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Tin(II)chloride
Section1ChemicalProductandCompanyIdentification
MSDSName: Tin(II)chloride
CatalogNumbers: 196980000,196980250,196981000
Synonyms: Stannouschloride
CompanyIdentification: AcrosOrganicsBVBA
JanssenPharmaceuticalaan3a
2440Geel,Belgium
CompanyIdentification:(USA) AcrosOrganics
OneReagentLane
FairLawn,NJ07410
ForinformationintheUS,call: 800ACROS01
ForinformationinEurope,call: +3214575211
EmergencyNumber,Europe: +3214575299
EmergencyNumberUS: 2017967100
CHEMTRECPhoneNumber,US: 8004249300
CHEMTRECPhoneNumber,Europe: 7035273887
Section2Composition,InformationonIngredients
RiskPhrases: 223443
Section3HazardsIdentification
EMERGENCYOVERVIEW
Harmfulifswallowed.Causesburns.Maycausesensitizationbyskincontact.
PotentialHealthEffects
Eye: Causeseyeburns.
Skin: Causesskinburns.Maycausesensitizationbyskincontact.
Ingestion: Harmfulifswallowed.Causesgastrointestinaltractburns.
Inhalation: Causeschemicalburnstotherespiratorytract.
Chronic: Maycauseliverandkidneydamage.
Section4FirstAidMeasures
Eyes: Immediatelyflusheyeswithplentyofwaterforatleast15minutes,occasionallylifting
theupperandlowereyelids.Getmedicalaidimmediately.
Skin: Getmedicalaidimmediately.Immediatelyflushskinwithplentyofwaterforatleast15
minuteswhileremovingcontaminatedclothingandshoes.
Ingestion: Donotinducevomiting.Getmedicalaidimmediately.
Inhalation: Removefromexposureandmovetofreshairimmediately.Ifnotbreathing,give
artificialrespiration.Ifbreathingisdifficult,giveoxygen.Getmedicalaid.
Notesto
Treatsymptomaticallyandsupportively.
Physician:
Section5FireFightingMeasures
General Asinanyfire,wearaselfcontainedbreathingapparatusinpressuredemand,
Information: MSHA/NIOSH(approvedorequivalent),andfullprotectivegear.Substanceis
noncombustible.
Extinguishing
Useextinguishingmediamostappropriateforthesurroundingfire.
Media:
Section6AccidentalReleaseMeasures
GeneralInformation: UseproperpersonalprotectiveequipmentasindicatedinSection8.
Spills/Leaks: Vacuumorsweepupmaterialandplaceintoasuitabledisposalcontainer.
Section7HandlingandStorage
Handling: Avoidbreathingdust,vapor,mist,orgas.Avoidcontactwithskinandeyes.Useonlyina
chemicalfumehood.
Storage: Storeinacool,dryplace.Storeinatightlyclosedcontainer.Corrosivesarea.
Section8ExposureControls,PersonalProtection
EngineeringControls:
Facilitiesstoringorutilizingthismaterialshouldbeequippedwithaneyewashfacilityand
asafetyshower.Useadequateventilationtokeepairborneconcentrationslow.
Exposure
Limits
CAS#7772998:
UnitedKingdom,WELTWA:(tininorganiccompounds):2mg/m3TWA(except
SnH4,asSn)UnitedKingdom,WELSTEL:(tininorganiccompounds):4mg/m3
STEL(exceptSnH4,asSn)
UnitedStatesOSHA:2mg/m3TWA(asSn)(Tininorganiccompounds).
BelgiumTWA:(tininorganiccompounds):2mg/m3VLE(asSn)
Malaysia:(tininorganiccompounds):2mg/m3TWA(asSn,excepttinhydride)
Netherlands:(tininorganiccompounds):2mg/m3MAC(asSn)
Spain:(tininorganiccompounds):2mg/m3VLAED(asSn)
PersonalProtectiveEquipment
Eyes: Wearchemicalsplashgoggles.
Skin: Wearappropriateprotectiveglovestopreventskinexposure.
Clothing: Wearappropriateprotectiveclothingtopreventskinexposure.
Respirators: FollowtheOSHArespiratorregulationsfoundin29CFR1910.134orEuropeanStandardEN
149.UseaNIOSH/MSHAorEuropeanStandardEN149approvedrespiratorifexposure
limitsareexceededorifirritationorothersymptomsareexperienced.
Section9PhysicalandChemicalProperties
PhysicalState: Crystallinepowder
Color: whitefine
Odor: weakodor
pH: 2(10%inwater)
VaporPressure: Notavailable
Viscosity: Notavailable
BoilingPoint: 652degC@760mmHg(1,205.60F)
Freezing/MeltingPoint: 246degC(474.80F)
AutoignitionTemperature: Notavailable
FlashPoint: Notavailable
ExplosionLimits:Lower: Notavailable
ExplosionLimits:Upper: Notavailable
DecompositionTemperature: Notavailable
Solubilityinwater: inwater:2700g/l(20C)
SpecificGravity/Density: 3.950
MolecularFormula: Cl2Sn
MolecularWeight: 189.6
Section10StabilityandReactivity
ChemicalStability: Stableundernormaltemperaturesandpressures.Hygroscopic:absorbsmoisture
orwaterfromtheair.
ConditionstoAvoid: Incompatiblematerials,heatingtodecomposition,exposuretomoistairorwater.
Incompatibilities Metals,strongoxidizingagents,strongbases,brominetrifluoride,ethyleneoxide,
withOtherMaterials nitrates,potassium,hydrogenperoxide,sodium,azo,diazo,andhydrazines(e.g.
dimethylhydrazine,hydrazine,methylhydrazine),waterreactivesubstances(e.g.
aceticanyhdride,alkylaluminumchloride,calciumcarbide,ethyldichlorosilane),
metalnitrates.
Hazardous
Decomposition Hydrogenchloride,carbonmonoxide,carbondioxide,tin/tinoxides.
Products
Hazardous
Willnotoccur.
Polymerization
Section11ToxicologicalInformation
RTECS#: CAS#7772998:XP8700000
LD50/LC50: RTECS:
CAS#7772998:Oral,mouse:LD50=250mg/kg
Oral,rabbit:LD50=10gm/kg
Oral,rat:LD50=700mg/kg
.
Carcinogenicity: Tin(II)chlorideNotlistedasacarcinogenbyACGIH,IARC,NTP,orCAProp65.
Other: SeeactualentryinRTECSforcompleteinformation.Thetoxicologicalpropertieshave
notbeenfullyinvestigated.
Section12EcologicalInformation
Notavailable
Section13DisposalConsiderations
Disposeofinamannerconsistentwithfederal,state,andlocalregulations.
Section14TransportInformation
Section15RegulatoryInformation
European/InternationalRegulations
EuropeanLabelinginAccordancewithECDirectives
HazardSymbols:C
RiskPhrases:
R22Harmfulifswallowed.
R34Causesburns.
R43Maycausesensitizationbyskincontact.
SafetyPhrases:
S26Incaseofcontactwitheyes,rinseimmediatelywithplentyofwaterandseekmedical
advice.
S36/37/39Wearsuitableprotectiveclothing,glovesandeye/faceprotection.
S45Incaseofaccidentorifyoufeelunwell,seekmedicaladviceimmediately(showthe
labelwherepossible).
WGK(WaterDanger/Protection)
CAS#7772998:1
Canada
CAS#7772998islistedonCanada'sDSLList
USFederal
TSCA
CAS#7772998islistedontheTSCAInventory.
Section16OtherInformation
MSDSCreationDate: 7/16/1996
Revision#3Date 1/22/2008
RevisionsweremadeinSections: 1,2,3,9,10,14
Theinformationaboveisbelievedtobeaccurateandrepresentsthebestinformationcurrentlyavailableto
us.However,wemakenowarrantyofmerchantibilityoranyotherwarranty,expressorimplied,with
respecttosuchinformation,andweassumenoliabilityresultingfromitsuse.Usersshouldmaketheirown
investigationstodeterminethesuitabilityoftheinformationfortheirparticularpurposes.Innoeventshall
thecompanybeliableforanyclaims,losses,ordamagesofanythirdpartyorforlostprofitsorany
special,indirect,incidental,consequential,orexemplarydamageshowsoeverarising,evenifthecompany
hasbeenadvisedofthepossibilityofsuchdamages.