Arihant-Jeemain Practiceset 5 PDF

PRACTICE SET 5 131
JEE Main
Joint Entrance Examination Question Booklet Code P
5
Duration: 3 Hours Max. Marks: 360
Read the Following Instructions Carefully

1. Immediately fill the particulars on this page of the test booklet with blue / black ball point pen. Use of pencil
is strictly prohibited.
2. The test is of 3 hours duration.
3. The test booklet consists of 90 questions. The maximum marks are 360.
4. There are three parts in the question paper A, B, C consisting of Physics, Chemistry and Mathematics
having 30 questions in each part of equal weightage. Each question is allotted 4 (four) marks for correct
response.
5. Candidates will be awarded marks as stated in above instructions for correct response of each question.
(one fourth) marks will be deducted for indicating incorrect response of each question. There is no negative
marking for unattampted questions.
6. There is only one correct response for each question. Filling up more than one response in any question will
be treated as wrong response and marks for wrong response will be deducted accordingly as per above
instructions.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, paper, mobile
phone, any electronic device, etc., except the Admit Card inside the examination hall/room.
8. Rough work is to be done on the space provided for this purpose in the test booklet only. This space is given at
the bottom of pages.
Name of the Candidate (in Capital Letters)
Roll Number (in Figures) in Words

PART A Physics
1. A B
10 F
3 F 6 F
3 F
6 F
20 F
A B
(a) 24.5 F (b) 22 F (c) 20 F (d) 30 F
2. m v
v =0
(Plane
(a) if v = Rg , the block will leave the surface at the same instant R surface)
(b) if v > Rg , the block will leave the surface at very next instant
(c) if v < Rg , the block will leave the surface after moving some distance along
the surface
(d) None of the above
3. d
XX
B
B B
(a) X X (b) X X
d/2 d/2 d/2 d/2
B B
d/2 d/2
(c) X X (d) X X
d/2 d/2
4. 100
60
60
(a) zero (b) 200 (c) 400 (d) 800
5.
(a) mg cos is positive
(b) tension is negative l
(c) mg sin could be zero at an instant
(d) None of the above mg
PRACTICE SET 5 133
6.
Y
v
m M
r
(a) (M + m ) v 2l (b) mlv l
2 mvl
(c) mv l (d) O
(M + m ) X
7. A1 A2
h1
h2
(a) h1 = h2
(b) h1 must be greater than h2 M N
(c) h2 may be greater than h1
(d) h2 must be greater than h1
8. p- V
C B
V2
V
A
V1
T1 T2 T
A B B A B A
p p p p
C A C C C B
O O O V1 V2 O V1 V2
V1 V2 V1 V2
V V V V
(a) (b) (c) (d)
9. AC 4l m
O J B
AO = l OC = 3 l A O C
VA VC
5 BJ 7 BJ
(a) (b) B
12 m 12 ml 2
12 BJ 12 BJ
(c) (d)
7 m 7 ml 2
10.
(a) Parallel L-C-R circuit at resonance acts as a rejector circuit
(b) Series L-C-R circuit at resonance acts as a acceptor circuit
1
(c) Resonance frequency of both the circuits is always given by =
2 LC
(d) Acceptor circuit is used for voltage magnification while rejector circuit is used for current magnification
134 JEE Main Practice Sets
11.
f1 = + 20 cm f2 = 5 cm
Object
u X
(a) u = 20 cm, X = 5 cm (b) u = 10 cm, X = 10 cm

(c) u = 40 cm, X = 20 cm (d) u = 20 cm, X = could have any value
12.
(a) there is no force acting on the people present in the satellite
(b) the acceleration of satellite is zero (as seen from the Earth) as in the satellite the condition is of free fall
(c) Both (a) and (b) are correct
(d) Both (a) and (b) are wrong
13.
(a) must be applied if the motion is circular
(b) could be towards the centre of the circle
(c) may be applied if the motion is circular
(d) is a real force
14.
M l l/2
l/2
3gl 3gl
(a) (b)
2 8
3gl 3gl
(c) (d)
2 4
15. l M
T
(a) mg/2 (b) mg (c) mg/4 (d) mg/8
16.
Heat
PRACTICE SET 5 135
dT/dx dT/dx dT/dx dT/dx
A A A A
t
(a) (b) (c) (d)
17.
X
=l
O X CM Plank
(a) The CM of the system is displaced by a distance X towards left
l Frictionless surface
(b) The boy had covered a distance of X with respect to plank
2
(c) The boy had moved a distance l / 2 with respect to the plank
(d) None of the above
18.
fo = 300 air = 108 km / h sound = 330 m/s

(a) 335 Hz (b) 300 Hz (c) 285 Hz (d) 315 Hz
19.
A B ( 2, 2)
A B
(a) zero (b) 9 V (c) 2 V (d) 4.5 V
20.

v = 10 m/s v = 10 m/s
+
(a) 3 s (b) 4 s
a = g/5
(c) 5 s (d) Not possible
21.
+q +q
(a) (b)
+q +q
(c) (d)
22. 5%
(a) 5% (b) 25% (c) 30% (d) 15%
23. A B 6 :1
rA rB A B rB / rA
(a) 1/ 2 (b) 1/ 4 (c) 1/ 6 (d) 1/ 3
24. I B
B B /B
2 2 2 8
(a) 8 / (b) 8 2 / (c) 16 / (d)
2 2
25.
l d (d << l)
v x
1
(a) x x (b) v x 1/ 2
(c) v x (d) v x 1/ 2
26. 20% 90%

(a) 4 h (b) 6 h (c) 5 h (d) 2 h
27. t
=1.5
S1
d
P
O
Source S2
t Screen
D D
(a) d 2 /D (b) 2 d /D
d2
(c) 2 (d) It is not possible for any value of t
D
28.
A
(a) OR (b) AND (c) NAND (d) NOR

I max
29. Statement I
I min
Statement II
(a) Statement I is true, Statement II is also true and Statement II is the correct explanation of the Statement I
(b) Statement I is true, Statement II is also true and Statement II is not the correct explanation of the Statement I
(c) Statement I is true, Statement II is false
(d) Statement I is false, Statement II is false
PRACTICE SET 5 137
30. Statement I
Statement II FGravitational + FCentripetal
(d) Statement I is false, Statement II is false
PART B Chemistry
31.
IE
Cl Cl Cl Cl
EA IE IE
Cl Cl + Cl Cl 2+
(a) | IE of Process (iv)| = | IE of Process (iii)| (b) | IE of Process (iii)| = | IE of Process (ii)|
(c) | IE of Process (ii)| = | EA of Process (i)| (d) | IE of Process (iv)| = | EA of Process (i)|
32. A 2( g ) AB
2AB ( s) s A 2( g ) + B 2 ( g ) K p = 0.06 atm2
(a) 0.5 atm (b) 0.2 atm (c) 0.7 atm (d) 1.4 atm
33.
50 cm3
Hint
(a) 17.46 (b) 28.56 (c) 28 (d) 15.68
34.
(a) H4P2O7 (b) H4P2O6 (c) H3P3O9 (d) H5P5O15
kf
35. s
kb
2
10 k f = 3 10 5 s 1
(a) 5.6 104 s (b) 9.8 102 s (c) 2.3 104 s (d) 7.5 103 s
36. FeCr2O 4
Na 2CrO 4
X
Cr2O 3
Y
Cr
Z
X, Y Z
(a) NaOH /air carbon carbon (b) Na 2CO3 /air carbon carbon
(c) Na 2CO3 /air NH4Cl Al (d) NaOH /air carbon Al
37.
(a) 3, + 5 (b) 3, 3 (c) + 5, + 5 (d) + 2, 3
38. X
O O
X
CH3
COOCH3 C CH3
OH
(a) HOCH2 CH2OH | H+ , LiAlH4 | ether, 2CH3MgBr, H3O+
(b) 2CH3MgBr and H3O+
(c) HOCH2 CH2OH | H+ , 2CH3MgBr, H3O+
(d) HOCH2 CH2OH H+ , H2 Pt, CH3OH, H+
39.
NH 3 , PH 3 AsH 3 O +3 , O 3 NO 2 O3 XS X SOCl 2
SOF2
(a) NH3, O+3, O3, SOCl2 (b) AsH3, O3, NO2, SOF2 (c) PH3, O+3, NO2 (d) AsH3, O+3 , O3, SOF2
40. CaCO 3 3 Ca 3 (PO 4 ) 2

(a) 40.54 % (b) 35.56 % (c) 15.40 % (d) 41.95%
41.
(a) Polystyrene (b) Urea formaldehyde resin
(c) Bakelite (d) Glyptal
42. (C12H 25 SO 4 Na + ) 10 4
1013 1 mm 3
N A = 6 10 23 }
(a) 1012 (b) 1013 (c) 12 (d) 6
43. [PdCl 2 (PMe 3 ) 2 ]

[NiCl 2 (PMe 3 ) 2 ]
(a) 3 (b) 2 (c) 1 (d) Zero
44.
(CH 3 ) 3 N, (CH 3 ) 2 NH, CH 3CH 2NH 2
(a) (CH3 )3 N > (CH3 )2 NH > CH3CH2NH2 (b) (CH3 )2 NH > (CH3 )3 N > CH3CH2NH2
(c) (CH3 )3 N < (CH3 )2 NH < CH3CH2NH2 (d) (CH3 )3 N < CH3CH2NH2 < (CH3 )2NH
45. () Li 2+
9 2K 2me 4 27 3 mK 2e 4 9 3 K 2m 2e 4 27 2m 3 K 3e 2
(a) (b) (c) (d)
h3 h2 h3 h2
46.
(a) gauche > eclipsed > anti (b) gauche > anti > eclipsed
(c) eclipsed > gauche > anti (d) anti > eclipsed > gauche
47. HNO 3
()
(a) Fe2O3, FeO, FeCl3 (b) ZnO2, PbO2, ZnCl2
PRACTICE SET 5 139
(c) Mn2O3, MnO, MnCl2 (d) Pb3O4, PbO2, PbCl2
48. Na 2CO 3 NaHCO 3 2H 2O

0.05 M HCl, x
( ) ( ) ( x y)
(a) 120 mL (b) 80 mL (c) 100 mL (d) 40 mL
49. P [Fe (CN) 6 ]4 [Fe (CN) 6 ]3 Fe 4 [Fe (CN) 6 ]3 X, Y Z

X Y
P Q P S
Pale yellow Yellow Regenerated Deep blue
solution solution solution
(a) H2O2 / OH , H2O2 neutral medium, Co2+ solution

(b) H2O2 / H+ , H2O2 neutral medium, Cu2+ salt solution
(c) H2O2 / H+ , H2O2 / OH , Fe3+ salt solution
(d) H2O2 / OH , H2O2 / H+ , Fe3+ salt solution
50.
CH3
Cl
NaNH2
Product
NH3
CH3 CH3 CH3
NH2 H2N NH2

(a) (b) (c) (d) None of these
NH2 NH2
51.
Pt | H 2 ( g , 0.1 atm ) | H + ( aq , 102 M )| | MNO 4 ( aq , 0.1 M
Mn 2+ ( aq), 0.1 M), H + ( aq, 0.01 M ) Pt
EMnO 2+ = 1.50 V
4 / Mn
(a) 1.21 V (b) 1.41 V (c) 1.82 V (d) 1.91 V
52.
conc. H2SO4
Product

OH
(a) , 2 (b) , 1
(c) , 3 (d) , 1
53. Na 2CO 3
(a) NH3 + CaCO3 + NaCl (b) NaCl + NH4HCO3 (c) NH4Cl + CaO + NaCl (d) CaCO3 + NaCl
54.
COOH COOEt COOEt COOEt
(a) (b) (c) (d)
55.
HIO 4?
(a) Cyclohexan, 1, 2-diol (b) Cyclohexan, 1, 2, 3-triol
(c) 1-hydroxy cyclohexyl methanol (d) 2-hydroxy cyclohexyl methanol
56.
(a) LiCl > BeCl2 > BCl3 > CCl4 (b) LiCl < BeCl2 < BCl3 < CCl4
(c) LiCl > BeCl2 > CCl4 > BCl3 (d) LiCl < BeCl2 , BCl3 > CCl4
57. C 2H 6 s 2CH 3
3.14 10 +2 s 1
10 5 CH 3 C 2H 6
(a) 1.57 1014 Lmol1s 1 (b) 3.14 1015 L mol1 s 1

1 1
(c) 1.57 10 Lmol
7
s (d) 3.14 1010 Lmol1 s 1
58.
(a) more powerful inert pair effect in Pb than Ge
(b) the ionisation energy of Pb < IE of Ge
(c) Pb is more electronegative than Ge
(d) the ionic radius of Ge2+ and Ge4+ are greater than Pb2+ and Pb4+
59. Statement I
Statement II
(a) Statement I is true, Statement II is also true and Statement II is the correct explanation of Statement I
(b) Statement I is true, Statement II is also true and Statement II is not the correct explanation of Statement I
(d) Statement I is false, Statement II is true
60. Statement I
Statement II
PRACTICE SET 5 141
PART C Mathematics
61. x 2 + 8x + 4y = 0
(a) x = 4 (b) y = 8
(c) y = 4 (d) y = 8
62. z1 z2 | z1| = | z 2| ( z1) + ( z 2) = z1
(a) z 2 (b) z 2 (c) z 2 (d) z 2
( x + 1) 2 + y 3
63. (2, 0) ( x , y)
x +1
x
(a) 2 (b) 1/3 (c) 4/3 (d) 4
a cos x + bx sin x 5
64. lim b
x 0 x4
(a) 2.5 (b) 2.5 (c) 5 (d) 5
65.
A A
(a) Only 1 (b) Only 2, 3 (c) Only 1, 3 (d) All of these
66. 2x y + 2z + 3 = 0
3 x 2y + 6 z + 8 = 0
(a) 23x 13y + 32 z + 45 = 0 (b) 11x 11y + 20z + 20 = 0
(c) 5x y + z + 40 = 0 (d) 23x + 13y + 32 z + 45 = 0
f( x ) ( x ) f ( x ) ( x ) ( x)
67. log dx
f ( x) ( x) f( x )
2
(x ) 1 (x ) (x ) (x )
(a) log +C (b) log +C (c) log +C (d) None of these
f (x ) 2 f (x ) f (x ) f (x )
68. AD ABC AB sin ( A )

b c a b
(a) sin (b) sin (c) sin (d) sin
c b b a
69.
1 1 1 2
(a) (b) (c) (d)
5 4 6 15
70. ([P + 1 ], [P ]), []

x 2 + y 2 2x 15 = 0 x 2 + y 2 2x 7 = 0,
(a) P [ 1, 0) [ 0, 1) [1, 2) (b) P [ 1, 2) {0, 1}
(c) P ( 1, 2) (d) None of these
71. A = a$j + b$j + c k$ , B = $i + c$j C = $i $j
(a) a 2b = 1 (b) a 2b = 2 (c) a 2b = 3 (d) a 2b = 0
72. (3 + 2x ) 74
(a) 30th and 31st terms (b) 29th and 30th terms
(c) 31st and 32nd terms (d) 28th and 29th terms
1 4 4
73. 33 P 2 1 7 , P

1 1 3
(a) 2 (b) 1 (c) 3 (d) 4
74. p q
(a) p ~ q (b) p q (c) q ~ p (d) Both (a) and (c)
75. ax + bx + c = 0 2
, (,
/ { 1 })
a( x + 1) b ( x + 1) x + cx = 0
2 2
1 1 1 1
(a) ( + 1), ( + 1) (b) , (c) , (d) ,
+1 + 1 +1 + 1 +1 +1
76. f ( x) > g ( x) x f(0) = g (0) f( x ) < x

(a) ( , 2) (b) ( , 0) (c) ( , 3) (d) ( , 1)
77. x +y +z=6
(a) 41 (b) 61 (c) 51 (d) 2 41
ex
78. {1 + ( x + 2) log ( x + 2)} dx
x +2
ex
(a) e x log ( x + 2) + C (b) +C (c) e x ( x + 2) + C (d) e x ( x 2) + C
x +2
79. A B
A B BA
(a) 299 (b) 992 (c) 100 (d) 18
80. ABC C
AB
Y
B C
O A X
(a) x 2 + y 2 xy + 1 = 0 (b) x 2 + y 2 + xy 3 =1
(c) x + y = 1 + xy
2 2
3 (d) x 2 + y 2 xy 3 +1= 0
PRACTICE SET 5 143
81.
(a) 170 (b) 40 (c) 150 (d) None of these

1 1

82. ym + y m = 2x ( x 2 1) y 2
(a) xy1 + m 2y (b) xy1 m 2y
(c) xy1 + m y 2
(d) xy1 m 2y
1
1 tan 1 tan a b
83. I= =
tan 1 tan 1 b a

(a) a = 1, b = 1 (b) a = cos 2, b = sin 2

(c) a = sin 2, b = cos 2 (d) None of these
84.
3x + 4y 6z + 1 = 0
3 4 6 3 6 6 3 6 6 3 4 6
(a) , , (b) , , (c) , , (d) , ,
61 61 61 61 61 61 61 61 61 61 61 61
85.
(a) 7/65 (b) 6/65 (c) 7/55 (d) 5/56
86. a, b, c, d, e a + b + c + d + e = 15
ab 2c 3d 4e 5 = (120) 3 (50) a 2 + b2 + c 2 + d 2 + e 2
(a) 40 (b) 50 (c) 45 (d) 55
87. x
(0, 1)
1 + 1 y 2 1 + 1 y 2
(a) x = 1 y 2 log (b) x = 1 y 2 + log
y y

2 + 1 y2
(c) x = 2 1 y 2 + log (d) None of these
3y

88. a$ b$ a$ + b$
$a b$
(a) acute angle (b) right angle (c) obtuse angle (d) straight angle

sin sin
89. Statement I 2 2 = tan
4
cos + cos
2 2
n n A B
cos A + cos B sin A + sin B 2 cotn , n is odd
+ = 2
sin A sin B cos A cos B 0 , n is even
cos A + cos B A B
Statement II = cot
sin A sin B 2
90. Statement I
Statement II
2 :1
Physics
1. (a) Idea This question is based on the distribution of mv 2max
mg = vmax = Rg
charges through capacitors. Here one more R
thing should be noted that the net charge of the As the block moves downward, its speed starts
isolated part must be zero. increasing (increasing the FC ) and the
From the charge distribution, component of force (mg cos ) towards centre
10 F
will start decreasing.
M N The block will leave the surface when
N
v
Q3 +Q2
mg
3 F 6 F =0
Q2 +Q3 Q2
+ Q3 w
+Q2 (Plane
Q3
6 F 2 R surface)
3 F FC = mv
R
+Q1 Q1
20 F mg cos < FC
A B
Now, we redraw the circuit. or mg < FC, highest point
3 F 3 F Now, you can check why option (c) is correct.
TEST Edge In almost every question of circular
motion first one must see the forced acting on
A B
that body and then one should find net
20 F
external force acting towards the centre. This
net force (towards the centre) will act as a
centripetal force.
6 F 6 F
3. (b) As direction of current is out of plane. So by right
Ceq = 24.5 F hand thumb rule, direction of field to the left of
TEST Edge The question based on combination of wire is downwards and to the right is upwards.
capacitors could be solved by distribution of By using this and superimposing the fields due
charges, series and parallel combination and Wheat to two wires. We get the net field as shown by
stone bridge. option (b).
1
2. (c) Idea This question is of circular motion and one Note Strength of field
thing should be noticed that the centripetal distance
force will be provided by the net external force So, near the wire strength of field is more and
acting on that body (there could be more than approaching to infinity and it declines gradually
one force). as the distance increases.
Always remember that centripetal force is not a real |X X C |
4. (c) tan = L
force. Here in FBD, it is provided by mg R
m v Case I When capacitor is removed, then
=0 X
(Plane tan 60 = L X L = 3 R
R
mv 2 R surface)
FC = R Case II When inductor is removed, then
XC = 3 R
If (FC ) required < mg
So, Z = R 2 + ( 3 R 3 R )2 = R
mv 2
Then, mg N = N =W So, L-C-R would acts as pure resistor and thus
R
power factor cos = 1
For vmax , the box will not press the surface below and
the entire m will use as the centripetal force. V 2 200 200
Power dissipated is P = =
N =W = 0 R 100
= 400 W
PRACTICE SET 5 145
5. (d) Idea At the lowest point mg sin = 0. 8. (a)

So work done by it will be zero at the lowest
Name Information Pressure Volume Nature of
point.
of the obtained p-V graph
process from the
graph
T
AB V T Constant Increasing Straight
v line
p =
mg constant parallel to
V -axis as
At the lowest point, V and T
both are p=
mg sin = 0 increasing constant
It seems, Wmg sin = 0 at the lowest point, but there is BC V = constant Decreasing Constant Straight
no such thing work done at an instant. line
p T
parallel to
TEST Edge Questions on vertical circular loop could T is p-axis, as
also be asked on this topic. In these questions, one decreasing.
V =
must know the conservation of mechanical energy p will constant
and how to find centripetal force expression. decrease
6. (b) Idea In this question, one can apply conservation CA T = constant Increasing Decreasing Rectangul
of linear momentum and conservation of 1 ar
p hyperbola
angular momentum. V
1
From conservation of angular momentum theorem, V is as p
V
Initial, Li = mv l decreasing
After collision, the common velocity of the system v . p should
increase
From linear momentum conservation,
The corresponding graph is shown in figure
mv = (M + m ) v
given below
m
v = v p
(M + m )
A B
So, the angular momentum of the system after
collision
Lf = (M + m ) v l C
mv
= (M + m ) l V
(M + m ) O
V1 V2
= mlv 9. (c) Moment of inertia of rod about point O is
Note Here, important thing to note is that the angular I = Moment of inertia of OA + Moment of inertia of
speed of ring will be zero. OC
TEST Edge Different types of questions could be 1 M 1 3M
= (l )2 + ( 3l )2
asked on the above concepts. A question is usually 3 4 3 4
asked where a point mass hits a stationary rod and M l 2 27 M l 2
stick to it the angular speed of the rod after collision = +
12 12
could be asked. Here just apply conservation of
7
linear momentum and conservation of angular = Ml 2
momentum. 3
As L = I = J
7. (c) pM > pN L 3J
= =
[pressure at M is greater than pressure at N] I 7M l 2
So, velocity Now, for rotating rod induced emf is
vM < vN 1
e = Bl 2
From this observation, it seems that h1 > h2 but there is 2
no relation given between A1 and A2. So, there could 1
For part AO , eOA = eO e A = Bl 2
be any relation possible between h1 and h2. 2
1
For part OC, eOC = eO eC = B ( 3l )2 13. (c) Idea To solve this question, one must
2 understand that centrifugal force is a pseudo
e A eC = 4Bl 2 force and it will be considered only when we
3J observe from the accelerated frame.
= 4Bl 2
7M l 2 Centrifugal force is a pseudo force (not a real force)
12 BJ and we apply it only when we observe from the
= accelerated frame. (i.e., frame of the revolving
7M
body).
10. (c) Resonance frequency of series L-C-R circuit is
1 F centrifugale
only when Z = 0 of that circuit.
2 LC Fcentrifugale m
11. (d) Idea Above question is based on combination
of lenses. The easier way to solve this So, option (c) is correct.
question is to draw the ray diagram.
From figure, it is clear that the final (virtual) image TEST Edge Questions on pseudo force are
will be at the focus of concave lens. So, the object generally asked in Laws of motion.
has to be at u = 20 cm (at the focus of the convex Just remember that we will apply pseudo
lens) force only if we are observing from accelerated
frame.
14. (a) When chain falls completely out of the table.
Let u = 0
M
f2 = 5 cm
l
u = 20 cm
x = Could
have any value
TEST Edge The questions on combination of lenses Loss of PE = Ui Uf

could also be solved by the direct formulae but in M l
this question it will be easier to draw ray diagram Ui = g
2 4
and solve this question.
[from centre of mass concept]
12. (d) Idea For this question, one must understand
the concept of centripetal force. l
Uf = M g
The gravitational force acts as a centripetal force, 2
i.e., people in the satellite feels weightlessness. [at table level let U = 0]
Mgl Mgl
So, Ui Uf = +
S 8 2
FG Mgl 1
e = 1
2 4
3 Mgl
U =
8
If we observe from the earth, the satellite needs a From mechanical energy conservation,
centripetal acceleration that is provided by the
U = KE
gravitational force.
3 Mgl 1
TEST Edge Free fall does not mean that there is, no = Mv 2
8 2
gravitational force is acting, it just means that the
person is not getting normal reaction. In satellite, 3gl 3gl
v = =
the gravitational force acts on the person but it 4 2
acts like centripetal force to revolve it. So, the
person will not get any normal reaction (free fall).
PRACTICE SET 5 147
15. (c) Let the tension in the string be T and the q q

19. (a) VA = and VB =
acceleration of the centre of mass of the rod 4 0rA 4 0rB
downwards be a. q 1 1
VA VB =
4 0 rA rB
T
G
a B (2, 2)
mg
Then, mg T = ma (i) (2, 0)

mgl ml 2 a
Again, =l =
2 3 l /2 Now, rA = distance of point A from origin = 2 units
3 and rB = distance of point B from origin
a= g ...(ii)
4
= [( 2 )2 + ( 2 )2 )1/ 2 = 2 units
mg
T = As rA = rB
4
dT VA VB = zero
16. (b) H = KA is same in steady state condition.
dx 20. (c) Idea This question is based on one-dimensional
dT motion.
A = constant
dx Here, one thing should be noticed that the
dT final displacement of boy and ball is same.
= Temperature gradient)
dx When the ball come back into the hands of the boy,
the displacement of boy and ball will be same.
So, graph will be hyperbolic graph with shifted
origin. Boy Ball
17. (c) As the external force on the system is zero then the u = + 10 m /s, u = 10 m /s,
centre of mass of the system will not change its a = + 2 m /s 2 a = + 10 m /s 2
position. This condition is possible when boy and Q S Boy = S Ball
centre of plank reaches at centre of mass. 1 1
l 10 t + 2 t 2 = 10 t + 10 t 2
So, the boy had moved a distance with respect to 2 2
2
20 t = 5t 2 t 2,
plank.
20t = 4t 2
18. (d) Idea This question is based on Doppelers effect. t =5s
Hence, one thing should be understood that
air flow will only change the speed of sound, TEST Edge In these types of questions, we can
it will not effect relative motion between the solve the question from any frame of reference
observer and source. (whether it is lift or ground frame).
The motion of air just changes the speed of sound 21. (a) Idea This question shows that the electric field
in air. lines are always perpendicular to a
5 conducting surface.
v sound in blowing air = 330 108
18 Charge distribution would be like this,
= 300 m /s
+
v sound
f = f0 +
v sound vs +q +
+
300
= 300
300 15 Now, (i) field lines originate from positive charge
and ends at negative charge.
300 300
= (ii) Field lines are always perpendicular to surface
285 of a conductor.
= 315 Hz
TEST Edge The electric field inside a conducting
TEST Edge For these types of questions where the sphere will also be zero. The electric field inside a
air flow is considered, then one can take the frame conducting shell will be zero if there is no charge
of reference of air to solve the question. is placed inside it.
22. (d) Idea This is a simple question based on errors. TEST Edge Different types of current
x nA configurations like straight wire, circular wire,
If x = An then %= % solenoid and toroid are also exists. So, questions
x A
based on these configurations could also be
x is error in calculation of x. asked.
r
% = 5% 25. (d) T is tension in the strong, then
r
4 kq 2
V = r 3 T sin = Fe = (i)
3 x2
V r and T cos = mg (ii)
=3
V r
V r
%=3 % l
T
V r T
V Fe
90
Fe
% = 3 5 = 15 % x
V
mg mg
TEST Edge On errors different questions could be
asked. Some questions could be asked on From Eqs. (i) and (ii), we get
absolute error, error in subtraction, addition,
kq 2
multiplication and division. tan mg =
x2
23. (a) In series, potential difference resistance mg
Hence,
rA 3
= q2 =tan x 2
rB 2 k
x
Now, R L / A and A = area = r 2 Now, tan ~
= [Q d << l ]
2 2l
LA rB 3
= q2 =
mg 3
x
LB rA 2 2k l
2
6 rB 3 mg
= q = C x 3/ 2
1 rA 2 or Here, C =
2k l
rB 1
= dq 3 dx
rA 2 = C x 1/ 2
dt 2 dt
24. (b) Idea This question is based on magnetic field dx
= velocity
due to a current carrying configurations. dt
Radius of circular loop is dq 3
= C x 1/ 2 v
4 dt 2
R = [Q 2R = 4]
2 or v x 1/ 2
dq
[Q is also constant as given in question]
dt
26. (b) Idea This question is based on radioactivity.
Just apply the formula of radioactive decay
45 45 and solve the question.
1/2
Thalf = 20 min
1m
Now, N =N0 (1/ 2) t /T , for given conditions we have,
So, field at centre of circle is 0.8 N0 = N0 (1/ 2)t1 /T
i 0i
B = 0 = and . N0 = N0 (1/ 2)t 2 /T
01
2R 4
Taking their ratio, we get
Field due to square is t 2 t 1
i 0.1 1 T
B=4 0 (sin 45 + sin 45 ) =
4 1/ 2 0.8 2
3 t 2 t 1
2 2 0i 1
B= = (1/ 2) T
2
So, B /B = 8 2 / 2
PRACTICE SET 5 149
t 2 t1
=3 t 2 t1 = 6 h 30. (d) Idea The centripetal force needed for the moon
2 is provided by the gravitational force. Here,
TEST Edge From radioactivity some question one should notice that the only real force
could be asked (from concept of) and decay. here is gravitational force.
Some questions could be asked from half-life. The moon revolve around the earth due to a real
27. (c) Path difference of light reaching O is gravitational force. As that force acts towards the
centre also called centripetal force.
x = (PS1 + S1O ) [PS 2 + S 2O + ( 1) t ]
The net force on the moon = FGrav
Note ( 1)t is the net increase of path length due
to introduction of glass plate. TEST Edge In the case of a car moving on a
circular banked road, the centripetal force is
Now, PS1 = S1O = d + D 2 2
provided by the friction and the component of the
d2 normal reaction.
= D 1 + (using binomial expansion).
2D 2
and PS 2 = S 2O = D, Chemistry
also given is = 1.5 and x = 0 for central maxima. 31. (c) Idea This problem includes conceptual mixing
d2 of IE and EA. This problem can be solved by
Hence, 0 = 2 D + [ 2 (D ) + 0.5 t ] knowing the exact concept involved in IE
2D
and EA.
d2 2d 2 Amount of energy involved in loosing electron from
0= 0.5 t t=
D D outermost shell is known as IE while amount of
energy involved in accepting one extra electron is
28. (b) A known as EA and we know that
Y = NOR gate
B
IE = EA
Here, Y = A + B In process (ii), IE is involved
Cl Cl + e
A Y = NOT gate
While in process (i), EA is involved.
Here, Y = A Cl + e Cl
So, in the given problem So, same amount of energy is released when
Y = A +B electron is absorbed.
So, | IE of process (ii)| = | EA of process (i)|
= A B (using De-Morgans law)
TEST Edge JEE Main includes this type of
= AB problems in examination to judge the
AND gate. understanding of the student in basic inorganic
periodic properties. So students are advised to go
29. (b) Idea In YDSE Imax = ( a + a )2 = 4a 2 through better understanding of periodic trends
= 4 I0 of various atomic properties, such as
electronegativity, metallic character, size of atom
and Imin = ( a a ) = 0 etc.
In YDSE, Imax = 4I 0 [I 0 is the intensity of single
beam] and Imin = 0 i.e., minima is perfectly dark.
32. (c) Idea This problem includes concept of
determination of equilibrium constant. This
Imax
problem can be solved by using the skill of
Imin partial pressure and K p .
But when width of any one of the slit is slightly 2AB (s ) s A2 (g ) + B2 (g )
increased then intensity of two waves would (0.5 + p0 ) p0
become different and thus minimas will not be
perfectly dark and thus Imin 0 K p = pA 2 pB 2
I 0.06 = ( 0.5 + p0 ) p0
max would become finite.
Imin p02 + 0.5 p0 0.06 = 0
TEST Edge In YDSE when we use white light we p0 = 0.1
get central white fringe and red and blue ptotal = pA 2 + pB 2 = ( 0.5 + p0 ) + p0
dominant fringes on both the sides of central = 0.6 + 0.1 = 0.7 atm
fringe.
TEST Edge Similar questions including conceptual 34. (c) H3P3O9 is a cyclic trimetaphosphoric acid.
mixing of Kp , Kc can be asked in JEE Main which is O OH
a general trend of JEE Main and can be solved by P
using relation O O
Kp = Kc RT n O O
O P
33. (a) Idea This problem includes conceptual mixing HO OH
P O
of various calculation involved in Dumas
Structure of H3P3O9
method viz, determination of volume of
nitrogen and determination of % age of 35. (c) Idea This problem can be solved by using the
nitrogen as follows concept of determination of rate of reversible
l Determine the % of N2 at STP using reaction as follows
p1V1 p2 V2
= l Write the chemical transformation at t = 0,
T1 T2 t = t and t = t eq and calculate the value of kb
l Determine the mass of N2 using gram molar kf
l using relation k(aq) =
volume then calculate % of N2. kb
Determination of volume of nitrogen l Now, calculate the value of t using relation
Given, mass of substance = 0.30 g 2.303 x
VN2 (volume of N2 ) = 50 cm 3 k = log
t x a
Atmospheric pressure = 715 mm Hg kf
Room temperature = 300 K cis - Z s trans - Z
kb
Vapour pressure of water at 300 K = 15 mm
Initial a 0 kf
Actual vapour pressure of dry gas k (aq) =
kb
= 715 15 = 700 mm Hg
at time t ax x 3 105
Now, the volume at experimental condition is kb =
102
standarize by converting it into STP.
At a xe xe = 3 103 = kb
p1 = 700 mm p2 = 760 mm equilibrium
V1 = 50 cm 3, N2 = ? According to relation
T1 = 300 K, T2 = 273 K 2.303 xe
(kf + kb ) = log
As we know
pV
1 1 pV
= 2 2 t xe x
T1 T2 xe
Given, x =
700 50 760 V2 2
=
300 273 2.303
(kf + kb ) = log 2
273 700 50 t
V2 = = 41.9 cm 3
300 760 0.693
( 3 105 + 3 103 ) =
The mass of nitrogen in 41.9 cm 3 gas is calculated t
0.693 0.693
by using concept of gram molar volume. t= =
3 103 (1 + .01) 3 103 0.01
22400 cm 3 of N2 at STP weigh = 28 g
= 2.3 104 s
41.9 cm 3 of N2 at STP weigh
28 41.9 TEST Edge In JEE Main, these questions are asked
= g frequently to know the in depth knowledge of
22400
student in rate equation of different types of
Percentage of N2 questions. So students are advised to go through
Mass of N2 in depth study of consecutive reaction and
= 100
Total mass of organic compound parallel reaction also.
Heat
28 41.9 100 36. (c) 4FeCr2O4 + 8 Na 2 CO3 +7O2 8 Na 2CrO4
= = 17.46 % (X ) air
22400 0.3 + 2 Fe2O3 + 8 CO2
TEST Edge Similar questions having % of P or % of Na 2CrO4 + 2NH 4 Cl (NH4 )2 Cr2O7 + 2 NaCl
S may also be asked in JEE Main so students are Heat
advised to go through quantitative calculation of
Al
% of P or % of S. Cr2O3 Cr
(Z )
PRACTICE SET 5 151
37. (a) Idea This problem is based on concept of TEST Edge Similar problems taking the keto group
oxidation number of elements in various or another group under protection and reaction
compound. This problem can be solved by of ther group are also be asked in JEE Main very
considering the oxidation state of element is frequently.
equal to x. (which has to determine). 39. (b) This problem includes conceptual mixing of bond
NH4NO3 exists as NH+4 NO3 angle, Drago rule and Bent rule.
In NH4+ , N have oxidation state (i) Drago rule According to Drago rule bond angle of
NH3, PH3 and AsH3 decreases top to bottom
x + 4 = +1 x = 3 NH3 > PH3 > AsH3
In NO3, N have oxidation state Here, AsH3 has smallest bond angle.
x 6 = 1 x + 5
TEST Edge This problem is asked in JEE Main to O O+
judge the basic understanding of students in
x y
calculation of oxidation state. Students are O O O O
advised to go through calculation of oxidation
x <y
state of elements oxoacid of chlorine and
sulphur. Lone pair-double bond repulsion is O3 is greater
than single electron-double bond repulsion in O+3
38. (c) Idea This problem includes conceptual mixing of The repulsion between lone -pair single bond in O3
protecting of carbonyl group and addition is greater than repulsion between single electron
reaction to the carbonyl group. This problem single bond in O3.
is solved by protecting the keto group first
(ii) According to Bents rule bond order of N-O bond
followed by nucleophilic addition reaction to
in NO2 has more p character than OO bond in O3.
carbonyl centre and subsequent hydrolysis
to get the desired product.
Protection of carbonyl group Aldehyde and N O
ketone are protected by formation of acetal. x y
O O O O
O O O 2
O3 has sp hybridisation central oxygen atom.
HO OH (iii) According to Bent rule p-character of S-Cl bond in
H+ SOCl2 is lower than p-character of S - F bond in
C O O O SOF2.
CH3 CH3
O O
Keto group is protected
S S
Addition of Grignard reagent to ester group leading x F Y Cl
O O
to formation of ketone and then alcohol after F Cl
hydrolysis. Hence, the correct choice regarding smallest bond
O O O O angle is (b).
+ 16 27
40. (d) % of O = 100 = 41.95 %
CH3MgBr
+ CH3OMgBr 100 + 3 310
O CH3
CH3 41. (a) Idea This problem involves conceptual mixing
O CH3MgBr O of preparation of styrene and addition
polymerisation of styrene. Students are
O O O advised to follow these steps.
l Complete the reaction first using
CH3 H3O +
CH3 information provided in question. (use
elimination reaction)
OH CH3 OMgBr CH3 l Then, using the product of above reaction as
Hence, the correct choice is (c). starting material identify the correct
product.
Preparation of styrene Inductive effect CH3 group has +I effect as the

H H number of CH3 group around N-atom increases the
KOBut basic strength increases hence according to this
C C Cl C C H
concept basic strength order is
H H H H (CH3 )3N > (CH3 )2NH > CH3CH2NH2
1,chloro 2-phenyl ethane Styrene Steric effect Greater the CH3 group around
Styrene is obtained due to elimination reaction of N-atom greater is the steric hindrance which
1-chloro-2 phenyl ethane in presence of strong causes decrease in basic strength.
base KOBut Solvation effect As the number of H-atom directly
Polymerisation of styrene attached to N-atom increases solvation increases
hence basic strength increases on this basics
H Polymerisation strengths basic are as follows
C C CH CH
H (CH3 )3 NH < (CH3 )2 N < CH3CH2NH2.
H n
Polystyrene The basic strength of 1, 2 and 3 amine are the
weighted result of these above three factors which
TEST Edge Problems related to preparation of is as follows.
bakelite, nylon 6, nylon 6,6 and other polymers
(CH3 )2 NH > (CH3 )3 N > CH2 NH2
using different modes of reaction to prepare the
monomer are asked in JEE Main frequently, TEST Edge Problems related to basicity of
students are advised to go through these topics. aliphatic and substituted aromatic amines as
well as heterocyclic compound are generally
42. (d) Number of sodium lauryl sulphate
asked in JEE Main. Students are advised to
[C12 H25 SO4 Na+ ] in 1 L solution study these concepts using inductive effect in
depth.
= 104 6 1023 = 6 1019
n 2h 2 2KZe 2
Number of sodium lauryl sulphate per mm 3 45. (a) v = r, rn = and vn =
4 KZme
2 2
nh
= 6 10 13
2KZe 2 n 2h 2
Number of colloidal particles per mm =1013 3 =
nh 4 2KmZ e 2
Number of molecules per colloidal particle
8 3me 4K 2Z 2
6 1013 =
= =6 n 3h 3
1013
Given, n = 2, Z = 3
43. (d) [NiCl2 (PMe3 )2 ] 9 3K 2me 4
2+ =
Ni in [NiCl2 (PMe3 )2 ] h3
46. (b) Idea This problem includes conceptual
3d 4s 4p mixing of conformational structure of
sp3 hybridisation molecule and H-bonding. Students are
advised to draw the conformational
Structure: tetrahedral structure of organic molecule first followed
2 by analysing the effect of H-bonding on
Cl
molecule.
Ni
Gauche > anti > eclipsed
Cl PMe3
PMe3 Hydrogen bonding The presence of hydrogen
bonding stabilises, the structure. The
So, no isomer is possible, so answer is zero. conformations of 2-amino ethane 1-ol are
44. (b) Idea This problem is a conceptual mixing of H
NH2 N H H2N
basic character, inductive effect, steric effect, OH
H H H O H
solvation effect.
H
Students are advised to go through study of H H H H H H
H
effect of each factor and then come to a final
OH H
conclusion using the effect of all factors Anti Gauche eclipsed
comparatively.
Out of above gauche form have more stability due
to hydrogen bonding.
PRACTICE SET 5 153
TEST Edge The problem related to preparation of CH3

such molecule and then relating the concept of Cl
conformational isomerism an H-bonding as well
as steric hindrance are asked very frequently in
JEE Main. Students are recommended to study H
the effect of these concepts in conformational
isomerism. TEST Edge In JEE Main, questions containing the
substrate having substituent different directive
47. (d) Pb3O4 ( X ) is red coloured mixed oxide (PbO and influence are also be asked in JEE Main
PbO2 ) frequently.
Pb3O4 + 4 HNO3 2Pb(NO3 )2 + PbO2 + 2 H2O
(A ) (B ) 51. (b) Idea This problem includes concept of Nernst
equation along with its application to
PbO2 + 4HCl PbCl2 + 2H2O + Cl2 determine cell potential.
(B ) (C )
Anode H2(g ) 2H+ (aq ) + 2e , E = 0 V
PbCl2 is insoluble in cold water but soluble in hot Cathode MnO4 (aq ) + 8 H+ (aq ) + 5e
water.
Mn2+ (aq ) + 4H2O (e ),
Pb3O4 + 8 HCl 3 PbCl2 + 4H2O + Cl2
(A ) E = 1.50 V
E cell = E RP (RHS) E RP (LHS)
48. (b) When phenolphthalein is used as an indicator
0.05 y = 10 0.2 1 0.06 [Mn2+ ]
= 1.50 log + 8

y = 40 mL 5 [MnO4 ] [H ]
When methyl orange is used as an indicator 0.06 PH 2
0 log + 2 {0.0591 0.06}
0.05 x = 10 0.2 3 2 [H ]
x = 120 mL 0.06 10 2
Hence, x y = 80 mL = 1.50 log 2 8

5 . (10 )
01
49. (c) 2 [Fe(CN)6 ] + H2O2 + 2 H+ 4
0.06 0.1
(P) (X ) + log
2 (102 )2
2[Fe(CN)6 ]3 + 2 H2O 0.06
Yellow (Q) = 1.50 log 1015 + 0.03 log103
5
2 [Fe(CN)6 ] 3 + 2OH +H2O2
(Y )
= 1.50 0.012 15 + 0.03 3
= 1.50 0.18 + 0.09
2[Fe(CN)6 ] 4 + 2 H2O + O2
(P ) =1.41 V
4 TEST Edge
3 [Fe(CN)6 ] + 4Fe 3+
Fe4 [Fe (CN)6 ]3 Problem related calculation of
(Z ) (Deep blue) equilibrium constant and pH of cell are also
asked frequently in JEE Main so students are
50. (a) Idea This reaction includes the nucleophilic advised to build up the skill in determination of
substitution reaction on haloarene. these parameters using Nernst equation.
l Form the benzyne intermediate first.
52. (c) Idea This problem includes conceptual
l Now, complete the reaction using the NH2 as
mixing of rearrangement of carbocation ring
a nucleophile keeping in mind the stability
cyclisation and number of assymmetric
of product.
carbon.
CH3 CH3 CH3
While solving this question, students are
Cl NH2
NaNH2 NH2 advised to follow this route:
NH3 l Generate the stablest carbocation
H (intermediate) using rearrangement.
Benzyne
l Complete the reaction using process of
Benzyne formation Benzyne formation can be interamolecular nucleophilic substitution
detected if and only if there is presence of reaction (double bond acts as a nucleophile
hydrogen atom at ortho position to here.)
chlorine/halogen in haloarene.
Rearrangement and ring cyclisation The reaction 54. (b) Idea This problem includes conceptual
proceed through rearrangement of carbocation mixing of favorskii rearrangement and
and ring cyclisation leading to the formation of 6 migrating aptitude.
membered ring as follows.
While solving such problems, students are
H + advised to follow these steps
Formation of carbanion takes place first by
-H abstraction then formation of
OH OH2 cyclopropane by removal to leaving group.

Reattack of nucleophilic O Et to formation of
rearranged product.
Favorskii rearrangement Conversion of -bromo
Rearrangement reaction is the characteristic ketone to ester in presence of base is known as
property of carbocation where carbocation favorskii rearrangement. This reaction proceeds by
undergoes rearrangement to stabilise the intramolecular nucleophilic substitution reaction
carbocation to more extent. through cyclopropane intermediate.
Rearrangement 6 O O O
1 3 H Br Br Br
2 4 5 NaOEt
Ring cyclisation
5 O EtO O
6 4
3 NaOEt
1
2
Major
Assymmetric carbon The carbon attached to the COOEt

four different substituents are known as assymetric
carbon. In the given product, we may count the
total number of assymetric carbon which is equal
to 3 (denoted by #).
H H H H
Note In case of substituted -bromo -alkyl
H ketone undergo rearrangement then the
C C H
H H H rearrangement occurs in such a way to stabilise
H C C C H carbanion.
C #C #C H
H O O
H
C C# C OR
H C C H
OR
H H
H H H H
More stable carbanion
TEST Edge Problems involving concept of various
rearrangement reactions such as O
RO
pinacol-pinacolone rearrangement, nucleophilic
addition reaction to carbonyl compound and
identification of isomerism in product are also
asked frequently. Less stable carbanion
53. (b) Solvay soda ammonia process is
NH3 + H2O + CO2 NH4HCO3 TEST Edge Problem related to Beckmann
rearrangement, Hoffmann bromaamide reaction
NaCl + NH4HCO3 NaHCO3 + NH4Cl are generally asked in JEE Main. Students are
NH3 + H2O + CO2 + NaCl NaHCO3 + NH2Cl advised to study these topics in depth.

2 NaHCO3 Na 2CO3 + H2O + CO2
PRACTICE SET 5 155
55. (c) Idea This problem includes conceptual As we know polarisation is directly proportional to
mixing of malaprade oxidation and covalent charactor. Hence, correct answer is (b).
nomenclature. TEST Edge Question based on Fazans rule in
While solving this problem, students are determination of covalent character, ionic
advised to write the structure of both character, acidic character are also asked very
product of the reaction and given choices frequently, students are advised to go through
then choose the correct starting material these concepts.
keeping the basic concept of Malaprade k [ CH3 ] 2
57. (b) k eq = f =
oxidation in mind. kb [ C2H6 ]
Malaprade oxidation This oxidation is done by 105
treating vicinal diol with HIO4. [ CH3 ] = mol L1 = 106 mol L1
10
H
100
R1 OH R1 CHO [ C2H6 ] = = 10 mol L1 = 10 M
HIO4 10
+
R2 OH R2CHO k
k eq = f
H kb
Breaking of this type
bond take place [106 ]2 3.14 102 s 1
=
10 kb
The product of reaction in above given question is
. 103+ 12 L mol1s 1
kb = 314
H
O+O C . 1015 L mol1s 1
= 314
H
58. (a) Inert pair effect increases in 14th group as the
means they must be made by Malaprade oxidation atomic number increases.
of (1-hydroxy cyclohexyl) methanol as follows On moving top to bottom on group 14
OH OH OH
(Z)
H HIO4 H C 26 Atomic
+O
H H Si 14 number
Ge 32 increases
TEST Edge Similar questions having Malaprade Sn 50 Inert pair
oxidation of -amino alcohol are also be asked in pb 82 effect
JEE Main, so students are advised to sutdy in increase.
depth these and preparation of their starting
59. (b) Relative lowering in vapour pressure is a colligative
material also.
properties i.e., depends upon the number of
56. (b) Idea This problem includes conceptual mixing of particles. More the number of particles lower is the
covalent character and Fazans rule. While vapour pressure. Thus, 0.1M sugar solution has
solving the problems student is advised to higher vapour pressure than the KCl solution of
choose the common ion in all and then same concentration.
arrange the trend of polarisibility of cation Relative lowering in vapour pressure is directly
and anion on the basis of these two trend. proportional to the mole fraction of the solute ( xB ).
One can easily find the answer as
p0 p
polarisation covalent character. xB
p0
Fazans rule According to Fazans rule, the
polarisibility of smaller cation and large anion are 60. (d) This problem includes conceptual mixing of
larger. sequence of amino acid in nucleic acids and
Here out of LiCl, BeCl2, BCl3, CCl4 all the anion are bonding in them.
same i.e., Cl. While cations are different hence Sequence of amino acid in nucleic acid The
polarising power will depend upon size of cation. presence of different sequence of amino acid is
Polarisation of cation of Li+ , Be2+ , B3+ , C4+ are as responsible for the different types of nucleic acid.
follows
+ 2+ 3+ 4+
Sequence of base in DNA and RNA are as follows
< Be < B
Li <C
Types of nucleic acid Sequence of base
Size of cation decreases. DNA TGAACCCTT
Polarisation increases. mRNA ACUUGGGAA
Covalent nature increases.
According to base pairing principle 63. (c) Idea Convert the given equation as linear
T in DNA faces A in mRNA dy
differential equation such as + Py = Q
G in DNA faces C in mRNA dx
A in DNA face U in mRNA.
IF = e
P dx
Bonding in nucleic acid is hydrogen bonding and solution is
which is responsible for passing of different bases y IF = (IF Q ) dx
to each other.
Given that slope of the tangent,
TEST Edge Similar questions relating type of dy y 3
linkage between nitrogeneous based and number = x +1+
dx x +1
of hydrogen bonding between the two nucleic acids
are also asked generally in JEE Main, so students Let x + 1 = X , y 3 = Y
dY Y 1
are recommended to study these topic in depth. = X , IF =
dX X X
[This is linear differential equation]
Mathematics Y y 3
=X +c = x +1+ c
61. (c) Idea Convert the given equation of tangent as X x +1
x 2 = 4ay, find the vertex. x = 2, y = 0 c = 4
Given, the equation of tangent x 2 + 8x + 4y = 0 y 3 = ( x + 1)2 4 ( x + 1) = x 2 2x 3
Y
y = x 2 2x meets x-axis are 3 at ( 0, 2)
2 8
Area = ( 2x x 2 )dx = 4 = 4 / 3
0 3
Area = 4 / 3 sq units
X
TEST Edge Area bounded by the ellipse, parabola,
circle and axis related questions are asked,
students are advised to understand the concept of
area bounded by the curve and also acquainted
( x + 4 )2 = 4 ( y 4 ) yourself with properties of definite integral.
X 2 = 4Y (by shifting the origin) 3 5
64. (b) Idea Qsin = + ...
X = x + 4, Y = y 4 3! 5!
Vertex = 4 2 4 6
and cos = 1 + + ...
2! 4! 6!
Tangent at vertex is Y = 0
Apply these formulae and go with concept of limit.
y 4 = 0 or y = 4
TEST Edge Equation of parabola of tangent and in It is given that lim exists
x0 x4
other form related questions are asked. To solve and is finite.
these types of questions, students are advised to
understand the basic concept of parabola. Now, lim
x0 x4
62. (d) We have given that
x2 x4 x3
| z1| = | z 2| and arg( z1) = arg ( z 2 ) a 1 + + + bx x + 5
2 24 6
z 2 = rei , z 2 = re i = lim 4
x0 x
z1 = rei ( ) = rei e i
= r (cos + i sin ) e i a a b
(a 5) + + b x 2 + x4 +
= r e i z 2 2 24 6
= lim
Alternate Solution x0 x4
z2
Since limit is finite.
z1 a
a 5 and + b must be equal to zero.
2
a 5 = 0 a = 5
a
and +b=0
2
z2 5
b = = 2.5
From figure, it is clear that z1 = z 2 2
PRACTICE SET 5 157
TEST Edge Algebraic limit, exponential limit and f ( x ) ( x ) ( x ) f ( x )

dx = dt
logrithmic limits related questions are asked. To f (x ) (x )
solve these types of questions students are 2
t2 1 ( x )
advised to understand the direct substitution
method, factorisation method, rationalisation
tdt =
2
+C =
2
log

+C
f (x )
method.
68. (b) Idea Here, for a triangle ABC
65. (b) 1. Universal relation is the largest relation and a b c
identity relation in a finite set A is a subset of = =
sin A sin B sin C
universal relation. Therefore, identity relation on a
finite set A is not the greatest relation. Given that in ABC, median AD makes an angle
with side AB.
2. Consider the set A = {1, 2}
In ABD,
R {(1, 1), (1, 2), ( 2, 1), ( 2, 2)}
BD AD
R is a symmetric relation =
sin sin B
R is not anti symmetric sin B
AD = BD (i)
3. By definition, union and intersection of 2 sin
symmetric relations are also symmetric relation.
A
So, only 2 and 3 are correct.
66. (a) Idea The equation of planes bisecting the angles c b
A

between planes
a1x + b1y + c1z + d1 = 0 B
D
C
and a2 x + b2 y + c2 z + d2 = 0 are a/2 a/2
a1x + b1y + c1z + d1 a x + b2 y + c2 z + d2
= 2 In ACD,
a1 + b1 + c1
2 2 2
a22 + b22 + c22 CD AD
=
sin ( A ) sin C
The given planes are
sin C
2x y + 2z + 3 = 0 AD = CD (ii)
sin ( A )
and 3x 2y + 6z + 8 = 0
a1 a 2 + b1b2 + c1c 2 = 6 + 2 + 12 = 24 > 0 From Eqs. (i) and (ii), we get
sin B sin C
So that, the acute angle bisectors is BD = CD
2x y + 2z + 3 3x 2y + 6z + 8 sin sin ( A )
=
3 7 sin B sin
=
Solving we get, sin C sin ( A )
23x 13y + 32z + 45 = 0 b sin
=
c sin ( A )
TEST Edge Generally in JEE Main, equation of c
parallel planes, distance of a point from a plane sin ( A ) = sin
b
related questions are asked. To solve these types
of questions, students are advised to understand TEST Edge Generally in JEE Main, properties of
the basic concept of the different forms of triangle based questions are asked. To solve these
equation of plane. types of questions, students are advised to
67. (b) We have given that understand the basic concept of properties of
triangle.
f ( x ) ( x ) f ( x ) ( x ) (x )
f (x ) (x )
log
f (x )
dx
69. (a) Idea Probability of occurence of A given that B
has already happened is P( A / B)
(x )
Let, log =t n( A B)
f (x ) P( A / B) =
n( B)
f ( x ) d ( x )
= dt Let A be the event that sum of the all three dies is
( x ) dx f ( x )
15.
f ( x ) f ( x ) ( x ) ( x ) f ( x )
dx = dt B be the event that the first throw was four.
( x ) [f ( x )]2 3!
A = {6, 6, 3} = =3
2!
= {6, 5, 4} = 3! = 6 Let, the consecutive termsTr andTr + 1 having equal

{5, 5, 5} = 1! = 1 coefficient.
n ( A ) = 10 Coefficient of Tr th term = coefficient of Tr th+ 1 term
n 1
n (B ) = 36 but n ( A B ) = 2 2 2
r
74
Cr 1 374 = 74
Cr 374
Required probability 3 3
n( A B ) 2 1 74
Cr 1 3 = 74Cr 2
P (B / A ) = = =
n (A) 10 5 3 74! 2 74!
=
TEST Edge Multiplication theorem on probability, (r 1)! (75 r )! r ! (74 r )!
conditional probability related questions are 3 2
asked. To solve these types of questions, students =
75 r r
are advised to understand the basic concept of
probability. 150 2r = 3r r = 30
70. (d) Centre and radius of first and second circles are T30 and T31 are two consecutive terms whose
coefficients are same.
C1 (1, 0), r1 = 4
and C2 (1, 0), r2 = 8 73. (a) Idea Here, if A is non-singular square matrix
then,
Q The region ( [P + 1], [P ] ) lines inside the circle
x 2 + y 2 2x 15 = 0, then adj (adj A) =|A|n 2 A
[P + 1]2 + [P ]2 2 [P + 1] 15 < 0 1 4 4
It is given that adj (P ) = 2 1 7

1 1 3
(1, 0)
4
| adj (P )| = 1 ( 3 7) 4 ( 6 7) + 4 ( 2 1)
O
=4+ 4+ 4
8
=4
Q | adj (P )| = | P |2 {Q | adj A| = | A|(n 1) }
([P ] + 1)2 + [P ]2 2 ([P ] + 1) 15 < 0 |P | 2 = 4
2 [P ]2 16 < 0 [P ]2 < 8 ...(i) |P | = 2
Q Circles are concentric. TEST Edge Properties of matrix related questions

are asked in JEE Main. To solve these types of
Point ([P + 1], [P ]) outside the circle
questions, students are advised to understand the
x 2 + y 2 2x 7 = 0 basic concept of matrix.
[P + 1] + [P ]2 2 [P + 1] 7 > 0
2
74. (d) Truth table for the mathematical conditions is given
([P ] + 1)2 + [P ]2 2 ([P ] + 1) 7 > 0 as
2[P ]2 8 > 0 p q ~p ~q p~q q~p p q
[P ] > 4 2
...(ii) T F F T T T F
From Eqs. (i) and (ii), we get As per the above truth table, it is clear that P ~ q
4 < [P ]2 < 8, which is impossible. is true (T ) and q ~ P is true (T ).
For no value of P the point will be within the region. 75. (c) Q and are roots of the equation
71. (a) If A, B and C are collinear, then AB = BC ax 2 + bx + c = 0 (i)
Comparing, we get a ( x + 1) b ( x + 1) x + cx 2 = 0
2
c = 0, 1 a = 2 and b = x + 1
2
x + 1
a b +c=0
a 2b = 1 x x
n
Idea Here, ( a + x )n = a n 1 +
2
72. (a)
x x + 1 x + 1
a + b +c=0 (ii)
a x x
n r 1
coefficient of Tr th in 1 +
x x
= n Cr 1 From Eqs. (i) and (ii), we get
a a
x + 1
r = x = x 1
and Tr + 1 = nCr x
x
a
PRACTICE SET 5 159
x ( + 1) = 1 x =
1 OA = 2 cos
1+ x = OA + AM
1 1 = 2 cos + 2 cos (120 )
Required roots are = and
1+ 1+
76. (b) Here, suppose that h( x ) = f ( x ) g ( x ) (x, y)

2
B C
h( x ) = f ( x ) g ( x ) > 0 x R
h( x ) is an increasing function and
2 2
h ( 0) = f ( 0) g ( 0) = 0
120
h( x ) > 0 x ( 0, )
O A M
and h( x ) < 0 x ( , 0)
77. (b) Idea Number of permutation of n different x = 2 cos + 2 cos (120 )
things taken all at a time is n! = 2 cos + 2 [ cos 120 cos + sin 120 sin ]
We have given that, x + y + z = 6 is true for 1 3
= 2 cos + 2 cos + sin
x = 1, y = 2, z = 3 2 2
These values of x , y and z can be exchanged by = 2 cos cos + 3 sin
x , y and z, hence total number of ways
x = cos + 3 sin ...(i)
= 3! = 3 2 = 6
y = 2 sin (120 )
TEST Edge Generally in JEE Main permutation = 2 (sin 120 cos cos 120 sin )
under certain condition such as repetition of
3 1
items are allowed or not related questions are =2 cos + sin
asked. To solve these types of questions students 2 2
are advised to understand the basic concept of
y = 3 cos + sin
permutation under certain condition.
x + y 2 = 4 + 4 3 cos sin
2
78. (a) We have given that
xy = 3 + 4 sin cos
ex
x +2
{1 + ( x + 2) log ( x + 2)} dx x + y2 = 4 +
2
3 ( xy 3 )
x2 + y2 = 4 + 3 xy 3
1
= x
e + log ( x + 2) dx x + y = 3 xy + 1
2 2
x + 2
TEST Edge Generally in JEE Main, coordinate
Here, f ( x ) = log ( x + 2) geometry in two dimensional and properties of
1 triangle based questions are asked. To solve these
f ( x ) =
x +2 type of questions, students are advised to
understand the basic concept of coordinate
e [f ( x ) + f ( x )] dx = e x f ( x ) + C
x
Q geometry.
Required solution is e x log ( x + 2) + C 81. (d) If the observations greater than the median is
increased by 10, then there will be no change in
79. (b) Here, given that n ( A B ) = 99 median.
Now, 82. (c) The given equation is
( A B ) (B A ) = n ( A B ) (B A ) 1

1
ym + y m = 2x
= n ( A B ) n (B A )
= n (A B) n (A B) Differentiating on both sides, we get
1 m 1 1
1 1
= 99 99
y y m y1 = 2
= 992 m

So, correct option is (b). 1
1
2my = y m y m y1
80. (c) Idea sin ( A + B) = sin Acos B + cos Asin B, and
cos( A B) = cos Acos B + sin A sin B 2
From the figure, 1
1
4m 2 y 2 = y m y m y12
OA = AB cos
1 1 2

x y
= =
z
=k ...(ii)
= y m + y m 4 y12 3 4 6

The coordinates of any point P on (ii) are
4 ( x 1) y12
2
= 4m y2 2 ( 3k , 4k , 6k ). If this point lies on the plane 1 then
( x 2 1) y12 = m 2y 2 3 ( 3k ) + 4 ( 4k ) 6 ( 6k ) + 1 = 0
1
Again differentiating, we get i . e., k =
61
2xy12 + 2y1 ( x 2 1) y 2 = 2m 2yy1
Put k = 1/ 61
xy1 + ( x 2 1) y 2 = m 2y
We get, coordinates of the foot of the perpendicular
( x 2 1)y 2 = m 2y xy1 3 4 6
P are , ,
83. (b) Idea Here, for a square matrix A 61 61 61
1
A 1 = .adj A [QA is non-singular matrix] TEST Edge Image of a point in plane, intersection
|A| of line and plane related questions are asked. To
If two matrices are equal then their solve such types of questions, students are
corresponding elements are also equal. advised to understand the basic concept of plane
and line.
Here, it is given that
a+c
tan 1 tan
1 85. (a) If a, b, c are in AP, then = b a + c = 2b
1 2
I = tan
tan 1 1 i.e., sum of a and c must be even.
1 tan 1 1 tan Both a and c are either even or both are odd. Here
= 2
tan 1 1 + tan tan 1 even number is 7 and odd number is 8
1 tan2 2 tan Favourable case to choose a and c = 7C2 + 8 C2
1
= Total possible cases to choose a, b and c = 15C3
1 + tan 2 tan 1 tan2
2
Hence, required probability
1 tan2 2 tan 7! 8!
+
1 + tan2 1 + tan2 cos 2 sin 2
7
C2 + 8C2 5! 2! 6! 2! 7
= = = = =
2 tan 1 tan sin 2 cos 2
2 15 15!
C3 65
2 12! 3!
1 + tan 1 + tan
2
a b 86. (d) We have given that a + b + c + d + e = 15

Since, I =
b a b b c c c
a+
+ + + + +
d
cos 2 sin 2 a b 2 2 3 3 3 4
sin 2 cos 2 = b a d d d e e e e e
+ + + + + + + +
AM = 4 4 4 5 5 5 5 5
a = cos 2, b = sin 2 15
TEST Edge Generally in JEE Main, adj of a matrix, AM = 1
inverse of square matrix related questions are 1
asked to solve these types of questions. Students b 2 c 3 d 4 e 5 15

GM = a 2 3 4 5
are advised to understand the basic concept of 2 3 4 5
non-singular matrix.
(120)3 50
84. (d) Idea Write the equation of line passing through GM = =1
2 33 44 55
2
P( x1 , y1 , z1 ) and normal to the given plane as
x x1 y y1 z z1 GM = 1
= =
a b c AM = GM
It is given that the equation of plane b c d e
Hence, a= = = =
3x + 4y 6z + 1 = 0 ...(i) 2 3 4 5
The direction ratios of the normal to the plane (i) are a = 1, b = 2, c = 3, d = 4, e = 5
3, 4, 6 a + b2 + c 2 + d 2 + e 2
2
Now, equation of line through ( 0, 0, 0) and = 12 + 22 + 32 + 42 + 52

perpendicular to the plane (i) are 5 6 11
= = 55
6
PRACTICE SET 5 161
87. (b) Idea Equation of circle with ( a , b) as radius r a$ a$ + b$ b$ + 2 a$ b$ = 1

( x a )2 + ( y b )2 = r 2 1 + 1 + 2 a$ b$ = 1
Now, use differentiation convert the 2 a$ b$ = 1
equation as polynomial in derivative and
apply the concept of orthogonal trajectories. a$ b$ = 1 / 2
The circles are ( x h )2 + y 2 = 1 (i) cos = 1/ 2
Differentiating w.r.t. x, we get cos = cos 120
dy dy ( x h ) = 120
(x h ) + y =0 = (ii)
dx dx y So, is a obtuse angle.
To eliminating ( x h ), put ( x h )2 = 1 y 2 from
TEST Edge Angle between two vectors, vectors are
From Eqs. (i) and (ii), we get perpendicular or parallel related questions are
2
1 y 2 1 y2 asked. To solve these types of questions students
dy dy
= = are advised to understand to basic concept of
dx y2 dx y vectors.
dy
For orthogonal trajectories replacing by 89. (d) Consider the given expression,
dx n n
1 cos A + cos B sin A + sin B
+
(dy /dx ) sin A sin B cos A cos B
dy y 1y2 A +B A B n
= dy + dx = 0 2 cos cos
= 2 2
dx 1y2 y
2 cos A + B sin A B
2 2
1 y2
y
dy + dx = 0 A +B A B
n
2 sin . cos
+ 2 2
1 y2
x +c= dy , let y = sin 2 sin B A sin A + B
y 2 2
cos 2 A B BA
x +c= d = (sin cosec ) d = cotn + cotn
sin 2 2
= cos + log ( cosec + cot ) 0, if n is odd

= n A B
x = 0, y = 1, = / 2 c = 0 2 cot , if n is even
2
1 + cos
x = cos + log Statement I is false. Statement II is true by using
sin
given identity.
1 + 1 y 2 So, correct option is (d).
= 1 y 2 + log
y
90. (c) Statement I is true and Statement II is false.
x + x 2 + x 3 y1 + y 2 + y 3
TEST Edge Different types of differential Centroid 1 ,
3 3
equations based questions are asked. To solve
these types of questions students are advised to is rational point. Orthocentre is intersection point of
understand the basic concept of differential two altitudes which will have rational coefficient
equation. when expressed as a straight line. So, orthocentre
88. (c) Idea Here a b =|a|b|cos for a unit vector is also rational. Similarly, circumcentre will also
possesses rational point.
such as a |a|= 1
But Statement II is false as for equilateral triangle all
Given that a$ and b$ be unit vectors, then four points coincide at one.
(a$ + b$ ) (a$ + b$ ) = 1

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PRACTICE SET 5 131

Read the Following Instructions Carefully

Name of the Candidate (in Capital Letters)

Roll Number (in Figures) in Words

d/2 d/2 d/2 d/2

(a) u = 20 cm, X = 5 cm (b) u = 10 cm, X = 10 cm

(a) mg/2 (b) mg (c) mg/4 (d) mg/8

dT/dx dT/dx dT/dx dT/dx

fo = 300 air = 108 km / h sound = 330 m/s

26. 20% 90%

(a) OR (b) AND (c) NAND (d) NOR

40. CaCO 3 3 Ca 3 (PO 4 ) 2

43. [PdCl 2 (PMe 3 ) 2 ]

(c) Mn2O3, MnO, MnCl2 (d) Pb3O4, PbO2, PbCl2

48. Na 2CO 3 NaHCO 3 2H 2O

(a) 120 mL (b) 80 mL (c) 100 mL (d) 40 mL

49. P [Fe (CN) 6 ]4 [Fe (CN) 6 ]3 Fe 4 [Fe (CN) 6 ]3 X, Y Z

(a) H2O2 / OH , H2O2 neutral medium, Co2+ solution

CH3 CH3 CH3

NH2 H2N NH2

(a) 1.57 1014 Lmol1s 1 (b) 3.14 1015 L mol1 s 1

62. z1 z2 | z1| = | z 2| ( z1) + ( z 2) = z1

(a) z 2 (b) z 2 (c) z 2 (d) z 2

(a) Only 1 (b) Only 2, 3 (c) Only 1, 3 (d) All of these

68. AD ABC AB sin ( A )

70. ([P + 1 ], [P ]), []

71. A = a$j + b$j + c k$ , B = $i + c$j C = $i $j

(a) a 2b = 1 (b) a 2b = 2 (c) a 2b = 3 (d) a 2b = 0

(a) 2 (b) 1 (c) 3 (d) 4

76. f ( x) > g ( x) x f(0) = g (0) f( x ) < x

(a) 170 (b) 40 (c) 150 (d) None of these

(a) a = 1, b = 1 (b) a = cos 2, b = sin 2

(a) 7/65 (b) 6/65 (c) 7/55 (d) 5/56

(d) Statement I is false, Statement II is true

5. (d) Idea At the lowest point mg sin = 0. 8. (a)

TEST Edge The questions on combination of lenses Loss of PE = Ui Uf

15. (c) Let the tension in the string be T and the q q

Then, mg T = ma (i) (2, 0)

Preparation of styrene Inductive effect CH3 group has +I effect as the

TEST Edge The problem related to preparation of CH3

Assymmetric carbon The carbon attached to the COOEt

TEST Edge Algebraic limit, exponential limit and f ( x ) ( x ) ( x ) f ( x )

= {6, 5, 4} = 3! = 6 Let, the consecutive termsTr andTr + 1 having equal

([P ] + 1)2 + [P ]2 2 ([P ] + 1) 15 < 0 |P | 2 = 4

2 [P ]2 16 < 0 [P ]2 < 8 ...(i) |P | = 2

Q Circles are concentric. TEST Edge Properties of matrix related questions

76. (b) Here, suppose that h( x ) = f ( x ) g ( x ) (x, y)

a b 86. (d) We have given that a + b + c + d + e = 15

asked to solve these types of questions. Students b 2 c 3 d 4 e 5 15

Now, equation of line through ( 0, 0, 0) and = 12 + 22 + 32 + 42 + 52

87. (b) Idea Equation of circle with ( a , b) as radius r a$ a$ + b$ b$ + 2 a$ b$ = 1

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