SAUDI ARABIAN OIL COMPANY

OPRNS

THIS DOCUMENT AND THE INFORMATION CONTAINED HEREIN ARE THE SOLE PROPERTY OF SAUDI ARAMCO. NO REPRODUCTION IN WHOLE OR PART SHALL BE MADE WITHOUT THE PRIOR WRITTEN CONSENT OF THE OWNER.
PMT
CERT
ENGG

PROJECT SPECIFICATION
DESCRIPTION
JO/EWO

CATALYST AND CHEMICAL SUMMARY

DATE

POWER GENERATION BLOCK

REV NO.

DISCIPLINE
ENGINEER
_______________

DATE _________

PROJECT
ENGINEER
_______________

DATE _________
JIGCC PROJECT
_______________
CERTIFIED
JAZAN
DATE _________ SAUDI ARABIA
CONSTRUCTION
AGENCY
_______________

DATE _________

OPERATIONS

_______________

DATE _________

C3 25/2/2013 Issue for Client Approval GR RS RS

EDSD VERIFICATION

------------------------------
CONTROL NUMBER

DATE: __________
BY: ____________

C2 30/1/2013 Issue for Client Approval GR RS RS

C1 19/12/212 Issue for Client Review GR RS RS
B1 3/12/2012 Issue for EDC GR RS RS

Rev Date Description Prep Chk App Proj SAPMT

THIS INDICATES THAT REV. NO. ______

KBR Revision History (to be removed at IFP issue)

FOR ALL APPROVAL / CERTIFICATION
OF THIS DOCUMENT IS COVERED,
REVISION CERTIFICATION

REQUIREMENTS, BY DOCUMENT
COMPLETION CERTIFICATE
(DCC) NO. ___________

PROJECT DESIGN BASIS DWG. TYPE PLANT INDEX DOC. SHT. REV.

Catalyst and Chemical Summary DOC

A10 A VE-726242 1
IGCC of C3
5
JAZAN SAUDI ARABIA
 SAUDI ARABIAN OIL COMPANY

OPRNS

THIS DOCUMENT AND THE INFORMATION CONTAINED HEREIN ARE THE SOLE PROPERTY OF SAUDI ARAMCO. NO REPRODUCTION IN WHOLE OR PART SHALL BE MADE WITHOUT THE PRIOR WRITTEN CONSENT OF THE OWNER.
Table of Contents

PMT
1 INTRODUCTION............................................................................... 4
CERT
2 CATALYST AND CHEMICAL REQUIREMENTS ............................. 4
2.1 Catalyst ...................................................................................... 4
ENGG

2.2 Chemicals .................................................................................. 4

Oxygen Scavenger:.................................................................... 4
Neutralizing Amine (pH Control): ............................................... 4
DESCRIPTION

Corrosion/Scale Inhibitor (Phosphate): ...................................... 5

TABLE 1 Catalyst Requirements ...................................................... 4

TABLE 2 Chemical Storage Requirements ....................................... 5
JO/EWO
DATE
REV NO.

DISCIPLINE
ENGINEER
_______________

DATE _________

PROJECT
ENGINEER
_______________

DATE _________

CERTIFIED

_______________

DATE _________

CONSTRUCTION
AGENCY
_______________

DATE _________

OPERATIONS

_______________

DATE _________
EDSD VERIFICATION

------------------------------
CONTROL NUMBER

DATE: __________
BY: ____________
THIS INDICATES THAT REV. NO. ______

FOR ALL APPROVAL / CERTIFICATION

OF THIS DOCUMENT IS COVERED,
REVISION CERTIFICATION

REQUIREMENTS, BY DOCUMENT
COMPLETION CERTIFICATE
(DCC) NO. ___________

PROJECT DESIGN BASIS DWG. TYPE PLANT INDEX DOC. SHT. REV.

Catalyst and Chemical Summary DOC

A10 A VE-726242 2
IGCC of C3
5
JAZAN SAUDI ARABIA
 SAUDI ARABIAN OIL COMPANY

OPRNS

THIS DOCUMENT AND THE INFORMATION CONTAINED HEREIN ARE THE SOLE PROPERTY OF SAUDI ARAMCO. NO REPRODUCTION IN WHOLE OR PART SHALL BE MADE WITHOUT THE PRIOR WRITTEN CONSENT OF THE OWNER.
List of Acronyms & Abbreviations
PMT
Use of acronyms and abbreviations shall be in accordance with Jazan
CERT
Integrated Gasification Combined Cycle Acronyms and Abbreviations.
The following acronyms and abbreviations are used in this document:
ENGG

BFW Boiler Feed Water

DESCRIPTION

CCB Combined Cycle Block

FEED Front End Engineering and Design

HRSG Heat Recovery Steam Generator

JO/EWO

JIGCC Jazan Integrated Gasification Combined Cycle

DATE

IP Intermediate Pressure
REV NO.

PGB Power Generation Block

DISCIPLINE
ENGINEER
_______________
PPM Parts per Million
DATE _________

PROJECT
ENGINEER
WBS Work Breakdown Structure
_______________

DATE _________
VHP Very High Pressure
CERTIFIED

_______________

DATE _________

CONSTRUCTION
AGENCY
_______________

DATE _________

OPERATIONS

_______________

DATE _________
EDSD VERIFICATION

------------------------------
CONTROL NUMBER

DATE: __________
BY: ____________
THIS INDICATES THAT REV. NO. ______

FOR ALL APPROVAL / CERTIFICATION

OF THIS DOCUMENT IS COVERED,
REVISION CERTIFICATION

REQUIREMENTS, BY DOCUMENT
COMPLETION CERTIFICATE
(DCC) NO. ___________

PROJECT DESIGN BASIS DWG. TYPE PLANT INDEX DOC. SHT. REV.

Catalyst and Chemical Summary DOC

A10 A VE-726242 3
IGCC of C3
5
JAZAN SAUDI ARABIA
 SAUDI ARABIAN OIL COMPANY

OPRNS

THIS DOCUMENT AND THE INFORMATION CONTAINED HEREIN ARE THE SOLE PROPERTY OF SAUDI ARAMCO. NO REPRODUCTION IN WHOLE OR PART SHALL BE MADE WITHOUT THE PRIOR WRITTEN CONSENT OF THE OWNER.
1 INTRODUCTION

PMT
Aramco Services Company, ASC, have employed the services of KBR to
CERT provide Front End Engineering and Design (FEED) for the Jazan Integrated
Gasification Combined Cycle project, from here on referred to as JIGCC.
This document summarizes the catalyst and chemical requirements
ENGG

necessary for the Power Generation Block (PGB).

2 CATALYST AND CHEMICAL REQUIREMENTS
DESCRIPTION

2.1 Catalyst
Not Applicable This work breakdown structure (WBS) has no catalyst
requirements.
JO/EWO

Catalyst Loading Catalyst Volume

Type Method (m3)
DATE
REV NO.

TABLE 1 Catalyst Requirements

DISCIPLINE
ENGINEER Supplier (Mandatory): Not Applicable This WBS has no catalyst
_______________
requirements
DATE _________
2.2 Chemicals
PROJECT
ENGINEER
_______________ Oxygen Scavenger:
DATE _________ The oxygen scavenger specified in Table 2 is required to minimize corrosion in
CERTIFIED the condensate and Boiler Feedwater (BFW) system as well as the Heat
_______________
Recovery Steam Generator (HRSG). Typical chemicals used include
DATE _________
Hydroquinone or Erythorbic Acid. The solution injection location will be located
either downstream of the deaerator feedwater and condensate mixing, near
CONSTRUCTION
AGENCY
the HRSG area, in one (1) common header or directly into the deaerator.
_______________ Injection location and any alternative locations shall be confirmed during
DATE _________ detailed engineering. There will be one (1) oxygen scavenger skid per
OPERATIONS
combined cycle block (CCB). The chemical volume specified in Table 2 is
estimated for 60 days of normal operation based on a ratio of 120 parts per
_______________
million (ppm) chemical feed solution (diluted to 10% active Hydroquinone) to
DATE _________
feedwater resulting in a dosing rate of 0.22 m3/day and is for one (1) CCB
only. This will be confirmed by the detailed engineering contractor.
EDSD VERIFICATION

------------------------------
CONTROL NUMBER

DATE: __________
BY: ____________

Neutralizing Amine (pH Control):

The neutralizing amine for pH control, specified in Table 2, is required to
manage the acidity of the BFW and condensate. Typical chemicals used
THIS INDICATES THAT REV. NO. ______

include Morpholine and Cyclo-hexylamine. The solution injection location will

FOR ALL APPROVAL / CERTIFICATION

be located either downstream of the deaerator feedwater and condensate

OF THIS DOCUMENT IS COVERED,
REVISION CERTIFICATION

REQUIREMENTS, BY DOCUMENT

mixing, near the HRSG area, in one (1) common header or directly into the
COMPLETION CERTIFICATE
(DCC) NO. ___________

PROJECT DESIGN BASIS DWG. TYPE PLANT INDEX DOC. SHT. REV.

Catalyst and Chemical Summary DOC

A10 A VE-726242 4
IGCC of C3
5
JAZAN SAUDI ARABIA
 SAUDI ARABIAN OIL COMPANY

OPRNS

THIS DOCUMENT AND THE INFORMATION CONTAINED HEREIN ARE THE SOLE PROPERTY OF SAUDI ARAMCO. NO REPRODUCTION IN WHOLE OR PART SHALL BE MADE WITHOUT THE PRIOR WRITTEN CONSENT OF THE OWNER.
deaerator. Injection location and any alternative locations shall be confirmed
during detailed engineering. There will be one (1) amine skid per CCB. The

PMT
chemical volume specified in Table 2 is estimated for 60 days of normal
CERT operation based on a dosing rate of 0.28 m3/day and is for one (1) CCB only.
This is based on the estimate of a concentration of 1 ppm amine to
condensate flow. This will be confirmed by the detailed engineering
ENGG

contractor.
DESCRIPTION

Corrosion/Scale Inhibitor (Phosphate):

The corrosion/scale inhibitor specified in Table 2 is required to minimize the
formation of corrosion and scale (dissolved solids, i.e. hardness) on the heat
transfer surfaces of the HRSG. Typical chemicals used include blends of Di &
Tri -sodium Phosphates. The solution shall be injected into the Very High
JO/EWO

Pressure (VHP) and Intermediate Pressure (IP) steam drums of each HRSG.
Injection location and any alternative locations shall be confirmed during
detailed engineering. The chemical volume specified in Table 2 is estimated
DATE

for 60 days based on a maximum continuous blowdown rate of 5% and a

concentration of 5 ppm Phosphate to feedwater water. The resultant dosing
REV NO.

rate is 0.08 m3/day and is for one (1) CCB only. This will be confirmed by the
detailed engineering contractor.
DISCIPLINE
ENGINEER
_______________
60-Day Storage Volume, m3
DATE _________ Chemicals
(Notes 1 & 2)
PROJECT
ENGINEER Oxygen Scavenger -
_______________ 13.5 m3
Hydroquinone or Erythorbic Acid
DATE _________
Neutralizing Amine (pH Control) -
CERTIFIED
Morpholine and Cyclo- 17.5 m3
_______________
hexylamine
DATE _________
Scale Inhibitor (Phosphate) -
CONSTRUCTION
AGENCY blend of di & tri -sodium 5.0 m3
_______________
Phosphates
DATE _________

OPERATIONS

_______________
TABLE 2 Chemical Storage Requirements One Combined
DATE _________
Cycle Block
Notes:
EDSD VERIFICATION

------------------------------
CONTROL NUMBER

DATE: __________
BY: ____________

1. Detailed engineering contractor to finalize chemical selection and

determine all chemicals requirements.
2. The volumes in Table 2 are for bulk chemical storage and are based on a
100% chemical concentration. Additional dilution tanks may be required
for mixing purposes.
THIS INDICATES THAT REV. NO. ______

FOR ALL APPROVAL / CERTIFICATION

OF THIS DOCUMENT IS COVERED,
REVISION CERTIFICATION

REQUIREMENTS, BY DOCUMENT
COMPLETION CERTIFICATE
(DCC) NO. ___________

PROJECT DESIGN BASIS DWG. TYPE PLANT INDEX DOC. SHT. REV.

Catalyst and Chemical Summary DOC

A10 A VE-726242 5
IGCC of C3
5
JAZAN SAUDI ARABIA