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Designation: G 24 05

Standard Practice for


Conducting Exposures to Daylight Filtered Through Glass1
This standard is issued under the fixed designation G 24; the number immediately following the designation indicates the year of original
adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A superscript
epsilon (e) indicates an editorial change since the last revision or reapproval.

1. Scope G 113 Terminology Relating to Natural and Artificial


1.1 This practice evaluates the resistance of nonmetallic Weathering Tests of Nonmetallic Materials
materials to solar radiation filtered through glass. G 173 Tables for Reference Solar Spectral Irradiances:
1.2 For direct exposures, refer to Practice G 7. Direct Normal and Hemispherical on 37 Titled Surface
1.3 This practice is limited to the method of conducting the G 177 Tables for Reference Solar Ultraviolet Spectral Dis-
exposures. The preparation of test specimens and evaluation of tributions: Hemispherical on 37 Tilted Surface
results are covered in various standards for the specific 2.2 Other Documents:
materials. WMO Guide to Meteorological Instruments and Methods of
1.4 Exposure conducted according to this practice can use Observation WMO No. 8, Fifth Edition.3
two types of exposure cabinets. ISO 105 B01 TextilesTests for Colour Fastness, Interna-
1.4.1 Type AA cabinet that allows passive ventilation of tional Standards Organization, Geneva, Switzerland.4
specimens being exposed behind glass. ISO 877 PlasticsMethods of Exposure to Direct Weath-
1.4.2 Type BEnclosed cabinet with exterior painted black ering, to Weathering Using Glass-Filtered Daylight, and to
that allows no ventilation of specimens exposed behind glass. Intensified Weathering by Daylight Using Fresnel Mirrors,
Exposures conducted using a Type B cabinet are typically International Standards Organization, Geneva, Switzer-
referred to as black box under glass exposures. land4
AATCC 16C Colorfastness to Light, Daylight5
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1.5 Type A exposures of this practice are technically similar


to Method B of ISO 877. 3. Terminology
1.6 This standard does not purport to address all of the
safety concerns, if any, associated with its use. It is the 3.1 Definitions:
responsibility of the user of this standard to establish appro- 3.1.1 The definitions contained in Terminology G 113 are
priate safety and health practices and determine the applica- applicable to this practice.
bility of regulatory limitations prior to use. 4. Significance and Use
2. Referenced Documents 4.1 Since solar irradiance, air temperature, relative humid-
2.1 ASTM Standards: 2 ity, and the amount and kind of atmospheric contaminants vary
C 1036 Specification for Flat Glass continuously, results from exposures based on time may differ.
E 824 Method for Transfer of Calibration from Reference to The variations in the results may be minimized by timing the
Field Pyranometers exposures in terms of one or more environmental parameters
E 903 Test Method for Solar Absorptance, Reflectance, and such as solar radiant exposure, or in terms of a predetermined
Transmittance of Materials Using Integrating Spheres property change of a reference specimen with known perfor-
E 1084 Test Method for Solar Transmittance (Terrestial) of mance.
Sheet Materials Using Sunlight 4.2 Variations in temperature, moisture and atmospheric
G 7 Practice for Atmospheric Environmental Exposure contaminants can have a significant effect on the degradation
Testing of Nonmetallic Materials caused by solar radiation. In addition, exposures conducted at
different times of the year can cause large differences in rate of
degradation. Different materials may have different sensitivi-
ties to heat, moisture, and atmospheric contaminants. This may
1
This practice is under the jurisdiction of ASTM Committee G03 on Durability
of Nonmetallic Materials and is the direct responsibility of Subcommittee G03.02
on Natural Environmental Testing.
3
Current edition approved Jan. 1, 2005. Published February 2005. Originally Available from World Meteorological Organization, Geneva, Switzerland.
4
approved in 1973. Last previous edition approved in 1997 as G 24 97. Available from American National Standards Institute (ANSI), 25 W. 43rd St.,
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or 4th Floor, New York, NY 10036.
5
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Available from American Association of Textile Chemists and Colorists
Standards volume information, refer to the standards Document Summary page on (AATCC), One Davis Dr., P.O. Box 12215, Research Triangle Park, NC 27709-
the ASTM website. 2215.

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G 24 05

FIG. 1 a and 1b Typical Well-Ventilated Under Glass Exposure Cabinet, Type A

radiation or total solar UV radiation to determine exposure


periods is not sensitive to these differences. For materials very
sensitive to differences in short wavelength UV radiation,
monitoring UVB radiation behind glass may be the best
approach for use when radiant energy is used to determine the
length of exposures. However, for materials sensitive to long
wavelength UV or visible radiation, monitoring UVB radiation
or using reference materials that are very sensitive to short
wavelength solar ultraviolet radiation to determine exposure
periods may produce erroneous results.
4.6 This practice is best used to compare the relative
performance of materials tested at the same time behind the
same lot of glass. Because of variability between lots of glass
and between exposures conducted at different times of the year,
comparing the amount of degradation in materials exposed for
FIG. 2 Typical Enclosed Under Glass Exposure Cabinet, Type B the same duration or radiant exposure at separate times, or in
(Black Box Under Glass) separate fixtures using different lots of glass is not recom-
mended.
explain differences in rankings of specimens exposed to 4.7 It is strongly recommended that at least one control
equivalent solar radiant exposure when other environmental material be exposed with each test. The control material should
conditions vary. be of similar composition and construction. and be chosen so
4.3 Since the method of mounting may influence the tem- that its failure modes are the same as that of the material being
perature and other parameters of the specimen during expo- tested. It is preferable to use two control materials, one with
sure, there should be a mutual understanding as to the method relatively good durability, and one with relatively poor dura-
of mounting the specimen for the particular exposure test under bility. If control materials are included as part of the test, they
consideration. shall be used for the purpose of comparing the performance of
4.4 There can be large differences among various single the test materials relative to the controls.
strength window glasses in their transmission in the 300 to 350 4.8 There are other standards which describe exposures to
nm region. For example, at 320 nm, the percent transmission glass filtered daylight. Three cited standards are ISO 105-B01,
for seven different lots of single strength window glass ranged ISO 877, and AATCC 16C.
from 8.4 to 26.8 %. For this range of transmission, the rate of 4.9 Because of the possibility that certain materials may
degradation for materials sensitive to short wavelength UV outgas during exposure, it is recommended that only similar
from 300 to 320 nm could vary by as much as 300 %.6 materials be exposed in the same under glass cabinet.
4.5 Differences in UV transmission between different lots of
glass persist after solarization. The largest differences among 5. Apparatus
window glasses in UV transmission are in the spectral range of 5.1 Exposure Cabinet:
300 to 320 nm. Use of radiant exposure based on total solar 5.1.1 Type AExposures shall be conducted in a glass-
covered enclosure or cabinet of any convenient size. It shall be
6
constructed of wood, metal, or other satisfactory material, in
Ketola, W. D., and Robbins, J.S., III, UV Transmission of Single Strength
order to protect the specimens from rain and weather, and shall
Window Glass, Accelerated and Outdoor Durability Testing of Organic Materials,
ASTM STP 1202, Warren D. Ketola and Douglas Grossman, Eds., American Society be open on the back or sides to allow ambient air to circulate
for Testing and Materials, Philadelphia, 1994. over the specimens (Fig. 1a and b).
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G 24 05
5.1.2 Type B (Black Box Under Glass)Exposures shall be is compatible with the test specimens. In order to minimize
conducted in a glass-covered enclosure or cabinet of any shadowing from the top and sides of the cabinet, the usable
convenient size. It shall be constructed of corrosion resistant exposure area under the glass shall be limited to that of the
metal and be enclosed to prevent ambient air from circulating glass cover reduced by twice the distance from the cover to the
over specimens. Exterior non-glass surfaces shall be painted specimens. Three types of mounting frames or backings may
flat black. The interior shall remain unpainted (Fig. 2). be used.
NOTE 1The black box under glass test method is often used to
5.1.4.1 Unbacked or Open MountingSpecimens are at-
simulate under glass exposures under conditions of high temperature, such tached only at edges.
as the interior of an automobile. However, because black box under glass 5.1.4.2 Expanded Aluminum MountingSpecimens are at-
cabinets are enclosed, air temperatures may exceed 80C under conditions tached to an expanded aluminum backing.
of high outside ambient air temperature and solar irradiance. In addition, 5.1.4.3 Solid MountingSpecimens are attached to a solid
significant differences in air and specimen temperatures can be experi- backing such as plywood.
enced between upper and lower portions of the cabinet. Frequent
temperature measurement and specimen repositioning may be required to NOTE 4The method used to mount specimens shall be related to their
properly use this test method. end-use. In evaluating the specimens, the edges of these specimens that

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are used to secure the specimen to the framework should be disregarded.
5.1.3 Unless otherwise specified the glass cover shall be a
piece of non-laminated, transparent flat glass, greenhouse 5.1.5 The cabinet shall be located where it will receive
quality Q4 or better as specified in section 4.1 of Specification direct sunlight throughout the day and where shadows of
C 1036. Glass thickness shall be 2 to 3.2 mm. objects in the vicinity will not fall upon it. When the cabinet is
5.1.3.1 In order to reduce variability due to changes in UV installed over grass, the distance between the bottom of the
transmission of glass, all new glass shall be exposed facing the cabinet and the ground shall be sufficient to prevent contact
equator, at any convenient exposure tilt angle within the range with plant growth, or to minimize damage that might occur
of 5 to 45, according to Practice G 7, or on an empty under during maintenance.
glass exposure cabinet, for at least three months prior to 5.1.6 The glass cover and the test specimens shall be
installation in test cabinets. oriented in a manner mutually agreed upon between interested
5.1.3.2 After the three-month pre-exposure period, it is parties. The angle shall be reported in the results of the test.
recommended that the spectral transmittance of representative Possible exposure orientations are listed as follows:
samples from each lot of glass be measured. Typically, single 5.1.6.1 Fixed tilt angle equal to the latitude of the exposure
strength glass will have a transmittance of 10 to 20 % at 320 site with cabinet facing equator,
nm and at least 85 % at wavelengths of 380 nm or higher after 5.1.6.2 Tilt angle of 45 facing the equator,
the three month pre-aging procedure. If transmittance of the 5.1.6.3 Tilt angle of 5 facing the equator,
glass is measured, report the average for at least three pieces of 5.1.6.4 Tracking azimuth and tilt angle in order to maintain
the lot of glass being tested. Follow the instructions for the exposure plane normal to the suns direct beam.
measurement of transmittance of solid samples recommended 5.1.6.5 Any other angle that is mutually agreed on by all
by the manufacturer of the UV-visible spectrophotometer used. interested parties may be used. In some instances, exposures
If a spectrophotometer with an integrating sphere is used, the facing directly away from the equator or some other specific
measurements shall be performed in accordance with Test direction may be desired. The test report shall contain the exact
Method E 903. angle and specimen orientation.
5.2 Climatological Instruments:
NOTE 2Other standards describing exposures behind glass have
different requirements for glass transmittance and do not require pre- 5.2.1 Instruments suitable for determining maximum, mini-
aging. mum, and average daily ambient air temperature, cabinet air
NOTE 3After the initial pre-aging period, the UV transmission of temperature (optional), and specimen temperature (optional).
window glass is suitable for at least 60 months of use. UV transmission Ambient air temperature will be measured in a shielded,
differences between lots of glass persist during this time, however. elevated location in the general vicinity of the under glass
Different pieces of single-strength window glass can have different optical exposure cabinet.
properties even if purchased from the same manufacturer.
5.2.2 Instruments suitable for determining the maximum,
5.1.3.3 Wash the exterior surface of the glass cover every minimum, and average daily ambient air humidity, and cabinet
month, and the interior surface of the glass cover every 3 humidity (optional).
months (or more frequently, if required) to remove dust 5.2.3 Instruments for recording solar radiant exposure.
particles and other undesirable material. 5.2.3.1 Instrumental means of measuring full-spectrum so-
5.1.4 The enclosure or cabinet shall be equipped with a rack lar radiant exposure shall consist of a pyranometer connected
which supports the specimens in a plane parallel to the glass. to an integrating device to indicate the total energy received
Whenever possible, the specimens should be supported at a over a given period. The pyranometer shall be sensitive to solar
distance of 75 6 25 mm (3 6 1 in.). Formed specimens with irradiance received at a geometry similar to that over which
irregular dimensions may require custom mounting with vary- solar irradiance is received by the test specimens. The pyra-
ing distances from the glass cover. In such cases, mount the test nometer shall be a World Meteorological Organization (WMO)
sample surface of major interest parallel to the glass cover at a Second Class instrument or better as defined by the WMO
distance of 75 6 25 mm (3 6 1 in.) from the glass cover. The Guide to Meteorological Instruments. The pyranometer shall
mounting frame or plate shall be constructed of a material that be calibrated in accordance with Method E 824 no less often

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G 24 05
than annually against a WMO Secondary Standard pyranom- parallel to the surface of the pyranometer or UV-radiometer
eter or a reference pyranometer whose calibration is traceable sensor, 75 6 10 mm above it, and at the same orientation (tilt
to the World Radiometic Reference (WRR). angle) as the glass cover and test specimens as specified in
5.2.3.2 Instrumental means of measuring solar radiant ex- 5.1.6. The glass shall be at least 600 by 600 mm in size.
posure in specific wavelength regions (such as all or a portion 6.5.2 Indirect Calculation MethodThe pyranometer or
of the ultraviolet spectrum) shall consist of a wavelength-band UV-radiometer shall be mounted direct to the weather at the
specific global irradiance radiometer connected to an integrat- same orientation as specimens being tested. The radiant expo-
ing device to indicate the energy received in a specified sure shall be calculated using the following equation:
wavelength band over a given period (optional). The spectral Rug 5 Rdir 3 T (1)
response of the narrow-band radiometer shall be known and
shall be as flat as possible throughout the spectral region where:
utilized. Rug = solar radiant exposure, under glass,
Rdir = solar radiant exposure, direct, and
NOTE 5Solar radiant exposure should be measured and expressed in T = glass solar transmittance.
SI units of joules per square metre. One langley is equivalent to
4.184 3 104 J/m2. The glass solar transmittance shall be determined using Test
Method E 903 or E 1084. Test Method E 903 is a method for
6. Procedure calculating the solar transmittance of the glass based on
6.1 Unless otherwise specified, or agreed to by all interested spectrophotometer measurements. Test Method E 1084 is a
parties, it is recommended that a minimum of three replicates method for directly measuring the solar transmittance of the
of each material being tested be exposed. The simultaneous glass using the sun as the source and a pyranometer as the
exposure of a similar number of specimens of a control is also sensor. Regardless of the method chosen, it shall be performed
strongly recommended. on at least three representative pieces of glass. If Test Method
6.2 Expose the test specimens, control specimens, and/or E 903 is used, the calculated solar transmittance for the above
specimens of an applicable weathering reference material, (for equation shall be based on the spectral irradiance distributions
example, blue wool) in the glass-covered exposure cabinet in Tables G 177 for UV only or Tables G 173 for total solar. If
continuously 24 hours a day and remove from the cabinet only E 1084 is used, the pyranometer or UV-radiometer used to
for inspection, return, or to protect specimens from possible determine the glass solar transmittance must be of the same
damage during severe weather events. type and wavelength sensitivity as the pyranometer or UV-
6.3 Measure and record daily the maximum, minimum, and radiometer used to determine radiant exposure.
average air temperature and relative humidity in the vicinity of
the test cabinet. It is also recommended that cabinet air 7. Report
temperature and humidity as well as specimen temperature be 7.1 The report shall include the following:
recorded. 7.1.1 Type of exposure cabinet used (Type A or B). Report
NOTE 6While these conditions cannot be controlled, a record of them
the transmittance characteristics of the glass, if measured, and
is desirable to indicate the general conditions that prevailed during the thickness. All interested parties should agree upon the wave-
exposure. lengths at which transmittance is reported,
7.1.2 Dates and location of exposure, including the latitude
6.4 Remove the test specimens, control specimens, and/or
of the exposure site, and
specimens of applicable weathering reference material from
7.1.3 Tilt and Azimuth Angles or Compass Orientations at
the cabinet based on one of the following:
which the exposure cabinet was oriented during the test.
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6.4.1 Amount of Solar Radiant ExposureExpose the test


7.2 The report may optionally contain the following infor-
specimens for a specified solar radiant exposure dose, either
mation:
total (all wavelengths) or a selected wavelength band. Report
the results in terms of any specified method of measuring 7.2.1 Applicable physical property or appearance data for
changes in test specimens. each specimen obtained prior to exposure and after each
6.4.2 Predetermined Property ChangeExpose the test exposure increment, if measured. If replicate specimens are
specimens (and any specified control or weathering reference used, report the mean and standard deviation of each property
specimen if desired) until a specified amount of property measured,
change has occurred in either the candidate materials or 7.2.2 Methods used for measuring physical or appearance
standard samples. properties of test and control specimens,
6.4.3 Duration of ExposureExpose the test specimens for 7.2.3 Solar radiant exposure data expressed in SI units, if
a specified time period. Report the results in terms of any measured,
specified method of measuring changes in test specimens. 7.2.4 Maximum, minimum, and average daily temperatures,
6.4.4 Any Other Specified Environmental Parameter. as well as cabinet air and specimen temperatures, if recorded,
6.5 Two methods can be used to determine solar radiant 7.2.5 Maximum, minimum, and average daily relative hu-
exposure under glass. midity, as well as cabinet humidity, if recorded,
6.5.1 Direct Measurement MethodThe pyranometer or 7.2.6 Any other specified environmental parameter,
UV-radiometer shall be mounted under glass having the 7.2.7 Any variations from the specified conditions, and
characteristics specified in 5.1.3. The glass shall be mounted 7.2.8 Type of specimen rack and mounting employed.

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G 24 05
8. Keywords
8.1 aging; exposure; glass; ultraviolet; weathering

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