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Polytetrafluoroethylene
Product Comparison Guide
3
Dyneon Polytetrafluoroethylene (PTFE)
www.dyneon.com 2
Dyneon Polytetrafluoroethylene
Dyneon PTFE is
supplied in the form of:
3 www.dyneon.com
New Dyneon PTFE dispersions with
bimodal particle-size distribution
www.dyneon.com 4
Dyneon TFM PTFE
A second-generation PTFE with improved properties
An important further development
on classic polytetrafluoroethylene
is Dyneon TFM PTFE,
a second-generation PTFE, which
represents a unique extension
to the Dyneon Fluoroplastics product
portfolio.
long-time experience
meets many specifications
(e.g. FOA approval; UL94 listing)
application support through
specialists
5 www.dyneon.com
Dyneon TM
Dyneon TFM PTFE second-generation PTFE Dyneon PTFE Selection of free-flowing compounds made from Dyneon PTFE and Dyneon TFM PTFE8) 2nd generation PTFE Dyneon PTFE
Powder properties Unit Test method Test specimen TFM 1700 TFM 1705 TFM 1600 TFM 1635 TFR 1105 TFR 1502 TF 1750 TF 1620 TF 1641 TF 1645 TF 4103 TF 4105 TFM 4105 TF 4212 TFM 4212 TF 4215 TFM 4215 TF 4216 TF 4303 TF 4220 TFM 4220 TF 4262 TFM 2001 TFM 2033 TFM 2070 TF 2021 TF 2025 TF 2035 TF 2029 TF 2071 TF 2072 TF 2073
ASTM D 4894 , D 4895 ,
5) 6)
type III type III type III type IV type V 2)
type VI type II type IV type IV type IV type II type II type II type II type I type I type I type I type I type I type I type I type I type I
ASTM D 47457) gr. 1 gr. 1 gr. 2 gr. 2 gr. 2 gr. 2 gr. 2
Bulk density g/l DIN EN ISO 60 410 410 820 825 800 740 380 870 840 840 820 820 820 770 770 750 750 730 750 760 760 750 450 470 460 490 470 480 450 490 480 470
Average particle size m ISO 13320 25 25 450 230 870 860 25 220 450 450 500 500 500 500 500 500 500 500 500 500 500 580 500 500 500 500 500 500 500 500 600 600
Powder flow properties non-free- non-free- very good limited very good very good non-free- limited very good very good very good very good very good very good very good very good very good very good very good very good very good very good free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing
flowing flowing free-flowing free-flowing free-flowing free-flowing flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing
Moulding pressure MPa 15 15 30 20 15 20 30 30 50 70 70 40 40 70 70 70 50 35 35 40
Extrusion at RR 400
3)
MPa ASTM D 4895 26 31 19 30 40 35 50
pressure at RR3) 1600 MPa ASTM D 4895 53 40 30
min. RR internal Dyneon method 20 20 20 20 20 15 5 20 50 50
max. RR internal Dyneon method 1000 100 2000 500 300 300 100 1600 3000 4200
Filler type glass fibre glass fibre glass fibre electrocarbon electrocarbon electrocarbon electrocarbon electrocarbon graphite cond. pigm. cond. pigm. carbon fibre
Filler content wt.% internal Dyneon method 15 25 25 10 10 25 25 33 15 2 2 10
Mechanical properties, measured at 23 C on sintered moldings
Specific gravity g/cm3 DIN EN ISO 12086 2,165 2,16 2,165 2,165 2,16 2,16 2,16 2,15 2,15 2,15 2,21 2,24 2,24 2,14 2,14 2,11 2,11 2,07 2,16 2,15 2,16 2,08 2,15 2,16 2,16 2,15 2,15 2,16 2,15 2,16 2,16 2,17
Tensile strength MPa DIN EN ISO 527-3 test specimen 43 47 37 37 26 33 42 38 38 38 20 15 12 21 12 15 13 15 11 12 17 22 22 20 20 21 34 34 34 30 30 34 30 32 32 32
thickness, mm 0,1 0,1 0,2 0,2 2,0 2,0 0,1 0,2 0,2 0,2 1,0 1,0 1,0 2,0 2,0 2,0 2,0 1,0 2,0 1,0 1,0 1,0 2,0 1,0 2,0 1,0 1,6 1,6 1,6 1,6 1,6 1,6 1,6 1,6 1,6 1,6
Elongation at break % DIN EN ISO 527-3 test specimen 625 560 600 600 400 500 450 430 430 430 400 350 450 350 300 180 70 40 50 50 280 320 270 450 350 280 400 400 400 340 340 450 340 380 380 380
thickness, mm 0,1 0,1 0,2 0,2 2,0 2,0 0,1 0,2 0,2 0,2 1,0 1,0 1,0 2,0 2,0 2,0 2,0 1,0 2,0 1,0 1,0 1,0 2,0 1,0 2,0 1,0 1,6 1,6 1,6 1,6 1,6 1,6 1,6 1,6 1,6 1,6
Ball indentation hardness N/mm2 DIN ISO 2039 part 1 plaque, 4 mm 28 28 28 28 24 26 26 26 26 31 34 37 37 40 32 25 30 33
Shore hardness D DIN EN ISO 868 59 59 59 59 56 53 56 56 56 56 59 61 63 66 66 68 63 60 63 62
Deformation under load % similar to ASTM D 621 cylinder, 9 10 9 10 14 14 17 17 17 17 17 14 6,5 13 7 8,5 4,5 11 15 9 7
( 15 MPa, 100 h ) 10 mm x 10 mm
Tensile modulus MPa DIN EN ISO 527 650 650 650 650 650 600 600 600 600
Shrinkage % a) internal Dyneon method cylinder, 45 mm 5,6 5,4 3,4 4,1 4,3 2,9 2,7 2,5 1,5
b) ASTM D 4894 sheet, 80 mm 2,2 1,7 2,3 3,0 3,3 2,3 3,3 2,2 2,7 3,6 5
c) internal Dyneon method ram extruded rod, 23 mm 11,5 5,5 10,5 11 11 7 6 6 5,5 6,5 10 10,5
Thermal properties
Thermal conductivity W/m K DIN 52 612 0,22 0,22 0,22 0,22 0,22 0,22 0,22 0,22 0,22 0,22 0,22 0,35 0,35 0,60 0,80 0,60 0,60
Coefficient of linear expansion K 4) -1
DIN 53 752 30-100 C 12 10-5 12 10-5 12 10-5 12 10-5 12 10-5 12 10-5 12 10-5 12 10-5 12 10-5 12 10-5 12 10-5 10 10-5 9 10-5 9 10-5 11 10-5
(parallel to molding direction) 30-200 C 14 10-5 14 10-5 14 10-5 14 10-5 14 10-5 14 10-5 14 10-5 14 10-5 14 10-5 14 10-5 14 10-5 13 10-5 11 10-5 10 10-5 12 10-5
30-260 C 17 10-5 17 10-5 17 10-5 17 10-5 17 10-5 17 10-5 17 10-5 17 10-5 17 10-5 17 10-5 17 10-5 15 10-5 13 10-5 12 10-5 14 10-5 16 10-5 16 10-5
Electrical properties, measured at 23 C
Dielectric strength kV/mm DIN EN ISO 12086 film, 100 m 90 90 95
200 m 78 78 74 60 55
Volume resistivity cm IEC 60093 1018 1018 1018 1018 1018 1018 1018 1018 1018 1018 1016 1016 1016 103 1011 104 104 1018 1018 1018 1018 1018 1018 1018
Surface resistance IEC 60093 10 17
10 17
10 17
10 17
10 17
10 17
10 17
10 17
10 17
10 17
10 16
10 16
10 16
10 3
10 12
10 3
10 3
10 17
10 17
10 17
10 17
10 17
10 17
1017
1)
not for specification purposes General moulding materials, Ramextrusion General compression moulding General compression moulding, automatic and isostatic moulding, ram extrusion High perfor- High perfor- High perfor- Unsintered Liners Pipe liners Electrical Tubing Very high Extreme high
2)
except bulk density and average particle size resistant to deformation under load, mance tubing mance pipes mance tubing tapes with medium to insulating tapes Wire/cable reduction ratio reduction ratio
3)
RR = reduction ratio weldable High pressure Denser polymer High pressure Sealing cords large diameters Yarns insulation More cost- Even more
4)
measured with a dilatometer 2 C/min resistance structure with resistance thick wall production efficient cost-efficient
5)
compression moulding powder (suspension polymers) Large Tall, thick-walled Ram extrusion Isostatic Ramextruded Ramextruded Skived films Isostatic Isostatic and Automatic, Bearings Piston rings Bearings Antistatic, Piston rings under surge lower perme- under surge
cylinder for cylinders for Linings moulding continuous continuous > 20 m moulding automatic isostatic and Seals/gaskets Seals/gaskets Sliding electrically conductive Bearings stress ability stress Wire/cable Wire/cable
6)
paste extrusion grades (emulsion polymers)
skived-film skived-film Moulded parts Large sheets rods, pipes rods, pipes Skived films moulding general Mouldings Bearings surfaces Linings Denser polymer Denser polymer insulation insulation
7)
compounds (free-flowing)
production, production Skived films Large cylinders and profiles and profiles > 200 m Seals/gaskets compression Valve seats Packings Seals/gaskets Seals/gaskets structure with structure with Spaghetti Spaghetti
8)
a comprehensive service offering a wide range skived films Higher stability > 500 m Skived films with thinner with higher Small parts moulding Piston rings Mouldings lower perme- lower perme- tubing tubing
of customised products is available > 20 m in the gel state > 200 m wall thickness wall thickness ability ability
Skived-films High flexural Pipe liner for
> 20 m, high fatigue strength the chemical
flexural fatigue Higher stability industry
strength in the gel state
www.dyneon.com 6 7 8 9
Dyneon TM
Dyneon TFM PTFE second-generation PTFE Dyneon PTFE Selection of free-flowing compounds made from Dyneon PTFE and Dyneon TFM PTFE8) 2nd generation PTFE Dyneon PTFE
Powder properties Unit Test method Test specimen TFM 1700 TFM 1705 TFM 1600 TFM 1635 TFR 1105 TFR 1502 TF 1750 TF 1620 TF 1641 TF 1645 TF 4103 TF 4105 TFM 4105 TF 4212 TFM 4212 TF 4215 TFM 4215 TF 4216 TF 4303 TF 4220 TFM 4220 TF 4262 TFM 2001 TFM 2033 TFM 2070 TF 2021 TF 2025 TF 2035 TF 2029 TF 2071 TF 2072 TF 2073
ASTM D 4894 , D 4895 ,
5) 6)
type III type III type III type IV type V 2)
type VI type II type IV type IV type IV type II type II type II type II type I type I type I type I type I type I type I type I type I type I
ASTM D 47457) gr. 1 gr. 1 gr. 2 gr. 2 gr. 2 gr. 2 gr. 2
Bulk density g/l DIN EN ISO 60 410 410 820 825 800 740 380 870 840 840 820 820 820 770 770 750 750 730 750 760 760 750 450 470 460 490 470 480 450 490 480 470
Average particle size m ISO 13320 25 25 450 230 870 860 25 220 450 450 500 500 500 500 500 500 500 500 500 500 500 580 500 500 500 500 500 500 500 500 600 600
Powder flow properties non-free- non-free- very good limited very good very good non-free- limited very good very good very good very good very good very good very good very good very good very good very good very good very good very good free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing
flowing flowing free-flowing free-flowing free-flowing free-flowing flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing
Moulding pressure MPa 15 15 30 20 15 20 30 30 50 70 70 40 40 70 70 70 50 35 35 40
Extrusion at RR 400
3)
MPa ASTM D 4895 26 31 19 30 40 35 50
pressure at RR3) 1600 MPa ASTM D 4895 53 40 30
min. RR internal Dyneon method 20 20 20 20 20 15 5 20 50 50
max. RR internal Dyneon method 1000 100 2000 500 300 300 100 1600 3000 4200
Filler type glass fibre glass fibre glass fibre electrocarbon electrocarbon electrocarbon electrocarbon electrocarbon graphite cond. pigm. cond. pigm. carbon fibre
Filler content wt.% internal Dyneon method 15 25 25 10 10 25 25 33 15 2 2 10
Mechanical properties, measured at 23 C on sintered moldings
Specific gravity g/cm3 DIN EN ISO 12086 2,165 2,16 2,165 2,165 2,16 2,16 2,16 2,15 2,15 2,15 2,21 2,24 2,24 2,14 2,14 2,11 2,11 2,07 2,16 2,15 2,16 2,08 2,15 2,16 2,16 2,15 2,15 2,16 2,15 2,16 2,16 2,17
Tensile strength MPa DIN EN ISO 527-3 test specimen 43 47 37 37 26 33 42 38 38 38 20 15 12 21 12 15 13 15 11 12 17 22 22 20 20 21 34 34 34 30 30 34 30 32 32 32
thickness, mm 0,1 0,1 0,2 0,2 2,0 2,0 0,1 0,2 0,2 0,2 1,0 1,0 1,0 2,0 2,0 2,0 2,0 1,0 2,0 1,0 1,0 1,0 2,0 1,0 2,0 1,0 1,6 1,6 1,6 1,6 1,6 1,6 1,6 1,6 1,6 1,6
Elongation at break % DIN EN ISO 527-3 test specimen 625 560 600 600 400 500 450 430 430 430 400 350 450 350 300 180 70 40 50 50 280 320 270 450 350 280 400 400 400 340 340 450 340 380 380 380
thickness, mm 0,1 0,1 0,2 0,2 2,0 2,0 0,1 0,2 0,2 0,2 1,0 1,0 1,0 2,0 2,0 2,0 2,0 1,0 2,0 1,0 1,0 1,0 2,0 1,0 2,0 1,0 1,6 1,6 1,6 1,6 1,6 1,6 1,6 1,6 1,6 1,6
Ball indentation hardness N/mm2 DIN ISO 2039 part 1 plaque, 4 mm 28 28 28 28 24 26 26 26 26 31 34 37 37 40 32 25 30 33
Shore hardness D DIN EN ISO 868 59 59 59 59 56 53 56 56 56 56 59 61 63 66 66 68 63 60 63 62
Deformation under load % similar to ASTM D 621 cylinder, 9 10 9 10 14 14 17 17 17 17 17 14 6,5 13 7 8,5 4,5 11 15 9 7
( 15 MPa, 100 h ) 10 mm x 10 mm
Tensile modulus MPa DIN EN ISO 527 650 650 650 650 650 600 600 600 600
Shrinkage % a) internal Dyneon method cylinder, 45 mm 5,6 5,4 3,4 4,1 4,3 2,9 2,7 2,5 1,5
b) ASTM D 4894 sheet, 80 mm 2,2 1,7 2,3 3,0 3,3 2,3 3,3 2,2 2,7 3,6 5
c) internal Dyneon method ram extruded rod, 23 mm 11,5 5,5 10,5 11 11 7 6 6 5,5 6,5 10 10,5
Thermal properties
Thermal conductivity W/m K DIN 52 612 0,22 0,22 0,22 0,22 0,22 0,22 0,22 0,22 0,22 0,22 0,22 0,35 0,35 0,60 0,80 0,60 0,60
Coefficient of linear expansion K 4) -1
DIN 53 752 30-100 C 12 10-5 12 10-5 12 10-5 12 10-5 12 10-5 12 10-5 12 10-5 12 10-5 12 10-5 12 10-5 12 10-5 10 10-5 9 10-5 9 10-5 11 10-5
(parallel to molding direction) 30-200 C 14 10-5 14 10-5 14 10-5 14 10-5 14 10-5 14 10-5 14 10-5 14 10-5 14 10-5 14 10-5 14 10-5 13 10-5 11 10-5 10 10-5 12 10-5
30-260 C 17 10-5 17 10-5 17 10-5 17 10-5 17 10-5 17 10-5 17 10-5 17 10-5 17 10-5 17 10-5 17 10-5 15 10-5 13 10-5 12 10-5 14 10-5 16 10-5 16 10-5
Electrical properties, measured at 23 C
Dielectric strength kV/mm DIN EN ISO 12086 film, 100 m 90 90 95
200 m 78 78 74 60 55
Volume resistivity cm IEC 60093 1018 1018 1018 1018 1018 1018 1018 1018 1018 1018 1016 1016 1016 103 1011 104 104 1018 1018 1018 1018 1018 1018 1018
Surface resistance IEC 60093 10 17
10 17
10 17
10 17
10 17
10 17
10 17
10 17
10 17
10 17
10 16
10 16
10 16
10 3
10 12
10 3
10 3
10 17
10 17
10 17
10 17
10 17
10 17
1017
1)
not for specification purposes General moulding materials, Ramextrusion General compression moulding General compression moulding, automatic and isostatic moulding, ram extrusion High perfor- High perfor- High perfor- Unsintered Liners Pipe liners Electrical Tubing Very high Extreme high
2)
except bulk density and average particle size resistant to deformation under load, mance tubing mance pipes mance tubing tapes with medium to insulating tapes Wire/cable reduction ratio reduction ratio
3)
RR = reduction ratio weldable High pressure Denser polymer High pressure Sealing cords large diameters Yarns insulation More cost- Even more
4)
measured with a dilatometer 2 C/min resistance structure with resistance thick wall production efficient cost-efficient
5)
compression moulding powder (suspension polymers) Large Tall, thick-walled Ram extrusion Isostatic Ramextruded Ramextruded Skived films Isostatic Isostatic and Automatic, Bearings Piston rings Bearings Antistatic, Piston rings under surge lower perme- under surge
cylinder for cylinders for Linings moulding continuous continuous > 20 m moulding automatic isostatic and Seals/gaskets Seals/gaskets Sliding electrically conductive Bearings stress ability stress Wire/cable Wire/cable
6)
paste extrusion grades (emulsion polymers)
skived-film skived-film Moulded parts Large sheets rods, pipes rods, pipes Skived films moulding general Mouldings Bearings surfaces Linings Denser polymer Denser polymer insulation insulation
7)
compounds (free-flowing)
production, production Skived films Large cylinders and profiles and profiles > 200 m Seals/gaskets compression Valve seats Packings Seals/gaskets Seals/gaskets structure with structure with Spaghetti Spaghetti
8)
a comprehensive service offering a wide range skived films Higher stability > 500 m Skived films with thinner with higher Small parts moulding Piston rings Mouldings lower perme- lower perme- tubing tubing
of customised products is available > 20 m in the gel state > 200 m wall thickness wall thickness ability ability
Skived-films High flexural Pipe liner for
> 20 m, high fatigue strength the chemical
flexural fatigue Higher stability industry
strength in the gel state
www.dyneon.com 6 7 8 9
Dyneon TM
Dyneon TFM PTFE second-generation PTFE Dyneon PTFE Selection of free-flowing compounds made from Dyneon PTFE and Dyneon TFM PTFE8) 2nd generation PTFE Dyneon PTFE
Powder properties Unit Test method Test specimen TFM 1700 TFM 1705 TFM 1600 TFM 1635 TFR 1105 TFR 1502 TF 1750 TF 1620 TF 1641 TF 1645 TF 4103 TF 4105 TFM 4105 TF 4212 TFM 4212 TF 4215 TFM 4215 TF 4216 TF 4303 TF 4220 TFM 4220 TF 4262 TFM 2001 TFM 2033 TFM 2070 TF 2021 TF 2025 TF 2035 TF 2029 TF 2071 TF 2072 TF 2073
ASTM D 4894 , D 4895 ,
5) 6)
type III type III type III type IV type V 2)
type VI type II type IV type IV type IV type II type II type II type II type I type I type I type I type I type I type I type I type I type I
ASTM D 47457) gr. 1 gr. 1 gr. 2 gr. 2 gr. 2 gr. 2 gr. 2
Bulk density g/l DIN EN ISO 60 410 410 820 825 800 740 380 870 840 840 820 820 820 770 770 750 750 730 750 760 760 750 450 470 460 490 470 480 450 490 480 470
Average particle size m ISO 13320 25 25 450 230 870 860 25 220 450 450 500 500 500 500 500 500 500 500 500 500 500 580 500 500 500 500 500 500 500 500 600 600
Powder flow properties non-free- non-free- very good limited very good very good non-free- limited very good very good very good very good very good very good very good very good very good very good very good very good very good very good free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing
flowing flowing free-flowing free-flowing free-flowing free-flowing flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing
Moulding pressure MPa 15 15 30 20 15 20 30 30 50 70 70 40 40 70 70 70 50 35 35 40
Extrusion at RR 400
3)
MPa ASTM D 4895 26 31 19 30 40 35 50
pressure at RR3) 1600 MPa ASTM D 4895 53 40 30
min. RR internal Dyneon method 20 20 20 20 20 15 5 20 50 50
max. RR internal Dyneon method 1000 100 2000 500 300 300 100 1600 3000 4200
Filler type glass fibre glass fibre glass fibre electrocarbon electrocarbon electrocarbon electrocarbon electrocarbon graphite cond. pigm. cond. pigm. carbon fibre
Filler content wt.% internal Dyneon method 15 25 25 10 10 25 25 33 15 2 2 10
Mechanical properties, measured at 23 C on sintered moldings
Specific gravity g/cm3 DIN EN ISO 12086 2,165 2,16 2,165 2,165 2,16 2,16 2,16 2,15 2,15 2,15 2,21 2,24 2,24 2,14 2,14 2,11 2,11 2,07 2,16 2,15 2,16 2,08 2,15 2,16 2,16 2,15 2,15 2,16 2,15 2,16 2,16 2,17
Tensile strength MPa DIN EN ISO 527-3 test specimen 43 47 37 37 26 33 42 38 38 38 20 15 12 21 12 15 13 15 11 12 17 22 22 20 20 21 34 34 34 30 30 34 30 32 32 32
thickness, mm 0,1 0,1 0,2 0,2 2,0 2,0 0,1 0,2 0,2 0,2 1,0 1,0 1,0 2,0 2,0 2,0 2,0 1,0 2,0 1,0 1,0 1,0 2,0 1,0 2,0 1,0 1,6 1,6 1,6 1,6 1,6 1,6 1,6 1,6 1,6 1,6
Elongation at break % DIN EN ISO 527-3 test specimen 625 560 600 600 400 500 450 430 430 430 400 350 450 350 300 180 70 40 50 50 280 320 270 450 350 280 400 400 400 340 340 450 340 380 380 380
thickness, mm 0,1 0,1 0,2 0,2 2,0 2,0 0,1 0,2 0,2 0,2 1,0 1,0 1,0 2,0 2,0 2,0 2,0 1,0 2,0 1,0 1,0 1,0 2,0 1,0 2,0 1,0 1,6 1,6 1,6 1,6 1,6 1,6 1,6 1,6 1,6 1,6
Ball indentation hardness N/mm2 DIN ISO 2039 part 1 plaque, 4 mm 28 28 28 28 24 26 26 26 26 31 34 37 37 40 32 25 30 33
Shore hardness D DIN EN ISO 868 59 59 59 59 56 53 56 56 56 56 59 61 63 66 66 68 63 60 63 62
Deformation under load % similar to ASTM D 621 cylinder, 9 10 9 10 14 14 17 17 17 17 17 14 6,5 13 7 8,5 4,5 11 15 9 7
( 15 MPa, 100 h ) 10 mm x 10 mm
Tensile modulus MPa DIN EN ISO 527 650 650 650 650 650 600 600 600 600
Shrinkage % a) internal Dyneon method cylinder, 45 mm 5,6 5,4 3,4 4,1 4,3 2,9 2,7 2,5 1,5
b) ASTM D 4894 sheet, 80 mm 2,2 1,7 2,3 3,0 3,3 2,3 3,3 2,2 2,7 3,6 5
c) internal Dyneon method ram extruded rod, 23 mm 11,5 5,5 10,5 11 11 7 6 6 5,5 6,5 10 10,5
Thermal properties
Thermal conductivity W/m K DIN 52 612 0,22 0,22 0,22 0,22 0,22 0,22 0,22 0,22 0,22 0,22 0,22 0,35 0,35 0,60 0,80 0,60 0,60
Coefficient of linear expansion K 4) -1
DIN 53 752 30-100 C 12 10-5 12 10-5 12 10-5 12 10-5 12 10-5 12 10-5 12 10-5 12 10-5 12 10-5 12 10-5 12 10-5 10 10-5 9 10-5 9 10-5 11 10-5
(parallel to molding direction) 30-200 C 14 10-5 14 10-5 14 10-5 14 10-5 14 10-5 14 10-5 14 10-5 14 10-5 14 10-5 14 10-5 14 10-5 13 10-5 11 10-5 10 10-5 12 10-5
30-260 C 17 10-5 17 10-5 17 10-5 17 10-5 17 10-5 17 10-5 17 10-5 17 10-5 17 10-5 17 10-5 17 10-5 15 10-5 13 10-5 12 10-5 14 10-5 16 10-5 16 10-5
Electrical properties, measured at 23 C
Dielectric strength kV/mm DIN EN ISO 12086 film, 100 m 90 90 95
200 m 78 78 74 60 55
Volume resistivity cm IEC 60093 1018 1018 1018 1018 1018 1018 1018 1018 1018 1018 1016 1016 1016 103 1011 104 104 1018 1018 1018 1018 1018 1018 1018
Surface resistance IEC 60093 10 17
10 17
10 17
10 17
10 17
10 17
10 17
10 17
10 17
10 17
10 16
10 16
10 16
10 3
10 12
10 3
10 3
10 17
10 17
10 17
10 17
10 17
10 17
1017
1)
not for specification purposes General moulding materials, Ramextrusion General compression moulding General compression moulding, automatic and isostatic moulding, ram extrusion High perfor- High perfor- High perfor- Unsintered Liners Pipe liners Electrical Tubing Very high Extreme high
2)
except bulk density and average particle size resistant to deformation under load, mance tubing mance pipes mance tubing tapes with medium to insulating tapes Wire/cable reduction ratio reduction ratio
3)
RR = reduction ratio weldable High pressure Denser polymer High pressure Sealing cords large diameters Yarns insulation More cost- Even more
4)
measured with a dilatometer 2 C/min resistance structure with resistance thick wall production efficient cost-efficient
5)
compression moulding powder (suspension polymers) Large Tall, thick-walled Ram extrusion Isostatic Ramextruded Ramextruded Skived films Isostatic Isostatic and Automatic, Bearings Piston rings Bearings Antistatic, Piston rings under surge lower perme- under surge
cylinder for cylinders for Linings moulding continuous continuous > 20 m moulding automatic isostatic and Seals/gaskets Seals/gaskets Sliding electrically conductive Bearings stress ability stress Wire/cable Wire/cable
6)
paste extrusion grades (emulsion polymers)
skived-film skived-film Moulded parts Large sheets rods, pipes rods, pipes Skived films moulding general Mouldings Bearings surfaces Linings Denser polymer Denser polymer insulation insulation
7)
compounds (free-flowing)
production, production Skived films Large cylinders and profiles and profiles > 200 m Seals/gaskets compression Valve seats Packings Seals/gaskets Seals/gaskets structure with structure with Spaghetti Spaghetti
8)
a comprehensive service offering a wide range skived films Higher stability > 500 m Skived films with thinner with higher Small parts moulding Piston rings Mouldings lower perme- lower perme- tubing tubing
of customised products is available > 20 m in the gel state > 200 m wall thickness wall thickness ability ability
Skived-films High flexural Pipe liner for
> 20 m, high fatigue strength the chemical
flexural fatigue Higher stability industry
strength in the gel state
www.dyneon.com 6 7 8 9
Dyneon TM
Dyneon TFM PTFE second-generation PTFE Dyneon PTFE Selection of free-flowing compounds made from Dyneon PTFE and Dyneon TFM PTFE8) 2nd generation PTFE Dyneon PTFE
Powder properties Unit Test method Test specimen TFM 1700 TFM 1705 TFM 1600 TFM 1635 TFR 1105 TFR 1502 TF 1750 TF 1620 TF 1641 TF 1645 TF 4103 TF 4105 TFM 4105 TF 4212 TFM 4212 TF 4215 TFM 4215 TF 4216 TF 4303 TF 4220 TFM 4220 TF 4262 TFM 2001 TFM 2033 TFM 2070 TF 2021 TF 2025 TF 2035 TF 2029 TF 2071 TF 2072 TF 2073
ASTM D 4894 , D 4895 ,
5) 6)
type III type III type III type IV type V 2)
type VI type II type IV type IV type IV type II type II type II type II type I type I type I type I type I type I type I type I type I type I
ASTM D 47457) gr. 1 gr. 1 gr. 2 gr. 2 gr. 2 gr. 2 gr. 2
Bulk density g/l DIN EN ISO 60 410 410 820 825 800 740 380 870 840 840 820 820 820 770 770 750 750 730 750 760 760 750 450 470 460 490 470 480 450 490 480 470
Average particle size m ISO 13320 25 25 450 230 870 860 25 220 450 450 500 500 500 500 500 500 500 500 500 500 500 580 500 500 500 500 500 500 500 500 600 600
Powder flow properties non-free- non-free- very good limited very good very good non-free- limited very good very good very good very good very good very good very good very good very good very good very good very good very good very good free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing
flowing flowing free-flowing free-flowing free-flowing free-flowing flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing free-flowing
Moulding pressure MPa 15 15 30 20 15 20 30 30 50 70 70 40 40 70 70 70 50 35 35 40
Extrusion at RR 400
3)
MPa ASTM D 4895 26 31 19 30 40 35 50
pressure at RR3) 1600 MPa ASTM D 4895 53 40 30
min. RR internal Dyneon method 20 20 20 20 20 15 5 20 50 50
max. RR internal Dyneon method 1000 100 2000 500 300 300 100 1600 3000 4200
Filler type glass fibre glass fibre glass fibre electrocarbon electrocarbon electrocarbon electrocarbon electrocarbon graphite cond. pigm. cond. pigm. carbon fibre
Filler content wt.% internal Dyneon method 15 25 25 10 10 25 25 33 15 2 2 10
Mechanical properties, measured at 23 C on sintered moldings
Specific gravity g/cm3 DIN EN ISO 12086 2,165 2,16 2,165 2,165 2,16 2,16 2,16 2,15 2,15 2,15 2,21 2,24 2,24 2,14 2,14 2,11 2,11 2,07 2,16 2,15 2,16 2,08 2,15 2,16 2,16 2,15 2,15 2,16 2,15 2,16 2,16 2,17
Tensile strength MPa DIN EN ISO 527-3 test specimen 43 47 37 37 26 33 42 38 38 38 20 15 12 21 12 15 13 15 11 12 17 22 22 20 20 21 34 34 34 30 30 34 30 32 32 32
thickness, mm 0,1 0,1 0,2 0,2 2,0 2,0 0,1 0,2 0,2 0,2 1,0 1,0 1,0 2,0 2,0 2,0 2,0 1,0 2,0 1,0 1,0 1,0 2,0 1,0 2,0 1,0 1,6 1,6 1,6 1,6 1,6 1,6 1,6 1,6 1,6 1,6
Elongation at break % DIN EN ISO 527-3 test specimen 625 560 600 600 400 500 450 430 430 430 400 350 450 350 300 180 70 40 50 50 280 320 270 450 350 280 400 400 400 340 340 450 340 380 380 380
thickness, mm 0,1 0,1 0,2 0,2 2,0 2,0 0,1 0,2 0,2 0,2 1,0 1,0 1,0 2,0 2,0 2,0 2,0 1,0 2,0 1,0 1,0 1,0 2,0 1,0 2,0 1,0 1,6 1,6 1,6 1,6 1,6 1,6 1,6 1,6 1,6 1,6
Ball indentation hardness N/mm2 DIN ISO 2039 part 1 plaque, 4 mm 28 28 28 28 24 26 26 26 26 31 34 37 37 40 32 25 30 33
Shore hardness D DIN EN ISO 868 59 59 59 59 56 53 56 56 56 56 59 61 63 66 66 68 63 60 63 62
Deformation under load % similar to ASTM D 621 cylinder, 9 10 9 10 14 14 17 17 17 17 17 14 6,5 13 7 8,5 4,5 11 15 9 7
( 15 MPa, 100 h ) 10 mm x 10 mm
Tensile modulus MPa DIN EN ISO 527 650 650 650 650 650 600 600 600 600
Shrinkage % a) internal Dyneon method cylinder, 45 mm 5,6 5,4 3,4 4,1 4,3 2,9 2,7 2,5 1,5
b) ASTM D 4894 sheet, 80 mm 2,2 1,7 2,3 3,0 3,3 2,3 3,3 2,2 2,7 3,6 5
c) internal Dyneon method ram extruded rod, 23 mm 11,5 5,5 10,5 11 11 7 6 6 5,5 6,5 10 10,5
Thermal properties
Thermal conductivity W/m K DIN 52 612 0,22 0,22 0,22 0,22 0,22 0,22 0,22 0,22 0,22 0,22 0,22 0,35 0,35 0,60 0,80 0,60 0,60
Coefficient of linear expansion K 4) -1
DIN 53 752 30-100 C 12 10-5 12 10-5 12 10-5 12 10-5 12 10-5 12 10-5 12 10-5 12 10-5 12 10-5 12 10-5 12 10-5 10 10-5 9 10-5 9 10-5 11 10-5
(parallel to molding direction) 30-200 C 14 10-5 14 10-5 14 10-5 14 10-5 14 10-5 14 10-5 14 10-5 14 10-5 14 10-5 14 10-5 14 10-5 13 10-5 11 10-5 10 10-5 12 10-5
30-260 C 17 10-5 17 10-5 17 10-5 17 10-5 17 10-5 17 10-5 17 10-5 17 10-5 17 10-5 17 10-5 17 10-5 15 10-5 13 10-5 12 10-5 14 10-5 16 10-5 16 10-5
Electrical properties, measured at 23 C
Dielectric strength kV/mm DIN EN ISO 12086 film, 100 m 90 90 95
200 m 78 78 74 60 55
Volume resistivity cm IEC 60093 1018 1018 1018 1018 1018 1018 1018 1018 1018 1018 1016 1016 1016 103 1011 104 104 1018 1018 1018 1018 1018 1018 1018
Surface resistance IEC 60093 10 17
10 17
10 17
10 17
10 17
10 17
10 17
10 17
10 17
10 17
10 16
10 16
10 16
10 3
10 12
10 3
10 3
10 17
10 17
10 17
10 17
10 17
10 17
1017
1)
not for specification purposes General moulding materials, Ram extrusion General compression moulding General compression moulding, automatic and isostatic moulding, ram extrusion High perfor- High perfor- High perfor- Unsintered Liners Pipe liners Electrical Tubing Very high Extreme high
2)
except bulk density and average particle size resistant to deformation under load, mance tubing mance pipes mance tubing tapes with medium to insulating tapes Wire/cable reduction ratio reduction ratio
3)
RR = reduction ratio weldable High pressure Denser polymer High pressure Sealing cords large diameters Yarns insulation More cost- Even more
4)
measured with a dilatometer 2 C/min resistance structure with resistance thick wall production efficient cost-efficient
5)
compression moulding powder (suspension polymers) Large Tall, thick-walled Ram extrusion Isostatic Ram extruded Ram extruded Skived films Isostatic Isostatic and Automatic, Bearings Piston rings Bearings Antistatic, Piston rings under surge lower perme- under surge
cylinder for cylinders for Linings moulding continuous continuous > 20 m moulding automatic isostatic and Seals/gaskets Seals/gaskets Sliding electrically conductive Bearings stress ability stress Wire/cable Wire/cable
6)
paste extrusion grades (emulsion polymers)
skived-film skived-film Moulded parts Large sheets rods, pipes rods, pipes Skived films moulding general Mouldings Bearings surfaces Linings Denser polymer Denser polymer insulation insulation
7)
compounds (free-flowing)
production, production Skived films Large cylinders and profiles and profiles > 200 m Seals/gaskets compression Valve seats Packings Seals/gaskets Seals/gaskets structure with structure with Spaghetti Spaghetti
8)
a comprehensive service offering a wide range skived films Higher stability > 500 m Skived films with thinner with higher Small parts moulding Piston rings Mouldings lower perme- lower perme- tubing tubing
of customised products is available > 20 m in the gel state > 200 m wall thickness wall thickness ability ability
Skived-films High flexural Pipe liner for
> 20 m, high fatigue strength the chemical
flexural fatigue Higher stability industry
strength in the gel state
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Dyneon PTFE Dyneon PTFE Micropowders
Dispersions
Properties Unit Test method TF 5032 R TF 5035 R TF 5050 R TF 5060 RG TF 5030 RG area BET DIN ISO 9277 10 2 17
(bimodal)
Melting Peak Temperature C DIN EN ISO 12086 330 325 330
Solid content % DIN EN ISO 12086 60 58 58 59 59 Melt flow rate MFR 1) g/10 min DIN EN ISO 1133 <2 12 6
Emulsifier non-ionic non-ionic non-ionic non-ionic non-ionic
Thickening effect very good good excellent
APE-free3) APE-free3)
Emulsifier content Food contact use FDA 2)
yes no yes
(based on solid internal EU3) yes yes yes
content) % Dyneon method 5 5 5 7,5 7,5 Applications - not recommended + recommended ++ good experience
pH Dyneon method >9 >9 >9 >9 >9 Lubricants
Viscosity mPas DIN EN ISO 3219 silicone oils + +
D = 30s-1 20 15 13 20 20 engine oils + +
greases + _ +
Specific gravity g/cm3 internal 1,5 1,5 1,5 1,5 1,5
Dyneon method Printing inks ++ +
Average particle Non-stick and antifriction coatings ++ ++
size PTFE nm DIN ISO 13321 160 220 210 220 220 Non-stick and antifriction sprays + - +
Food contact use FDA1) yes yes yes yes yes Dry lubricants + + ++
EU2) yes yes yes yes yes
Applications
1)
The measurements are carried out at 372 C with different test weights DyneonTM PTFE Test weight Nozzle
and nozzle diameters. The melt viscosity of micropowders can be
Micropowders (kg) diameter (mm)
Impregnation Metal coating Formulation Coating Formulation calculated from the melt flow rate (MFR) by Hagen-Poiseuilles law to
Impregnation of coating of fabrics of coating obtain an indication of molecular weight. The molecular weight of the
TF 9201 10,0 2,095
systems Impregnation systems micropowder products increases in the following order:
TF 9205, TF 9207, TF 9201. TF 9205 2,16 1,0
1)
These products comply with 21 CFR 177.1550 and may be used 2)
These products comply with 21 CFR 177.1550 and may be used TF 9207 2,16 2,095
as articles or components of articles intended to contact food subject as articles or components of articles intended to contact food subject
to the provisions, including specifications, conditions of use, to the provisions, including specifications, conditions of use,
and limitations, if any, in this regulation. and limitations, if any, in this regulation.
2)
The monomers used for the production of these products comply 3)
The monomers used for the production of these products comply
with EU-Directive 2002/72/EC about materials and articles made of with EU-Directive 2002/72/EC about materials and articles made of
plastics and intended to come into contact with foodstuffs or toys and plastics and intended to come into contact with foodstuffs or toys and
with the new edition of the German Bedarfsgegenstndeverordnung with the new edition of the German Bedarfsgegenstndeverordnung
of December 23rd, 1997. of December 23rd, 1997.
3)
Amonium Perfluorinated Ether
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Dyneon PTFE Dyneon PTFE Micropowders
Dispersions
Properties Unit Test method TF 5032 R TF 5035 R TF 5050 R TF 5060 RG TF 5030 RG area BET DIN ISO 9277 10 2 17
(bimodal)
Melting Peak Temperature C DIN EN ISO 12086 330 325 330
Solid content % DIN EN ISO 12086 60 58 58 59 59 Melt flow rate MFR 1) g/10 min DIN EN ISO 1133 <2 12 6
Emulsifier non-ionic non-ionic non-ionic non-ionic non-ionic
Thickening effect very good good excellent
APE-free3) APE-free3)
Emulsifier content Food contact use FDA 2)
yes no yes
(based on solid internal EU3) yes yes yes
content) % Dyneon method 5 5 5 7,5 7,5 Applications - not recommended + recommended ++ good experience
pH Dyneon method >9 >9 >9 >9 >9 Lubricants
Viscosity mPas DIN EN ISO 3219 silicone oils + +
D = 30s-1 20 15 13 20 20 engine oils + +
greases + _ +
Specific gravity g/cm3 internal 1,5 1,5 1,5 1,5 1,5
Dyneon method Printing inks ++ +
Average particle Non-stick and antifriction coatings ++ ++
size PTFE nm DIN ISO 13321 160 220 210 220 220 Non-stick and antifriction sprays + - +
Food contact use FDA1) yes yes yes yes yes Dry lubricants + + ++
EU2) yes yes yes yes yes
Applications
1)
The measurements are carried out at 372 C with different test weights DyneonTM PTFE Test weight Nozzle
and nozzle diameters. The melt viscosity of micropowders can be
Micropowders (kg) diameter (mm)
Impregnation Metal coating Formulation Coating Formulation calculated from the melt flow rate (MFR) by Hagen-Poiseuilles law to
Impregnation of coating of fabrics of coating obtain an indication of molecular weight. The molecular weight of the
TF 9201 10,0 2,095
systems Impregnation systems micropowder products increases in the following order:
TF 9205, TF 9207, TF 9201. TF 9205 2,16 1,0
1)
These products comply with 21 CFR 177.1550 and may be used 2)
These products comply with 21 CFR 177.1550 and may be used TF 9207 2,16 2,095
as articles or components of articles intended to contact food subject as articles or components of articles intended to contact food subject
to the provisions, including specifications, conditions of use, to the provisions, including specifications, conditions of use,
and limitations, if any, in this regulation. and limitations, if any, in this regulation.
2)
The monomers used for the production of these products comply 3)
The monomers used for the production of these products comply
with EU-Directive 2002/72/EC about materials and articles made of with EU-Directive 2002/72/EC about materials and articles made of
plastics and intended to come into contact with foodstuffs or toys and plastics and intended to come into contact with foodstuffs or toys and
with the new edition of the German Bedarfsgegenstndeverordnung with the new edition of the German Bedarfsgegenstndeverordnung
of December 23rd, 1997. of December 23rd, 1997.
3)
Amonium Perfluorinated Ether
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Our Worldwide Commitment To Quality The Dyneon Product Portfolio: Dyneon Customer Service
Europe Phone: 00 800 396 366 27
Indicative of our commitment, most Dyneon design, Dyneon Italy
Fax:
Phone:
00 800 396 366 39
00 800 7 910 18
development, production and service facilities have PTFE, TFM PTFE,
Fax: 00 800 7 910 19
achieved global quality management certification. PTFE Compounds, TFM PTFE Compounds USA Phone: +1 800 810 8499
Production facilities have also received certification Fax: +1 800 635 8061
for their environmental management system. Dyneon Dyneon GmbH & Co. KG
PFA, ETFE, FEP, THV, HTE, PVDF Werk Gendorf
Please see the Dyneon website (www.dyneon.com)
Fluorothermoplastics D-84504 Burgkirchen
for the most up-to-date certification details. Germany
Dyneon Phone: +49 8679 7 4709
Fax: +49 8679 3992
Fluoroelastomers
Important Notice:
Low Temperature Fluoroelastomers Dyneon GmbH & Co. KG
All information set forth herein is based on our pre- Perfluoroelastomers Carl-Schurz-Strae 1
D-41453 Neuss
sent state of knowledge and is intended to provide Germany
general notes regarding products and their uses. Dynamar Phone: +49 2131 14 2265
Polymer Processing Additives Fax: +49 2131 14 3857
It should not therefore be construed as a guarantee
of specific properties of the products described or Dyneon Dyneon B.V.
Werk Kerkrade
their suitability for a particular application. Because Polymer Additives, Melt Modifier Tunnelweg 95
conditions of product use are outside Dyneons NL-6468 EJ Kerkrade
control and vary widely, user must evaluate and Dynamar The Netherlands
Elastomer Additives Phone: +31 45 567 9600
determine whether a Dyneon product will be suit-
Fax: +31 45 567 9619
able for users intended application before using it. Dyneon Dyneon LLC
The quality of our products is warranted under our Monomers 6744 33rd Street North
General Terms and Conditions of Sale as now are Oakdale, MN 55128
or hereafter may be in force. The PTFE products illustrated are examples USA
Phone: +1 651 733 5353
of specific customer applications. We will be Fax: +1 651 737 7686
Technical information, test data, and advice provi-
pleased to provide the addresses of suppliers.
ded by Dyneon personnel are based on information Dyneon GmbH & Co. KG
and tests we believe are reliable and are intended Succursale France
Please contact us if you wish to know
Boulevard de lOise, Tour 3M
for persons with knowledge and technical skills further addresses of any of our sales offices F-95006 Cergy Pontoise Cedex
sufficient to analyze test types and conditions, and worldwide. France
to handle and use raw polymers and related com- Phone: +33 1 3031 6611
Fax: +33 1 3031 6613
pounding ingredients. No license under any Dyneon
Dyneon GmbH & Co. KG
or third party intellectual rights is granted or implied Sede Secondaria Italia
by virtue of this information. Via San Bovio, 3
Milano San Felice
General recommendations on health and safety I-20090 Segrate (MI)
in processing, on work hygiene and on measures Italy
Phone: +39 02 7035 3206-7
to be taken in the event of accident are detailed Fax: +39 02 7035 3208
in our material safety data sheets.
Dyneon GmbH & Co. KG
You will find further notes on the safe handling of UK Branch Office
3M Centre
fluoropolymers in the brochure Guide for the safe Cain Road
handling of Fluoropolymers Resins Bracknell
by PlasticsEurope, Box 3, B-1160 Brussels, Berkshire RG12 8HT
United Kingdom
Tel. +32 (2) 676 17 32. Phone: +44 1344 42 96 75
Fax: +44 1344 42 79 04
The present edition replaces all previous versions.
Please make sure and inquire if in doubt whether Sumitomo 3M Limited*
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you have the latest edition. Setagaya-ku, Tokyo
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