I

PART A - PHYSICS l1 A body of mass m= 10 -2 kg is moving ir\

ALL ME GRAPHS / D-IAGR, ,}fS GIYEN ART a medium and expedences a ftictional
SCHEA4AIIC AND NOT DRAWN TO SCALE, force F= -kr'2. Its initial speed rs
r.o=10 nu-l. tf, after 10 s, its energv is
1 A man grows into a giant 6uch that his
linear dimensions increase by a factor : mz'^2- the value of k will be
1
:
Ev
of 9.Assuming that hts density remain< \- t2^

same, the stress in the leg will change by a ' ?ndv --Fv-tc
factor of :
ld (1) 10 3kgm I s iav R (di
,r2{ 9 , l' v- -rnj
!'' (2\ '.1 d-ul 1.) J o
' 9 s1.q! = -r (2) 10-3 kg s-1 11 - r 1 -- * x r0.
(i) 8) @-,1 [-.-, ,"1
t
-,
(4)
1
10 l kg m-l
.L
to
= Fx)oDrr
81 J, k -_ lo
A body is thrown vertically uPwards.
Which one of the following graPhs (4) 10-r kg m-r s-1
corectly represent the velocitv vs time ?

(1)

t- .t A time dependent force f=6t acts on a

palticle oI mass l kg. II the Patticle starts
from rest, the work done bY the lorce
(2) during the ftst I sec. will be :
lrv . {fGtdi
\tq 4.5 J \,- = ata
V'9
$ e) nt ,"- tx 9
| : \J

(3) el
(4)

(4) 18 I

A/PaEe 2 SPACE FOR ROUGH WORK

 Tr1..v
The moment of inertia of a uniform 7 The variation of acceleration due to gravity
olinder of length I and radius R about its g with distance d from centre of the
perpendicular bisector is L What is the earth is best represented by (R=Earth's
ratio l/R such that the moment of inertia radius) :

is minimum ?
r'1f '
t \'= 7 ;f iX
ii
l:
!2 t- (1)
L =f..
'gl l= m6.r",1e
t\
o
(2) "5 ,4 L
2 ZL
, :L
(3) 1
fY t1i:
e l- a
VI
\2)
3 k''i o ^R
(l) { e1,
le
,nr, a
6 l3= ZY
,-fr
6 A slender uniform rod of mass M and
lenSti i is pivoted at one end so that it can
(3)
I'
o R
rotate i. a vertical plane(seefigu!e). There
is negligible friction at the pivot. The ftee
end is held vertically above the pivot and
then released. The angular acceleration
,6
of the rod rvhen it makes an angle I ia'ith
o Ii

the vertical is :

i A copper ball of mass 100 gm is at a

ut*vrrs =-Y4 temperature T. [t is dropped in a copper
calorimeter of mass 100 gm, filled v/ith
d= ? q-!i^g 170 gm ol water at room temperature.
{-t Subsequently, the temperature of the
system is found to be 75'C. T is given by :
*4 :-e sin 0
2I (Given : loom temperatute = 3ffC, specific
heat of copper=0.1 cal/gmf)
(2) 4sine
31 (1) 8oo"c ( T->s)roro,l
/-s_30)rL
- (r'
(3) :9
2t
cos 0 (zf ses"c
I tD,aO . I

2E
(3) 1250'C + l+o.
/.t\ cos 0
31 (4) 82s.c
A/Page 3 SPACE FOR ROUGH WORK --- -ii-oS) ro= us x[to+t+o]
9 ('?s) *\P= c15 x t8l
c f :-15t 8l o = #S
o
f
An external pressurc Pis applied oi a cube A paiticle is executing simPle harmonlc
I at trC so that it is equally compressed from motion vv'ith a time Period T. At time t = 0,
all sides. K is the bulk modulus of the it is at its Position of equilibrium The
material of the cube and d is its coefficient kinetic energy - time SraPh of the particle
of linear expansion. SuPPose we want to will look ljke
bring the cube to its original size by
heating. The temperatue should be laised KE
by, 3.( .AT
P= 6 6jl 0) T 't T t-
tgf
P \9 2
3cK 3 =t'f
.1,(K
P KE
(2\ dK (2) T tr
3a
(3)
PK o79
KE
(4) 3PKn
10. C, and C,, are specific heats at constant /ll T T t+
piessu-re and consrait volume resPectively'
2
It is observed that
Cp - C" = a for hYdrogen gas
KE

C- - Ci. =b for nitrogen gas

't*f TT Tt-
The correct relation between a and b is : 4Z
1
(1) a= 1a b
,,121 a=b
An obseryer is moving with halJ the sPeed
(3) a=14 b of light towards a stationaly microwave
(a) a=28 b
source emittinS waves at frequency
11. The temperature of an open room of 10 GHz. What is the frequencY of the
volume 30 m3 ihcleases ftom 1uC to 27c microwave measuted by the observer ?
due to the sunshine. The atmosPhelic (speed of tight =3 x 1d ms-l)
pressure in the room rcmains 1 x 105 Pa.
II q and n;are the numtr of moleoies in (1) 10.1 GHz
the room belore and after heating, then
n,- n, wi.ll be : t2\ 72.7 GHz
(U -1.61 x1023 I Yro,4r I lp-
-Coa.^ --^
(2) 1.38 x 102 ' gd tt.. CHz W^rA
(3) 2.5 x 1025 t
(4) 1s.3 GHz _lr_x
lo@ x lO
JA - 2.5x102s
A/PaEe 4 tq SPACE FOR ROUCH IVORK
6rf5
& l* 9:r-*,ot=n;{o-08,
r!a 1 6210 o
ror7j
\,h= erlei r^t"*[i;l{+ J
1.r\ -
5-t.) {u5
L
q2{o
r--
14. An electric dipole has a fixed dipole l6 In the given circuit diagram \/hen the
current reaches steady state in the circuiL
moment p' , which makes angle 0 with
the charge on the capacitor of capacitance
C will be
respect to jr-axis. When subiected to an
:

electric field E1= Ei , it experiences a

rl
torque T1="k. When subiected to
E-, =qc
another electric field Ez= J3 Er I it
& -- cer-
d +'rL-
experiences a totque Tz = - Tt . The angle (1) cE
0is: E P.9vn e -- Tr
la e (2) 6g
(1) 30" E+ros =J --I-
(12+r)
?
(2) 4s'
seio =,1-a @1e .*4 6B --!-
(r+!2 )
@r 60" 1o.r.o--{,
(4) e0" ({) 6s --.1-
(r1 +r)

ti . A capacitance of 2 pF is required in an
. electrical circuit across a Dotential 17 2\', 2\'
6d diJference of 1.0 kV. A
large number of
1 pF capacitors are available lyhich can 10 1Q 1o
I{'ithstand a potential difference of not
more than 300 V. 2V 2V 2V

The minimum number of capacitors

In the above circuit the current in each
lequired to achieve this is :
rcsistance is :
tkv
(1) 2)t- (1) 1A
lt
't6
\2) (2\ 0.25 A

(3) 21 (3) 0.s A

,1*f sz ,6 OA
A/Page 5 SPACE FOR ROUGH WORK
r1'l l\ )l rl
Fr\ \l lr ll
,Dk 8*4
 _1
@42 ioJ
5x
I o,at x6, Ixlo-2
'18 A magnetic ncedle of magnetic moment 2l Ar electron beam is accelerated by .r
6.7 x7O-2 Afi2 and moment of inertia potential difference V to hit a metalli.-
7., x IU " kg m' rs Perlormlng stmPle target to Produce X-rays. It Producer
harmonic oscillations in a magnetic Iield continuous as well as characteristic X-rays.
of 0.01 T. Time taken for 10 complete lf Lmh is the smallest possible r,!'aveleflgth
oscilla tions is : of X-ray in the spectrunr" the variation ol
$f 6.6s s log
^hm
with log V is correctly represente(l
(2) 8.89 s 6L.9 in:
(3) 6.98 s 75. to-z ev: hc
t4\ 8.76 s 6 a8 t='- Arni,.
f+-
J slct< 'r ltv h lc
19. When a cuffent of 5 mA is passed tfuough
a galvanometer having a coil of resistance -q dn{,
15 O, it shoh,s full scale deflection. The Pr log Lnun
value of the resistance to be put in series
log V
with the galvanometer to convert it into a
c voltmeter of raflge 0 - 10 V is :
\LLr 798s x7O3 O
lo=5((rrR)
1:l :9::'.1::: \o- s'd3L,s+F
t3l 2.515 r 10' O - olxlo--lS=K
(4) 4.005 Y 10r O to.. _ ,, , (2) log r.-'n
20. h a coil of resistance 100 O, a current is
Iog \'
induced b\ ch,rnging the magnetic flu\
thlough it as shou'n in the figule. The
magnitude of change in flux through the
coil is :

tl oxl x! : 95
10 ,LL (3) log lnnn
Current o dd
(n.,.p) { log V
o o
I --
.* Time 0.5 sec
b= 9.5r too
(1) 200 wb
(2) 2:25Wb (4) log I6n
@r 250 Wb
(4) 275 \\b log V

A/PaBe 6 SPACE FOR ROUGH WORK

 "z -,'.1 ^ -L r - r -l
-rr-F
,s
*'*-,10t ao !. !
,4 0 ;,$--;lJ
A diverging lens with magnitude of focal 2{
--jo -rf,"
A particle A of Erass m and initial velocity
a

22.
Iength 25 cm is placed at a distance of
15 cm from a converging lens of rnagnitude
., collides with a particle B of rr.,as. f
of focal length 20 cm. A beam of parallel which is at rest. The collision is head o&
tight falls on the diverging tens. The final and elastic. The ratio of the de-Broglie
image Iormed is :
vod ' wavelengths . to A" after the colliston is :
" vr'Y,
1
,9f real and at a distance of 40 cm from (t)
\B 3 bY,
convelgent lens.
\4 i(v.tnYliayr
(2) virtual and at a distance of 40 cm \Pf := ^ t
from convergent lens. .(
r^ =;2 lv:x'-Jv{
(3) qv =a.,r
(3) real and at a distance of 410 cm from ^" v,:q,v
the divergent lens. y
. AA-,
(4) -
rB , =* arjil"s
ar
u-=?,

(4) real and at a distance of 6 cm from

the convergent lens.
ir =J. mY ',-:r6-y
a;
25. Some energy levels oI a molecule are
shown in the figure. The ratio of the
wavelengths r= )rr/,r2, is &iven bv :
23, ln a Young's double slit experiment, sLits
are separated by 0.5 mm, and the screen E hc=t
is placed 150 cm ar'ay. A beam of light Ir
E.1... .
consisting of two $'avelengths, 650 nm }L
tr1
and 520 nm, is used to obtain interference
-2E
Iringes on the screen. The least distance
from the common cmhal Elaximum to the
a
-3 E
)
point where the bright fringes due to both
the wavelengths coincide is l
(1)
( lE6tlo
(1) 1.56 mm < O.sr\
2
l-T.
b lqs'i to{
|
'r. t.qs
12)
3
,g 7.8 mm
G S oY-[:-o x Y)]
3
o,s (3)
l
(3) 9.75 mm n'"
^.8:
o. 5, "r',.

(4) 15.6 mm 65x ao xnr -t{ 1

A/Page,7 a , - .SPACE FOR ROUGH W9 RK

v-lr5xrli l.qr.,na 1.b
,k 5
156.'n!. I.s( 6,n r-.3J
'10
'#
'& i'd >\
'?;
#
 26. A ladioactive nucleus A with a half lile l', 29
ffi Which oI the following statements is
de(avs intJ a nucleus B. At t = 0, there is
no nucleus B. At sometime t, the iatio of
the number of B to that of A is 0.3. Then,
(1) Wheatstone bridge is the most
sensitive when all the four
\v' t is given bJ
A b 3 resistances are of the same older 01

t' a:); (1)

T
los 2 magnitude.
2 log 1.3
s w log 1.3
log 2 t=
1,)
^.a2
U^ (..4)ir,-
1pl In a balanced wheatstone bridge iJ
the cell and the galvanometet are
er.changed, the null point is
(3) t=T log (1.3) Q/'r? disturbed.

({) ^Tlog (1.3) (3) A rheostat can be used as a potential

divider_,

(4) Kirchhoff's second law replesents

27. In a common emitter aulplifier circuit energy conseNation.
using an n-p-n transistor, the phase wl
difference between the input and the
output voltages will be :
lor The following observations were taken for
(1) 15" determining surface tension T of \.r'ater b)
(2) e0" capillary method :
(3) 13s"
diameter of capillary D=1.25x10-2 m
\,rf 180'
se of water, h= 1.45 x10-2 m.
28 In amplitude modulation, sinusoidal Using g=9.69 m/sz and the simplified
carrier frequency used is denoted by (,)c

and the signal frequency is denoted by om

relation 1= llg 1163 Nl7-. the
2
The bandwidth (A(,)n) of the signal is such possible error in surlace tension is closest
that Ao^<<ro.. Which of the Iollowing to:
frequencies is not contained in the
modulated wave ?
(1) 0.1s%

Jtf JA 1.5'/o

(2)
13\ 2.4.a
(3)
(4)
(4) 10%

A/P"8" 8 o'c SPACE FOR ROUGH WORKdr._ D,Ol

- 01
^,g
.,
! + o,o,
Jr{O-l
+r>ur'7 i'=' l9< lq-Ex I
1.2's Alo'L
l'\

"'&u ,
lo'r
l ,rJ
91 +)-
l.zs \s
I W -!l-
l-2Srl.\S'r
(ca t-
-r- ). qb
( \ o_ ---- CO r
6 ,
", r.r'!. --.1v.1:9+
L
o )a-I*r Y - ci l \l ls ntY 34 The Tyndall effect is obser,,,ed only w.hen
following condiuons are satisfied :
31. Given , lls
c (a) The diamete! of the dispersed
C{g'upt'it") + Oz(8) + CO2(g) ; 3
a#o= -393.5 kJ mol- I particles is much smaller than the
wavelength of the light used.
,
H2(g) + +O2(g) -., H2o0) ;
AJl'= - 285.8 kJ mol - 1
(b) The diameter of the dispersed
particle is not much srrn_ller than the
CO2(g) + 2HzO0) -+ CHo(g) + 2O2(g) ; wavelength of the light used.
A$o= +890.3 kJ mol-r --
Based on the above thermochemical
(c) The lefractive indices of the
dispersed phase and dispersion
equations, the value of A$' at 298 K for
medium are almost similar in
the reaction
magnitudei(
C(g.phit") + Hz(g) --r CHa(g) will be :
,1d -zl.s t1 rrrot-t (d) The refractive indices of the
(2) dispersed phase and dispersion
- 1,14.0 kJ mql-r
medium differ gteatly in magnitude.
(3) + 74.8 kJ mol-1
(1) (a) and (c)
({) + 144.0 kl mol-r
(2) @) and (c)
au
32. 1 glam of a carbonate (M?CO3) oir (3) (a) and (d)
treatment with excess HCI produces
0.01186 mole of CO2. The molar mass of J4 O) and (d)
M2CO3 in g mol-l is :

(1) 118.6 mrco6 IYF -t co' ' 35 A metal crystallises in a face cenrred cubi(
(2) 71.85
structure. lf the edge length of its unit cell
(3) 1186 is 'a', the closest aDDroach between two
atoEls in metallic crystal will be
{L't 84.3
ai\
_ q-a 0J-2-
=
f1) J2a
33. aU is equal to: t,fjo, ,v.l I'tr = 4
u l-a.
,]pf Adiabatic work ,9Y T
(2) Isothermat work
(3) 2a
(3) Isochoric work
(4) Isobaric work (4) 2"8 a

A/Page 9 SPACE FOR ROUGH WORK

r\,coa rala o ---am Ct +co-f q'o-
t .- .o. ot l8f<
rn
fn= ldb
I' t86
 s.rr:
t{s t z' 1}Y x,d!
36. Givql\ 39 'Iwo reactions Rl and R2 have identicrl
pre-exponential factors. Activation enerEv
El,.r.,- =1.36 V, Ea,r-ra, =-0.74 V
ofRt exceeds thatofR2by 10 kJ mol-1. f
-t-rr, -t 3'
E:;oi-lc,- =1.33 v, Eiilbi/Nhr. =1.51 v .
for reactions
k1 and k2 are rate constants
Rt and R2 respectively at 300 K, then
Among the following, the strongest tn(k2/k1) is equal to :
reducing agent G: 5cV o{id\st . (R=8.314 I mol-rx-1)
_1a *,,
..i$ cF. (1) 6 X1 . f,s -E?
(2) cl- (4 4 r.= A e-Fr
gf ct (3)
t-r. = e 1E
:'+ (4) Mn2 + (4) t2 E Rl
6;
37 The freezing poiht of benzene decreases 40. pKa ofa h,eak acid (HA) and p(5 ofaweak
by 0.45'C when 0.2 g of acetic acid is base (BOH) are 3.2 and 3.4, respectivelr'.
"*, added to 20 g of benzene. ll acetic acid The pH of their salt {AB) solution is :

associates to lorm a dimer in benzene, (1) 7.0 JI + +-L f z.r-ar1

eL
'- L- percentage association of acetic acid in (2) 1.0
*-o.t
benzene will be : \3) 7.2
t)^,-., (\ tor oenzene=r.12 K x8 mol 'l Jlf 6.e

(1,) 71.6",. a.\s: c)z'^toq rs't

Ld \")Z
,tz' - 94.6% a t- a 1
41 Both lithium and magnesium displav
(1) 64.6e" several simila! properties due to the
..r.'('7J
'1\t'2^\ (4) so.{% t '*, = '-r" diagonal relationship; however, the one
which G incorrect, is :
cL
Lj!j: \t
,ru, (1) both form nitrides,/.
3g. The radius of the second Boh! orbit lor
,"9 nitrates of both Li and Mg yield NO
h] drogen atom G heating
(PlancLs Consl h= 6.6262x1,0-v Js; (3) both basic carbonates -,
mass of eleckon = 9.1091x 10-31 kg;
(4) both form soluble bicarbonates
charge of elechon e=1.60210x10-19 C;
permittivity of vacuum
12 Which of the following species is not
eo = 8.854185 x 10- 12 kg-h-3A2)
parainagnetic ?
(1\ 0.529 A o.es9.l v4 A"
l7l o2.z
\6 2l2 A (2) B2 -
(3) 1.5s A (3) NQ r'
(4) 4.76 A rfr CO
A/Page 10 \ SPACE T'OR ROUGH WORK
lt)
r^?N o,
6-1No.2- {f\
- ts
t,
,lu Which of the following reactions is an 47 In the following reactions, ZnO is
example of a redox reaction ? respectively acting as a/an :

(1) xero + Hro --+ *Jor4 + 2HF < 1a; zl6i rva!-o'- ruarzno,
(2) \eFb + 2H2O -r XeO2F2 + 4HF " O) ZnO + CO"
ai)-t .. :
-, ZnCo_
X'#o + Orf, XeF6 + 02
(l) acid ana-acid
'P) -
(4) xtr, + eru --, 1xt4 * rFr- ;(2I acid and base
(3) base and acid
(4) base and base
44. A water sample has ppm level 4E, Sodium salt of an organic acid ,X, ploduces
concentration of following anions
_/ ),Fr, eflervescence with conc. H2SO4. ,X, reacts
F-=10; SOi-
". pi", with the acidified aqueous CaCl2 solulion
=100; Not =50
The anion/anions that make/makes the
to give a white precipitate which
decolourises acidic solution ofKMnOn.
water sample unsuitable for drinking is/
are
:
'X' is lt- .
(1) CH,COONa ' \o-: i":
JlJ. only F - (2) NarC2On .,,- 1 A3-
l'sPPY\
(2) only So!- ?b' (3) C6H'COONa d
(3) only NOt J4t HCooNa
49 The most abundant elements by mass in
(r) both 5Ol- and NOj the body of a healthy human adult ale :
Oxygen (6'1.4.k); Catbon (22.9.n\,
45. The $oup having isoeleckonic species is Hydrogen (10.0%); and Nikogen (2.6%).
The weight which a 75 kg person.wou.td
(1) 02-, F-, Na, M82+r
galin iI a[ 1H atorns are replaced by 2H
(2) O-, F-, Na+, fr.{gz+. atoms is : {.r nX + r,tl
dlf oa-, r-, Nut, rratz* ,.1d z.s r.s
(4) o-, F-, Na, Mg+ (2 ) 10 kg
(3 ) 1s kg

46 The products obtained when chlorine gas (4) 37.5 kg

reacts with cold and dilute a queous NaOH 50. On heatment of 100 mL of 0.1 M solution
nre of CoCl..6HrO with excess AgNO3;
,6 Cl- and CIO- I q' +oc\' 1.2x1022 ions are precipitated. The
complex is :
(2) Cl- and ClOi (1) ICo(H2o)6lCl3
(3) CIO- and ClOi ._.)pf [Co(HrO)rCl]Clr.HrO
(3) [Co(H2O).CI.]CL2H2O
(4) clo, arld clot (a) [co(Hro).CIr].3H2o
.L
A/Page 11 SPACE FOR ROUGH woRK o,rrl91_r
6.X pB
9-4..at = @z
r
51. Which of the lollowin8 compounds will 53. The formation of which of the followrng
form significant amount of ,n?ld Product poll'mers involves h1'drolvsis reaction ?
during monGnibation reaction ? (1) N-ylon 6, 6

fnz (2) Terylene

erl\--/ il J3f
(4)
Nylon
Bakelite
6

NHCOCII3

(2) 54. Which of the following molecules i5 least

resonance stabilized ?
OH
(1) ll I

(3) \zN
ff*, '.q
(1)
o (3) (\

(l)
h'hich of the follolving, upon treatment
$'ith tcrrBuONa followed by addition of 'o'
bromine w'ater, fails to decolourize the
colour of bromine ? cur
\-. The increasing order of the reactivity ot
o,- -,. Y,n the following halides for the Soal reaction
(1) isl
8r
CH]CHCH2CH'l cH3cH2cH2cl
L) I

CI
(2) { 0) 0t)
Rr p - H3CO-C6Ht-CH2CI
(III)

(3)
o-"1 CoH'
0)
(2)
(r) < 0II)

([) .(rn)
.(rD
.0) l\l>lr>l
, trl
(3) 0ll).0D<0)
IN (41 (tD.0).( I)

A./PaEe 72 SPACE FOR ROUCH }VORK

+
 B.)r: lsg I9-rr9i-
,J!
t\ ,1\ 2 i }lY I
adb

36 Giuq\. r. Two reactions R, and R2 have identical

u1y
pre-exponential factors. Activation energv
E:r,/o- =1.36 v, E:r]. /c.=-0.71v of Rl exceeds that of R2 by 10 kJ mol l. If
/ct] =1.33 V. E b;zrr,' = 1.51 \
k, and k2 are rate constants for reactions
o+-
R, and R2 respectively at 300 K, then
Among the following, the strongest ln(krlk) is equal to :
reducing agent is: 5!Y 6{idr.r -
(R = 8.314 J mol-lK-r)
Ju crt* O) 6 ir.Ae -tl.rl;
F!
(2) Cr - (4 4 F,-Ae C

t?f c, (3) li
1F*
(4) Mn2+ (4) t2 E k.-eRr

37 The freezing point of benzene decreases {0 pKu ofa weak acid(HA)and pKbofa weak
r.t -^ by 0.45'C when 0.2 g of a(etic acid is base (BOH) are 3.2 and 3.4, lespectivel) .
added to 20 g of benzene. If acetic acid The pH of thet salt (AB) solution is :
associates to form a dimer in benzene, (1) 7.0 Jr + +-L
9Lf a.r-ar1
percentage assocration of acetic acid in (2) 1.0
i1' benzene will be : (3) 7.2
n-o,t
i1'- (K1 for benzene=5.12 K kg mol 1)
{el 6.e

o) 74.6"/. o.\s: otz-,Vd ,,S t

t_6 _)4 41 Both lithium and magnesium displaY
,14 94.6%
t-,
{ (3) 64.6'n 3 t
!-,r J,1' t-{
+l several similar properties due to thL,

tr,)'
LI!}J L<lc1)
(4) 80.4L Po
diagonal relationship; however, the oflc
which is incorrect, is : ,
(1) both form nitrides.,.
38. The radius of the second Bohr olbit for
hy1l1g9g319pr is :
,p nitrates of both Li and M g yield NO,
heating
(Planck's Const. h= 6.6262><70-v Js;
(3) both rm basic carbonates -.
mass of elechon = 9.1091 x 10-31 kg;
(4) both form soluble bicarbonates
charge of electron e = 1.60210 x 10-19 C;
permittivity of vacuum
o= 8.854185 x 10-12 kg- lm-3A2)
42. Which of the following species is nor
paramagnetic ?
(r) 0.529 A o,esig vq A" (7) 02 "'
ttzf z.rz A (2) B, z
(3) 1.6s A (3) No i
(4\ 4.76 A co
'JA
A/Page 10 t SPACE FOR ROUGH WORK

, r^?No>
o+ Nor.
- f\ ls
 43. Which of the following reactions is an 47. In the following reacrrons, ZnO is
example of a redox reaction ?
|
respective}/ acting as a/an :
(1) XeF. + Hro + *bFa + 2I{F " (a) ZnO + Na2O + NarZnO2
(2) XeFu + 2HrO --+ XeO2F2 + 4HF < (b) ZnO + CO, -, ZnCO,
X+eln + orF, --r XeF" + O,
(1) acid and"Scid
tP)
x'3r, * er, 1xtrl* nrr-
g(4 acid and base
(1)
- (3) base and acid
(4) base and base
44. A water sample has ppm level 448,' Sodium salt of an organic acid,X, produces
concentration of following anions
rd effervescence with conc. HrSOn. ,X, reacts
... - PPr,
F- =10; SOi- =100; NOi=5Ofr" with the acidfied aqueous CaCl2 solution
The anion/anions that make/makes the
to give a white precipitate which
decolourises acidic solution oJ-KMnOo.
water sample unsuitable for drinking is/
'X'is ln
ct{__{(
.
ale: )!- <tE
(1) cHrCOoNa ' \o-ia
\lI) only F- "-'. to (2) Na"C,O, (e^- . ]3'
t 5, ?P6
(2) only Soi fb. (3) C.H.COONa o
(3) only Not l-.(*f HCOONa
49. The most abundant elements by mass in
(4) both SO!- and NO3 the body of a healthy human adult are :
Oxyge\ (6-l.4.kl; Carbon (22.9.,1),
45. The group having isoelectronic species is:
Hydrogen (10.0%); and Nitrogen (2.6%).
The weight which a 75 kg person.would
(1) CP-, F-, Na, Mg2+' gejn if all lH atoms are replaced by 2H
(2) O-, F-, Na+, Mg2+. atoms is : l-s kq r..t I
ug -
{?f d- ,F-,Na+, Mg2+
o
,.1d z.s
(4) O-, F-, Na, Mg+ (2) r0 kg
(3) 1s kg

45. The products obtained whn ct orine gas

(q 37.5 kB

reacts with col d and dilute ueous NaOH 50. On beaknent of 100 mL of 0.1 M solution
are : of CoCl3.6H2O with excess AgNO3;
,p{ a *.,a ctO- 1.2x1022 ions are plecipitated. The
complex is :
(2) cl- and clo! (1) [Co(H2O)6]Cl1
(3) CIO- and ClO3 UA [Co(Hzo)5cllClr.Hro
(3) [co(HrO)rClr]cl.2H.o
(4) clo, and clot (a) [Co(H2o)3Clr].3H2O
L
A/PaEe 71 SPACE FOR ROUGH WORK
-@ PA
6.r P )a
(r-r( \ ?t) O-<2_ 2-
y--_U.
51 Which of the following compounds will 53 The formation of which of the following
form significant amount of metn product polvmers involves hvdrolysis reaction ?
during mono-nitration reaction ? (1) N-Ylon 6,6
\ll. (2) Terylene

NYIon 6
.9r ( JPf
({) Bakelite
NHCOCHI

(2) lli 54 l\trich of the following molecules is least

resonance stabilized ?

OH

(3)
U
(1)
G
ococH3 ,.PI

({) ( (r)

(1)
@ Which of the Iollowing, upon keatment
with terrBuONa Iollowed by addition of C)

bromine water, fails to decoloulize the

colour of bromine ? cur 5; The incleasing order of the reactivity of
L \ill the following halides for the SN1 reaction
(1) c\ is:
Br
CH3CHCH2CH3 cH3cH2cH2cl
o
CI
(2) 0) 0t)
( p-H3CO-C6H{-CH2CI
Er
(rII)
,-o\ <0II).0D
(3) (1) (I)
Br
(2\ ([).(rII).(D l\l>)r>l
CoH;
(3) (rrD.(rr).(r)
,J4
8r Atr (rD<0<0n)
A/ Page 12 SPACE FOR ROUCH WORK

9'^,
 The major product obtained in the 5u 3-Methyl-pent-2-ene on reaction with HBr
following reaction is : in presence of peroxide forms an addition
product. The number of Possible
BI
II stereoisomers (or the product is :
tBuOK
I (
coH;
A (1) Two
(+) I'
(1) ( + )c6HscH(otBu)cH2c6Hs (2, Four

(2) ( - )C5HrCH(OtBu)CH2CuH5 (3) Six

(3) ( a )c6HscH(olBu)cH2C6Hs

C5H5CH =CHC'H5
(4) Zerc
J4)

57 which of the following compounds will

behave as a reducing sugar in an aqueous 59. The correct sequence of reagents for the
KOH solution ? following conversion will be :

(1) HOH"C o CH,OH o HO CH

\ HC)
ocHl
OH n))(*.
CHO cHl
(2) o C
L_O cHzocHl
1o, (1) CH3MgBr, [Ag(NH3)2]*oH.
{
d).L--7
()ll
CH3lrlgBr
{n HOH]C O. CH,OH 4zl teg0'lH3)rl*on
H+/CH3OH

'?,4.o. LI:
OH 1s1 {AeNHa)u I*oH , H+/cH3oH'
CH3MgBr
(4) HoH2q o CH,OLI

HO (4) CH3MgBr, H*/cH3oH,

l(

OH
lAg(NH3)2]+oH- (

A/Page 13 SPACE FOR ROUGH WORK

{r*
$ I

s -o-i.
uo -(
 .+l+++:,+'1-..\, .r.) - x(e4
(t 19'
@ The major product obtained in the PART C _ MATHEMATICS
following reaction is :

'l
61. The function -, 11
/: R
2 l defined
()
o as 71x; = --I---,
-l is
+.x'
DIBAL - tI (1) iniective but not surjectivel
,KJ surjective but not in ective. .

(3) neither injective not suiective

.t,^l,t -f"? (4) invertible.,
-c -
62. If, lor a positive integer n, the quadlatic
CHO equation,
o)
r(r +1) + (r + 1)(r +2) +....
COOH
+ (r + i=l) (r+n;=166
has two consecutive integral solutions,
then n is equal to :
(1) 9 <((+r) { l,i+r)(d.rz) '-; lol
CHO (<+r) (<+!) + : ron'
(2)
( (2) l0{ --
( (r +rl (r +ru (a * n+rl
HO ,$l 1t =
t'=o;f't""n')"
(4) 12 < " *'
{- r,,L
o 63. Let ro be a complex numbet such that
2l,r+1=z where z= J4. A
v{ cHo
1 1l
'.rzl
q,, Ji i _r
I 2, 2
= 3k,
1
27
l-(a,-q ta"-,1 -_ ,o.n :
then k is equal to I trt
oll { (l)
., z I
I
(1) CHO
(2) -t
(3) 1 *+ t
+"4
418
CHO
1gf -, G. 6"
A/PaBe 14 SPACE FOR ROUGH WO ItK

,t*
sl*r' -- *L+ chrl +r )+ I
,nd ? 't'!.
,i, ea
5
o -1" 1. ! .{
221 ,
) t_
-b+
w)iF
 Ie
t:q ,'lL: :J .$*,: J

If A= -i]' *, (3A2+12A) is
67. The value of
64
I "* ("c, -'oc,) + (2rc, - locr) +
equal to : -r1 [,, -
\Ji (je9 t _ ,ocr) + (21cn _ roc.) +.
6 l?^
63
72
LY
t 5l '16
(rrc,
(21cr6 - 1ocr6) c, ieo-9ro
+

51 8.1
--':;-
(2)
63 72 e\ 221-Z1o

72 -63.l e) 2m -2e
(3)
8.1 51 l 1$ zm -2ro

72 -U (4) 221-21r
(4)
-53 51

65 If S is the set of distinct values of 'b' for 68 For any thre positive teal numbets
wtrich the following system of lineat a, b and c,
equations I
ll o I
9(25a2 + b2\ + 25(c2 - 3ac) = 15b(3a + c).
--7T,Y+z=1 lr I j
_then: t JSrgar+ 9 ba {-}sca- }risa.(
r+ay+z=7 o.4 -rrrrat'-lS'Dc'O
ar + by+z =0
/t( b, c and a are in A.P. (te-s.)"
has no solutio& then 5 is :
(2) a. b and c are in A.P. +(eb-rc)'
(2f an inlinite set -r l-sq)""
(2) a finite set containing two or more Ot( a, b and c are in G.P. t6b-
elements (4) b, c and a are in G.P.
(3) a singleton
an empty set
W 69 Let a, b, c R. f /(r)=ar2+br+c is such
66 A man X has 7 friends, 4 of them are ladies
that a+b+c=3 and
and 3 are men, His wife Y also has 7
v-- Git
friends, 3 of them are ladies and 4 are men. f(l+y\=f(t\ + f(y)+ ry, Y x,y eR'
Assume X and Y have no common friends.
l0
Then the total number of ways in which then t /(n) is equal to '3+
X and Y together can throw a Party n=1
r ro(r,)(}r)l+9 IioDi
inviting 3 ladies and 3 men, so that 3 friends
(1) 165
I
[;. J' -aJ
of each of X and Y are in this Party, is: ts
385 +1 I
(1) 468 (2) 190 t
1 95
(2) 469 n L (3) 255
((o
(3) 484 Y-, t4 q

\tEl 48s \H 330

Y- )
A/Page 15 SPAcE FOR ROUGH WORK .r.t $ -- 1\TY+ f( +16-
=co.1g _ o 3 Y'o Sllrq=rc J'
oco
.!^ {g^\ =i r r -fr :o__c ?, r +' lo) + .,h 1*
+
ab-- s. 't'.5 ,,,.
+ rqq,U'\ ,. ,6Ye 5-T 5i
-i- au = s<. (cr
* bcr.\6, , qr,*t1 :tcvg .l't*i. b l.q4 i b+x
+ :cox9qon! 15q =g "4:'L
'v9>
e,vb "'-t
 ('u-r(r.-rtr (ar--E)
I 6 4t :re
t
J

70 lim cot:! - cos.r

equals
72 The normal to the curve
'-; (" - zr)3 y(t-2)(x-3)=t+6 at the poinr where
re.i' c6l3 I l:i5 the curve intersects the y-axis pass,.s
t-6us''Y- J through the point: (O,,
1
- cB tr-'r., + r ,ir y-
(1)
16
3( n-r1{F, -J {rr /1 1\ ta".
\z' z)
+) qtr^- + ce3 ,( ( t-r.) =-(',<-)
6 I
8 tla(n-9)..) (2)
11
2
!+v.= |

- .r .-+at&. { Z" - s"n * 1 1)

(3)
(3) 1
4 -2't = 4 11
-lq 2'e ({)
1
(-l)
u 73. Twenty meters oI wite is available for
fencing off a flower-bed in the form of a
circular sector. Then the maximum arca

I
(in sq. m ) of the flower-bed ts:

71. U tot rclo. 1

(1) 10
the derivative of
{ {2r 2s
lc - a rlTEL
(3) 30 ,o . tr( r1e)
tan
i#
I
g(r), then g(r) (4) 12.s
equals
I r P"Xn)
(a 74 Let I^ = Jtan^ r d-r, (n > 1). If
(l) 3x Ji : ia,6 r a-r- I{+16=a tan5r+b.t5+C, where C is a
'l
- 9x3 ,l .J^:]- 1t constant of integtation, then the ordered
l+3r "4 ^-a,y paiI (a, b) is equal to :
(s('--{) r
(2\
3r
J*l' I I.= J ton'* . ,t

| - 9t' 5
0
re ..
b!-n,
1

-l
(2) (5
(3)
1 + ,rft
(3) ( -1. o)

.,tvf I
1 + 9-r3 ({) ( 1J

A/PaEe 16 SPACE FOR ROUGH WO

l\= !Y,c \
t''')
a-- t rz IQo-rrl
7 L-zl b0 (a,
=
i*5;'.-.r.f,l\C\
-
7A. Let k be an integer such that the kiangle
d,I with vertices (k, -3k), (5, k) and (-k,2)
is equal to
75. I h gr
I 1+cos.t has area 28 sq. units. Then the orthocentre
of this kiangle is at the point (r,-3h)
I- @3r-d-
,fi 2 I
(1) ,,)
3

4 = cotcc'rc -.rxcc,a.<,I 11
(2) ( 5/ F) l-'f,4
(3) - 1t ' - w* " ,*.. ^/'n'
,tr.
-
- - L- (2) (r.-i) 1 2s - I f k(a-0 -h(\ R)
(4) -25 '-'l + t24Z " + s (-"k-9

P, (', r 56:'L, ts- Fr-,r k)-ls k

76 The area (in sq. units) of the region i) 5Fttrlh+,o--t 5c
l(x, u\ | t>0, x+Y<3, x2<4Y ar.d sla'+t 3 h
(4) (r. -1) -
y<1+Glis: (xr0
(r) 1
2 79. The radius of a circle, having minimum
q.zD q-D < 1'. a!ea, which touches the culve y=4-12, q-1
7
(2)
3
and the lines, y = lrl is ,y'\ ,
(r) i N z]-z
-t) @.
'w
2 +ltl-t)
({)
59
'6
(3) r(ll + r)
L2
,",rq-51'='L:&
(4) z(.tl + r)

If (2+sinr)f +[r+r)cosr= O and

80 The eccenkicity of an ellipse whose centre

l is equal to is at the orlsrn t ff one of its directrices

Y(0) = then Y
) ].

0)
4*= -.#; is r = - 4, thefl the equation of the normal
L .L
3
(q -' ler-**
Ja-rs".. to it at
't, 1
(,
q 1
(2) L JYtt 2 "--
3
,n(
tr-tr
) =-l^1(ir s!i, JLI 41- 2Y ='L
I
'Ff 3 t ,+syi,!
(2) 4x+2y=7 l"1+ 1!-= t
..1 3

(4)
l
I tr=t (3)
(4)
t+21J=4
2y-t=2

L/Page 17 SPACE FOR ROUGH WORK

aLr - ,]
,*L. y (o-,9. -d; '1,
t s a - bll)\1=
I g
qr- rt --
t ,^kti,,o
c(L--
('
5"J(.-.r ot
<, o.-
81' A hyperbola passes through the point
L +r2'-l 84. Let a=2i+I-2kad.b= i j
P(,/2, v5) and has foci at (12,0). Then
or l -o) the tangent to this hyperbola at P also
l- +l
t4-l-bt--
Let c be a vector such that lc - al = l,
passes through the point

-d b
tl
,sf Oa,z$) a Ir c = 3 and the angle between
q-,rt-2af
(2) 1.15, ,tZl c an.l a ^ hbe ?0o. Then a c is
(3) F"e,-.tl) eoual to :
' t .+l -
(4) (tJl, z"5l \(o'd b -\q' D( l-5
,*rf : g= (o.O-9 + gir_{0..) )
82 The distance of the point (1, 3, -n frcrn -3
the plane passing through the point \a) r \q 9-+r{
(1, - 1, -1), having norrral perpendicular
t'2-35';2=a
ro both thp tines :, ___ = !____: -
-1
._ (3) 8- I
,..-u (t-r)--.,
"I -2 3

a-2 y +7
*d2= -1
ls 25
-1 (r)
10 v'> T
(l) \
J83 7 ,i3
I \
)
V) E *<, 9k'
41 tt5 A box contains 15 green and 10 yellow
J)
l0 ,'v''i b9
,l (3) balls. If 10 balls are randot y drawn,
.51
.\
one-by-one, with replacement, then the
20
(1) variance of the number of qreen balls
,174
drawn is. .A.lO.
P= ls= Q
83. ff the image of the point P(1, -2,3)inthe 25S
(1) 6 4. ?_
plane, 2.t+3y-42+22=0 measured s
2-
parallel to the tine, I=I=IisQ,tfren
.l 45 (2) l ' w\z'f J-
^?q-- s.
PQ is equal to: ? \'4lto (o
-,el 6 >s
,yf zJtz c-n*b\ (3)
t5 t2-
s
(2) JO
(3) 6G q
l2
1. ,Jrf
(4) 3J5
* A/PaEe.18
o
I E
1-
TOR ROUCH WORK

\5
Jn 6
+
Gto \'I-
6
r ,/,,
) I
86 For three events A, B and C, If 5(tan2 r
'40 IJIJ
- cos2 r1 = 2cos 2r + 9, then the
P(Etactly one of A or B occurs) value of cos 4r is :

= P(Exactl), one of B or C occurs) 5 +..r'- - s.&'^ -- rr <*r">. 9 t9

1 (l) -!
,
-
= P{Exactly one of C or A occursl = aid S{o."^r.__ 3 qs.^ -t l
o:
P(All the three events occur (2)
g
I
simultaneouslv) = :
"16 .
tll
Then the probability that at least one of
the events occurs, is : (1) _t
5
\4 7
16 89 Let a vertical tower AB have its end A on
the level gtound. Let C be the mid-point
(2)
of AB and P be a point on the ground such
that AP=2A8. If zBPC 9, then ran p is
(3) 3 =

a
76 equal to

(4) i
7
0) I,l -4' ca D

87. If two different numbers ate taken ftom 2

the set {0, 7,2,3, ......, 101; then the '6 9 'irne = l-
probability that their sum as well as (3)
h,nG/. {

n
absolute diffetence are both multiple of
is:
4
q
I -l
!
,*p
(1) 6
-12
(1)
55 90, The following statement R I
'14 (p-rq)-r[(-p-,q)-rq] is : U 'l
-_9k
(2) I
45 (1) equivalent to -prq 7.r-
/- (2) equivalent to p+-q rl '-L
(3)
55 (3) a fallacy )
!Fr- a tautology
u{ 6
:=
-o0o-
i qt
SPACE FOR ROUGH WORK
? -('$ (t'IY
rf
1
oq8 3 T'f a f r
{ g. F f T F
L 6 I tr.;1
f T T
Auovc, A l B-ic- FAg-gnc-cArr 3
+
.to F 7 f
RnBn C T
T
A/Page 79
3q* 1,-'r aqr+ q t'
I
C"
3+a+o+l ) L
lg t1-x(o",
ss.