source or by evaporation, the evaporation being thermal,
as a paramagnetic donor. or by e-beam. The contacts are finally patterned by wet
Diamond layers are structured by selective area epitaxy chemical etching or the lift-off technique.
(SAE) or by reactive ion etching (RIE) in an RF-plasma Since oxygen-terminated devices have a pinned surface
of an Ar/O2 mixture [11]. Selective area epitaxy is used potential at 1.7 eV above the valence band [13] ohmic contacts
mainly for the definition of the heavily boron-doped contact need to be tunnelling contacts, which can be realized by
regions. SiO2 layers are used as mask, since without bias using heavily doped diamond contact areas (NA > 1020 cm3)
enhanced nucleation (BEN) diamond grows only on diamond [14]. On hydrogen-terminated surfaces the surface potential is
and not on SiO2. The SiO2 layer is patterned by using a CF4 unpinned and therefore contact properties (ohmic or rectifying)
process. depend on the metal work function difference to diamond [4].

S60
Diamond diodes and transistors

thickness of the homoepitaxial


103 Ebr = 2x106 V/cm
diamond layer
-2
10
EBR 0 r
2

VBr (V)
VBR =
10 -3
102 2qNA

10 -4 fit
NA (cm-3)
10 -5 101
1016 1017 1018
I (A)

10 -6 0.5 m 1.5 m 3 m 7 m

-7
10 VBR = 14V VBR = 39V VBR = 82V VBR = 192V

-8
10

-9
10

-10
10
-20 0 20 40 60 80 100 120 140 160 180 200

reverse bias V(V)


Figure 4. Breakdown behaviour of Schottky contacts to diamond (inset shows the breakdown-field strength); for details on the extrapolation
of the breakdown field see [3].

3. Diodes highly doped small surface area clusters [18]. Such diamond
diodes also show a clear breakdown behaviour at reverse bias
3.1. Schottky diodes as seen in figure 4. Thus, it was possible to obtain a first rough
estimation of the breakdown field of CVD diamond films with
Diodes for technical applications need to show high blocking
EBR = 2 106 V cm1 [3], which is however still well below
voltages and a low forward loss, i.e. a low series resistance.
the value for natural diamond.
Therefore, diamond pn-diodes are not technologically relevant
for such applications. However, lightly boron-doped (NA 
1017 cm3) Schottky diodes on oxygen-terminated surfaces 3.2. Boron/nitrogen pn-junction diodes and the diamond BJT
show good performance at high temperatures, i.e. acceptable
forward currents and high breakdown voltages at reverse bias. Due to the high activation energy of the nitrogen donor,
In order to enable high-temperature operation of these in the past, nitrogen-doped layers were never considered
diodes a high-temperature stable contact metallization was to be technically relevant. However, studies on junctions
developed. This contact system has several layers. The actual between boron- and nitrogen-doped diamond layers clearly
Schottky contact to diamond is formed by quasi-metallic Si show that despite its deep level the fabrication of abrupt pn-
obtaining a temperature stable interface [15]. The temperature junctions with a high built-in voltage is feasible [1921].
stability of the contact is further improved by incorporation of The pn-junctions and the BJTs were fabricated on heavily
nitrogen and carbon. Such contacts show no change of the boron-doped HTHP single crystals (Sumitomo). The junctions
Schottky barrier height (SBH) up to 700 C [16]. However, were fabricated entirely from epitaxially grown layers.
due to the relatively high resistivity of the quasi-metallic Si this The pn-junction properties were studied by the
layer has to be as thin as possible and the contacts need a low temperature-dependent analysis of the forward and reverse
resistance cap layer such as Au. In order to avoid alloying of current characteristics (I V ) and by RT capacitancevoltage
Au and Si at elevated temperatures a diffusion barrier layer is (CV ) measurements. The I V characteristics of a pn-
necessary between these layers, such as W:Si:N. Diodes using junction diode are shown in figure 5. The curves in figure 5
this contact metal stack have operated up to 1000 C [16, 17] as show that in the forward direction the diode can be fitted with
seen in figure 2. Plotted in a linear scale almost no leakage is the analytical model for a pn-junction with a temperature-
observed up to 800 C for V reverse < 20 V. This measurement dependent series resistance. This fit is used to estimate
has been conducted in vacuum in order to protect the device the specific resistance of the n-layer and the temperature
from oxidation, the contact was without the Au overlayer, due dependence of the saturation current density JS extrapolated
to diffusion barrier failure at temperatures above 800 C. from small currents. At RT the specific resistivity of the n-
From the Arrenius plot of the saturation current I0 the layer is extremely high n = 10.8 G cm. From the Arrenius
SBH is extrapolated to approximately 1.7 eV (figure 3), a plot shown in figure 6, JS was found to have an activation
value in good agreement with other Schottky contact metal energy of 3.8 eV. This value is expected, if the energy level of
systems on oxygen-terminated diamond [10]. The reverse the nitrogen donor is taken as the position of the Fermi level
diode current shows very low activation up to 500 C, most EF in the n-doped part, EA = 3.8 eV = 5.51.7 eV = EG
likely due to the stabilized interface, possibly passivating (EC ED) [22].
defects. Nevertheless, the ideality factor is dominated by this This result indicates that at the diamond boron/nitrogen-
current and approaches n  1.1 only for high temperatures. doped interface indeed a pn-junction is formed and this can be
Thus, the reverse current is still well above the theoretical limit, confirmed by CV measurements. Here, the transition of the
assuming that it originates from the crystal defects acting as capacitance from the space-charge to the diffusion-dominated

S61
A Aleksov et al

10-4 400C
NT Rb(T)
G 50 nm p+ emitter
k p-
200C
10-6
Current, (A)

T, (C): =
230 nm NT base
400

10-8 200 20C


p- collector
320 nm
20
fit:
10-10
p+ subcollector (diamond substrate)
q(V IRb (T ))
I = J s Aexp 1
kT
reverse bias forward bias Figure 7. Cross section of a diamond pnp-BJT structure with n-type
10-12 base using deep nitrogen donor NT.
-40 -30 -20 -10 0 10 20 30
Voltage, (V) The experiments show that operation of diamond
Figure 5. IV characteristics of a diamond nitrogen/boron pnp-BJTs is possible even with a nitrogen-doped base;
pn-junction diode: Rb, series resistance; solid line, fit of the forward however, due to the high base resistance the operation is limited
diode characteristics after the equation shown as an inset. to the dc mode, small currents and moderate temperatures.
Further improvement depends on the employment of a
10-15 shallow donor such as P or S, which has however not been
p- n attempted yet, since doping with P or S is still in a preliminary
EA EC stage of investigation [23, 24].
10-25 ED
JS (A/cm2)

EV 4. Diamond FETs
EG - ED=3.8 eV
10-35
4.1. Boron delta-doped channel JFET
In FETs the channel carrier density is that of the ionized
10-45 impurities, whereas the channel depletion will depend both
slope ~ Eact = 3.8 eV
on ionized and non-ionized impurities [4]. In consequence,
a channel with deep impurities will yield low currents due
10-55 to incomplete ionization, but at the same time the electrical
1,5 2,0 2,5 3,0 3,5 field strength necessary to deplete the channel will be the
1000/T (1/K)
same as in the case of full activation. In diamond full
Figure 6. Activation energy of the pn-diode saturation current JS; activation of the boron acceptor at RT is obtained only for
for details on the extrapolation see [22]. doping concentrations NA  1020 cm3. In this case, the
sheet charge and therefore the thickness of the channel are
regime is observed at a forward bias of 3.0 V. This value again limited by the breakdown field to pS  3 1013 cm2 and thus
is in good agreement with the pn-junction model since it is d  3 nm [4] leading to pulse or delta-doped channels. This
close to the value of the built-in voltage V bi assuming that the represents a challenge for diamond epitaxy, since monolayer
Fermi levels in the neutral regions of the diode are pinned at precise growth is necessary. Indeed, it is possible to fabricate
the partially activated acceptor, i.e. donor level. delta-doped layers with a FWHM of approximately 4 nm and
By combining two boron/nitrogen pn-junctions a a sheet boron concentration of approximately 1 1014 cm2
diamond BJT was fabricated. The device features a nitrogen- as shown in figure 9.
doped base 200 nm thick [22]. The structure of this The potential advantages of diamond pn-junctions in
diamond BJT is shown in figure 7. From the analysis of diamond delta-FET structures over Schottky contacts are a
the pn-diodes it is clear that BJT operation will be limited low leakage current and high breakdown as well as the higher
by high series resistance of the semi-insulating base. The built-in voltage of above 3.0 V [20] compared to the 1.7 V of
G-range of the base series resistance RB provokes high the Schottky contact [10]. This leads to a shift in the pinch-off
input voltages in order to lower the emitterbase junction voltage towards enhancement-mode operation. In the JFET
potential. This induces leakage currents in the reverse biased the gate metal is separated from the channel by an N-doped
basecollector diode. Therefore transistor action could only layer as shown in figure 10. The N-doped layer is a lossy
be observed in the nA-current range. Transistor action was dielectric represented by a leakage resistor in parallel to the
observed both in common-base as well as in common-emitter dielectric capacitance inserted in between the gate metal and
configuration shown in figures 8(a) and (b), respectively. channel (figure 10). Depending on the layer properties and
Nevertheless, the current gain (IC/IB) of the device in common- dimensions the behaviour can be either resistive or capacitive.
base configuration was measured to approximately 200. In At quasi-dc and as a thick layer with a neutral part between
the common-emitter configuration this value was measured to the interfaces the lossy dielectric will act as a series resistor
about 3, mainly because of the higher-base collector reverse to the controlling pn-junction. In this case, the gate length
bias which causes a higher leakage current across the junction. is given by the length of the n-layer or that part of the
Due to the temperature activation of leakage current transistor n-layer to which sufficient bias potential can be delivered
operation was only observed up to 200 C [20]. by the distributed dielectric leakage resistor. On the other

S62
Diamond diodes and transistors

8
IE (nA)
80 (a) 70 (b) IB (nA)
6
50 6
60

IC (nA)

IC, (nA)
4
30 4
40
2
2
20 10
0
0 0
-10 0 10 20 30 40 0 10 20 30 40
VCB (V) VEC (V)

Figure 8. BJT dc characteristics: (a) common-base, (b) common-emitter.

-120
25 S D nitrogen doped VG = -10V
substrate
Boron conc. (x1019 cm-3)

ID/wG (mA/mm)
20 -80 LG

gate metal
15 VG = 5V
FWHM = 4 nm
-40
10

5 VG = 30V
0
0 -10 -20
0
20
VD (V)
0 10 30 40 50 60 70

Depth (nm) Figure 11. The dc characteristics of a back-gate JFET at 250 C


(LG = 2 m) after [6].
Figure 9. Boron doping spike in diamond with FWHM = 4 nm,
measured by ERD. VG = - 4 V
-20
nitrogen doped
G cap layer
gate metal S D
-15
ID/wG (mA/mm)

N-doped LG VG = 2 V
RD CD lossy dielectric -10

dD
depeltion CPN
region -5
channel
VG = 22 V
0
0 -5 -10 -15 -20 -25 -30
VD (V)
Figure 10. N-doped lossy dielectric layer between gate metal and
Figure 12. The dc characteristics of a top-gate JFET at 200 C
channel: RD, dielectric leakage resistor; CD, dielectric capacitance;
(LG = 20 m) after [6].
CPN, depletion region capacitance.

hand, a thin layer will be depleted by the interfacial barrier the gate metal and the channel, the N-layer will act as a series
space-charge layers. Here the lossy dielectric will act as a resistance to the pn-junction. Since a conductivity of the
capacitor enabling an MIS-like device control by the gate substrate is needed to sufficiently distribute the potential to the
metal. However the thickness of the N-layer must be sufficient controlling pn-junction device, operation is expected only at
to suppress tunnelling across the junction. elevated temperatures and not at RT. Therefore, this structure
There are two possibilities to place the gate control can only be used as devices to test the dc behaviour.
junction; on top as conventionally done or at the channel Figure 12 depicts another JFET concept where the N-layer
back-side. is grown on top of the delta-layer (top-gate JFET). Here
In figure 11, an FET structure with a back-gate (back- the top N-layer is sufficiently thin and therefore acts as a
gate JFET) and the related dc output of a device are shown. capacitor between gate metal and channel and as expected
The nitrogen-doped Ib substrate is used as a large area gate device operation is observed at RT and even in cooled devices.
underneath the channel. Due to the large distance between In figure 12, the dc characteristics shown were measured at

S63
A Aleksov et al

gate metal gate recess nitrogen-doped layer


metalization
(a) 0 1m
(b)
field plate
Drain Source Source Drain
gate recess
buffer layer
Gate nominally
undoped type Ib diamond substrate
delta-doped
nitrogen - doped layer channel
p+-doped ohmic contact top layer

Figure 13. Diamond recessed gate FET: (a) SEM image, (b) schematic device cross section after [12].

250 C. At this temperature the activation of the boron acceptor -2,0


reached saturation, thus maximizing ID. VG = -4 V LG = 200 nm
In the top-gate JFET structure in figure 12 the pn- T= 300 K
junction overlaps the gate metal to source and drain. Here -1,5
the pn-junction partially depletes the channel by the built- RLoadOpt = 66.7 mm

ID (A/mm)
in potential, thus reducing the drain current as shown by
electrical 2D device simulation. Therefore, it is necessary -1,0
Vbreakdown = 130 V
to shield the channel outside the gate metal from the pn- PRFsim = 27 W/mm
junction and surface depletion making a recessed gate diamond
JFET structure necessary. Also elimination of parallel current -0,5
paths beneath the channel is necessary. This can be obtained
by a back-side N-type shielding layer [12]. Here the pn- VG = 3 V
0,0
junction is close to the delta-channel only in the area of the 0 -20 -40 -60 -80 -100 -120 -140
gate metal. This maximizes the drain current. The structure
shown in figure 13(a) also utilizes gate field plates to maximize VDS (V)
drain voltage swing as known from Si and SiC power FET
technologies [25, 26]. Figure 13(b) shows a SEM micrograph Figure 14. Simulated dc output characteristics of a recessed gate
JFET (LG = 0.2 m). For details see [27].
of a fabricated recessed gate JFET with gate field plates. The
gate was fabricated by using e-beam lithography to obtain
sub-m gate lengths below 200 nm as shown. The recessed
surface Fermi level of hydrogenated diamond is unpinned [14],
gate structure presents a technological challenge, since besides
Schottky barrier heights depend on the metal work function
a nanometre-precise growth also nanometre-precise etching
difference to diamond [14]. Thus, Au is used for ohmic
producing smooth etched diamond surfaces with no defects
contacts, while Al gives Schottky contacts with a barrier of
influencing the regrowth of the N-doped layer is necessary.
approximately 0.8 eV. However, due to the unpinned surface
Electrical simulation of a recessed gate JFET using the ideal
Fermi level, besides the gate surface depletion is also sensitive
case of a several monolayer thick doping spike surrounded to adsorbates. Therefore devices on hydrogen-terminated
by low-doped areas of high mobility [6, 11] has shown the diamond suffer from instabilities.
advantage of this structure and the influence of an additional Sub-m gate length devices were fabricated by standard
field plate [11]. The simulated device showed an RF output T-gate e-beam lithography as used for InP and GaAs HEMTs.
power of about 27 W mm1 [27]. The resulting dc output Figure 15 shows the dc output characteristics of a 200 nm
characteristics are shown in figure 14. gate length FET. The maximum drain current reaches above
300 mA mm1 and the maximum drain bias up to 68 V giving
4.2. Hydrogen surface channel MESFET a possible RF output power of up to 3 W mm1. However,
the RF tests of this device were limited to small signal
Hydrogen-induced surface conductive channels are very parameter measurements at low drain current due to unstable
attractive for the fabrication of diamond MESFET devices. performance at high current levels. The cut-off frequencies
Surface p-type channel devices show extremely low leakage f T and f max were extracted from the current gain plots as
current and high breakdown voltages. However, there is shown in figure 16. Here f max was extracted from both the
an ongoing debate related to the origin of the conductivity maximum available gain plot f max (MAG) and the maximum
mechanism and several models are under discussion [14, 28, unilateral gain f max (U). The maximum values obtained were
29]. Single-crystal diamond layers show high sheet charge f T = 11.5 GHz and f max (MAG) = 31.7 GHz and f max (U) =
densities in the range of 1013 cm2 and carrier mobilities 40.22 GHz. The high f max/f T ratio of above 3 is related to
above 100 cm2 V1 s1 [14, 30]. The conductivity also the high voltage gain of above 100 obtained from the g m/g DS
seems to follow the surface structure since devices operate ratio. With this value for f max, diamond FET operation may
on polycrystalline diamond as well as on single-crystalline reach into the millimetre-wave region with even higher cut-off
diamond, only here the mobility is lower [28, 31, 32]. Since the frequencies expected for shorter gate lengths.

S64
Diamond diodes and transistors

VG = -3.2V of diamond. At high temperatures it is necessary to shield


-300
diamond from oxidation for operation in normal atmosphere
-250 by passivation. Diamond surface conductive devices are still
plagued by stability problems, which might again be solved by
ID (mA/mm)

-200 proper passivation. On the other hand, the most challenging


devices both with respect to technology and perspective are
-150 diamond delta-doped FETs, where simulation promises an
extraordinary power handling capability.
-100

-50 VG = -0.8 V Acknowledgment


0 The authors wish to thank the German Research Council
0 -2 -4 -6 -8 -10
(Deutsche ForschungsgesellschaftDFG) for supporting this
VD (V) work financially through their contract KO1201/8-1.

Figure 15. DC-output characteristics of a surface-channel FET with


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Figure 16. Cut-off frequencies of a 0.2 m gate-length surface
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