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Amine

Amide
By
Mint, Fahsai, Yuyu, Ice, Aom
1107
Amine
derives from ammonia
H in ammonia is replaced by Hydrocarbon group
one at a time

Structure of Amine:
Examples:
Methylamine (CH3NH2)
Ethylamine (C2N5NH2)
Propylamine (CHCHNH)
Classes

Primary Secondary Tertiary


Only one H is Two H are Three H are
replaced by R replaced by R replaced by R
Physical
Properties:

Normal state : liquid or gas


pH : mostly base
Melting points : higher than alkane
Boiling points : higher than alkane
Solubility in water : All three classes
can participate in hydrogen
bonding with water. Small amine
are soluble.
Reaction:
Reaction and Utilization or Application:

Conversion from amine to amide Reaction of amine with copper(II)

with carboxylic acid ions : give off


tetraamminediaquacopper(II) ions

Reaction of amines and water :


ammonia produce ammonium Reaction of amine with nitrous acid

ions and hydroxide ions from :

hydrogen ion If react with primary, the


product will be nitrogen gas
If react with secondary, the
product will be insoluble oil
If react with tertiary, the
product will be clear solution
Reaction and Utilization or Application:
Utilization and Application:
Ethanolamine Methylamine
Production of detergents, Solvent similar to
emulsifiers, polishes, ammonia
chemical immediates, etc. Refining
Alkalinization of water in
stream cycles of power Chloramine
plant disinfectant
Amide
derives from carboxylic acids.
OH of -COOH group is replaced with -NH2
so amide has -CONH2 group.

Structure of Amide:
Examples:
Methanamide (HCONH2)
Ethanamide (CH3CONH2)
Propanamide
(CH3CH2CONH2)
Normal state : solid except Physical

methanamide, which is liquid


pH : neutral
Properties:
Melting points : generally high
because of its ability to form
hydrogen bond, which needs a lot
of energy to break.
Boiling points : generally high
because its polar.
More polarity means higher boiling points.

Solubility in water : soluble because


of its ability to form hydrogen bond
with H2O.
Reaction:
Reaction and Utilization or Application:

Dehydration : Removing water


Hydrolysis : reaction with water. If
from mixture of amide and
hydrolyzed with acidic water, the
phosphorus oxide will leave a nitrile
product will contain ammonium
group-- can be collected through
ions.
distillation.
- If hydrolyzed with alkaline water,
the reaction will involve with
Reduction : amide reduce to
hydroxide ions.
primary amines.

Conversion from Amide to Amine


with LiAlH4
Reaction and Utilization or Application:
Utilization and Application:
Sodamide Dimethylformamide
Production of indigo, Solvent and Catalyst
hydrazine, and sodium Production of acrylic
cyanide fibers, plastics, and
Reagent for drying pesticides
ammonia Manufacture of adhesives,
Strong base in organic synthetic leathers, fibers,
chemistry films, and surface coatings
Lithium amide Potassium amide
Strong base Pesticides
Naming : Amine

End with -mine


Add N- to show that its
attach to N atom
Add number prefix to
show which carbon is
amine attached to
If name it as a branch, add

Butylamine / N-Butylamine
amino-
If theres more amino
groups, add prefix (Di-, Tri-,
etc.)
Naming : Amide

End with -mide


First part of the name
comes from amine atom
Second part of the name
comes from carboxylic
acid
Which one is amine?

Which one is amide?

Question
Name this molecule

Question
Name this molecule

Question
Which substance is

needed to turn amine to


amide?

Question
What products can be

produced by amide?

Question
What are the normal

states of amine?

Question
Thanks!
Any questions?

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