INORGANIC CHE IN Resonence” Educating for better tomorrow TARGET : JEE (ADVANCED) 2016 Course : VIJETA & VIJAY (ADP & ADR) Date : 01.05.2016 TEST INFORMATION DATE : 04.05.2016 PART TEST-04 (PT - 04) [Syllabus : Qualitative Analysis, Metallurgy, d & f-block elements DPP No. # 08 (JEE-ADVANCED) Total Marks : 160 Max, Time : 118 min. Single correct Objective ('-1" negative marking) Q.1 to Q.15 (3 marks, 2 min.) [45,30] One or more correct objective ('-1" negative marking) @.16 toQ.20 (4 marks, 2 min.) _—_[20, 10] Assertion and Reason ('-1' negative marking) Q.21 to Q.23, (3 marks, 3 min.) [09,09] Comprehension ('-1' negative marking) Q.24 to 0.32 (3 marks, 2 min.) (27, 18] Single digit integer type ('-1" negative marking) @.33 to Q.41 (3 marks, 3 min.) [27,27] Match the Following (no negative marking) Q.42 to Q.45 (8 marks, 6 min.) [32,24] 4. Which of the following statements is false ? (A) In 3d series, there is a regular increase in the first ionisation enthalpy of transition elements from left to right. (B) In 2d series, the negative value of standard electrode potential (E9 for M'/M decreases in the order Ti>Mn>Cr> Fe. (C) The decrease in metallic radius coupled with increase in atomic mass results in a general increase in the density of transition elements from lef to right (D) The higher oxidation state are favoured by the heavier elements (i.e. heavier members) in the groups of d- block, 2. Extraction of zino from zinc blende is done industrially by (A) electrolytic reduction (B) roasting followed by reduction with carbon (C) roasting followed by reduction with another metal (©) roasting followed by self-eduction 3. Which of the nitrates on strong heating leaves the metal as the residue ? (A)AQNO, @)PbINO,), (©) CuNo,), @AKNO,, 4, Manganous salt in presence of catalyst zinc sulphate or zinc oxide is oxidised by potassium permanganate in neutral or faintly alkaline medium to (A) Mn, ©) Mn.0, (©)Mn.0, (0) Can not be oxidised PNGesonence’ be Educating for better tomorow10. 1. 12. V,0, reacts with alkalies to give (avo (vo, (vor A.white crystalline substance dissolves in water. On passing H,S gas in this solution, a black precipitate is, obtained. The black precipitate dissolves completely in hot HNO... On adding a few drops of conc. H,SO,, a white precipitate is obtained. This precipitate is that of (A) BaSO, (S80, (©) PSO, ()cas0, 4 [——Fritrate 22> white needio Salt mixture st HCl, white ppt. Hest —{ like crystal tinder nat eedon NH Sol {5 Residue-“45°'5 Clear solution Salt Is consisting of cations (A) Pb and Hg (B)Agt and Hg.* (©) Pb* and Ag” () None of these ‘An aqueous solution of a substance (X) gives a black precipitate on treatment with H,S gas in presence of NH,OH and NH,Cl which dissolves in aqua regia on heating, The ammoniacal solution of substance (X) gives red precipitate with dimethyiglyoxime. The substance (X)is (A) Cu salt (B) Fe* salt (©) Nit salt (0) Pb* salt Consider the following metallurgical processes () Heating impure metal with CO and distilling the resulting volatile carbonyl (boiling point 43°C) and finally decomposing at 150°C to 200°C to get the pure metal (i) Heating the sulphide ore in air until a part is converted to oxide and then further heating in the absence of airto let the oxide react with unchanged sulphide, (iil) Electrotysing the molten electrolyte containing approximately equal amounts of the metal chloride and CaCl, to obtain the metal, The process used for obtaining sodium, nickel and copper are, respectively, (A), (land Git) 8) Gi, Gil) and () © (ii), @ and (i) (i, @ and i) Impure + |, ——> Metal iodide "2" Pure Metal + |, ia Vapour Revsed The above method of purification is (A) Van ~ arkel process for Zr, Hg etc (8) Distillation for Zn, Cd, Hg ete (C) Electro refining for W, Ag, Au, ete (D)Zone refining of germanium, gallium, silicon etc. Which of the following is desirable as a slag in extraction of copper but not during the extraction of iron (A) CuFes, (®)Fesio, (© casio, @)cusi0, Which of the following is not correctly matched with respect to the processes involved in the extractive metallurgy of the respective metal ? (A)AI,03.2H,0 -> Al: Leaching, precipitation, calcination and electrolytic reduction (molten state). (8) Ag,S > Ag : Leaching and displacement method, (C) PbS — Pb: Froth flotation process, roasting and self reduction. (0) KCLMgCI, 6H,0 > Mg : Dehydration by simple heating and electrolytic reduction (molten state). Resonance’ fiz Educating for better tomorow13. 14. 15. 16" a7 48° 19" 20. 24 Which of the following will not give positive chromyl chloride test (A) Copper chloride, CuCl, (©) Merouric chloride, HgCI, (©) Zinc chloride, ZnCl, (0) Aniline hydro chloride C,H,NH_HCl Which of the following statements is correct for matte which is formed during extraction of copper ? (A) Matte is a molten mixture of mostly cuprous sulphide and alittle iron sulphide (8) Matte is a solid mass consisting of CuO and FeO. (C) Matte is a molten mixture largely consisiting of CuS and FeS,, (D) None of these H,S and SO, can be distinguished by (A) Litmus paper (®Mno, (©)(CH,COO), Po (O)Alllof these Which of the following statements is/are true about Mohr's salt ? (A) Itdecotourises KMnO, (®)Itgives NH, on heating with KOH, (©) itis a double salt (0) Oxidation state of iron is +3 in this salt ‘Suppose Cu* and Pb* both are present in a mixture, then they can be separated by (A) adding KI solution (©) adding NH, solution (©) adding NaOH solution (©) adding citute HCI (2M) In electrolysis of Al,O, by Hall-Heroult process (A) eryolite Na, AIF, lowers the melting point of Al,O, and increases its electrical conductivity. (B)Alis obtained at cathode and probably CO, at anode (C) electrolysis is carried out in aqueous medium (©) anode consist of graphite Heating which of the following salts in a dry test tube may cause a change in their colour ? (A)ZACO, (white) (© Co(NO),,6H.0 (red) (©) FeSO,6H.0 (green) (©) MnS0, (faint pink) ‘Complexes formed in the cyanide process are (A) IAWCN) (®)IAG(CN).F (©)[Cu(CN),F ()[2n(cn) F Statement-t : MgO bricks are used for inner lining ofthe zone of combustion of blast furnace in extraction ofiron ‘Statement-2 : MgO fails to react with SiO, under the furnace condition where it is used as inner lining. (A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1 (B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1. (C) Statement-1 is True, Statement-2 is False. (©) Statement-t is False, Statement-2is True Resonance’ fiz Educating for better tomorow22. 23. Statement-1 : Adding KCN to CuSO, produces a white ppt which dissolves in excess KCN Statement-2 : With excess KCN, CuSO, forms K,[Cu(CN),] complex (A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1 (©) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1 (©) Statement-t is True, Statement-2 is False. (0) Statement-t is False, Statement-2 is True. Statement-1 : NH,Cl is added while analysing the III group basic radicals to suppress the ionisation of NH,OH Statement-2 : With high concentration of OH ions, basic radicals of other groups also get precipitated wit IIL group cations, (A) Statement is True, Statement-2is True; Statement-2 is a correct explanation for Statement-1 (©) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1 (©) Statement-t is True, Statement-2 is False. (©) Statement-t is False, Statement-2 is True Comprehension # 1 24. 25. 28. When 16.8 g of white solid (X) was heated, 4.4 g of acid gas (A) that turned lime water milky was driven off together with 1.8 g of a gas (B) which condensed to a colorless liquid. The solid that remained (Y) dissolved inwaterto given an alkaline solution, which with excess of BaCl., solution gave a white precipitate (Z). The precipitate effloresces with acid giving off CO, gas. Compounds A and B are respectively (A) CO, and H,0 (®) SO, and H,0 (©) CO, and N0, (0)SO, andN.0, ‘Compounds X and Y are respectively (A) Na,CO, . 10H,0 and Nao (®@KHCO, and co, (C) NaHCO, and Na,CO, ()Na,CO, NaHCO, 1.5H,O and Na,CO, Compound Zis (a) BaSo, (8) Baso, (©)BatHco,, ()Baco,, Comprehension # 2 27. 28. ‘A mixture (M) of two salts was treated as follows () The mixture was heated with MnO, and concentrated H,SO,, when yellowish green gas (P) was liberated. (il) The mixture on heating with NaOH solution gave a gas (Q) that turned red litmus blue. (ii) ts solution in water gave blue precipitate (R) with potassium ferricyanide and red cololration (S) with ammonium thiocyanate. (v) The mixture was boiled with KOH and the liberated gas was bubbled through on alkaline solution of K.Hgl, to give brown precipitate (1). Gas P and Q are respectively. (A) ClO, and NH, (®)SOCI,andso, —_(C) NH, andl, (0) Cl, and NH, Compounds R and S confirm the presence of (A) Fe* and Fe* respectively (8) Fe* and Fe* respectively (C) Fe* ions only (©) Fe* ions only Resonance’ fiz Educating for better tomorowComprehension # 3 X+dil HSO, —> brown colored vapours turing wet starch iodide paper blue X+NaOH —*+ NH, gas X —2.+ Y(g) + Z(g) but liquid at room temperature. 29, ‘Compound X is (A) (NH),SO, (@NHNO, (©)(NH),CO, (©) none of these 30. Compound Y and Z are respectively (@)co, Ho (0)SO, HO Comprehension # 4 no, Malm die en ¢y & cry oan BO Pasta > ™” cin What is (2)? (A) Its a salt of Fe* (6) Itis a salt of Sn* (C) Itisa salt of Mn’* (O) Itisa salt of Cr* 32 What happens when X is keptin acidic medium? (A) neutralisation reaction. (8) disproportionation reaction. (C) double decomposition reaction (©) pyrolytic reaction 33. Mn’ +8,0,-+H,O—> [X]+S0,> +H" ‘The magnetic moment (spin only) of [X] is 34. Amongst the following the total number of ions which produce colour inthe solutions (in water) is. Ti ME, CP PB*, Fe, Zn, NF, SO, gH 35. Which of the following will produce an insoluble precipitate with NH,(aq.)/H.S. BaCl,, NiSO,, Mohr's salt, AICI,, Bi(NO,),, Hg(CH,COO),, ABNO,, SnCl,, CoSO,, 36. NaCl+Solid K,Cr,0, + Conc, HS0, —> "x" (reddish brown fumes) How many axial-d-orbital are involved in hybridization of "X"? 37. What is the oxidation number of Cr in the product of the reaction of K,Cr,O, with H,0, / H’, followed by boiling, followed by treatment with excess KOH. Resonance’ Educating for better tomorow38. 39. 40. a. 42. 43. How many of the following contain at least one iron atom in +2 oxidation state? (@)Fes, (b)Haematite (©) Magnetite (@ Brown ring complex (©)NaJFe(CN).{NO)] (f)FelFe(CN),] @KFelFeCn)] (0) Ferrocene (Fe(C.H.).) @Fewo, Amongst the following, the total numiber of compounds whose aqueous solution gives white precipitate with Pb* ions is KI, NH,, Na,CO,, K,CrO,, NaCl, Na,SO,, NaS, KNO,, NaClO, How many of the following metallurgies involve leaching ? ALO, —> Al, ; Ag,S —> Ag ; Au —> Au; CuFeS, —> Cu; PbS —> Pb MgCl, —> Mg; FeCO, —> Fe ; Low grade copper ore —> Cu;HgS —> Hg ‘The number of reducing agents involved in the extraction of iron (as pig iron) using blast furnace from ore haematite is(are), Match the compound in column (|) with the properties of products obtained on heating it in column (I). Column -1 Column - It (A) Feso, (P) One of the product is basic oxide (@)NHNO, (@) One of the product is acidic oxide (Ba), (9 One of the products unreactive towards O, at room temperature. (0) MgCl, 6H, (6) Atleast one of the product is neutral oxide. Match the reactions given in column - | with the nature of the reaction/products given in column - I Column -1 Column - It (A) S,03 (aq) + H"(aq)—> (p) Show disproportionation (B) Cu (aq) + F (aq) > (q) Redox reaction (©) C103 (aq) +H" (aq) —> (At least one of the products is diamagnetic (0) Mg(NH,)vo, —— (s) One of the products has metal-oxygen-metal bond/ linkage. Resonance’ fiz Educating for better tomorowIn column-I there are certain reactions which are given by different basic radicals with the reagents given in column-I in qualitative analysis. Now match the entries given in column-I with entries given in column-t Column (A) Pb* ions form yellow precipitate with, (8) Zn** ions form first white precipitate and then dissolves in excess with (©) Ni* ions form green precipitate with (D) Cu**ions form blue precipitate with Column (®)K,Cr0, solution (@) NaOH solution (Kisolution (9) NH, solution (KCN solution IDPP No. # 07 (JEE-ADVANCED) 1. 15. 22. 29. 36. ® 2 © 2 © 4 OQ »%. A 10. Q ® 16" (AB) 17" (AB) 18+ A B&B A wm © Bw @® 3% © 3. & 32 7 8% 2 888, A) >s:8)>8;(©)>p; ©) ar A or,s;@or.s:C)> piO)oq 45. Column-1 Column - (A) White or buff colored (@)Mn(OH), (©) Oxidisable by air (@Z00H, (C)Amphoteric () Fe(OH), (©)Green (.CrOH), (NIOH), ANSWER KEY ® 5. #® & OO 7 @& Oo 2 © 8 O % & (ABD) 18° (ACD) 20" (ABD) 21. A) Oo 62 ®8 %7% © B ® © 32 ®@ 4 8 3 4 Gye Fr). hf) Cy 4. (A) >p,8:8) 918; ©) >p,s;O)>ns [corporate ome Resonsnce® Educating for better tomorow (66 Tovar A & 82, PI,